CN206156809U - Electrolysis water generation device and electrode unit - Google Patents
Electrolysis water generation device and electrode unit Download PDFInfo
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- CN206156809U CN206156809U CN201590000320.5U CN201590000320U CN206156809U CN 206156809 U CN206156809 U CN 206156809U CN 201590000320 U CN201590000320 U CN 201590000320U CN 206156809 U CN206156809 U CN 206156809U
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- generating device
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Automation & Control Theory (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
According to embodiment, electrolysis water generation device possess the formation water containing ware (12) that holds water, by the diaphragm separate and hold electrolyte electrolysis liquid chamber (20), pressing from both sides the diaphragm positive pole (34a) and the negative pole (34b) of opposition each other, this electrolysis water generation device still possesses electrode unit (16) of soaking into the aquatic in generating water containing ware (12) and detects detector (60) of the water yield of holding the water in formation water containing ware (12).
Description
Technical field
The embodiment of here narration is related to electrolytic water generating device and electrode unit.
Background technology
Conventionally, there is known generating the electrolytic water generating device of hypochloric acid water, alkali ion water etc. by being electrolysed.As this
Kind electrolytic water generating device proposes that the electrolytic cell to the Room type of 1 barrier film 2 or the electrolytic cell of the Room type of 2 barrier film 3 flow into electrolyte and water
To generate the electrolytic water generating device of the continuous-flow type of electrolysis water.
Propose to have as not having electrolytic water generating device pipe arrangement, that construction is more succinct involved by water supply and sewage
Anode and negative electrode and the electrode unit of electrolyte is isolated and has put in existing tank, made the water in the tank be changed into electrolysis water
Hydrostatic formula (or batch (-type)) electrolytic water generating device.In the case of this composition, electrolyte can be isolated from electricity
Solution liquid is taken out by electrolytically generated generation water in the state of room.Further, due to the water under electrolysis hydrostatic state, pipe arrangement is simple
Change, electrolyte properties are also more stable, by increasing capacitance it is possible to increase the species of the barrier film that can be used.
Look-ahead technique document Prior Art
Patent document
Patent document 1：No. 3500173 publications of Japanese Patent No.
Patent document 2：No. 3551288 publications of Japanese Patent No.
Patent document 3：Japanese Unexamined Patent Publication 11-319829 publication
Patent document 4：Japanese Unexamined Patent Publication 2003-53344 publications
Patent document 5：Japanese Unexamined Patent Publication 2004-2900937 publications
Utility model content
Utility model problem to be solved
However, having isolated the electrolysis water generating dress of the hydrostatic formula (batch (-type)) of the electrode unit of electrolyte in above-mentioned use
In putting, in the state of the water for forgetting to flow into tank, or, in the state of water is inadequate, even if being electrolysed, can also produce logical
Cross segregate electrolyte and produce the cell reaction of chlorine in anode.In the state of having water in the sink, produce in anode
Chlorine react with water immediately and become hypochlorous acid and hydrochloric acid, but without there is chlorine in the state of water directly into tank
Or the problem of tank external diffusion.
The present embodiment problem to be solved is, there is provided a kind of not produce the high hydrostatic formula of the gases such as chlorine and reliability
Electrolytic water generating device and electrode unit.
The means to solve the problem
According to embodiment, electrolytic water generating device possesses the generation water receptacle of receiving water, separates and accommodate electricity by barrier film
Solve the electrolyte liquor chamber of liquid and clip the mutually opposing anode of the barrier film and negative electrode, the electrolytic water generating device possesses leaching
Electrode unit and detection thoroughly in the water in the generation water receptacle is contained in the water yield of the water in the generation water receptacle
Detector.
Description of the drawings
Fig. 1 is the profile of the electrolytic water generating device involved by the 1st embodiment.
Fig. 2 is the stereogram of the electrode unit for representing the electrolytic water generating device involved by the 1st embodiment.
Fig. 3 is the profile of the electrolytic water generating device involved by the 2nd embodiment.
Fig. 4 is the profile of the electrolytic water generating device involved by the 3rd embodiment.
Fig. 5 is the profile of the electrolytic water generating device involved by the 4th embodiment.
Fig. 6 is the profile of the electrolytic water generating device involved by the 5th embodiment.
Specific embodiment
Hereinafter, various embodiments are illustrated referring to the drawings.In addition, being commonly constructed imparting in embodiment
Identical symbol, and the repetitive description thereof will be omitted.Additionally, each figure is the ideograph for promoting embodiment and its understanding, its shape
Shape, size, ratio etc. have difference with the device of reality, and these can be appropriate with reference to the following description and known technology
Be designed change.
(the 1st embodiment)
Fig. 1 is the profile being monolithically fabricated for representing the electrolytic water generating device involved by the 1st embodiment, and Fig. 2 is table
Show the stereogram of the electrode unit of electrolytic water generating device.
In the present embodiment, electrolytic water generating device 10 becomes as the aquatic of hydrostatic state that will be received in container
Electrolysis water, that is, it is changed into the hydrostatic formula or step electrolytic water generating device of electrolysis water and constitutes.As shown in figure 1, electrolysis is aquatic
Possess into device 10：Accommodate the generation water receptacle (tank) 12 of the liquid such as water；Disassembly ease it is installed on and generates water receptacle 12
Upper end open, and the electrode unit 16 for being supported by and being configured in generation water receptacle 12；And supply to the electrode of electrode unit 16
To the power supply 30 of electrolysis electric power.Power supply 30 is connected to dc source (not shown).In addition, power supply 30 can also be by supplying
Battery of constant pressure etc. is constituted.
Water receptacle 12 is generated for example by the acid resistances such as borosilicate glass, ethlyene dichloride, polypropylene, polyethylene, alkali resistance
Outstanding glass or resin is formed, and is formed as circular cone shape.Generate water receptacle 12 and there is upper end open 12a.Generate water receptacle
12 for example formed as the capacity that can accommodate 1L water.
As shown in Figure 1 and Figure 2, electrode unit 16 possesses：Be formed as the supporting mass (lid) 14 of circular plate shape；It is supported on
Supporting mass, and the basket 18 of the substantially cylindrical shape configured in the mode coaxial with supporting mass；And be arranged under basket 18
The drainage mechanism 50 of end.
Supporting mass 14 is for example formed by the outstanding resin of the acid resistances such as ethlyene dichloride, polypropylene, polyethylene, alkali resistance.
Hold body 14 and be installed on upper end open 12a that generates water receptacle 12 with also serving as disassembly ease and by upper end open 12a closing
Lid and function.The inlet 14a for injecting electrolyte is formed with the central portion of supporting mass 14.Further, supporting mass
14 are provided integrally with the ascending pipe 14b extended from the lower surface of the supporting mass, and ascending pipe 14b is connected with inlet 14a.
Basket 18 is for example formed by the outstanding resin of the acid resistances such as ethlyene dichloride, polypropylene, polyethylene, alkali resistance.Basket
18 have：Form the intermediate frame 21 of medial compartment (electrolyte liquor chamber) 20；Form the cathode section 24 of cathode chamber (generation room) 22；Formed
The agitator tank 28 of teeter chamber (generation room) 26.Cathode section 24 and agitator tank 28 are bonded on the both sides of intermediate frame 21, and conduct
Overall cylindrical shape.
The 1st rectangular-shaped barrier film 32a is provided with the way of to close the opening of a side of medial compartment 20, to close medial compartment
The mode of the opening of 20 the opposing party is provided with the 2nd rectangular-shaped barrier film 32b.1st barrier film 32a and the 2nd barrier film 32b are mutually right
Put.Thus, medial compartment 20 is spaced between the 1st barrier film 32a and the 2nd barrier film 32b.Medial compartment 20 (is generated with teeter chamber 26
Inside water receptacle 12) between separated by the 1st barrier film 32a, separated by the 2nd barrier film 32b between medial compartment 20 and cathode chamber.Medial compartment
20 for example formed as 10mL capacity.The upper end of medial compartment 20 connects with ascending pipe 14b, additionally, in the lower end shape of medial compartment 20
Into there is electrolyte discharge outlet (the 1st discharge outlet) 20a.
In the present embodiment, the 1st barrier film 32a and the 2nd barrier film 32b are the barrier films respectively with water penetration.For example,
1 barrier film 32a and the 2nd barrier film 32b are respectively using miillpore filter (the Microfiltration Membrane of water penetration：MF
Film), milipore filter (Ultrafiltration Membrane：UF films) etc..Additionally, the 1st barrier film 32a and the 2nd barrier film 32b are for example
By containing outstanding polyvinylidene fluoride (the PolyVinylidene DiFuoride of chemically resistant and drying property：) and oxygen PVDF
The material for changing titanium is formed.Porous barrier film has water penetration and the electrolyte consumed in electrolysis is supplemented to around anode and negative electrode
Ability it is higher, but continuous-flow type it is this apply differential water pressures electrolytic water generating device in, because differential pressure causes electrolytically generated thing
Flow out so being difficult to use.In the electrolytic water generating device of this hydrostatic formula of present embodiment, because this kind of differential pressure is not acted on,
Therefore, it is possible to using Porous barrier film, there is no problem, can be electrolysed with high formation efficiency, and can also be after use
It is dried and places electrode unit.
In the outside of the 1st barrier film 32a, the anode 34a and the 1st barrier film 32a of rectangular plate-like are adjoined and are opposed to be set.Sun
Pole 34a is located in teeter chamber 26.In the outside of the 2nd barrier film 32b, the negative electrode 34b and the 2nd barrier film 32b of rectangular plate-like is adjacent and right
It is set with putting.Negative electrode 34b is located in cathode chamber 22.Medial compartment 20 is sandwiched in into centre and mutually in anode 34a and negative electrode 34b
It is opposed.Anode 34a and negative electrode 34b is electrically connected via connection terminal and wiring with power supply 30.
Additionally, anode 34a forms iridium etc. and generate with oxygen in the electrode for being provided with permeable hole of titanium-based material relatively can drop
The catalyst of the overvoltage that low chlorine is generated.Negative electrode 34b is the electrode for being provided with permeable hole of titanium-based material, but in order to further drop
Low decomposition voltage can also form platinum etc. for reducing the catalyst of the overvoltage of water decomposition.
Anode 34a and negative electrode 34b are for example formed by the titanium-based material of the substantially rectangular tabular of thickness 1mm or so, and in
Centre portion (effecting reaction region) is formed with the small through hole (not shown) for passing through liquid.Anode 34a is in base material
Surface is formed with the catalyst that iridium etc. generates the overvoltage that can reduce chlorine generation relative to oxygen.In order to further reduce electrolysis
Voltage, negative electrode 34b is formed with platinum etc. for reducing the catalyst of the overvoltage of water decomposition on the surface of base material.
Capacity of the cathode chamber 22 for example formed as 20mL or so.The lower end of cathode chamber 22 is provided with negative electrode water discharge outlet
(the 2nd discharge outlet) 22a.Additionally, being formed with for discharging the gas produced in cathode chamber 22 in the upper end of cathode section 24
Exhaust outlet 24b, and for being taken into the intake 24c for generating the water in water receptacle 12 to cathode chamber 22.
The agitator tank 28 for forming teeter chamber 26 has for being taken into the multiple of the water generated in water receptacle 12 to teeter chamber 26
Intake 28a, and multiple outlet 28b that the electrolysis water for making to be generated in teeter chamber 26 is discharged into generation water receptacle 12.
Additionally, agitator tank 28 has multiple agitating plates (blade) 36 of the configuration in teeter chamber 26.The difference of multiple agitating plates 36 substantially water
Level land extends, and is set at spaced intervals on the length direction (short transverse) of agitator tank 28.Teeter chamber 44 is by multiple stirrings
Plate 36 separates into the multiple rooms arranged on the length direction of agitator tank 40, and each room connects with anode 34a.Multiple rooms lead to respectively
Cross intake 28a and outlet 28b to connect or open with outside (generating inside water receptacle 12).Consisting of makes the generation water capacity
Water in device 12 is taken into by intake 28a to each room of teeter chamber 44, and from outlet 28b to row in generation water receptacle 12
Go out.
As shown in Figure 1 and Figure 2, drainage mechanism 50 has the lid of the bottom that can be rotatably arranged at basket 18
52.Lid 52 is formed as the lid of the cylinder that lower end is closed.Lid 52 has the diapire 52a opposed with the lower end of basket 18,
The pad (seal member) 58 of for example circular tabular is pasted with the central portion of diapire 52a.Additionally, in the periphery of diapire 52a
Portion is formed with the discharge outlet 56 of multiple arc-shapeds.Pad 58 and diapire 52a are used as valve body function.At pad 58 and bottom
Wall 52a has been formed through osculum 57, and the osculum 57 is located relative to the rotary middle spindle of lid 52 and off-centered position
Put.
When lid 52 is located at the detent position of diagram, positional deviation electrolyte discharge outlet 20a of osculum 57 and the moon
Pole water discharge outlet 22a, additionally, pad 58 is abutted so as to close electrolyte discharge outlet 20a and negative electrode water with the lower end of basket 18
Discharge outlet 22a.By the way that lid 52 is arranged as a row to osculum 57 and electrolyte discharge outlet 20a or negative electrode water discharge outlet 22a
1st release position or the 2nd release position rotate such that it is able to alternately through negative electrode water discharge outlet 22a or negative electrode water discharge outlet
22a, the electrolyte of the negative electrode water of cathode chamber 22 or medial compartment 20 is discharged.
Electrolytic water generating device 10 possesses the detector 60 for detection in the water yield for generating the water accommodated in water receptacle 12.
In the present embodiment, detector 60 is built in electrode unit 16.That is, as shown in figure 1, the agitator tank 28 of electrode unit 16 has
Have：It is formed at the measuring chamber 62 of the upper end of teeter chamber；The water intaking that the water generated in water receptacle 12 is taken into into measuring chamber 62
Mouth 64a；And the exhaust outlet 64b for discharging the air in measuring chamber 62.Detector 60 has and is arranged in measuring chamber 62 and position
In the float sensor 66 more closer to the top than anode 34a.The detection of float sensor 66 generates the water surface position of the water in water receptacle 12
Put, the position of the water surface in here detection measuring chamber 62.
Float sensor 66 has and is configured in measuring chamber 62 and swims in the float 66a on the water surface in measuring chamber 62,
And by float 66a supporting for lifting freely and detect float 66a float position hinge portion 66b.Hinge portion 66b is via setting
The wiring 47 put in supporting mass 14 is electrically connected with the controller 68 of power supply 30.Controller 68 is according to from float sensor 66
The detection signal of hinge portion 66b the energization from power supply 30 is controlled.That is, if accommodating in generation water receptacle 12
The water of ormal weight, and the water of ormal weight is flowed into into measuring chamber 62, then float 66a is risen in the way of emerging.Hinge portion
66b detects the float position of float 66a, and sends detection signal to controller 68.When controller 68 is judged as that float 66a is floated
When assigned position, i.e. be judged as generate water receptacle 12 in the water yield be received for ormal weight when, then allow from power supply 30 to
The energization of electrode.When the float position of float 66a is relatively low, i.e. when the water yield for generating the water in water receptacle 12 is inadequate, control
Device processed 68 stops or forbids the energization from power supply 30.
By the electrolytic water generating device 10 that constitutes as described above to generate water in the case of, in removal electrode list
In the state of unit 16, to the water for generating inflow ormal weight in water receptacle 12, and the water of 1L is substantially accommodated.Input water can be
The general obtainable water such as running water.Additionally, as containing muriatic electrolyte such as sodium chloride, potassium chloride, will make in advance
The salt solution of concentration 20% or so inject to the medial compartment 20 of electrode unit 16 from inlet 14a.The salt solution of injection about 10mL, uses
Salt solution fills up medial compartment 20.When salt solution injects, the lid 52 of drainage mechanism 50 is previously set in detent position.
Next, generating in water receptacle 12 as shown in figure 1, the electrode unit 16 for being filled with salt solution is inserted, supporting mass is made
14 are embedded in upper end open 12a for generating water receptacle 12.Thus, electrode unit 16 is installed in generation water receptacle 12, and immerses
In generating the water in water receptacle 12.The part for generating the water in water receptacle 12 flows into negative electrode from the intake 24c of cathode section 24
The water of room 22, about 20mL is filled with cathode chamber 22.Additionally, generating a part for the water in water receptacle 12 from agitator tank 28
Multiple intake 28a flow into teeter chamber 26, and each room is filled up by water.
Like this, teeter chamber 26 becomes the construction opened into generation water receptacle 12, therefore stirring comprising electrode unit 16
Mix room 26 becomes big anode chamber in the interior entirety of water receptacle 12 that generates.Therefore, electrolytic water generating device 10 is used as device entirety
And there is the construction of the Room type of 2 barrier film 3, the construction of the Room type of 2 barrier film 3 has medial compartment 20, cathode chamber 22 and anode chamber.
Further, when generation water receptacle 12 accommodates the water of ormal weight, the water generated in water receptacle 12 flows from intake 64a
Enter measuring chamber 62, in measuring chamber 62 water surface of specified altitude is formed.Thus, the float 66a of float sensor 66 rises and floats
In the water surface.Hinge portion 66b detects the floating of float 66a, and sends detection signal to controller 68.Controller 68 is judged as
The water that ormal weight is accommodated in water receptacle 12 is generated, and allows the energization from power supply 30.
In the above state, by the electricity of 4 minutes or so the 1A that are powered to anode 34a and negative electrode 34b from power supply 30
The salt solution for solving electric current to be electrolysed in medial compartment 20.The sodium ion ionized in the salt solution of medial compartment 20 is attracted by negative electrode 34b, and
Cathode chamber 22 is flowed into by the 2nd barrier film 32b.In cathode chamber 22, decomposed by electricity by negative electrode 34b water and generate hydrogen, and
Sodium hydrate aqueous solution (alkaline water) is generated by the hydrogen and sodium ion.Thus, the 20mL of pH13 or so is generated in cathode chamber 22
NaOH water.
The chlorion ionized in salt solution in medial compartment 20 is attracted by anode 34a, and is stirred by the 1st barrier film 32a inflows
Mix room (anode chamber, generation room) 26.In teeter chamber 26, chlorion gives electronics and generates chlorine to anode 34a.Generated
Water that chlorine is dissolved in teeter chamber 26 and generate acid water (hypochloric acid water and hydrochloric acid).The acid water for so generating is by with oxygen
For the delay of the bubble of main body, flowing and be stirred from outlet 28b along agitating plate 36 is expelled to the water generated in water receptacle 12
In.Like this, the auxiliary of multiple agitating plates 36 makes the electrolytically generated thing of anode-side stir to generating in water receptacle 12, and plays and make therefrom
Compartment 20 diffuses to the effect that the concentration of the electrolyte in teeter chamber 26 is temporarily improved in surrounding them via the 1st barrier film 32a.This
Outward, the water generated in water receptacle 12 is taken at any time in teeter chamber 26, is become acid water and is mixed with the water generated in water receptacle 12
Close.Water thereby, it is possible to make the 1L in generation water receptacle 12 is changed into being generated as the hypochloric acid water of effective chlorine density 50ppm.Separately
Outward, the salt solution of the 10mL for disposably injecting to medial compartment 20 can be continuous relative to the generation of the hypochloric acid water of 1L, 50ppm concentration
Using 10 times or so.
After electrolysis water generating terminates, by electrode unit 16 from the removal of water receptacle 12 is generated, will generate in water receptacle 12
The hypochloric acid water of generation is discharged and for various sterilizing uses.Additionally, using the alkaline water (NaOH generated in cathode chamber 22
Water) in the case of, the lid 52 of drainage mechanism 50 is rotated from detent position to the 1st release position, so as to open cathode water row
Mouth of a river 22a.Thereby, it is possible in the state of making the salt solution in medial compartment 20 remain stationary, only selectively take out alkaline water, and
Apply flexibly in clean etc..
In this condition only residue of saline is in electrode unit 16, feelings of the salt solution in the hypochloric acid water for generating above-mentioned 50ppm
Under condition, therefore, it is possible to the water for generating water receptacle 12 is replaced with into new water, and can be repeated using 10 times or so (generating 10L)
Above-mentioned generation action is electrolysed, and lavishly can not effectively consume salt solution.
The electrolytic water generating device 10 constituted like that according to more than, by the electrode list for filling salt solution in advance in electrolyte liquor chamber
Unit 16, can make the water for being contained in generation water receptacle 12 be changed into namely being generated as with bactericidal hypochloric acid water, and can
Generating the NaOH water with cleaning function in cathode chamber 22, and can not only take out hypochloric acid water can also take out hydroxide
Sodium water.Further, since salt solution is isolated in medial compartment (electrolyte liquor chamber) 20, salt solution will not in a large number be mixed into above-mentioned 2 kind electrolysis water
In, and salt solution water quality also do not go bad because of electrolytically generated thing.By the drainage mechanism 50 arranged in the lower end of electrode unit 16,
Salt solution (electrolyte) and negative electrode water can be optionally discharged, for example, can be left salt solution and only selectively be discharged negative electrode water.
Thereby, it is possible to effectively utilizes from generate water receptacle 12 in generate electrolysis water it is different, cathode chamber 22 generate electrolysis water.
Additionally, by only exchanging the negative electrode water for generating the water with cathode chamber 22 of water receptacle 12, repeatedly can fully utilize electrolyte liquor chamber
Salt solution, lavishly can not effectively consume salt solution.
In electrolyte to be isolated in the electrolytic water generating device 10 of this composition of electrode unit 16, even if not used for life
Into the water of the generation water receptacle of electrolysis water, it is also possible to by the electrolyte for being isolated filling, produce and produce chlorine in the moon in anode
Pole produces the cell reaction of hydrogen.In the state of having the water of the regulation water yield in water receptacle 12 is generated, i.e. at least make accommodating
In the state of the water of anode 34a and the water-immersed water yields of negative electrode 34b, in the anode chlorine for producing and the water for generating water receptacle
React and be immediately generated hypochlorous acid and hydrochloric acid, the water for generating water receptacle is changed into hypochloric acid water.However, in the state of without water not
There is the chlorine reaction, chlorine directly spreads.
According to present embodiment, electrolytic water generating device 10 possesses the detector 60 being built in electrode unit 16, for example
Float sensor 66, can detect and generate the water that the appropriate water yield whether is accommodated in water receptacle 12.That is, if generating water receptacle
There is appropriate water in 12, as shown in figure 1, the float 66a of float sensor 66 floats, be detected as normal situation.On the other hand,
If non-rising without appropriate water, float 66a in water receptacle 12 is generated, float sensor 66 detects the situation, controller
68 controls are powered so as to not carry out electrolysis action.Like this, by the way that float sensor 66 to be arranged at the sun than electrode unit 16
Pole 34a is closer to the top, and whether can reliably detect in generation water receptacle 12 has appropriate water.
By the above, can be provided according to present embodiment and not produce the high hydrostatic formula of the gases such as chlorine and reliability
Electrolytic water generating device and electrode unit.
Next, illustrating to the electrolytic water generating device involved by other embodiments.In addition, in following explanation
Other embodiments in, pair give identical reference marks with above-mentioned the 1st embodiment identical part and omit it
Detailed description, is described in detail centered on the part different from the 1st embodiment.
(the 2nd embodiment)
Fig. 3 is the profile for representing the electrolytic water generating device involved by the 2nd embodiment.According to the 2nd embodiment, electricity
Solution water generating device 10 possesses the detector 60 being built in electrode unit 16, and the detector 60 uses electrostatic capacitance sensor
65.Electrostatic capacitance sensor 65 is arranged in the measuring chamber 62 of electrode unit 16, is configured at more closer to the top than anode 34a, special
It is the height and position of the water surface of appropriate water.Electrostatic capacitance sensor 65 is electrically connected via wiring 67 with controller 68.In addition, by
In without the need for being taken into water into measuring chamber 62, therefore it is not provided with intake and exhaust outlet.
The electrostatic capacitance of the adjacent domain set by electrostatic capacitance sensor 65 pairs detects, and quiet with water to air
Electric capacitance difference is detected so as to detect generate in water receptacle 12 whether have appropriate water.Controller 68 is according to from electrostatic capacitance
The detection signal of sensor 65 come the energization that controls to be carried out by power supply 30, i.e., only when the appropriate water yield is detected, it is allowed to come
The energization in self-powered portion 30.
In the 2nd embodiment, other electrolysis constituted with the 1st above-mentioned embodiment of electrolytic water generating device 10
Water generating device is identical.Also, the effect effect same with the 1st above-mentioned embodiment is also obtained in that in the 2nd embodiment
Really.
(the 3rd embodiment)
Fig. 4 is the profile for representing the electrolytic water generating device involved by the 3rd embodiment.According to the 3rd embodiment, electricity
Solution water generating device 10 possesses mounting and supports the supporting station 70 of generation water receptacle 12, and extends upward from supporting station 70
Power supply handle 76.Detector 60 is arranged at the inside of supporting station 70.Power supply handle 76 constitutes a part for power supply 30.
As shown in figure 4, supporting station 70 possesses base 72, and lifting freely it is configured on base 72 and loads generation water
The support plate (container tray) 74 of container 12.Support plate 74 is by multiple dampers, such as elastic by multiple helical springs 75
Be supported on base 75.Pressing convex portion 74a is integrally formed with the lower surface central portion of support plate 74.
Detector 60 utilizes in supporting station 70 and presses convex portion 74a to be opposed to the strain transducer 61 for arranging.Strain is passed
Sensor 61 is configured under pressing convex portion 74a in the way of the lifting according to support plate 74 can be shifted.That is, if in support plate
Mounting generates water receptacle 12 on 74 and support plate 74 declines, then strain transducer 61 is pressed convex portion 74a pressings, according to generation water
The weight of container 12 and shift.Strain transducer 61 detects the weight for generating water receptacle 12 by detection deflection.
Strain transducer 61 is electrically connected with the controller 68 being arranged in supporting station 70.Controller 68 is according to from strain biography
The detection signal of sensor 61, the weight to generating water receptacle 12 is detected, and controls the energization from power supply 30.If rule
More than fixed weight, then controller 68 is judged as accommodating the water of ormal weight in generation water receptacle 12, and allows to carry out self-powered
The energization in portion 30.If less than the weight of regulation, controller 68 is judged as that generating unfilled water or the water yield in water receptacle 12 does not fill
Foot, and stop or forbid the energization from power supply 30.
Additionally, power supply handle 76 from supporting station 70 along generate water receptacle 12 side, extend to the side with supporting mass 14
Opposite position.Power supply 30 has a pair of energising terminals 82 of the upper end for being arranged on power supply handle 76, these energization ends
Son 82 is configured to and contact opposite with the connection terminal 84 exposed in the side of supporting mass 14.Power supply 30 possesses：
Energising terminal 82；Through power supply handle 76 it is interior extend and with energising terminal 82 turn on wiring 80；From under power supply handle 76
The derived service cable 85 in end；And the AC adapters 86 being connected with the midway part of service cable 85.Controller 68 is via cloth
Line and service cable 85 are connected with AC adapters 86.
If generating water receptacle 12 to be correctly placed on supporting station 70, connection terminal 84 and the power supply of electrode unit 16
The energising terminal 82 in portion 30 is contacted, and anode 34a and negative electrode 34b is turned on power supply 30.Thus, becoming can be from power supply 30
To the state that anode 34a and negative electrode 34b is powered.In other words, if being configured to be not suitably arranged in generation water receptacle 12
Then can not be powered in the state of supporting station 70.
As shown in figure 4, according to present embodiment, electrode unit 16 is configured to eliminate cathode chamber and only possess medial compartment
(electrolyte liquor chamber) 20 and teeter chamber 26.That is, the side of medial compartment 20 is closed by intermediate frame 21, and the opening of another side is by the 1st
Barrier film 32a is closed and separated.The outside of anode 34a and the 1st barrier film 32a is adjacent to be opposed to be set.Negative electrode 34b is arranged at centre
In room 20, and by the barrier film 32a of medial compartment 20 and the 1st be clipped in the middle it is opposite with anode 34a.Additionally, as described above, anode
34a and negative electrode 34b is electrically connected via wiring with the connection terminal 84 of the side for being arranged on supporting mass 14.Electrode unit 16
Others are constituted except detector is identical with the electrode unit 16 of the 1st above-mentioned embodiment.
When electrode unit 16 is set to into the only composition with medial compartment (electrolyte liquor chamber) 20, it is also possible to only made by becoming
The state that electrolyte mixes with negative electrode water, and normally will generate in water receptacle 12 aquatic becomes hypochloric acid water.
The 3rd embodiment for constituting in accordance with the above, is placed on supporting station 70 by will generate water receptacle 12
Appropriate location, generate water receptacle 12 weight be all transferred to strain transducer 61 via support plate 74.Thereby, it is possible to pass through
The detection of strain transducer 61 generates the weight of water receptacle 12, generates in water receptacle 12 whether accommodate appropriate water.Also, control
According to the detection signal from strain transducer 61, the weight to generating water receptacle 12 is detected device processed 68, and control from
The energization of power supply 30.When more than the weight for regulation, controller 68 is judged as accommodating ormal weight in generation water receptacle 12
Water, and allow from power supply 30 energization.When than regulation it is lightweight when, controller 68 be judged as generate water receptacle 12 in
Unfilled water or the water yield are inadequate, and stop or forbid the energization from power supply 30.Therefore, also can in the 3rd embodiment
Enough offer does not produce the high electrolytic water generating device of the gases such as chlorine and reliability and electrode unit.
(the 4th embodiment)
Fig. 5 is the profile for representing the electrolytic water generating device involved by the 4th embodiment.According to the 4th embodiment,
The composition of cushion cap 70 is different from the supporting station of the 3rd above-mentioned embodiment.
That is, according to present embodiment, mounting generates the supporting station 70 of water receptacle 12 and possesses base 72, and is arranged on base
On 72 and can according to generate water receptacle 12 weight and elastic deformation cover body part 77.The cover body part 77 of tray shape
It is formed integrally with base 72, i.e., seamlessly it is close to base 72 and is formed.In the present embodiment, the one of cover body part 77
Ground has the upside convex portion 77a that projects upward from upper face center portion, and prominent downwards from the central portion of lower surface
Downside convex portion 77b.
The strain transducer 61 of detector 60 is in the supporting station 70 and is arranged on base 72, and with cover body part 77 under
77b is opposite for side convex portion.
If the appropriate location that water receptacle 12 is placed on the cover body part 77 of supporting station 70 is generated, by generating the water capacity
The weight of device 12, cover body part 77 bends downwards, and downside convex portion 77b presses strain transducer 61.Thereby, it is possible to pass through to answer
Become the deflection of the detection of sensor 61 cover body part 77 to detect the weight for generating water receptacle 12.Here, water receptacle 12 will be generated
Weight be scaled the deflection of cover body part 77 and measure, and make the solution of the relation for representing deflection and container weight in advance
Analysis curve, thus, it is possible to the suitable quantity of water of detection container.
Additionally, according to present embodiment, by making the base 72 of supporting station 70 integrated with cover body part 77 such that it is able to
Eliminate the part for cutting off of the water capacity easily immersion.In the 4th embodiment, electrolytic water generating device 10 it is other constitute with it is above-mentioned
The 3rd embodiment involved by electrolytic water generating device it is identical.Therefore, can also provide in the present embodiment and not produce chlorine
The high electrolytic water generating device of the gases such as gas and reliability and electrode unit.
(the 5th embodiment)
Fig. 6 is the profile for representing the electrolytic water generating device involved by the 5th embodiment.According to the 5th embodiment, electricity
Solution water generating device 10 possesses the detector 60 for being built in electrode unit 16, and the detector 60 uses conductivity sensor 90.Lead
Electric rate sensor 90 has be spaced arranged opposite with gap 2 piece electrode 90a, 90b.Electrode 90a, 90b are arranged at electrode list
In the measuring chamber 62 of unit 16, the height and position of the water surface of more closer to the top than anode 34a, particularly appropriate water is configured at.Electrode
90a, 90b are electrically connected via wiring 67 with controller 68.
Apply the voltage waveform for specifying between conductivity sensor 90 2 electrodes 90a, 90b, and detect the electric current of response etc.
So as to detect to interelectrode conductance.Electrode 90a, 90b are state of insulation in the state of without water, are being immersed in the water
In the state of due to the ionic conduction in water conductance improve, therefore, it is possible to by the difference come in measuring chamber 62 water enter
Situation is detected.Controller 68 is controlled by leading to that power supply 30 is carried out according to the detection signal from conductivity sensor 90
Electricity, i.e. only when the appropriate water yield is detected, it is allowed to from the energization of power supply 30.
In the 5th embodiment, other electrolysis constituted with the 1st above-mentioned embodiment of electrolytic water generating device 10
Water generating device is identical.Also, the effect effect same with the 1st above-mentioned embodiment is also obtained in that in the 5th embodiment
Really.
The utility model be not limited to above-mentioned embodiment itself, can be in implementation phase in the model without departing from its purport
Inscape is set to deform and embody in enclosing.Additionally, by the appropriate group of multiple inscapes disclosed in above-mentioned embodiment
Close, various utility models can be formed.For example, several compositions are deleted in the whole inscapes that can be illustrated from embodiment
Key element.Even, it is also possible to which the inscape in different embodiments is appropriately combined.
The composition that the water for generating water receptacle is changed into hypochloric acid water is illustrated in the above-described embodiment, but it is also possible to handed over
Anode and negative electrode are changed, water receptacle is generated alkaline electrolysis water is generated.In the above-described embodiment, electrolyte is set to into salt
Water, by generate water be set to hypochloric acid water and NaOH water, but not limited to this, the electrolysis water generating involved by present embodiment
Device can be using various electrolyte and various generation water.Generate water receptacle and be not limited to above-mentioned embodiment, various containers,
As long as tank, other can store water and just can apply.Barrier film has used the multiple aperture plasma membrane with water penetration, but not limited to this,
The amberplex with ion selectivity can also be used.
Claims (21)
1. a kind of electrolytic water generating device, possesses：
Water receptacle is generated, for accommodating water；
Electrode unit, the electrode unit possesses and is separated by barrier film and accommodated the electrolyte liquor chamber of electrolyte, and clip it is described every
The mutually opposing anode of film and negative electrode, and the electrode unit be saturated in it is described generation water receptacle in water in；And
Detector, detection is contained in the water yield of the water in the generation water receptacle.
2. electrolytic water generating device as claimed in claim 1, wherein,
The detector is built in the electrode unit.
3. electrolytic water generating device as claimed in claim 2, wherein,
The detector has the float sensor being arranged in the electrode unit, to detect the water in the generation water receptacle
The water surface.
4. electrolytic water generating device as claimed in claim 3, wherein,
The electrode unit has the measuring chamber for the water immersion in the generation water receptacle,
The float sensor has that to be configured at the measurement indoor and swim in the float of the indoor water surface of measurement, and by institute
Float supporting is stated to lift freely and the hinge portion of the float position of the float is detected.
5. electrolytic water generating device as claimed in claim 2, wherein,
The detector has the electrostatic capacitance sensor being arranged in the electrode unit, to detect in the generation water receptacle
Water the water surface.
6. electrolytic water generating device as claimed in claim 2, wherein,
The detector has the conductivity sensor being arranged in the electrode unit, to detect in the generation water receptacle
The water surface of water.
7. the electrolytic water generating device as any one of claim 1～6, wherein,
The electrolytic water generating device possesses the power supply to the anode and cathodal closing, and by the detector
The controller of the energization that permission is carried out by power supply when detecting the water of ormal weight.
8. electrolytic water generating device as claimed in claim 1, wherein,
The electrolytic water generating device possesses the mounting supporting station for generating water receptacle, and the detector is built in the supporting
Platform.
9. electrolytic water generating device as claimed in claim 8, wherein,
The detector is arranged at the inside of the supporting station, and the detector possesses the weight according to the generation water receptacle
And the strain transducer for shifting.
10. electrolytic water generating device as claimed in claim 9, wherein,
The supporting station possesses base, and is lifting freely configured on base and loads the supporting for generating water receptacle
Plate, the strain transducer is configured under the support plate in the way of the lifting according to the support plate can be shifted.
11. electrolytic water generating devices as claimed in claim 9, wherein,
The supporting station possesses base, and is arranged on base and being capable of elasticity according to the weight of the generation water receptacle
The cover body part of deformation, the strain transducer is configured at institute in the way of the deformation according to the cover body part can be shifted
State under cover body part.
12. electrolytic water generating devices as any one of claim 8～11, wherein,
The electrolytic water generating device possesses the power supply to the anode and cathodal closing, and by the detector
The controller of the energization that permission is carried out by power supply when detecting the water of ormal weight.
13. electrolytic water generating devices as claimed in claim 1, wherein,
The electrode unit has, and is spaced between 2 opposite barrier films and accommodates the electrolyte liquor chamber of electrolyte, and
The cathode chamber of the storage negative electrode adjoined with the electrolyte liquor chamber, the container side of the anode and the electrolyte liquor chamber is adjacently
It is set.
14. electrolytic water generating devices as claimed in claim 1, wherein,
The negative electrode is arranged in the electrolyte liquor chamber, and the anode is arranged at the outside of the barrier film and the generation water receptacle
Inner side.
15. electrolytic water generating devices as claimed in claim 1, wherein,
The electrolyte contains chloride.
16. electrolytic water generating devices as claimed in claim 15, wherein,
The water generated in the generation water receptacle is hypochloric acid water.
A kind of 17. electrode units, possess：
Electrolyte liquor chamber, by barrier film electrolyte is separated and accommodates；Anode and negative electrode, clip the barrier film mutually opposing；And inspection
Device is surveyed, detection accommodates the water yield of water in a reservoir.
18. electrode units as claimed in claim 17, wherein,
The detector has float sensor.
19. electrode units as claimed in claim 17, wherein,
The detector has electrostatic capacitance sensor.
20. electrode units as claimed in claim 17, wherein,
The detector has conductivity sensor.
21. electrode units as any one of claim 17～20, wherein,
The electrode unit possesses the power supply to the anode and cathodal closing, and is being detected by the detector
The controller of the energization that permission is carried out by the power supply during water of ormal weight.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015068814 | 2015-03-30 | ||
| JP2015-068814 | 2015-03-30 | ||
| PCT/JP2015/075245 WO2016157570A1 (en) | 2015-03-30 | 2015-09-04 | Electrolyzed water producing apparatus and electrode unit |
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| CN206156809U true CN206156809U (en) | 2017-05-10 |
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| CN201590000320.5U Active CN206156809U (en) | 2015-03-30 | 2015-09-04 | Electrolysis water generation device and electrode unit |
Country Status (3)
| Country | Link |
|---|---|
| JP (2) | JP6143968B2 (en) |
| CN (1) | CN206156809U (en) |
| WO (1) | WO2016157570A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2020081191A1 (en) * | 2018-10-18 | 2020-04-23 | Colgate-Palmolive Company | Electrolysis device |
| JP7041731B1 (en) | 2020-11-30 | 2022-03-24 | 株式会社日本トリム | Electrolyzed water generator |
| JP7284845B2 (en) * | 2020-11-30 | 2023-05-31 | 株式会社日本トリム | Electrolyzed water generator |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5858890U (en) * | 1981-10-09 | 1983-04-21 | シャープ株式会社 | Ionized water conditioner diaphragm holding device |
| JPS58189933U (en) * | 1982-06-11 | 1983-12-16 | 松下電器産業株式会社 | platform scale |
| JPH0655174A (en) * | 1992-08-06 | 1994-03-01 | Nippon Intetsuku Kk | Electrolytic water producing apparatus |
| JPH07227594A (en) * | 1994-02-18 | 1995-08-29 | Funai Electric Co Ltd | Automatic electrolytic device of strongly acidic water generator |
| JP2904009B2 (en) * | 1994-06-07 | 1999-06-14 | 松下電器産業株式会社 | Water treatment method and water treatment device |
| JP2000093966A (en) * | 1998-07-21 | 2000-04-04 | Toto Ltd | Electrolytic apparatus |
| JP2003034889A (en) * | 2001-07-24 | 2003-02-07 | Chemicoat & Co Ltd | Method for electrolysis in device for generating strong- electrolyzed water |
| JP2003062569A (en) * | 2001-08-27 | 2003-03-04 | Matsushita Electric Ind Co Ltd | Electrolytic water generator |
| JP3711943B2 (en) * | 2002-02-07 | 2005-11-02 | 松下電器産業株式会社 | Electrolyzed water generator |
| JP2006239674A (en) * | 2005-03-02 | 2006-09-14 | Hokuetsu:Kk | Electrolytic water generating device |
| JP4091062B2 (en) * | 2005-05-20 | 2008-05-28 | ファースト・オーシャン株式会社 | Electrode for water electrolysis |
| JP4950547B2 (en) * | 2006-04-13 | 2012-06-13 | ヒロセ電機株式会社 | Slightly acidic water generator |
| JP2007007657A (en) * | 2006-10-16 | 2007-01-18 | Matsushita Electric Works Ltd | Electrolytic water producing apparatus |
| JP2010007281A (en) * | 2008-06-25 | 2010-01-14 | Eintesla Inc | Sterilization and cleaning equipment for water closet |
| JP2011191126A (en) * | 2010-03-12 | 2011-09-29 | Ishida Co Ltd | Strain element, load cell, and multi-point type balance |
| JP5688103B2 (en) * | 2013-01-28 | 2015-03-25 | ペルメレック電極株式会社 | Electrolyzed water production method and apparatus |
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| JPWO2016157570A1 (en) | 2017-04-27 |
| JP6143968B2 (en) | 2017-06-07 |
| WO2016157570A1 (en) | 2016-10-06 |
| JP6353115B2 (en) | 2018-07-04 |
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