CN206076394U - The enhancing device that hydrogen manufactures hydrogen fuel cell is leached with graphene film - Google Patents

The enhancing device that hydrogen manufactures hydrogen fuel cell is leached with graphene film Download PDF

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CN206076394U
CN206076394U CN201621131078.8U CN201621131078U CN206076394U CN 206076394 U CN206076394 U CN 206076394U CN 201621131078 U CN201621131078 U CN 201621131078U CN 206076394 U CN206076394 U CN 206076394U
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hydrogen
graphene film
gas
fuel cell
workshop
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林华
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Wuxi Tongchun New Energy Technology Co Ltd
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Wuxi Tongchun New Energy Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

This utility model is related to leach the enhancing device that hydrogen manufactures hydrogen fuel cell with graphene film, belongs to technical field of new energy application.The mixed gas containing hydrogen are compressed in gas compressing apparatus, drive the mixed gas containing hydrogen after compression pipeline to be input into by gas leach hydrogen device into graphene film, mixed gas containing hydrogen are leached in graphene film and run in hydrogen device ground floor filtration hydrogen graphene film, the non-hydrogen gas of molecular weight more than 40 can not filter hydrogen graphene film by ground floor, then run into the second layer and filter hydrogen graphene film, the non-hydrogen gas of molecular weight more than 17.5 can not filter hydrogen graphene film by the second layer, eventually encounter third layer and filter hydrogen graphene film, the non-hydrogen gas of molecular weight more than 2.5 can not filter hydrogen graphene film by third layer.The hydrogen molecule of molecular weight 2.016 continues to pass through three layer filtration hydrogen graphene film and produces pure hydrogen, for producing hydrogen fuel and hydrogen fuel cell.

Description

The enhancing device that hydrogen manufactures hydrogen fuel cell is leached with graphene film
Technical field
This utility model is related to leach the enhancing device that hydrogen manufactures hydrogen fuel cell with graphene film, and belonging to new forms of energy should Use technical field.
Background technology
September -5 days on the 4th in 2016, two Group of Ten leaders(G20)Hangzhou summit is that global economic governance is mainly put down Platform, G20 summits specify the sustainable development direction of green, low-carbon (LC) to the whole world.
Hydrogen Energy is the green energy resource of low-carbon (LC).Protium is distributed very extensively on earth, and water is the compound of hydrogen and oxygen, the earth Contain hydrogen in atmospheric thermodynamics, in soil, oil, natural gas, animal and plant body, food, all contain hydrogen, the relative atomic mass of hydrogen is 1.008, hydrogen has 2 stable isotopes and radiosiotope, and two hydrogen atoms constitute a hydrogen molecule.Hydrogen be cleaning can Generative fuel, can produce hydrogen fuel cell using hydrogen fuel, and the application for promoting Hydrogen Energy can reduce haze to human body and society The harm of meeting, modern society are increasing to the demand of hydrogen.
Hydrogen fuel cell produces electric energy and water, environmentally safe by electrochemical reaction.Hydrogen fuel cell is producing electricity Carbon dioxide and sulfur dioxide are not discharged in the course of work of energy and water, can provide to automobile or aircraft be beneficial to environmental conservation Hydrogen power.In some cities in the world, there are hydrogen energy automobile and hydrogenation stations.However, manufacture hydrogen fuel cell is needed Substantial amounts of hydrogen is wanted, and originally various dusty gass can be discharged in peripherad environment with during Fossil fuel hydrogen manufacturing.Common electricity Solution water hydrogen manufacturing, energy utilization rate only have 15% -20%, waste big.Scientific and technical personnel always search for the new method of low cost making Hydrogen is taken, and the market competitiveness of hydrogen fuel cell is improved with the relatively low hydrogen fuel of price.
Utility model content
The purpose of this utility model is to overcome deficiency of the prior art, there is provided leach hydrogen manufacture hydrogen with graphene film The enhancing device of fuel cell.
The two dimensional crystal of only one layer of atomic thickness that Graphene is made up of carbon atom.Graphene film is very fine and close, people Be initially considered that the hydrogen atom of only 0.79 angstrom of atomic radius cannot penetrate graphene film.With the progress of scientific experimentss method, The change of the noegenesis of people.2013, the engineers of South Carolina, USA university developed oxygen most thin in the world Graphite alkene filter membrane, this graphene oxide filtration membrane just as a sieve, the kinetic diameter of hydrogen small molecule is 0.289 nanometer, the atomic sieve aperture of graphene oxide filter membrane can be passed through, the kinetic diameter of carbon dioxide macromole is 0.33 Nanometer, it is impossible to through the atomic sieve aperture of graphene oxide filter membrane.2016, the research worker of Univ Manchester UK was in reality In testing, discovery special graphite alkene film can leach hydrogen from the mixed gas such as air, this scientific discovery, be the mankind with into This opens new approach than relatively low new method hydrogen making.Shuo Suo universities then carry out the science reality of this problem in the world Test, it is commonly found that:The mankind can produce the stone of the graphene film in tiny aperture, the graphene film of fine pore size and atomic aperture Black alkene film, for filtering respectively or separating the mixed gas being made up of the different gaseous molecular of various molecular weight.
Gas compressing apparatus 1 drive the gas after compression to be input into pipeline 2 by gas and leach hydrogen dress into graphene film 3 are put, compressed gas include gaseous molecular of the hydrogen in the interior, mixed gas that molecular weight is below 40 through tiny aperture Ground floor filters hydrogen graphene film 4, filters hydrogen graphene film 4 into ground floor and filters hydrogen graphene film 5 with the second layer Between space, fail to filter hydrogen graphene film 4, the non-hydrogen gas that molecular weight is more than 40 through the ground floor in tiny aperture By the first input pressurization non-hydrogen gas of non-hydrogen gas outlet duct 7 storeroom 10.Hydrogen graphite is filtered through ground floor Mixed gas of the molecular weight of alkene film 4 less than 40 move forward and meet with the second layer filtration hydrogen graphene film of fine pore size 5, mixed gas that the second layer filters hydrogen graphene film 5, that molecular weight is below 17.5 can be passed through to enter the second layer and to filter hydrogen Gas graphene film 5 and third layer filter the space between hydrogen graphene film 6, and the second layer failed through fine pore size filters hydrogen Non-hydrogen gas of the molecular weight of gas graphene film 5 less than 40, more than 17.5 is added by second input of non-hydrogen gas outlet duct 8 Pressure non-hydrogen gas storeroom 10.Filtered through the second layer mixed gas of the molecular weight of hydrogen graphene film 5 less than 17.5 after The continuous third layer for meeting with forward atomic aperture filters hydrogen graphene film 6, and atomic aperture can only be for individual molecule amount below 2.5 Hydrogen molecule is continued through, fail through the third layer in atomic aperture filter hydrogen graphene film 6, molecular weight less than 17.5, Non-hydrogen gas more than 2.5 is by the 3rd input pressurization non-hydrogen gas of non-hydrogen gas outlet duct 9 storeroom 10.Storage is full to be measured The pressurization non-hydrogen gas storeroom 10 of non-hydrogen gas is after internal pressurization is by non-hydrogen gas pressurized, by non-hydrogen gas exhaustor Road 17 is emitted.Third layer through atomic aperture filters the purified hydrogen of hydrogen graphene film 6 by pure hydrogen gas conveying The input pure hydrogen gas pressurization of pipeline 11 workshop 12, applied the pressurized pure hydrogen of appropriate pressure in pure hydrogen gas pressurize workshop 12 Body is input into hydrogen fuel workshop 14 by pressurized pure hydrogen body conveyance conduit 13 and is used as raw material for producing hydrogen fuel, fires from hydrogen The hydrogen fuel of the material output of workshop 14 is input into hydrogen fuel cell workshop 16 by hydrogen fuel conveyance conduit 15, in hydrogen fuel 16 interior hydrogen fuel of battery production workshop is primary raw material manufacture hydrogen fuel cell 18, is transported from hydrogen fuel cell workshop 16 Go out the supply clean energy resource of hydrogen fuel cell 18 market.
In order to solve above-mentioned technical problem, this utility model is achieved through the following technical solutions:
Pipeline 2, graphene film is input into by gas compressing apparatus 1, gas and leaches hydrogen device 3, ground floor filtration hydrogen stone The black alkene film 4, second layer filters hydrogen graphene film 5, third layer and filters hydrogen 6, first non-hydrogen gas output tube of graphene film 7, second, road non-hydrogen gas outlet duct 8, the 3rd non-hydrogen gas outlet duct 9, pressurization non-hydrogen gas storeroom 10, pure hydrogen Gas transmission pipeline 11, pure hydrogen gas pressurization workshop 12, pressurized pure hydrogen body conveyance conduit 13, hydrogen fuel workshop 14, hydrogen Fuel tube 15, hydrogen fuel cell workshop 16, non-hydrogen gas discharge duct 17, hydrogen fuel cell 18 are collectively constituted;
Gas being installed on the right side of gas compressing apparatus 1 and being input into pipeline 2, graphite is installed on the right side for pipeline 2 being input in gas Alkene membrane filtration goes out hydrogen device 3, leaches the inside of hydrogen device 3 from left to right according to equal distance, pacify successively in graphene film Dress ground floor filters the hydrogen graphene film 4, second layer and filters hydrogen graphene film 5, third layer filtration hydrogen graphene film 6, The graphene film that gas is input between pipeline 2 and ground floor filtration hydrogen graphene film 4 is leached on the lower wall bottom surface of hydrogen device 3 First non-hydrogen gas outlet duct 7 is installed, and hydrogen graphene film 4 is filtered in ground floor and filters hydrogen graphene film with the second layer Graphene film between 5 is leached, in the second layer Filter the lower wall bottom that the graphene film between hydrogen graphene film 5 and third layer filtration hydrogen graphene film 6 leaches hydrogen device 3 3rd non-hydrogen gas outlet duct 9 is installed on face, and the right side for hydrogen device 3 being leached in graphene film is installed from left to right successively Pure hydrogen gas conveyance conduit 11, pure hydrogen gas pressurization workshop 12, pressurized pure hydrogen body conveyance conduit 13, hydrogen fuel workshop 14th, hydrogen fuel conveyance conduit 15 and hydrogen fuel cell workshop 16, have from hydrogen in the lower section of hydrogen fuel cell workshop 16 The hydrogen fuel cell 18 that fuel cell manufacture workshop 16 transports, the lower section for leaching hydrogen device 3 in graphene film is nearby installed Pressurization non-hydrogen gas storeroom 10, installs non-hydrogen gas discharge duct 17 on the right flank of pressurization non-hydrogen gas storeroom 10;
Gas compressing apparatus 1 are input into pipeline 2 with gas and are interconnected, and gas is input into pipeline 2 and leaches hydrogen with graphene film Device 3 is interconnected, and graphene film leaches hydrogen device 3 by first non-hydrogen gas outlet duct 7 and pressurization non-hydrogen gas The lower sides of the left surface of storeroom 10 connect and communicate, and graphene film leaches hydrogen device 3 by second non-hydrogen gas Output channel 8 is connected and communicates with the middle part of sliding channel of the left surface of pressurization non-hydrogen gas storeroom 10, and graphene film leaches hydrogen Device 3 is connected with the upper portion side wall of the left surface of pressurization non-hydrogen gas storeroom 10 by the 3rd non-hydrogen gas outlet duct 9 And communicate, pressurize non-hydrogen gas storeroom 10 and the non-hydrogen gas row being arranged on the right flank of pressurization non-hydrogen gas storeroom 10 Feed channel 17 connects and communicates, and graphene film is leached hydrogen device 3 and pressurizeed with pure hydrogen gas by pure hydrogen gas conveyance conduit 11 Workshop 12 connects and communicates, and pure hydrogen gas pressurization workshop 12 is by pressurized pure hydrogen body conveyance conduit 13 and hydrogen fuel workshop 14 connect and communicate, and hydrogen fuel workshop 14 is connected simultaneously with hydrogen fuel cell workshop 16 by hydrogen fuel conveyance conduit 15 Communicate.
Hydrogen fuel cell 18 be alkaline hydrogen fuel cell or phosphoric acid hydrogen fuel cell or soild oxide hydrogen fuel cell or PEM hydrogen fuel cell.
Compared with prior art, the beneficial effects of the utility model are:1. a hydrogen manufacturing new way is opened, stone has been widened The range of application of black alkene film.2. the purity of hydrogen making is improve, the economic worth and using value of pure hydrogen gas is improve.③ Reduce the production cost of hydrogen manufacturing.4. the production hydrogen process for leaching hydrogen device with graphene film is safer.
Description of the drawings
Fig. 1 is structural representation of the present utility model.
Specific embodiment
Hydrogen is fuel gas, and two hydrogen atoms constitute a hydrogen molecules, and the molecular weight of hydrogen is 2.016, pure hydrogen Can burn in air, hydrogen is faster with the burning velocity of the mixed gas of air than hydrogen with the burning velocity of the mixed gas of oxygen.Hydrogen Combustion products with the mixed gas of oxygen is water, and the material of pollution environment is not produced during burning, what burning was generated Water can be used for water electrolysis hydrogen production, can circulate and recycle, so Hydrogen Energy is both clean energy resource, it is regenerative resource again.
Hydrogen fuel cell is a kind of the chemical energy of hydrogen fuel reducing agent and oxidant to be efficiently converted into electric energy directly TRT, energy conversion efficiency up to 60% -80%, while having, aerofluxuss are clean, noise is little, reliability is high and easy maintenance The characteristics of, hydrogen fuel cell is the TRT using the efficient of hydrogen gas generation, energy-saving and environmental protection.
Manufacture hydrogen fuel cell need high-purity hydrogen, once someone with macromolecular material membrane separation technique from hydrogeneous gaseous mixture Hydrogen is obtained in body, but, macromolecular material is thermo-labile, the high temperature that resistance to 2000 DEG C of graphene film, the aperture of film have it is tiny, trickle, Atomic polytype, is suitable for from Gas Mixtures Containing Hydrogen isolating pure hydrogen step by step.In nature, simple substance hydrogen is few, from chemical combination It is hydrogen manufacturing in thing, varied with the method for biotechnology hydrogen manufacturing.Entered from the higher hydrogen rich feedstock gas of unstripped gas hydrogen content Gas compressing apparatus are compressed, and can improve the hydrogen generation efficiency that graphene film leaches hydrogen device.Graphene film leaches hydrogen Device can be used for pure hydrogen is extracted from air.The hydrogen content of unstripped gas typically requires to reach 30% -80%.
The Chinese Hydrogen Energy industry development Rugao summit on the 28th of August in 2016 is smoothly held, and two academicians of Chinese Academy of Engineering are in person To the Rugao of Nantong City, the economic Model City of Chinese first the United Nations's hydrogen is built up in power-assisted Rugao, and young automobile group exists Rugao main development hydrogen energy automobile, manufacture hydrogen energy automobile belong to rising industry, it is possible to achieve economic, society and environmental benefit it is many Win.
The embodiment combined in accompanying drawing is further described by this utility model below:
Pipeline 2, graphene film is input into by gas compressing apparatus 1, gas and leaches hydrogen device 3, ground floor filtration hydrogen stone The black alkene film 4, second layer filters hydrogen graphene film 5, third layer and filters hydrogen 6, first non-hydrogen gas output tube of graphene film 7, second, road non-hydrogen gas outlet duct 8, the 3rd non-hydrogen gas outlet duct 9, pressurization non-hydrogen gas storeroom 10, pure hydrogen Gas transmission pipeline 11, pure hydrogen gas pressurization workshop 12, pressurized pure hydrogen body conveyance conduit 13, hydrogen fuel workshop 14, hydrogen Fuel tube 15, hydrogen fuel cell workshop 16, non-hydrogen gas discharge duct 17, hydrogen fuel cell 18 are collectively constituted;
Gas being installed on the right side of gas compressing apparatus 1 and being input into pipeline 2, graphite is installed on the right side for pipeline 2 being input in gas Alkene membrane filtration goes out hydrogen device 3, leaches the inside of hydrogen device 3 from left to right according to equal distance, pacify successively in graphene film Dress ground floor filters the hydrogen graphene film 4, second layer and filters hydrogen graphene film 5, third layer filtration hydrogen graphene film 6, The graphene film that gas is input between pipeline 2 and ground floor filtration hydrogen graphene film 4 is leached on the lower wall bottom surface of hydrogen device 3 First non-hydrogen gas outlet duct 7 is installed, and hydrogen graphene film 4 is filtered in ground floor and filters hydrogen graphene film with the second layer Graphene film between 5 is leached, in the second layer Filter the lower wall bottom that the graphene film between hydrogen graphene film 5 and third layer filtration hydrogen graphene film 6 leaches hydrogen device 3 3rd non-hydrogen gas outlet duct 9 is installed on face, and the right side for hydrogen device 3 being leached in graphene film is installed from left to right successively Pure hydrogen gas conveyance conduit 11, pure hydrogen gas pressurization workshop 12, pressurized pure hydrogen body conveyance conduit 13, hydrogen fuel workshop 14th, hydrogen fuel conveyance conduit 15 and hydrogen fuel cell workshop 16, have from hydrogen in the lower section of hydrogen fuel cell workshop 16 The hydrogen fuel cell 18 that fuel cell manufacture workshop 16 transports, the lower section for leaching hydrogen device 3 in graphene film is nearby installed Pressurization non-hydrogen gas storeroom 10, installs non-hydrogen gas discharge duct 17 on the right flank of pressurization non-hydrogen gas storeroom 10;
Gas compressing apparatus 1 are input into pipeline 2 with gas and are interconnected, and gas is input into pipeline 2 and leaches hydrogen with graphene film Device 3 is interconnected, and graphene film leaches hydrogen device 3 by first non-hydrogen gas outlet duct 7 and pressurization non-hydrogen gas The lower sides of the left surface of storeroom 10 connect and communicate, and graphene film leaches hydrogen device 3 by second non-hydrogen gas Output channel 8 is connected and communicates with the middle part of sliding channel of the left surface of pressurization non-hydrogen gas storeroom 10, and graphene film leaches hydrogen Device 3 is connected with the upper portion side wall of the left surface of pressurization non-hydrogen gas storeroom 10 by the 3rd non-hydrogen gas outlet duct 9 And communicate, pressurize non-hydrogen gas storeroom 10 and the non-hydrogen gas row being arranged on the right flank of pressurization non-hydrogen gas storeroom 10 Feed channel 17 connects and communicates, and graphene film is leached hydrogen device 3 and pressurizeed with pure hydrogen gas by pure hydrogen gas conveyance conduit 11 Workshop 12 connects and communicates, and pure hydrogen gas pressurization workshop 12 is by pressurized pure hydrogen body conveyance conduit 13 and hydrogen fuel workshop 14 connect and communicate, and hydrogen fuel workshop 14 is connected simultaneously with hydrogen fuel cell workshop 16 by hydrogen fuel conveyance conduit 15 Communicate.
Hydrogen fuel cell 18 be alkaline hydrogen fuel cell or phosphoric acid hydrogen fuel cell or soild oxide hydrogen fuel cell or PEM hydrogen fuel cell.
The first half of the year in 2016, Univ Manchester UK have issued a current research, Graphene on ' Nature Journal ' Thin film can be used to extract the hydrogen in air, applies it to fuel cell field and can bring possibility for hydrogen gas generation.Science Boundary represents that this is most revolutionary progress in battery technology history.Relevant professor says:' nowadays can to have produced into one flat for Graphene The thin slice of square rice, its application on business-purpose fuel cell are urgent '.
The graphite ore reserves of China accounts for the 75% of world's gross reserves, and volume of production accounts for the 72% of Gross World Product, and current graphite is produced Based on low-end product, middle end product, high-end product Graphene is still used product for the experiment of Ge great research institutions, the big rule of distance Mould industry application is still needed the time.Graphene as a kind of new carbon nanomaterial, with high application potential and wide Market prospect.In recent years, Jiangsu Province, China, Zhejiang Province, the Graphene industry of Shandong Province begin to take shape, the Changzhou in Jiangsu Province, Wuxi City, Suzhou City, Nantong City have occurred 200 Yu Jia Graphenes enterprises, many concentrations of enterprises research and development graphene conductive products, Heat conduction product.At present, there is no a Corporation R & D graphene film hydrogen manufacturing product, Graphene technological applications are not opened in Hydrogen Energy Send out.The Graphene application and development in Jiangsu, it is important to will cut market pain spot, finds substantive application space.
Gas compressing apparatus drive the mixed gas after compression to be input into pipeline by gas and leach hydrogen into graphene film Device, mixed gas leach the ground floor filtration hydrogen Graphene that tiny aperture is initially encountered in hydrogen device in graphene film Film, carbon dioxide of the molecular weight gas more than 40(The molecular weight of carbon dioxide is 44.0095)Etc. non-hydrogen gas and dust not Hydrogen graphene film can be filtered by ground floor, the non-hydrogen mixed gas of this class and dust can only be defeated by first non-hydrogen gas Go out pipeline input pressurization non-hydrogen gas storeroom.Have already passed through ground floor hydrogen graphene film, molecular weight are filtered less than 40 Mixed gas and vapor run into forward fine pore size the second layer filter hydrogen graphene film, molecular weight gas below 40, More than 17.5 oxygen(The molecular weight of oxygen is 32)Etc. non-hydrogen mixed gas and vapor(The molecular weight of water is 18)Fail to lead to Cross the second layer and filter hydrogen graphene film, the non-hydrogen mixed gas of this class and vapor can only be by second non-hydrogen gas outputs Pipeline input pressurization non-hydrogen gas storeroom.Have already passed through the second layer hydrogen graphene film, molecular weight are filtered less than 17.5 Mixed gas continue forward, run into atomic aperture third layer filter the non-hydrogen of hydrogen graphene film, molecular weight more than 2.5 Body can not filter hydrogen graphene film by third layer, and molecular weight gas are below 17.5, more than 2.5 helium(Helium point Son amount is 4)Fail to filter hydrogen graphene film by third layer etc. non-hydrogen mixed gas, can only be defeated by the 3rd non-hydrogen gas Go out pipeline, input pressurization non-hydrogen gas storeroom.Finally, only molecular weight is that 2.016 hydrogen molecule is just passed through atomic aperture Third layer filter hydrogen graphene film, the only minimum hydrogen molecule of molecular weight could filter hydrogen Graphene through third layer The third layer that film, other elementary gas molecules and chemical compound gas molecule all cannot pass through filters hydrogen graphene film, therefore, even The purity of the continuous hydrogen separated by three layer filtration hydrogen graphene film is at a relatively high.
Embodiment is enumerated now as follows:
Embodiment one:
Hydrogen device is leached with graphene film pure hydrogen, the composition of first kind mixed gas are isolated from first kind mixed gas It is:Hydrogen accounts for 21%, carbon dioxide and accounts for 29%, nitrogen and account for 40%, methane gas and accounts for 10%.First kind is compressed in gas compressing apparatus Mixed gas, drive the first kind mixed gas after compression to be input into pipeline by gas and leach hydrogen device, first into graphene film Plant mixed gas and the ground floor filtration hydrogen graphene film that tiny aperture is initially encountered in hydrogen device, gas are leached in graphene film Carbon dioxide of the body molecular weight more than 40(The molecular weight of carbon dioxide is 44.0095)Fail etc. non-hydrogen gas and dust Hydrogen graphene film is filtered by ground floor, this class non-hydrogen gas and dust can only pass through first non-hydrogen gas outlet duct Input pressurization non-hydrogen gas storeroom.Have already passed through first kinds that ground floor filters hydrogen graphene film, that molecular weight is less than 40 to mix Close gas and vapor and run into forward the second layer of fine pore size and filter hydrogen graphene film, molecular weight gas below 40, More than 17.5 nitrogen(The molecular weight of nitrogen is 28.013)Etc. first kind mixed gas and vapor(The molecular weight of water is 18)Not Hydrogen graphene film can be filtered by the second layer, this class non-hydrogen first kind mixed gas and vapor can only pass through second non-hydrogen Gas outlet duct input pressurization non-hydrogen gas storeroom.Have already passed through the second layer filter hydrogen graphene film, molecular weight it is little In 17.5 first kind mixed gas continue forward, run into atomic aperture third layer filter hydrogen graphene film, molecular weight gas Below 17.5, more than 2.5 methane gas(The molecular weight of methane gas is 16)Fail by third layer mistake etc. first kind mixed gas Filter hydrogen graphene film, can only be by the 3rd non-hydrogen gas outlet duct, input pressurization non-hydrogen gas storeroom.Finally, only There is the hydrogen molecule that molecular weight is 2.016 to be just passed through the atomic aperture that gas molecule of the molecular weight below 2.5 can be allowed to pass through Third layer filters hydrogen graphene film, and the only minimum hydrogen molecule of molecular weight could filter hydrogen graphene film through third layer, The third layer that other elementary gas molecules and chemical compound gas molecule all cannot pass through filters hydrogen graphene film, therefore, continuously The purity of the hydrogen separated by three layer filtration hydrogen graphene film is at a relatively high.With the filtration of the plurality of specifications of high-quality Hydrogen graphene film isolates pure hydrogen from first kind mixed gas for production hydrogen fuel and the efficient hydrogen fuel electricity of manufacture Pond.
Embodiment two:
Hydrogen device is leached with graphene film pure hydrogen, the composition of second kind mixed gas are isolated from second kind mixed gas It is:Hydrogen accounts for 32%, sulfur dioxide gas and accounts for 19%, nitrogen and account for 38%, ammonia and accounts for 11%.Second kind is compressed in gas compressing apparatus to mix Gas is closed, and is driven the second kind mixed gas after compression pipeline to be input into by gas and is leached hydrogen device, second kind into graphene film Mixed gas leach the ground floor filtration hydrogen graphene film that tiny aperture is initially encountered in hydrogen device, gas in graphene film Sulfur dioxide of the molecular weight more than 40(The molecular weight of sulfur dioxide gas is 64.0638)Fail to lead to etc. non-hydrogen gas and dust Cross ground floor and filter hydrogen graphene film, this class non-hydrogen gas and dust can only be defeated by first non-hydrogen gas outlet duct Enter to pressurize non-hydrogen gas storeroom.Have already passed through second kinds that ground floor filters hydrogen graphene film, that molecular weight is less than 40 to mix Gas and vapor run into forward the second layer of fine pore size and filter hydrogen graphene film, and molecular weight gas are below 40,17.5 Nitrogen above(The molecular weight of nitrogen is 28.013)Etc. non-hydrogen gas and vapor(The molecular weight of water is 18)Fail by Two layers of filtration hydrogen graphene film, this class non-hydrogen gas and vapor can only be by second non-hydrogen gas outlet duct inputs Pressurization non-hydrogen gas storeroom.Have already passed through second kinds that the second layer filters hydrogen graphene film, that molecular weight is less than 17.5 to mix Gas continue forward, run into atomic aperture third layer filter hydrogen graphene film, molecular weight gas below 17.5,2.5 with On ammonia(The molecular weight of ammonia is 17.031)Fail to filter hydrogen graphene film, Zhi Nengtong by third layer etc. non-hydrogen gas Cross the 3rd non-hydrogen gas outlet duct, input pressurization non-hydrogen gas storeroom.Finally, only molecular weight is 2.016 hydrogen point Son is just passed through the third layer in the atomic aperture that gas molecule of the molecular weight below 2.5 can be allowed to pass through and filters hydrogen Graphene The third layer that film, other elementary gas molecules and chemical compound gas molecule all cannot pass through filters hydrogen graphene film, therefore, even The purity of the continuous hydrogen separated by three layer filtration hydrogen graphene film is at a relatively high.With the mistake of the plurality of specifications of high-quality Filter hydrogen graphene film isolates pure hydrogen from second kind mixed gas for production hydrogen fuel and the efficient hydrogen fuel of manufacture Battery.

Claims (2)

1. the enhancing device that hydrogen manufactures hydrogen fuel cell is leached with graphene film, it is characterized in that, by gas compressing apparatus(1)、 Gas is input into pipeline(2), graphene film leach hydrogen device(3), ground floor filter hydrogen graphene film(4), the second layer filter Hydrogen graphene film(5), third layer filter hydrogen graphene film(6), first piece non-hydrogen gas outlet duct(7), second piece it is non- Hydrogen output channel(8), the 3rd piece non-hydrogen gas outlet duct(9), pressurization non-hydrogen gas storeroom(10), pure hydrogen gas it is defeated Send pipeline(11), pure hydrogen gas pressurization workshop(12), pressurized pure hydrogen body conveyance conduit(13), hydrogen fuel workshop(14)、 Hydrogen fuel conveyance conduit(15), hydrogen fuel cell workshop(16), non-hydrogen gas discharge duct(17), hydrogen fuel cell(18) Collectively constitute;
In gas compressing apparatus(1)Right side install gas be input into pipeline(2), pipeline is input in gas(2)Right side install stone Black alkene membrane filtration goes out hydrogen device(3), hydrogen device is leached in graphene film(3)Inside from left to right according to equal distance, Ground floor is installed successively and filters hydrogen graphene film(4), the second layer filter hydrogen graphene film(5), third layer filter hydrogen stone Black alkene film(6), pipeline is input in gas(2)Hydrogen graphene film is filtered with ground floor(4)Between graphene film leach hydrogen Device(3)Lower wall bottom surface on install first non-hydrogen gas outlet duct(7), hydrogen graphene film is filtered in ground floor(4) Hydrogen graphene film is filtered with the second layer(5)Between graphene film leach hydrogen device(3)Lower wall bottom surface on install second Root non-hydrogen gas outlet duct(8), hydrogen graphene film is filtered in the second layer(5)Hydrogen graphene film is filtered with third layer(6) Between graphene film leach hydrogen device(3)Lower wall bottom surface on install the 3rd non-hydrogen gas outlet duct(9), in graphite Alkene membrane filtration goes out hydrogen device(3)Right side from left to right successively install pure hydrogen gas conveyance conduit(11), pure hydrogen gas pressurization car Between(12), pressurized pure hydrogen body conveyance conduit(13), hydrogen fuel workshop(14), hydrogen fuel conveyance conduit(15)And hydrogen fuel Battery production workshop(16), in hydrogen fuel cell workshop(16)Lower section have from hydrogen fuel cell workshop(16)Transport Hydrogen fuel cell(18), hydrogen device is leached in graphene film(3)Lower section nearby install pressurization non-hydrogen gas storeroom (10), in pressurization non-hydrogen gas storeroom(10)Right flank on install non-hydrogen gas discharge duct(17);
Gas compressing apparatus(1)Pipeline is input into gas(2)It is interconnected, gas is input into pipeline(2)Hydrogen is leached with graphene film Device of air(3)It is interconnected, graphene film leaches hydrogen device(3)By first non-hydrogen gas outlet duct(7)With pressurization Non-hydrogen gas storeroom(10)The lower sides of left surface connect and communicate, graphene film leaches hydrogen device(3)By Two non-hydrogen gas outlet ducts(8)With pressurization non-hydrogen gas storeroom(10)The middle part of sliding channel of left surface connect and communicate, Graphene film leaches hydrogen device(3)By the 3rd non-hydrogen gas outlet duct(9)With pressurization non-hydrogen gas storeroom(10) The upper portion side wall of left surface connect and communicate, pressurize non-hydrogen gas storeroom(10)With installed in pressurization non-hydrogen gas storeroom (10)Right flank on non-hydrogen gas discharge duct(17)Connect and communicate, graphene film leaches hydrogen device(3)By pure Hydrogen conveyance conduit(11)With pure hydrogen gas pressurization workshop(12)Connect and communicate, pure hydrogen gas pressurization workshop(12)By adding Pressure pure hydrogen gas conveyance conduit(13)With hydrogen fuel workshop(14)Connect and communicate, hydrogen fuel workshop(14)By hydrogen Fuel tube(15)With hydrogen fuel cell workshop(16)Connect and communicate.
2. graphene film according to claim 1 leaches the enhancing device that hydrogen manufactures hydrogen fuel cell, it is characterized in that, Described hydrogen fuel cell(18)Be alkaline hydrogen fuel cell or phosphoric acid hydrogen fuel cell or soild oxide hydrogen fuel cell or PEM hydrogen fuel cell.
CN201621131078.8U 2016-10-18 2016-10-18 The enhancing device that hydrogen manufactures hydrogen fuel cell is leached with graphene film Expired - Fee Related CN206076394U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106299423A (en) * 2016-10-18 2017-01-04 无锡同春新能源科技有限公司 Leach hydrogen with graphene film and manufacture the enhancing device of hydrogen fuel cell
CN110195671A (en) * 2019-05-14 2019-09-03 胡洋 Automotive energy-saving emission-reducing synergistic device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106299423A (en) * 2016-10-18 2017-01-04 无锡同春新能源科技有限公司 Leach hydrogen with graphene film and manufacture the enhancing device of hydrogen fuel cell
CN110195671A (en) * 2019-05-14 2019-09-03 胡洋 Automotive energy-saving emission-reducing synergistic device

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