CN206027158U - Processing apparatus before extraction module and liquid - Google Patents
Processing apparatus before extraction module and liquid Download PDFInfo
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- CN206027158U CN206027158U CN201621070129.0U CN201621070129U CN206027158U CN 206027158 U CN206027158 U CN 206027158U CN 201621070129 U CN201621070129 U CN 201621070129U CN 206027158 U CN206027158 U CN 206027158U
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Abstract
The utility model belongs to the technical field of the liquid component detection technique and specifically relates to a processing apparatus before extraction module and liquid is related to. The extraction module includes first cavity, first pore and second cavity including extraction module body, extraction module body from the bottom up in proper order, be equipped with first filter layer in the first pore, the inside second filter layer that is equipped with of first cavity, the inside swelling agent that all is equipped with of first filter layer and second filter layer, inside extractant layer and the porous filter element of being equipped with of second cavity, the diameter of first filter layer is less than the diameter of second filter layer, can one step of process that realizes liquid -liquid partition and solid -phase extraction. Processing apparatus before the liquid, including storage jar, transfer device and extraction module, the transfer device with the extraction is equipped with the filtration membrane who is used for filtering and supports between the module, only need that the one step of liquid -liquid partition that can realize the composition that awaits measuring of liquid sample extracts, solid -phase extraction purification, microporous membrane filtration, contain the transfer of the liquid sample of the composition that awaits measuring the institute in steps.
Description
Technical field
This utility model is related to liquid ingredient analysis technical field, more particularly, to a kind of extraction module and liquid preprocessing
Device.
Background technology
Processing mode before the detection of traditional liquid sample generally has sampling, sample preparation, weighing, liquid liquid distribution extraction
Take, solid extracting agent purification, sample filtering, sample transfer etc. step.These steps are all independent step-by-step operations at present:Example
Such as, after liquid sample sampling, sample preparation, weighing step are completed, a single utensil and step is needed to carry out liquid liquid point
With extraction, then change another utensil into or the step of equipment carries out Solid phase extraction, subsequently need using in addition
Equipment and utensil the step of carry out sample filtering, final sample transfer is also the same.
Wherein, current liquid liquid distribution extraction needs special liquid liquid distribution vial, by water and immiscible with water
Then solvent concussion, standing, layering release lower floor by valve, complete assigning process;Also to have been reported that liquid is carried out using kieselguhr
Liquid distributes.The shortcoming of above two method is all to need to complete using single utensil, can not be merged together with the step of other
Shi Jinhang, needs to expend substantial amounts of organic solvent, and the subsequent step that typically will also have concentrating under reduced pressure can just be completed.
Solid-Phase Extraction step is most commonly used that purifying step at present.And current Solid-Phase Extraction step is that solid extracting agent is filled out
Be attached in the pipe of syringe shape, vacuum state is caused using vacuum pump from below to make liquid carry sample by Solid-Phase Extraction
Agent, completes solid phase extraction procedure.Need to configure special vacuum pump and cavity device completes the step, it is impossible to other steps
Fusion is completed together.Or the pipe of syringe shape is not used, solid extracting agent is applied directly to into fluid sample to be measured directly
Interior, suck up impurity, but a disadvantage is that after effect of extracting is undesirable, and extraction step is completed, also have to have a filtration
Or solid extracting agent is separated with the sample after purification the step of centrifugation.
Current sample filtering step is that the liquid of testing sample is transferred to syringe or similar using special utensil
In the pipe of type effect, the sample in pressure injector is promoted using piston rod, make sample through the filter for being installed to syringe bottom
Film, reaches the purpose of filtration.Finally again the sample for having filtered is transferred in corresponding vial.
The pre-treatment of current liquid sample all steps (liquid-liquid extraction, Solid phase extraction, sample filtering,
Sample is shifted) all separately complete, step is cumbersome, and easily pollutes during filtering, purifying and shifting molten
Agent, so that have that testing result is inaccurate;And step is more, need the special implement for using also many, and structure
Complexity, so that the amount of the organic solvent for consuming is also more, the stability, accuracy to testing result, and the discharge of nuisance
Also it is bigger.
Utility model content
The purpose of this utility model is the extraction module and liquid preprocessing device for providing, to solve to deposit in prior art
Complex operation step, testing result is inaccurate, baroque technical problem.
This utility model provide extraction module, including extraction module body, the extraction module body from top to bottom according to
It is secondary including the first cavity, the first duct and the second cavity;
It is provided with the first filter layer in first duct, first cavity inside is provided with the second filter layer, described first
Extender is equipped with inside filter layer and the second filter layer, forms the filter for meeting water seal;
The second described cavity inside is sequentially provided with extraction oxidant layer and porous filter disc from top to bottom;
Diameter of the diameter of the first described filter layer less than second filter layer.
Further, the bottom of second filter layer is designed to trigonal pyramidal structure, collects can organic solvent layer.
Further, guide frame is provided with the outside of the extraction module body, rise and lead in extraction module moving process
To effect.
Further, the bottom of the extraction module body is arranged to trigonal pyramidal structure, and organic solvent layer can be made to converge
Collection.
Further, sealing structure is additionally provided with the outside of the extraction module body, make extraction module be inserted into container
Can be sealed by sealing structure when internal.
Further, collecting pipe, and the collecting pipe and the extraction mould are provided with the top of the extraction module body
Block body is integral type structure.
This utility model also provides a kind of liquid preprocessing device, including storage tank, transfer device and the extraction module,
The transfer device and the extraction module clamping, the extraction module is extend into inside the storage tank, in the storage tank
Organic solvent and water is had been injected into, organic solvent and water can not dissolve each other and be layered;Made inside storage tank by pressing transfer device
Upper strata organic solvent through extraction module, continue pressing, water layer touch meet water seal the first filter layer and second filter
During layer, the first filter layer and the second filter layer are blocked, and aqueous solution cannot then pass through, and be easy to the organic solvent containing composition to be measured
Liquid is shifted.
Further, the microporous filter for filtering and supporting is provided between the transfer device and the extraction module
Film, the organic solvent after being further separated by filtration make the testing result of organic solvent collected more accurate.
Further, the bottom of the transfer device is arranged to trigonal pyramidal structure, it is to avoid the organic solvent after filtration is blocked up
Plug is in transfer device bottom, and uses cooperatively with the top of the extraction module, further avoids micropore filtering film from blocking.
Further, the inside of the transfer device is additionally provided with the second duct, the duct of second duct side with
First duct is arranged on the same line, is easy to the outflow of organic solvent.
Further, storage lid is additionally provided with the storage tank, and the storage lid is connected using screw thread with the storage tank
Connect.
The beneficial effects of the utility model are:
The extraction module that this utility model is provided is by the first filter layer, the second filter layer, extraction oxidant layer and porous filter disc
Setting can reach the effect for blocking water, purify and filtering;Organic solvent first passes through the second filter layer, by oarse-grained impurity mistake
Filter, then pass through the first filter layer again, it is to avoid impurity blocks the first filter layer, due to containing expansion inside the second filter layer
Agent, can block the space inside the second filter layer, pass through aqueous solution difference, convenient transfer organic solvent, complete liquid extraction
Take process;When the extender in the second filter layer does not have enough time to work, aqueous solution enters the first filter layer, due to
The diameter of one filter layer is smaller, and aperture quantity is less, and the extender in the first filter layer is easier to block aqueous solution, from
And aqueous solution thoroughly can be sealed, extraction oxidant layer cannot be entered into completely;Then by extracting oxidant layer and porous filter disc, make
It can a step realize the distribution of liquid liquid, the process of Solid-Phase Extraction, operating procedure is simple, only need to a utensil by complete above-mentioned
Step.
The liquid preprocessing device that this utility model is provided, can realize filtration and the transfer step of sample with a step,
And by carrying out multiple times of filtration to organic solvent, so as to get organic solvent composition detection result it is more accurate.
The extraction module and sample transfer device that this utility model is provided is used cooperatively and can complete liquid liquid point with a step
With, Solid-Phase Extraction, sample filtering, sample transfer process.
Description of the drawings
In order to be illustrated more clearly that this utility model specific embodiment or technical scheme of the prior art, below will be right
Needed for specific embodiment or description of the prior art, accompanying drawing to be used is briefly described, it should be apparent that, describe below
In accompanying drawing be some embodiments of the present utility model, for those of ordinary skill in the art, do not paying creativeness
On the premise of work, can be with according to these other accompanying drawings of accompanying drawings acquisition.
Fig. 1 is the structural representation of the extraction module that this utility model embodiment one is provided;
Fig. 2 is the structural representation of the liquid preprocessing device that this utility model embodiment two is provided;
Fig. 3 is the exploded view of the liquid preprocessing device described in Fig. 2;
Fig. 4 is the structural representation of the extraction module that this utility model embodiment three is provided.
Reference:
1- transfer devices;2- filter membranes;3- extracts module body;
4- storage tanks;5- guide frames;The second ducts of 11-;
The first ducts of 31-;32- sealing structures;The first cavitys of 33-;
34- pallets;The second cavitys of 35-;41- storage lids;
The first filter layers of 311-;The second filter layers of 331-;351- porous filter discs;
352- extracts oxidant layer;361- collecting pipes.
Specific embodiment
The technical solution of the utility model is clearly and completely described below in conjunction with accompanying drawing, it is clear that described
Embodiment is a part of embodiment of this utility model, rather than the embodiment of whole.Based on the embodiment in this utility model, this
The every other embodiment obtained under the premise of creative work is not made by field those of ordinary skill, belongs to practical
Novel protected scope.
In description of the present utility model, it should be noted that term " " center ", " on ", D score, "left", "right", " perpendicular
Directly ", the orientation of the instruction such as " level ", " interior ", " outward " or position relationship are, based on orientation shown in the drawings or position relationship, to be only
For the ease of describe this utility model and simplify description, rather than indicate or imply indication device or element must have it is specific
Orientation, with specific azimuth configuration and operation, therefore it is not intended that to restriction of the present utility model.Additionally, term " the
One ", " second ", " the 3rd " are only used for describing purpose, and it is not intended that indicating or implying relative importance.
In description of the present utility model, it should be noted that unless otherwise clearly defined and limited, term " peace
Dress ", " being connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected, or be detachably connected, or integratedly
Connection;Can be mechanically connected, or electrically connect;Can be joined directly together, it is also possible to be indirectly connected to by intermediary,
It can be the connection of two element internals.For the ordinary skill in the art, above-mentioned art can be understood with concrete condition
Concrete meaning of the language in this utility model.
This utility model provide extraction module, including extraction module body, the extraction module body from top to bottom according to
It is secondary including the first cavity, the first duct and the second cavity;The first filter layer is provided with first duct, in first cavity
Portion is provided with the second filter layer, is equipped with extender inside first filter layer and the second filter layer, forms the mistake for meeting water seal
Filter disc, the filter can be by organic solvents, once contacting aqueous solution, the extender in the filter expands rapidly, blocks
Space in filter, prevents aqueous solution from passing through;The second described cavity inside be sequentially provided with from top to bottom extraction oxidant layer and
Porous filter disc, can reach the effect for blocking water, purify and filtering, can a step realize liquid liquid distribution and Solid-Phase Extraction process;
Diameter of the diameter of the first filter layer less than the second filter layer.
The extraction module can be reached by the setting of the first filter layer, the second filter layer, extraction oxidant layer and porous filter disc
The effect for blocking water, purify and filtering, can a step realize liquid liquid distribution and Solid-Phase Extraction process.
Embodiment 1
Fig. 1 is the structural representation of the extraction module that this utility model embodiment one is provided;As shown in figure 1, the present embodiment
The extraction module of offer, including extraction module body 3, extraction module body 3 includes the first cavity 33, first from top to bottom successively
Duct 31 and the second cavity 35;The first filter layer 311 is provided with first duct 31, inside the first cavity 33, the second filter layer is provided with
331, extender is equipped with inside the first filter layer 311 and the second filter layer 331, forms the filter for meeting water seal, the filtration
Piece can be by organic solvent, once contacting aqueous solution, the extender in the filter expands rapidly, blocks the sky in filter
Gap, prevents aqueous solution from passing through;It is sequentially provided with extraction oxidant layer 352 and porous filter disc 351, energy inside second cavity 35 from top to bottom
Enough reach the effect for blocking water, purify and filtering, can a step realize liquid liquid distribution and Solid-Phase Extraction process;First filter layer
Diameter of 311 diameter less than the second filter layer 331.
The extraction module is by the first filter layer 311, the second filter layer 331, extraction oxidant layer 352 and porous filter disc 351
Setting can reach the effect for blocking water, purify and filtering, can a step realize liquid liquid distribution and Solid-Phase Extraction process so that extract
The step of taking is simpler;And double-layer filter structure is provided with, and make extraction process more smooth, the organic solvent after extraction is miscellaneous
Matter is less.
During using extraction module, organic solvent first passes through the second filter layer 331, oarse-grained contaminant filter is fallen, then
Pass through the first filter layer 311 again, it is to avoid impurity blocks the first filter layer 311, due to containing expansion inside the second filter layer 331
Agent, can block the space inside the second filter layer 331, pass through aqueous solution difference, convenient transfer organic solvent, complete liquid
Extraction process;Sometimes accidental situation is there is also, aqueous solution passes through the second filter layer 331, the extender in the second filter layer 331
Do not have enough time to work, or aqueous solution, when permeating from 331 side of the second filter layer, aqueous solution enters the first filter layer
311, as the diameter of the first filter layer 311 is smaller, aperture quantity is less, and the extender in the first filter layer 311 is more
Aqueous solution is easily blocked, so as to aqueous solution thoroughly can be sealed, extraction oxidant layer 352 cannot be entered into completely.
It should be noted that compared to the first filter layer 311, the second filter layer 331, extraction oxidant layer 352 and porous filter disc
351 are located in same cavity, when extraction oxidant layer 352 is placed, understand some little particle absorption in extraction mould due to due to electrostatic
On the cavity inner wall of block, when the first filter layer 311 and the second filter layer 331 is installed, little particle can be clipped in the first filter layer 311
And second filter layer 331 side and cavity inner wall between, be easily caused aqueous solution from side permeate, mix with organic solvent, make
Into extraction failure, the design then solves this problem, aqueous solution is thoroughly sealed, and cannot enter into extractant completely
In layer 352.
Also, it should be noted that in installation process, the first filter layer 311 is first installed, then the second filter layer 331 is installed,
Then block inversion will be extracted, and extraction oxidant layer 352 and porous filter disc 351 be loaded successively from 35 porch of the second cavity, will extraction
Oxidant layer 352 is fixed.
Also, it should be noted that the bottom of the second filter layer 331 is designed to trigonal pyramidal structure, the triangle with extraction module
Pyramidal structure coordinates, and forms the funnel shaped for standing upside down, facilitates the organic layer on upper strata to collect, it is ensured that all of organic layer can be passed through
Second filter layer 331, without residual;The area that the second filter layer 331 is contacted with solution can also be increased simultaneously, upper strata is had
The absorbability of the particulate contaminant in the filter capacity and organic layer of machine layer is bigger, more difficult blocking.
In the alternative of the present embodiment, on the outside of extraction module body 3, guide frame is provided with, is moved through in extraction module
The effect that Cheng Zhongqi is oriented to, will not be crooked when extraction module is descending;And by guide frame be designed to make extraction mould
It is thinner that block is designed, and the material of consumption is less, not only material-saving also profit and environmental protection.
In the alternative of the present embodiment, the bottom for extracting module body 3 is arranged to trigonal pyramidal structure, can make organic
Solvent layer collects.
It should be noted that 3 top of extraction module body scribbles nonskid coating, when using extraction module, play anti-skidding
Effect.
In the alternative of the present embodiment, the outside for extracting module body 3 is additionally provided with sealing structure 32, wherein, sealing
Being provided in of structure 32 is extracted module and can be sealed by sealing structure 32 when being inserted into inside container;
Sealing structure 32 can be set to sealing ring or sealing gasket;
Wherein, sealing ring is set to HNBR hydrogenated nitrile-butadiene rubber sealing rings, SIL silicone rubber O-rings, EPDM EPDMs
Rubber seal, CR neoprene packings circle or ACM acrylate rubber seal etc..
In the alternative of the present embodiment, porous filter disc 351 arranges polyethylene filter, for fixed extractor agent.
In the alternative of the present embodiment, the top of the first cavity 33 is also configured to trigonal pyramidal structure, it is to avoid after filtration
Organic solvent be blocked in inside the first cavity 33.
Embodiment 2
Fig. 2 is the structural representation of the liquid preprocessing device that this utility model embodiment two is provided;Liquid of the Fig. 3 for Fig. 2
The exploded view of body pretreating device;As Figure 2-3, the fluid sample pretreating device that the present embodiment is provided, including storage tank
4th, transfer device 1 and extraction module, transfer device 1 and extraction module clamping, extraction module extend into inside storage tank 4, store
Organic solvent and water are had been injected in tank 4, organic solvent and water can not dissolve each other and be layered;Storage is made by pressing transfer device 1
Upper strata organic solvent inside tank 4 continues pressing through extraction module, and water layer touches the first filter layer 311 for meeting water seal
During with the second filter layer 331, the first filter layer 311 and the second filter layer 331 are blocked, and aqueous solution cannot then pass through, and be easy to contain
There is the organic solvent liquid transfer of composition to be measured;Can a step just realize liquid-liquid extraction, Solid phase extraction, sample filtering, sample
Four steps of product transfer.
In the alternative of the present embodiment, it is provided between transfer device 1 and extraction module micro- for what is filtered and support
Hole filter membrane 2, is filtered for the organic solvent after further to being separated with aqueous solution;
Wherein, the aperture inside filter membrane 2 is arranged on 0.2-0.5 microns;
Therefore, by multiple times of filtration organic solvent, the testing result of organic solvent collected can be made more accurate.
In the alternative of the present embodiment, the bottom of transfer device 1 is arranged to trigonal pyramidal structure, it is to avoid having after filtration
Machine solvent is blocked in 1 bottom of transfer device, and uses cooperatively with the trigonal pyramidal structure at the top of extraction module body 3, more enters
The micropore filtering film 2 that avoids of one step is blocked.
In the alternative of the present embodiment, the inside of transfer device 1 is additionally provided with the second duct 11,11 side of the second duct
Duct with extraction module body 3 inside the first duct 31 arrange on the same line, be easy to the outflow of organic solvent.
It should be noted that the outer wall of transfer device 1 scribbles nonskid coating, and when using liquid preprocessing device, can
Prevent liquid preprocessing device from sliding.
Also, it should be noted that the top of transfer device 1 is provided with spongy body, user is in pressing liquid preprocessing device
When it is relatively comfortable.
In the alternative of the present embodiment, storage lid 41 on storage tank 4, is additionally provided with, storage lid 41 is adopted with storage tank 4
Threaded connection, only need to be inserted into the extraction module for preparing and transfer device 1 inside storage tank 44 during transfer solution and be pressed,
Organic solvent is then extruded.
In the alternative of the present embodiment, the side of transfer device 1 is additionally provided with pallet 34, and pallet 34 and the second duct
The duct of 11 opposite sides is correspondingly arranged.
Embodiment 3
Fig. 4 is the structural representation of the extraction module that this utility model embodiment three is provided;As shown in figure 4, the present embodiment
The extraction module of offer, including extraction module body 3, extraction module body 3 includes the first cavity 33, first from top to bottom successively
Duct 31 and the second cavity 35;The first filter layer 311 is provided with first duct 31, inside the first cavity 33, the second filter layer is provided with
331, extender is equipped with inside the first filter layer 311 and the second filter layer 331, forms the filter for meeting water seal, the filtration
Piece can be by organic solvent, once contacting aqueous solution, the extender in the filter expands rapidly, blocks the sky in filter
Gap, prevents aqueous solution from passing through;It is sequentially provided with extraction oxidant layer 352 and porous filter disc 351, energy inside second cavity 35 from top to bottom
Enough reach the effect for blocking water, purify and filtering, can a step realize liquid liquid distribution and Solid-Phase Extraction process;First filter layer
Diameter of 311 diameter less than the second filter layer 331.
In the alternative of the present embodiment, the top for extracting module body 3 is provided with collecting pipe 361, and collecting pipe 361 with
Extraction module body 3 is integral type structure.
When extracting module and extending into inside storage tank, in storage tank, have been injected into organic solvent and water, organic solvent and
Water can not dissolve each other and be layered;The upper strata organic solvent exposure second inside storage tank is made by pressing organic solvent collecting pipe 361
Filter layer 331 and the first filter layer 311, the second filter layer 331 and the first filter layer 311 are the internal filter of the porous containing extender
Piece 351, organic solvent can pass through the second filter layer 331 and the first filter layer 311, enter into extraction oxidant layer 352 and many
Hole filter disc 351, the impurity in organic solvent are extracted agent absorption, and last organic solvent layer enters into organic solvent collecting pipe 361
It is interior;Continue pressing, when water layer touches the second filter layer 331 and the first filter layer 311 for meeting water seal, the second filter layer 331
Blocked with the first filter layer 311, aqueous solution cannot then pass through;Can a step just realize liquid-liquid extraction, Solid phase extraction,
Sample filtering, four steps of sample transfer.
Finally it should be noted that:More than each embodiment only illustrating the technical solution of the utility model, rather than to which
Limit;Although being described in detail to this utility model with reference to foregoing embodiments, one of ordinary skill in the art should
Work as understanding:Which still can be modified to the technical scheme described in foregoing embodiments, or to which part or complete
Portion's technical characteristic carries out equivalent;And these modifications or replacement, do not make the essence of appropriate technical solution depart from this practicality
The scope of new each embodiment technical scheme.
Claims (10)
1. it is a kind of to extract module, it is characterised in that to include:Extraction module body, the extraction module body is from top to bottom successively
Including the first cavity, the first duct and the second cavity;
The first filter layer is provided with first duct, and first cavity inside is provided with the second filter layer, and described first filters
Extender is equipped with inside layer and the second filter layer;
The second described cavity inside is sequentially provided with extraction oxidant layer and porous filter disc from top to bottom;
Diameter of the diameter of the first described filter layer less than second filter layer.
2. extraction module according to claim 1, it is characterised in that the bottom of second filter layer is designed to pyrometric cone
Shape structure.
3. extraction module according to claim 1, it is characterised in that be provided with guiding knot on the outside of the extraction module body
Structure.
4. the extraction module according to any one of claim 1-3, it is characterised in that the bottom of the extraction module body sets
It is set to trigonal pyramidal structure.
5. the extraction module according to any one of claim 1-3, it is characterised in that the outside of the extraction module body is also
It is provided with sealing structure.
6. the extraction module according to any one of claim 1-3, it is characterised in that set at the top of the extraction module body
Collecting pipe is equipped with, and the collecting pipe is integral type structure with the extraction module body.
7. a kind of liquid preprocessing device, it is characterised in that including storage tank, transfer device and any one of claim 1-6
Described extraction module;
The transfer device is extend into inside the storage tank with the extraction module clamping, the extraction module.
8. liquid preprocessing device according to claim 7, it is characterised in that the transfer device and the extraction module
Between be provided with filter membrane for filtering and supporting.
9. the liquid preprocessing device according to claim 7 or 8, it is characterised in that the bottom of the transfer device is arranged
Into trigonal pyramidal structure.
10. the liquid preprocessing device according to claim 7 or 8, it is characterised in that the inside of the transfer device also sets
The second duct is equipped with, the duct of second duct side is arranged on the same line with first duct.
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CN108333011A (en) * | 2018-02-12 | 2018-07-27 | 云南中烟工业有限责任公司 | A kind of device of achievable sample high throughput processing |
CN108489778A (en) * | 2018-02-12 | 2018-09-04 | 云南中烟工业有限责任公司 | A kind of high-throughput Continuous Flow Analysis method for potassium content in tobacco gene editor's material |
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WO2023216591A1 (en) * | 2022-05-11 | 2023-11-16 | 美羅醫藥科技有限公司 | Purification separation column for clinical detection pretreatment, pretreatment apparatus, pretreatment method and application |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108333011A (en) * | 2018-02-12 | 2018-07-27 | 云南中烟工业有限责任公司 | A kind of device of achievable sample high throughput processing |
CN108489778A (en) * | 2018-02-12 | 2018-09-04 | 云南中烟工业有限责任公司 | A kind of high-throughput Continuous Flow Analysis method for potassium content in tobacco gene editor's material |
CN112881553A (en) * | 2021-01-14 | 2021-06-01 | 中国科学院生态环境研究中心 | Extraction method of perfluoro and polyfluoro compounds |
CN112881553B (en) * | 2021-01-14 | 2023-01-13 | 中国科学院生态环境研究中心 | Extraction method of perfluoro and polyfluoro compounds |
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WO2023216591A1 (en) * | 2022-05-11 | 2023-11-16 | 美羅醫藥科技有限公司 | Purification separation column for clinical detection pretreatment, pretreatment apparatus, pretreatment method and application |
WO2023216590A1 (en) * | 2022-05-11 | 2023-11-16 | 美羅醫藥科技有限公司 | Extraction separation column for liquid-liquid extraction, liquid-liquid extraction separation apparatus and method, and use |
CN115025518B (en) * | 2022-05-11 | 2024-04-12 | 美罗医药科技有限公司 | Extraction separation column for liquid-liquid extraction, liquid-liquid extraction separation device, separation method and application |
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