CN108058469A - A kind of preparation method of anti-stab anti-cutting flexible material - Google Patents
A kind of preparation method of anti-stab anti-cutting flexible material Download PDFInfo
- Publication number
- CN108058469A CN108058469A CN201711340726.XA CN201711340726A CN108058469A CN 108058469 A CN108058469 A CN 108058469A CN 201711340726 A CN201711340726 A CN 201711340726A CN 108058469 A CN108058469 A CN 108058469A
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- Prior art keywords
- stab
- flexible material
- fiber
- preparation
- fabric
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/58—Cuttability
- B32B2307/581—Resistant to cut
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- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of preparation method of anti-stab anti-cutting flexible material, including：Base fabric is selected, adhesive is coated in scrim surfaces, then pastes one or both of high-molecular organic material, inorganic particle, obtain composite material, then by composite material hot pressing, obtain anti-stab anti-cutting flexible material.Of the invention simple, at low cost, the anti-stab anti-cutting flexible material being prepared is light-weight, and flexibility is high, has good anti-stab anti-cutting performance.
Description
Technical field
The invention belongs to physical protection field of material preparation, more particularly to a kind of preparation side of anti-stab anti-cutting flexible material
Method.
Background technology
With the fast development of modern society, there is a growing awareness that the importance of safety.With the sudden and violent increasing probably attacked
More, the demand of the stab-resistance body armor of individual protection also increasingly increases；In some industrial circles, for example, machinery, chemical industry, glass processing,
Building etc., then urgently develop it is a kind of can anti-stab but also anti-cutting fabric, it is simultaneous while so that it is met anti-stab anti-cutting requirement
It cares for lightweight, flexibly and make the functions such as simple.
At present, although having there is Many researchers to have developed the special protective articles for providing protection for anti-stab anti-cutting,
It is generally also more thick and heavy there are product, flexibility and flexibility are inadequate, and the shortcomings that higher price.Patent WO9603277 is then
Using fabric surface spray one layer it is plasma-coated, although intensive plasmasphere can play relatively good protection and make
With, but the technique of the higher plasma spray coating process of cost and long production time and complexity all causes this product can not
Volume production.Patent CN103791778A is used bonds epoxy resin big particle in base fabric, reaches anti-stab effect, grain with particle
Gap can possess preferable gas permeability between son, but anti-stab there are more thin due to there are larger gap, causing between particle
Weak link so that anti-stab effect is undesirable.The anti-cutting fabric prepared in patent US7127879B2 is carried out after being twisted using fiber
It weaves, although making being combined together for fibre compact and playing anti-cutting effect, since fiber is closer, and the number of plies
More, the gas permeability for causing anti-cutting fabric is poor, and with the increase of frequency of use, fiber is easily worn, and can cause to prevent
Cut continuously decreasing for effect.Using primer and re-glue technique in patent CN206182432U, with sand embedding equipment by rigid particles
Be fixed on kevlar fabric surface, product obtained has certain anti-stab anti-cutting performance, but technique is more complicated, using raw material into
This is higher, and as the continuous friction during use, surface particle can come off, under causing the anti-stab effect of anti-cutting gradual
Drop.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of preparation method of anti-stab anti-cutting flexible material, this method letter
Single, at low cost, the anti-stab anti-cutting flexible material being prepared is light-weight, and flexibility is high.
A kind of preparation method of anti-stab anti-cutting flexible material of the present invention, is as follows：
Base fabric is selected, adhesive is coated in scrim surfaces, base fabric is made to obtain good osmotic-pressure-tolerant, is then pasted organic high
One or both of molecular material, inorganic particle obtain composite material, then by composite material hot pressing, obtain anti-stab anti-cutting
Flexible material.
The base fabric is fabric, membrane material, rubber material or leather.
The fabric is woven fabric, knitted fabric or non-woven cloth.
The fabric is made of common natural fiber, chemical fibre or high-performance fiber.
The common natural fiber is cotton, hair, silk or fiber crops；Chemical fibre is terylene, polyamide fibre or acrylic fibers；High-performance fiber is
Aramid fiber, PSA fiber or high-strength high-modulus polyethylene fiber.
The high-molecular organic material for epoxy resin, fiber reinforced epoxy resin, polyurethane, fiber reinforcement polyurethane,
Makrolon, fiber reinforced polycarbonate, organic siliconresin, fiber reinforcement organosilicon, polyimides, fiber reinforced polyimide
Or the porous material with micropore.
The shape of the high-molecular organic material is particle or sheet.
The sheet is circular, square or polygon.
The inorganic particle is one kind in aluminium oxide, silicon nitride, pink fused alumina, wrong corundum, carborundum, diamond, glass
It is or several.
The grain size of the inorganic particle is 10-300 μm.
The hot pressing temperature is 150-300 DEG C, hot pressing time 50-400s.
The compound obdurability that can further increase material of organic material and inorganic particle in the present invention, can not only grind
Erosion, passivation sharp instrument can also weaken the shearing force of sharp instrument.The incorporation of organic material can reduce cost, nothing with lightening material weight
The use of machine particle can fill up the gap between organic material, and material is kept while the anti-stab anti-cutting performance of material is improved
Flexibility, the two effectively combine effective protection can be formed to user.Base fabric then plays the role of buffering and support, the present invention
In base fabric can use general fibre fabric, will further decrease production cost.
Advantageous effect
Of the invention simple, at low cost, the anti-stab anti-cutting flexible material being prepared is light-weight, and flexibility is high, has fine
Anti-stab anti-cutting performance.
Description of the drawings
Fig. 1 is the schematic diagram (1 silicon-carbide particle, 2 base fabrics) of anti-stab anti-cutting fabric in embodiment 1；
Fig. 2 is the schematic diagram (1 silicon-carbide particle and polycarbonate pellets, 2 ordinary gloves) of Anti-cut Gloves in embodiment 2；
Fig. 3 is schematic diagram (1 base fabric, 2 polycarbonate resin plates, 3 carborundum of anti-stab anti-cutting fabric in embodiment 3
Grain)；
Fig. 4 is that (1 base fabric, 2 glass fiber-reinforced polycarbonate resin sheets, 3 is viscous for the schematic diagram of anti-stab anti-cutting fabric in embodiment 4
Jelly).
Specific embodiment
With reference to specific embodiment, the present invention is further explained.It is to be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, people in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Scope.
Embodiment 1
(1) it is base fabric to select ordinary polyester fabric, and one layer of common adhesive is applied in base fabric, and recycling is paved into machine by size
Silicon-carbide particle for 80 microns is uniformly layered in the base fabric for scribbling adhesive, surface density 250g/m2, move on hot press
Hot pressing, hot pressing temperature are 210 DEG C, and the time is 200s to get anti-stab anti-cutting fabric.
(2) the anti-cutting performance of anti-stab anti-cutting fabric in one layer of step (1) is tested, reaches anti-cutting standard ISO13997-1999
A6 grades of testing standard, and the flexible and soft performance having had.
(3) in testing procedure (1) anti-stab anti-cutting fabric anti-stab performance, the non-penetration thickness of dynamic is 10 layers of fabric, is reached
To anti-stab standard GA68-2008.
Embodiment 2
(1) it is base fabric to select aramid fiber gloves, and the local location in base fabric applies one layer of common adhesive, and recycling is paved into machine
The silicon-carbide particle that size is 100 microns and the polycarbonate pellets that size is 100 microns are uniformly layered in base fabric, surface density
For 350g/m2, hot pressing on hot press is moved to, hot pressing temperature is 210 DEG C, and the time is 200s to get Anti-cut Gloves.
(2) the anti-cutting performance of above-mentioned Anti-cut Gloves is tested, reaches A8 grades of anti-cutting standard ISO13997-1999 testing standards,
And the flexible and soft performance having had.
(3) by the silicon-carbide particle that size is 100 microns and the makrolon that size is 100 microns in testing procedure (1)
The anti-stab performance for the base fabric that particle uniformly coats, the non-penetration thickness of dynamic is 7 layers of fabric, reaches anti-stab standard GA68-2008.
Embodiment 3
(1) it is base fabric to select kevlar fabric, and one layer of common adhesive, then the gathering for 2cm × 2cm by size are applied in base fabric
Carbonate resin piece is aligned to by 0.5cm gaps rule in base fabric, is then uniformly spread the silicon-carbide particle that size is 80 microns
In gap location, surface density 250g/m2, hot pressing on hot press is moved to, hot pressing temperature is 210 DEG C, and the time is 250s to get anti-
Pierce anti-cutting fabric.
(2) the anti-cutting performance of anti-stab anti-cutting fabric in one layer of step (1) is tested, reaches anti-cutting standard ISO13997-1999
A9 grades of testing standard, and the flexible and soft performance having had.
(3) in testing procedure (1) anti-stab anti-cutting fabric anti-stab performance, the non-penetration thickness of dynamic is 4 layers of fabric, is reached
Anti-stab standard GA68-2008.
Embodiment 4
(1) it is base fabric to select ordinary polyester fabric, and one layer of common adhesive is applied in base fabric, then by size is 2cm × 2cm
Glass fiber-reinforced polycarbonate resin sheet, be aligned to by 0.2cm gaps rule in base fabric, move to hot pressing on hot press, hot pressing
Temperature is 210 DEG C, and the time is 200s to get anti-stab anti-cutting fabric.
(2) the anti-cutting performance of anti-stab anti-cutting fabric in one layer of step (1) is tested, reaches anti-cutting standard ISO13997-1999
A6 grades of testing standard, and the flexible and soft performance having had.
(3) in testing procedure (1) anti-stab anti-cutting fabric anti-stab performance, the non-penetration thickness of dynamic is 6 layers of fabric, is reached
Anti-stab standard GA68-2008.
Embodiment 5
(1) it is base fabric to select nylon fabric, and one layer of common adhesive is applied in base fabric, and recycling is paved into machine and is by size
100 microns of organic polycarbonate pellets are uniformly layered in the base fabric for scribbling adhesive, surface density 250g/m2, move to heat
Hot pressing on press, hot pressing temperature are 210 DEG C, and the time is 150s to get anti-stab anti-cutting fabric.
(2) the anti-cutting performance of anti-stab anti-cutting fabric in one layer of step (1) is tested, reaches anti-cutting standard ISO13997-1999
A7 grades of testing standard, and the flexible and soft performance having had.
(3) in testing procedure (1) anti-stab anti-cutting fabric anti-stab performance, the non-penetration thickness of dynamic is 9 layers of fabric, is reached
Anti-stab standard GA68-2008.
Embodiment 6
(1) it is base fabric to select PSA fiber fabric, and one layer of common adhesive is applied in base fabric, and recycling is paved into machine and is by size
50 microns of silicon nitride particle is uniformly layered in the base fabric for scribbling adhesive, surface density 250g/m2, move to hot on hot press
Pressure, hot pressing temperature are 210 DEG C, and the time is 50s to get anti-stab anti-cutting fabric.
(2) the anti-cutting performance of anti-stab anti-cutting fabric in one layer of step (1) is tested, reaches anti-cutting standard ISO13997-1999
A8 grades of testing standard, and the flexible and soft performance having had.
(3) in testing procedure (1) anti-stab anti-cutting fabric anti-stab performance, the non-penetration thickness of dynamic is 8 layers of fabric, is reached
Anti-stab standard GA68-2008.
Claims (10)
1. a kind of preparation method of anti-stab anti-cutting flexible material, is as follows：
Base fabric is selected, adhesive is coated in scrim surfaces, then pastes high-molecular organic material, one kind in inorganic particle or two
Kind, composite material is obtained, then by composite material hot pressing, obtains anti-stab anti-cutting flexible material.
2. the preparation method of a kind of anti-stab anti-cutting flexible material described in accordance with the claim 1, which is characterized in that the base fabric is
Fabric, membrane material, rubber material or leather.
3. the preparation method of a kind of anti-stab anti-cutting flexible material described in accordance with the claim 2, which is characterized in that the fabric is
Woven fabric, knitted fabric or non-woven cloth.
4. according to a kind of preparation method of anti-stab anti-cutting flexible material described in Claims 2 or 3, which is characterized in that described to knit
Object is made of common natural fiber, chemical fibre or high-performance fiber.
5. according to a kind of preparation method of anti-stab anti-cutting flexible material described in claim 4, which is characterized in that the common day
Right fiber is cotton, hair, silk or fiber crops；Chemical fibre is terylene, polyamide fibre or acrylic fibers；High-performance fiber is aramid fiber, PSA fiber or high-strength
High-modulus polyethylene fiber.
6. the preparation method of a kind of anti-stab anti-cutting flexible material described in accordance with the claim 1, which is characterized in that described organic high
Molecular material is epoxy resin, fiber reinforced epoxy resin, polyurethane, fiber reinforcement polyurethane, makrolon, fiber reinforcement gather
Carbonic ester, organic siliconresin, fiber reinforcement organosilicon, polyimides, fiber reinforced polyimide or the porous material with micropore
Material.
7. according to a kind of preparation method of anti-stab anti-cutting flexible material described in claim 1 or 6, which is characterized in that described to have
The shape of machine high molecular material is particle or sheet.
8. according to a kind of preparation method of anti-stab anti-cutting flexible material described in claim 7, which is characterized in that the sheet is
Circular, square or polygon.
A kind of 9. preparation method of anti-stab anti-cutting flexible material described in accordance with the claim 1, which is characterized in that the inorganic particulate
Grain is the one or several kinds in aluminium oxide, silicon nitride, pink fused alumina, wrong corundum, carborundum, diamond, glass.
A kind of 10. preparation method of anti-stab anti-cutting flexible material described in accordance with the claim 1, which is characterized in that the hot pressing
Temperature is 150-300 DEG C, hot pressing time 50-400s.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711340726.XA CN108058469A (en) | 2017-12-14 | 2017-12-14 | A kind of preparation method of anti-stab anti-cutting flexible material |
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| CN201711340726.XA CN108058469A (en) | 2017-12-14 | 2017-12-14 | A kind of preparation method of anti-stab anti-cutting flexible material |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172833A (en) * | 2019-05-17 | 2019-08-27 | 福洹体育用品（苏州）有限公司 | A kind of coating anti-perforation fabric and preparation method thereof |
| CN110567320A (en) * | 2019-09-27 | 2019-12-13 | 东华大学 | Thermoplastic anti-piercing resin sheet formed by inorganic particle gradient sedimentation and preparation method and application thereof |
| CN110577726A (en) * | 2019-09-27 | 2019-12-17 | 东华大学 | Inorganic particle and thermoplastic resin powder mixed-layer hot-melt die-casting composite resin sheet and preparation method and application thereof |
| CN110588094A (en) * | 2019-09-27 | 2019-12-20 | 东华大学 | Waste fiber, fabric and inorganic particle four-layer fusion-casting composite anti-puncture sheet and preparation method and application thereof |
| CN110654079A (en) * | 2019-09-27 | 2020-01-07 | 东华大学 | Inorganic particle and thermoplastic resin powder interval-laying hot-melt die-casting composite resin sheet and preparation method and application thereof |
| CN110669331A (en) * | 2019-09-27 | 2020-01-10 | 东华大学 | Inorganic particle surface layer close-packed collision barrier type anti-piercing thermoplastic resin sheet and preparation method and application thereof |
| CN110834440A (en) * | 2019-11-13 | 2020-02-25 | 嘉兴泓盾服饰有限公司 | Production process of high-molecular nano composite stab-resistant fabric |
| CN111005237A (en) * | 2019-12-25 | 2020-04-14 | 上海固甲新材料科技有限公司 | Anti-cutting and anti-radiation composite material and preparation method thereof |
| CN111691069A (en) * | 2020-05-18 | 2020-09-22 | 苏州大学 | Puncture-resistant fiber composite membrane and preparation method thereof |
| CN114703678A (en) * | 2022-03-23 | 2022-07-05 | 南通大学 | Wear-resistant and scratch-resistant fabric and forming method thereof |
| CN115572456A (en) * | 2021-07-06 | 2023-01-06 | 南通大学 | Puncture-proof, cutting-proof, comfortable and breathable composite material and preparation method thereof |
| CN115928455A (en) * | 2023-02-15 | 2023-04-07 | 河北安泰富源安全设备制造有限公司 | Anti-puncture layer construction process and anti-puncture clothes |
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| CN1288513A (en) * | 1998-01-22 | 2001-03-21 | 阿克佐诺贝尔公司 | Stab and bullet proof protective clothing |
| CN105939850A (en) * | 2014-01-27 | 2016-09-14 | 纳幕尔杜邦公司 | Light weight trauma reducing body armor |
| CN205784871U (en) * | 2016-05-19 | 2016-12-07 | 苏州高甲防护科技有限公司 | Flexible ballistic-resistant stab-resistant material |
| CN106767165A (en) * | 2017-01-16 | 2017-05-31 | 江苏安卡新材料科技有限公司 | A kind of inorganic powder coating thronproof cloth and preparation method thereof |
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| CN1288513A (en) * | 1998-01-22 | 2001-03-21 | 阿克佐诺贝尔公司 | Stab and bullet proof protective clothing |
| CN105939850A (en) * | 2014-01-27 | 2016-09-14 | 纳幕尔杜邦公司 | Light weight trauma reducing body armor |
| CN205784871U (en) * | 2016-05-19 | 2016-12-07 | 苏州高甲防护科技有限公司 | Flexible ballistic-resistant stab-resistant material |
| CN106767165A (en) * | 2017-01-16 | 2017-05-31 | 江苏安卡新材料科技有限公司 | A kind of inorganic powder coating thronproof cloth and preparation method thereof |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172833A (en) * | 2019-05-17 | 2019-08-27 | 福洹体育用品（苏州）有限公司 | A kind of coating anti-perforation fabric and preparation method thereof |
| CN110588094B (en) * | 2019-09-27 | 2021-09-07 | 东华大学 | Waste fiber, fabric and inorganic particle four-layer fusion-casting composite anti-puncture sheet and preparation method and application thereof |
| CN110669331B (en) * | 2019-09-27 | 2022-03-04 | 东华大学 | Inorganic particle surface layer close-packed collision barrier type anti-piercing thermoplastic resin sheet and preparation method and application thereof |
| CN110588094A (en) * | 2019-09-27 | 2019-12-20 | 东华大学 | Waste fiber, fabric and inorganic particle four-layer fusion-casting composite anti-puncture sheet and preparation method and application thereof |
| CN110654079A (en) * | 2019-09-27 | 2020-01-07 | 东华大学 | Inorganic particle and thermoplastic resin powder interval-laying hot-melt die-casting composite resin sheet and preparation method and application thereof |
| CN110669331A (en) * | 2019-09-27 | 2020-01-10 | 东华大学 | Inorganic particle surface layer close-packed collision barrier type anti-piercing thermoplastic resin sheet and preparation method and application thereof |
| CN110577726A (en) * | 2019-09-27 | 2019-12-17 | 东华大学 | Inorganic particle and thermoplastic resin powder mixed-layer hot-melt die-casting composite resin sheet and preparation method and application thereof |
| CN110567320A (en) * | 2019-09-27 | 2019-12-13 | 东华大学 | Thermoplastic anti-piercing resin sheet formed by inorganic particle gradient sedimentation and preparation method and application thereof |
| CN110834440A (en) * | 2019-11-13 | 2020-02-25 | 嘉兴泓盾服饰有限公司 | Production process of high-molecular nano composite stab-resistant fabric |
| CN111005237A (en) * | 2019-12-25 | 2020-04-14 | 上海固甲新材料科技有限公司 | Anti-cutting and anti-radiation composite material and preparation method thereof |
| CN111691069A (en) * | 2020-05-18 | 2020-09-22 | 苏州大学 | Puncture-resistant fiber composite membrane and preparation method thereof |
| CN115572456A (en) * | 2021-07-06 | 2023-01-06 | 南通大学 | Puncture-proof, cutting-proof, comfortable and breathable composite material and preparation method thereof |
| CN114703678A (en) * | 2022-03-23 | 2022-07-05 | 南通大学 | Wear-resistant and scratch-resistant fabric and forming method thereof |
| CN114703678B (en) * | 2022-03-23 | 2024-04-26 | 南通大学 | Wear-resistant and scratch-resistant fabric and forming method thereof |
| CN115928455A (en) * | 2023-02-15 | 2023-04-07 | 河北安泰富源安全设备制造有限公司 | Anti-puncture layer construction process and anti-puncture clothes |
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