CN206045476U - A kind of injection needle on mechanical arm type solid-phase extracting instrument - Google Patents

A kind of injection needle on mechanical arm type solid-phase extracting instrument Download PDF

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Publication number
CN206045476U
CN206045476U CN201621055779.8U CN201621055779U CN206045476U CN 206045476 U CN206045476 U CN 206045476U CN 201621055779 U CN201621055779 U CN 201621055779U CN 206045476 U CN206045476 U CN 206045476U
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China
Prior art keywords
injection needle
liquid
utility
model
solenoid directional
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Expired - Fee Related
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CN201621055779.8U
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Chinese (zh)
Inventor
王志刚
张振方
刘峰
刘一峰
虞发海
杨水云
李婷
季金丹
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JINAN HANON INSTRUMENTS CO Ltd
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JINAN HANON INSTRUMENTS CO Ltd
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Priority to CN201621055779.8U priority Critical patent/CN206045476U/en
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Abstract

A kind of injection needle on mechanical arm type solid-phase extracting instrument, which includes, the first overall diameter being axially connected successively and first steel pipe and the second steel pipe with second external diameter and the second internal diameter of the first internal diameter, first external diameter are bigger than second external diameter, so as to form step in connection.Easy-to-leak liquid and intensity is not big when to solid-phase extraction column injecting fluid for the injection needle that this utility model is provided.

Description

A kind of injection needle on mechanical arm type solid-phase extracting instrument
Technical field
Utility model is related to a kind of injection needle on mechanical arm type solid-phase extracting instrument.
Background technology
In prior art, include for the injection needle on mechanical arm type solid-phase extracting instrument:Pintle, pin stalk and needle point, it is described Pin stalk is made up of about one uniform fine steel tube, and injection needle is inserted into solid-phase extraction column(SPE)Through hole when, easily from through hole In spill liquid, so as to cause leakage.In addition, pin stalk is made up of the steel of same material, when intensity is high, toughness is not enough;Toughness is high When, intensity is not enough, it is difficult to take into account intensity and toughness.
The content of the invention
In order to overcome shortcoming present in prior art, goal of the invention of the present utility model to be to provide a kind of for mechanical arm Injection needle on formula solid-phase extracting instrument, not easy-to-leak liquid when to solid-phase extraction column injecting fluid.
To realize the goal of the invention, this utility model provides a kind of injection on mechanical arm type solid-phase extracting instrument Pin, it is characterised in that include, the first steel pipe 1 with the first overall diameter and the first internal diameter being axially connected successively and has Second steel pipe of second external diameter and the second internal diameter, first external diameter are bigger than second external diameter, so as to form step in connection.
Preferably, sealing ring is provided with step.
Preferably, the free end of the second steel pipe forms inclined-plane.
Compared with prior art, this utility model provide for the injection needle on mechanical arm type solid-phase extracting instrument, giving During solid-phase extraction column injecting fluid, easy-to-leak liquid and intensity is not high.
Description of the drawings
Fig. 1 is the composition schematic diagram of the liquid-level tracking device that this utility model is provided;
The schematic diagram of the injection needle that Fig. 2 is provided for this utility model;
Fig. 3 is the schematic diagram of the injection needle that this utility model is provided and solid-phase extraction column;
Fig. 4 is the built-up circuit figure of the control system of the liquid-level tracking device that this utility model is provided;
Fig. 5 is the schematic diagram of the liquid-level tracking principle that this utility model is provided;
Fig. 6 is the control process schematic diagram of the control system of the liquid-level tracking device that this utility model is provided.
Specific embodiment
The technical solution of the utility model is clearly and completely described below in conjunction with accompanying drawing, it is clear that described Embodiment is a part of embodiment of this utility model, rather than the embodiment of whole.Based on the embodiment in this utility model, this The every other embodiment obtained under the premise of creative work is not made by field those of ordinary skill, belongs to practical Novel protected scope.
In description of the present utility model, " " center ", " on ", D score, " vertical ", " water it should be noted that term It is flat ", " interior ", the orientation of the instruction such as " outward " or position relationship be based on orientation shown in the drawings or position relationship, merely to just In description this utility model and simplified description, rather than indicate or imply that the device or element of indication there must be specifically side Position, with specific azimuth configuration and operation, therefore it is not intended that to restriction of the present utility model.
In description of the present utility model, it should be noted that unless otherwise clearly defined and limited, term " peace Dress ", " setting ", " being connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected, or be detachably connected, Or be integrally connected;Can be joined directly together, it is also possible to be indirectly connected to by intermediary, can also be two element internals Connection, for the ordinary skill in the art, can understand tool of the above-mentioned term in this utility model with concrete condition Body implication.
Fig. 1 is the composition schematic diagram of the liquid-level tracking device that this utility model is provided, as shown in figure 1, this utility model is carried For liquid-level tracking device can be from the liquid level in motion tracking container to be extracted, which includes control system and three shaft mechanical arms, The three shaft mechanicals arm includes orthogonal X arms(X-axis), Y arms(Y-axis), and Z arms(Z axis)(Do not show in figure), Z arms are vertical In the arm on ground, which can be movable along Y arms under motor M3 drivings;Y arms can drive lower edge X arm or so to move in motor M4 It is dynamic.Vertical axial is provided with screw mandrel 9 on Z arms, slide block 15, driving of the slide block 15 in motor M2 on the screw mandrel, is provided with Lower edge screw mandrel 15 is deceived oneself as well as others.Liquid-level tracking device also includes liquid level sensor 12, excellent in this utility model Select capacitance sensor as liquid level sensor 12, which is used to measure the liquid levels height in container, and this utility model preferably holds Device is test tube, in this utility model, in support(Do not show in figure)Upper to be provided with N*M test tube or SPE posts in rectangular, N and M is equal More than or equal to 2, test tube 16, test tube 17, test tube 18 and the SPE posts 19 for such as arranging in X direction, each test tube are used for storage not Same solution.Liquid-level tracking device also includes injection needle 8, and which is used to the solution of set metering is extracted from test tube and is expelled to In SPE posts, such as in SPE posts 19.Liquid-level tracking device also includes syringe pump 1, and the syringe pump 1 passes through pipeline and 8 phase of injection needle Even.Syringe pump 1 includes empty cylinder, piston and push-pull bar, and empty cylinder is preferably cylindrical drum, the first end connecting line of empty cylinder, the other end Opening, piston are placed in body, and piston is connected to push-pull bar, when push-pull bar band piston moves to empty cylinder bottom, liquid storage pipe 3 Interior liquid is discharged from injection needle, and when push-pull bar band piston is moved at the top of empty cylinder, injection needle suction from test tube is molten Liquid is in liquid storage pipe 3.The operation of push-pull bar is driven by motor M1.
In this utility model, a signal lead-out wire 13 of liquid level sensor 12 is connected to injection needle 8, liquid level sensor 12 Common port be connected to capacitor plate 14, the capacitor plate 14 is arranged under test tube, thus, injection needle 8 and capacitor plate 14 An electric capacity is formed, when injection needle 8 is moved down, when liquid level is touched, its capacitance changes such that it is able to which measurement is held Liquid level in device, it is generally the case that the diameter or lateral cross section of container is known, according to diameter or lateral cross section The volume of the solution in container can be calculated with liquid level, sectional area is multiplied with liquid level must liquor capacity.
Pressure transducer 4 is provided with quantitative liquid storage pipe 3 between injection needle and syringe pump, which is used to measure quantitative liquid storage The pressure of liquid pressure signal is converted into into the signal of telecommunication then sends control system in pipe 3.
The first electricity is additionally provided with pipeline between injection needle 8 and syringe pump 1 to valve 2, the second reversal valve 5 and the 3rd commutation Valve 6, the preferred solenoid directional control valve of the reversal valve, wherein, the first port of the first solenoid directional control valve 2 is connected to syringe pump, and second Port is connected to water pot or alcohol container, and the 3rd port is connected to the first port of the second solenoid directional control valve, the pipe by the road The preferably quantitative liquid storage pipe in road.First solenoid directional control valve 2 can make first in the presence of control signal S2 that control system is provided Port is connected with second port, so that water or ethanol are extracted from water pot or alcohol container, when needing to pipeline, injection needle, reversal valve When being cleaned, syringe pump 1 extracts water or ethanol from water pot or alcohol container.First solenoid directional control valve 2 is provided in control system Control signal S2 in the presence of first port can also connected with the 3rd port, with extract from container solution or note be put into In SPE posts.The first port of the second solenoid directional control valve 5 is connected to the 3rd port of the first solenoid directional control valve 2, the second end by the road Mouth is connected to nitrogen pot, and by pipeline connection in the first port of the 3rd electromagnetic valve 6, the second solenoid directional control valve 5 exists for the 3rd port In the presence of control signal S3 that control system is provided, first port can be made to connect with second port, to note from nitrogen pot Enter nitrogen.Second solenoid directional control valve 5 can also make first port and the 3rd in the presence of control signal S3 that control system is provided Port connects, so that pipeline is connected with injection needle.The second port of the 3rd solenoid directional control valve 6 is connected to the external world, the 3rd port Jing Liquid storage pipe 3 is communicated in injection needle 8, and the 3rd solenoid directional control valve 6 can be made in the presence of control signal S4 that control system is provided First port is connected with second port with from ambient inlet air.3rd solenoid directional control valve 6 is believed in the control that control system is provided In the presence of number S4, first port and the 3rd port can be made to connect so that pipeline is connected with injection needle.
The schematic diagram of the injection needle that Fig. 2 is provided for this utility model, as shown in Fig. 2 injection needle is preferably successively by axial phase First steel pipe 81 and the second steel pipe with second external diameter and the second internal diameter with the first overall diameter and the first internal diameter of connection 82, first external diameter is bigger than second external diameter, and so as to form step in connection, second external diameter is slightly less than the first internal diameter, be easy to by The first end of the second steel pipe is inserted into the second end of the first steel pipe.Sealing ring 83 is provided with step.The first of first steel pipe End is provided with the first reinforcing sleeve 84, and first sleeve 84 is connected with attachment means 85, and attachment means 85 are for injection needle is connected On slide block 15.Second end (free end) of the second steel pipe 81 forms inclined-plane to form needle point, facilitates insertion into solid phase extraction post In the through hole of sealing-plug.First steel pipe 82 is prepared using high strength steel, and the second steel pipe is standby using the white steel of high tenacity, and makes first The external diameter of steel pipe is bigger than the external diameter of the first steel pipe, thus, make injection needle have high intensity and high tenacity concurrently, so as to prevent injection needle from rolling over It is disconnected.
Fig. 3 is the schematic diagram of the injection needle that this utility model is provided and Solid-Phase Extraction, as shown in figure 3, solid-phase extraction column (SPE)19 sealing-plugs 192 for including bottle 191 and the bottleneck for sealed bottle body, sealing-plug central authorities are axially disposed through hole, The bottle lower end is provided with liquid receiving mouth 193, and bottle mouth position is provided with bulge loop.When injection needle penetrates the through hole in sealing-plug, by When the step of injection needle props up closure, the sealing ring 83 on injection needle just can be stuck in closure through hole, so that sealing Circle 83 occurs extruding to be played a part of to fully seal.
Fig. 4 is the built-up circuit figure of the control system of the liquid-level tracking device that this utility model is provided, as shown in figure 4, this The control system that utility model is provided includes:Controller, multiplexer 28, amplifier, A/D converter 29, isolator, it is used for The first driver of the first solenoid directional control valve 2 is driven, for driving second driver and use of the second solenoid directional control valve 5 of driving In the 3rd driver for driving the 3rd solenoid directional control valve 6.
Liquid level sensor 12 is used to track the liquid level information in container, and liquid level information is converted to telecommunications Breath, is then supplied to multiplexer 28.Pressure transducer 4 is used for the pressure for measuring liquid in liquid storage pipe 3, and by liquid Pressure conversion is electrical information, is then supplied to multiplexer 28.Multiplexer makes certain according to the signal that processor is provided Sensor is connected with the outfan of multiplexer, and the outfan of multiplexer is connected to proportional amplifier, proportional amplifier For being amplified to the signal that a certain sensor is provided.Exemplarily, proportional amplifier includes:Operational amplifier OP1, resistance R5, resistance R6 and resistance R4, the outfan Jing resistance R5 of multiplexer are connected to the end of oppisite phase of operational amplifier OP1, computing The outfan Jing resistance R6 of amplifier OP1 are connected to its inverting input;The in-phase end Jing resistance R4 connections of operational amplifier OP1 Yu Di.The outfan Jing A/D converters 21 of operational amplifier OP1 are connected to the input of phase inverter OP2, and phase inverter OP2's is defeated Go out the input that end is connected to processor, A/D converter is converted to number for the analogue signal for providing proportional amplifier Word signal, OP2 are anti-phase for carrying out to the signal that A/D converter 21 is provided, and are isolated.
For providing drive signal to solenoid directional control valve 2, exemplarily, the first driver includes transistor to first driver TR1, resistance R1 and diode D1, wherein, the base stage TR1 Jing resistance R1 of transistor TR1 are connected to controller, grounded emitter, Colelctor electrode connects the positive pole of diode D1.The negative pole of diode D1 connects power supply, the two ends of diode D1 and the line bag phase of relay J1 It is in parallel.The first end of the power supply of one termination AC220V of the normally opened contact of relay J1, one of another termination solenoid directional control valve 2 Terminal, another terminal of solenoid directional control valve 2 connect the second end of the power supply of AC220V.When needing solenoid directional control valve 2 to commutate, place Base stage offer one high potential signal of the reason device to transistor TR1, transistor turns, the relay J1's being connected with its colelctor electrode Line is surrounded by electric current and passes through, and its normally opened contact is closed, and solenoid directional control valve 2 is connected AC220V power supplys and commutated;Change when electromagnetism is not needed When commutating to valve 2, processor provides a low-potential signal to the base stage of transistor TR1, and transistor cutoff is connected with its colelctor electrode The line bag of relay J1 do not have electric current to pass through, its normally opened contact disconnects, and solenoid directional control valve 2 is disconnected with AC220V power supplys.
For providing drive signal to solenoid directional control valve 5, exemplarily, the second driver includes transistor to second driver The base stage TR2 Jing resistance R2 of TR2, resistance R2 and diode D2, wherein transistor are connected to controller, grounded emitter, current collection Pole connects the positive pole of diode D2.The negative pole of diode D2 connects power supply, and the two ends of diode D2 are in parallel with the line bag of relay J2. The first end of the power supply of one termination AC220V of the normally opened contact of relay J2, a terminal of another termination solenoid directional control valve 5, Second end of the power supply of another terminal connection AC220V of solenoid directional control valve 5.When needing solenoid directional control valve 5 to commutate, process Device provides a high potential signal, the line bag of the relay J2 that transistor TR2 is connected with its colelctor electrode to the base stage of transistor TR2 There is electric current to pass through, its normally opened contact is closed, solenoid directional control valve 5 is connected AC220V power supplys and commutated;When do not need solenoid directional control valve 5 During commutation, processor provides a low-potential signal to the base stage of transistor TR2, and transistor TR2 cut-offs are connected with its colelctor electrode The line bag of relay J2 does not have electric current to pass through, and its normally opened contact disconnects, and solenoid directional control valve 5 is disconnected with AC220V power supplys.
For providing drive signal to solenoid directional control valve 6, exemplarily, the 3rd driver includes transistor to 3rd driver The base stage TR3 Jing resistance R3 of TR3, resistance R3 and diode D3, wherein transistor are connected to controller, grounded emitter, current collection Pole connects the positive pole of diode D3.The negative pole of diode D3 connects power supply, and the two ends of diode D3 are in parallel with the line bag of relay J3. The first end of the power supply of one termination AC220V of the normally opened contact of relay J3, a terminal of another termination solenoid directional control valve 6, Second end of the power supply of another terminal connection AC220V of solenoid directional control valve 6.When needing solenoid directional control valve 6 to commutate, process Device provides a high potential signal, transistor TR3 conductings, the relay J3 being connected with its colelctor electrode to the base stage of transistor TR3 Line be surrounded by electric current and pass through, its normally opened contact is closed, and solenoid directional control valve 6 is connected AC220V power supplys and commutated;When not needing electromagnetism When reversal valve 6 commutates, processor provides a low-potential signal, transistor TR3 cut-offs, with its current collection to the base stage of transistor TR3 The line bag of extremely connected relay J3 does not have electric current to pass through, and its normally opened contact disconnects, and solenoid directional control valve 6 is broken with AC220V power supplys Open.
The control system that this utility model is provided also includes the stepper motor driver 21 for drive stepping motor M1, its It is connected with controller by photoisolator 20.Controller Jing isolators 22 provide control signal to stepper motor driver 21, 21 motor M1 of stepper motor driver is rotated forward or is inverted, so that injection pump work.More specifically, motor M1 drives note The rubbish plant that pushes away for penetrating pump is moved up and down in its empty cylinder with being further driven to piston, suction medium when moving down, when moving up Medium is discharged, the medium is water, ethanol, nitrogen or air.
Control system also includes the stepper motor driver 23 for drive stepping motor M2, and which passes through photoisolator 22 It is connected with controller.Controller Jing isolators 22 provide control signal, stepper motor driver 23 to stepper motor driver 23 Motor M2 is rotated forward or is inverted, so that slide block 15 is moved up and down in the driving lower edge screw mandrel of motor M2.Slide block 15 drives Injection needle 8 is moved up and down.As shown in figure 5, in this utility model, the length of screw mandrel is fixed value, by container in matrix in arrange In support(Do not show in figure)In, the position of screw mandrel and support is fixed, in other words, along short transverse, original position A of slide block 15 Fix with the position of the bottom C of container, slide block 15 drive injection needle 8 along screw mandrel move down when, the umber of pulse of motor Linearly increase increasing with the distance that moves down, and the step-length of pulsed drive motor to move down with movable slider 15 For, it is known that when injection needle 8 touches liquid level, i.e. during injection needle B` dynamic by B movements, by injection needle, capacitor plate and therebetween The value of the electric capacity that medium is formed changes, and capacitance sensor detects the change and the change of this electric capacity is converted into voltage Signal is then supplied to multiplexer 28, multiplexer 28 to be supplied to amplifier, amplifier amplify the voltage signal Signal afterwards is supplied to A/D converter 29, A/D converter 29 that the analogue signal for being received is converted to digital signal, Jing isolation After device is supplied to controller, controller to detect the signal, application program in memorizer is called, can be counted according to umber of pulse and step-length Calculate the distance that injection needle is moved down, slide block original position deducts and moves down distance and just obtain, height of liquid level inside container, the liquid in container Face is highly calculated the volume of the solution in container with the product of the cross section of container, it can be seen that, what this utility model was provided Liquid level tracks of device can track the liquid level of the liquid in container.
Control system also includes the stepper motor driver 25 for drive stepping motor M3, and which passes through photoisolator 24 It is connected with controller.Controller Jing isolators 24 provide control signal, stepper motor driver 25 to stepper motor driver 25 Motor M3 is rotated forward or is inverted, so that Z arms are movable along Y arms, further, Z arms is moved before and after carrying injection needle Move above the container of respective column.
Control system also includes the stepper motor driver 27 for drive stepping motor M4, and which passes through photoisolator 26 It is connected with controller.Controller Jing isolators 26 provide control signal, stepper motor driver 27 to stepper motor driver 27 Motor M4 is rotated forward or is inverted, so that Y arms can drive lower edge X to move left and right in motor M4, further, makes Y arms Z arms are carried, Z arms carry injection needle 8 and move to left above the container for moving to institute's corresponding line.
The liquid-level tracking device of this utility model offer is additionally included in regulated power supply, and regulated power supply is provided for giving each part Electric energy, arranges switch KH2 and KL2 between regulated power supply and AC220V power supplys, be to when control signal does not work, force to close Close power supply.
The liquid-level tracking device that this utility model is provided also includes memorizer 11, and which at least includes that ROM and RAM, ROM are used for Storage should program and data, RAM be used for store nonce.The liquid-level tracking device that this utility model is provided is also logical including first Letter module 10, which is wireless communication module, such as WIFI module, bluetooth module etc., and which is used for controller is carried out wirelessly with host computer Link.This utility model provide liquid-level tracking device also include second communication module 32, which is preferably network interface card, for it is upper Machine carries out wire link, and such host computer can be sent to controller by the first and second communication modules and be instructed, and from control Data are connect in device processed.Data that liquid level sensor 12 and pressure transducer are transmitted by controller packing framing by communication mould Block is sent to host computer, the calculating that host computer is also carried out mutually going according to these data.
The liquid-level tracking device that this utility model is provided also includes sound light alarming circuit, and which includes transistor TR4, resistance R7, resistance R8, speaker 30 and lamp LED, wherein, the base stage TR1 Jing resistance R7 of transistor TR4 are connected to controller, emitter stage Ground connection, colelctor electrode connect the negative pole of lamp LED.The positive pole Jing resistance R8 of lamp LED connect power supply.When the pressure in pipeline exceedes setting value When, processor provides a high potential signal to the base stage of transistor TR4, and transistor TR4 conductings, LED light, speaker 30 Sound.
Fig. 6 is the control process schematic diagram of the control system of the liquid-level tracking device that this utility model is provided, such as Fig. 6 institutes Show, the control process of the control system of liquid-level tracking device includes:
Initialize the control system of liquid-level tracking device, and the data of host computer are received by communication module, to motor M2, motor M3 and motor M3 provide drive signal, make three shaft mechanical arms run to the test tube position specified, and control system makes Z arms Top shoe 15 declines, and when the injection needle 8 carried in the central slide block of operation encounters liquid level, liquid level sensor sends a level signal To controller.
Controller receives this signal, and control syringe pump 1 extracts liquid, and adjusts the speed that injection needle declines on Z axis Degree, is allowed to be consistent with liquid level decrease speed, realizes that liquid level is followed.
When syringe pump is drawn into the set amount of experiment, can to controller one complete signal, then move in control slide block, it is sliding Block drives injection needle pull-up and control machinery arm runs to specified SPE posts position, then controls Z arm top shoes and move down, so that injection Pin declines the aperture at insertion SPE Zhu Zhugai centers, when the sealing ring at the injection needle step withstands the aperture on lid, syringe pump The liquid that injection has just been drawn from test tube.
Due to there is liquid residue in pipeline, so being mounted with second and the 3rd solenoid directional control valve 5 in pipeline connection With 6, the entrance of nitrogen or air is realized(Both optional one).When no nitrogen in laboratory, can be by syringe pump generation Air is carried out extracting for power source and then boosting, if laboratory has nitrogen, as long as accessing nitrogen(Nitrogen has in itself Pressure, need not be by injecting pumping).
Syringe pump also connects pure water or ethanol by the first solenoid directional control valve 2, because the liquid of suction does not enter syringe pump (If entering membership causes cross-contamination), liquid only can reach the 3rd solenoid directional control valve before in liquid storage pipe 3(Syringe pump is once inhaled It is 10ML to enter amount, is had between injection needle and three tunnel switching valves>The liquid storage pipe of 10ml is depositing the liquid of suction)If inhaling The liquid for entering does not enter syringe pump, then syringe pump because of the reciprocating motion that do not have medium can shorten injection in shell in suction The life-span of pump, therefore syringe pump can access pure water or ethanol by the first solenoid directional control valve 2, help aspirate, play lubrication Effect.
Due to there is large particulate matter in the liquid that some are tested, to the injection of SPE posts, flow rate of liquid is too fast may cause SPE Post is blocked, so adding pressure transducer 4 in the duct, when pressure exceedes setting value, instrument is returned by pressure transducer 4 Signal is reported to the police, and reaches safe handling device(Or instrument)Purpose.
In this utility model, due to by making liquid, gas are implanted sequentially in the liquid storage pipe between syringe pump and injection needle And solution, liquid and solution are separated using gas, solution is not entered syringe pump and is only temporarily stored in liquid storage pipe, and store up Liquid pipe is easy to be cleaned using liquid or gas, therefore avoids cross infection.
Above in association with accompanying drawing, operation principle of the present utility model is described in detail.But one of ordinary skill in the art It should be understood that description is only for explaining claims.But protection domain of the present utility model is not limited to description. Any those familiar with the art in the technical scope that this utility model is disclosed, the change that can readily occur in or Replace, should all cover within protection domain of the present utility model.Therefore, protection domain of the present utility model should be wanted with right The protection domain of book is asked to be defined.

Claims (3)

1. a kind of injection needle on mechanical arm type solid-phase extracting instrument, it is characterised in that include, for being axially connected successively First steel pipe and the second steel pipe with second external diameter and the second internal diameter of one overall diameter and the first internal diameter, first external diameter compare second External diameter is big, so as to form step in connection.
2. the injection needle on mechanical arm type solid-phase extracting instrument according to claim 1, it is characterised in that at step It is provided with sealing ring.
3. the injection needle on mechanical arm type solid-phase extracting instrument according to claim 2, it is characterised in that the second steel pipe Free end formed inclined-plane.
CN201621055779.8U 2016-09-14 2016-09-14 A kind of injection needle on mechanical arm type solid-phase extracting instrument Expired - Fee Related CN206045476U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106422413A (en) * 2016-09-14 2017-02-22 济南海能仪器股份有限公司 Injection needle used on mechanical arm type solid-phase extraction instrument

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106422413A (en) * 2016-09-14 2017-02-22 济南海能仪器股份有限公司 Injection needle used on mechanical arm type solid-phase extraction instrument

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Granted publication date: 20170329

Termination date: 20190914