CN206019055U - A kind of cyclic ammonia water waste heat recovery unit - Google Patents

A kind of cyclic ammonia water waste heat recovery unit Download PDF

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Publication number
CN206019055U
CN206019055U CN201620847282.3U CN201620847282U CN206019055U CN 206019055 U CN206019055 U CN 206019055U CN 201620847282 U CN201620847282 U CN 201620847282U CN 206019055 U CN206019055 U CN 206019055U
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China
Prior art keywords
pipeline
unit
water pipeline
water
heat exchanger
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CN201620847282.3U
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Chinese (zh)
Inventor
刘明军
夏克盛
张红岩
韩世庆
苏盈贺
宋黎
王立群
曲丰远
陶海臣
谷禹庆
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Panasonic Appliances Air Conditioning and Refrigeration Dalian Co Ltd
Panasonic Appliances Refrigeration System Dalian Co Ltd
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Panasonic Appliances Refrigeration System Dalian Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y02A30/274Relating to heating, ventilation or air conditioning [HVAC] technologies using waste energy, e.g. from internal combustion engine
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems
    • Y02B30/625Absorption based systems combined with heat or power generation [CHP], e.g. trigeneration

Abstract

This utility model belongs to technical field of exhaust heat recovery equipment, propose a kind of cyclic ammonia water waste heat recovery unit, including lithium bromide absorption-type machine unit, heat exchanger and control device, ammonia circulation main pipeline is provided with tie point and the second branch road, flow regulating equipment is respectively arranged with tie point and the second branch road, flow regulating equipment is electrically connected with control device, tie point connects unit hot water line's import, second branch road connects heat exchanger the first pipeline import, and unit hot water line outlet and the first tube outlet of heat exchanger are connected with ammonia circulation main pipeline respectively;Under cooling condition, unit cold water pipeline is connected with outer cold water pipe road;Outside cooling water pipeline connects the second pipeline of unit cooling water pipeline and heat exchanger;Under heat pump working condition, unit cold water pipeline and primary cooler cooling circulating water pipeline communication, heating hot water pipeline connection the second pipeline of unit cooling water pipeline and heat exchanger.This utility model can realize the effectively utilizes of cyclic ammonia water waste heat, energy-saving and emission-reduction.

Description

A kind of cyclic ammonia water waste heat recovery unit
Technical field
This utility model belongs to technical field of exhaust heat recovery equipment, more particularly to a kind of heat exchange of cyclic ammonia water waste heat recovery Unit.
Background technology
Coking of coal with coal as raw material, completely cuts off under air conditionses in coke oven, is heated to 950 DEG C also known as coal high-temperature retorting Left and right, produces coke through high-temperature retorting, while obtaining coal gas, coal tar and reclaiming a kind of coal conversion work of other chemical products Skill.Raw gas temperature from carbonization chamber derivation, has up to 650~700 DEG C for preventing the chemical productss in raw coke oven gas from cracking Beneficial to the chemical productss reclaimed in raw coke oven gas, mitigate the blocking and corrosion of recovery process pipeline and equipment, reduce the negative of aerator Lotus and energy expenditure, safely and reasonably convey coal gas, and coal gas need to finally be cooled to 21 DEG C or so, and current cooling technique is mainly Sprayed in bridge tube and discharge using cyclic ammonia water, gas temperature is dropped to 83 DEG C or so, then entering back into primary cooler is carried out Cooling.Gas temperature accounts for the 36% of coke oven heat from 700 DEG C of heats for being reduced to 21 DEG C, and the cyclic ammonia water for wherein spraying absorbs Most of heat, temperature rise to 83 DEG C or so, enter mechanical settling tank cooling simultaneously and tar separation, and temperature is down to 73 DEG C of left sides The right side, is then sprayed by cyclic ammonia water pump circulation, and in the technique, cyclic ammonia water sensible heat main environment is distributed, and is not utilized, and Winter needs to heat, and summer primary cooler needs substantial amounts of 16 DEG C of cold water, if it is possible to effectively utilizes cyclic ammonia water waste heat summer system Cold heat supply in winter, can bring huge economic benefit for coke-oven plant, while realizing energy-saving and emission-reduction.
Content of the invention
For solving problem above, this utility model provides a kind of suction-type lithium bromide heat exchanger of cyclic ammonia water waste heat recovery Group, the unit can reclaim cyclic ammonia water waste heat in summer and produce 16 DEG C of cold water, and winter reclaims cyclic ammonia water residual heat heating, realizes following The effectively utilizes of ring ammonia waste heat, while coke-stove gas cooling technique can also be improved, improve yield, energy-saving and emission-reduction.
The technical scheme adopted for achieving the above object by this utility model is:Propose a kind of cyclic ammonia water machine waste heat recovery Group, including lithium bromide absorption-type machine unit, heat exchanger and control device, lithium bromide absorption-type machine unit includes generator, condenser, suction Device and vaporizer is received, and unit hot water line is provided with generator, unit cold water pipeline, condenser and suction is provided with vaporizer Receive in device and be arranged in series unit cooling water pipeline, heat exchanger is internally provided with the first pipeline and the second pipeline, ammonia circulation master Pipeline is provided with tie point and the second branch road, is respectively arranged with flow regulating equipment, flow on tie point and the second branch road Adjustment equipment is electrically connected with control device, and tie point connects unit hot water line's import, and the second branch road connects the first pipeline Import, unit hot water line outlet and the first tube outlet are connected with ammonia circulation main pipeline respectively;Under cooling condition, unit is cold Water lines are connected with outer cold water pipe road;Outside cooling water pipeline connection unit cooling water pipeline and the second pipeline;Heat pump working condition Under, unit cold water pipeline and primary cooler cooling circulating water pipeline communication, heating hot water pipeline connection unit cooling water pipeline and the Two pipelines.
The outside cooling water pipeline or heating hot water pipeline using parallel way connect respectively unit cooling water pipeline and Second pipeline.
The outside cooling water pipeline or heating hot water pipeline using series system be sequentially connected unit cooling water pipeline and Second pipeline.
The material corroded using resistance to cyclic ammonia water inside the generator and heat exchanger.
The lithium bromide absorption-type machine unit is with heat exchanger using integral structure or split-type structural.
The beneficial effects of the utility model are as follows:
1st, realize that the recovery of cyclic ammonia water waste heat, refrigeration meet process requirements, heat and meet heating demands;
2nd, reduce cyclic ammonia water spray temperature, improve the heat that cyclic ammonia water absorbs high temperature crude-gas sensible heat;
3rd, reduce raw gas temperature before primary cooler, mitigate primary cooler cooling load;
4th, improve cold-blast machine operating condition;
5th, increase the yield of chemical products.
Description of the drawings
Fig. 1 is the first cyclic ammonia water waste heat recovery heat-exchange unit flow chart of the present utility model;
Fig. 2 is second cyclic ammonia water waste heat recovery heat-exchange unit flow chart of the present utility model;
In figure:1- lithium bromide absorption-type machine units;11- generators;12- unit hot water lines, 13- condensers;14- absorbs Device, 15- unit cooling water pipelines;16- vaporizers, 17- unit cold water pipelines;2- heat exchangers, the first pipelines of 21-, 22- second pipes Road;3- cyclic ammonia water main pipelines, 31- tie points, the second branch roads of 32-;Cooling water pipeline or heating hot water pipeline, 5- outside 4- Outer cold water pipe road or primary cooler cooling circulating water pipeline, 6- valves.
Specific embodiment
Describe in detail with reference to the first utility model and accompanying drawing, but this utility model is not limited to be embodied as Example.
Embodiment 1:
As shown in figure 1, a kind of cyclic ammonia water waste heat recovery heat-exchange unit, including lithium bromide absorption type cooling and heating Double-working-condition unit 1st, heat exchanger 2 and connecting line, lithium bromide absorption type cooling and heating Double-working-condition unit include generator 11, condenser 13, absorber 14 With vaporizer 16, inside which, annexation is connected with condenser 13 for generator 11, and absorber 14 is connected with vaporizer 16;Wherein Absorber 14, generator 11 are circulated for lithium-bromide solution, i.e., the lithium bromide weak solution from absorber 14 out passes through pump and pipeline Enter generator 11 and be changed into lithium bromide concentrated solution, return absorber 14;Condenser 13, vaporizer 16 are followed for cold-producing medium water Ring, enters vaporizer 16 from the water as refrigerant out of condenser 13 through throttling arrangement.
Wherein, unit hot water line 12 is provided with generator 11, arranged by unit cold water pipeline 17 in vaporizer 16, cold Unit cooling water pipeline 15 has been arranged in series in condenser 13 and absorber 14, and heat exchanger 2 is internally provided with the first pipeline 21 and Two pipelines 22, ammonia circulation main pipeline 3 are provided with tie point 31 and the second branch road 32, in tie point 31 and the second branch road 32 Valve 6 is respectively arranged with, valve 6 is connected with control device, 12 import of the connection unit of tie point 31 hot water line, the second branch road 32 connection 21 imports of the first pipeline, unit hot water line 12 exports and the first pipeline 21 export respectively with ammonia circulation main pipeline 3 Connection;Under cooling condition or heat pump working condition, unit cold water pipeline 17 and outer cold water pipe road or primary cooler cooling circulating water pipeline 5 Connection;Outside cooling water pipeline or heating hot water pipeline 4 connect unit cooling water pipeline 15 and second respectively using parallel way Pipeline 22.
The unit can realize that by switching operation mode whole year is reclaimed to cyclic ammonia water waste heat, and there is refrigeration summer The season of demand carries out cooling condition operating, and cyclic ammonia water drives the waste heat recovery unit unit, from vaporizer produce 16 DEG C cold Water meets the cooling of primary cooler coal gas and uses;Winter carries out heat pump working condition operating and drives the waste heat recovery unit using cyclic ammonia water, steams Send out device and reclaim sub-cooled circulating water afterheat in primary cooler, heat is produced from absorber, condenser, as heating.In system Heat exchanger 2 is set and mainly meets cyclic ammonia water waste heat and refrigeration or the balance of heating demands, situation, is filled by control according to demand Put and flow-control of the flow regulating equipment realization to tie point and the second branch road cyclic ammonia water, cyclic ammonia water all can be passed through Generator, also can all be passed through heat exchanger, also can a part be passed through generator, another part and be passed through heat exchanger.The heat-exchange unit Interior generator, heat exchanger material and processing mode using the corrosion of resistance to cyclic ammonia water.
Generator is passed through with a cyclic ammonia water part, as a example by another part is passed through heat exchanger, unit in summer running is: Cyclic ammonia water is partly into generator 11 as the lithium-bromide solution in driving heat source heating generator, lithium-bromide solution concentration Thicken, vapor evaporates into condenser 13, in condenser 13, the cooled water cooling of refrigerant vapor is changed into water as refrigerant, water as refrigerant Vaporizer 16 is entered through throttling arrangement, the heat of water produces 16 DEG C of cold water in cryogen water evaporation absorption tube in vaporizer 16, made For primary cooler coal gas cooling use, in vaporizer 16 evaporate refrigerant vapor enter absorber 14 in, in absorber 14 by from The lithium bromide concentrated solution of generator absorbs, and lithium-bromide solution concentration is thinning, while rejecting heat to cooling water;Another part is followed Ring ammonia enters heat exchanger 2, and in heat exchanger 2, cyclic ammonia water is exchanged heat with cooling water;So cyclic ammonia water is through generator, heat exchanger Waste heat recovery is realized, 16 DEG C of cold water is produced and is met process requirements, while realizing cyclic ammonia water waste heat recovery.Unit winter operation mistake Cheng Wei:Cyclic ammonia water is partly into generator 11 as the lithium-bromide solution in driving heat source heating generator, and lithium bromide is molten Liquid concentration thickens, and vapor evaporates into condenser 13, in condenser 13 refrigerant vapor heated hot water cooling be changed into cryogen Water, water as refrigerant enter vaporizer 16 through throttling arrangement, from primary cooler stage casing in cryogen water evaporation absorption tube in vaporizer 16 The heat of cooling circulating water, the refrigerant vapor that evaporates in vaporizer 16 are entered in absorber 14, are come spontaneous in absorber 14 The lithium bromide concentrated solution of raw device absorbs, and lithium-bromide solution concentration is thinning, while rejecting heat to the hot water that heats;Another part is followed Ring ammonia enters heat exchanger 2, cyclic ammonia water and heating hot water heat exchange in heat exchanger 2;So cyclic ammonia water is through generator, heat exchange Device realizes that waste heat recovery, hot water preparing meet heating demands, while realizing cyclic ammonia water waste heat recovery.
Embodiment 2:
Second cyclic ammonia water waste heat recovery heat-exchange unit flow process of the present utility model is as shown in Fig. 2 the present embodiment and reality The main difference for applying example 1 is that entrance lithium bromide absorption-type machine unit is different with the cooling water of heat exchanger or heating hot water mode, The first utility model is parallel way, and second utility model is series system.In the present embodiment outside cooling water pipeline or Heating hot water pipeline 4 is sequentially connected the second pipeline 22 of unit cooling water pipeline 15 and heat exchanger using series system.

Claims (5)

1. a kind of cyclic ammonia water waste heat recovery unit, including lithium bromide absorption-type machine unit, heat exchanger and control device, lithium bromide is inhaled Receipts formula unit includes generator, condenser, absorber and vaporizer, is provided with unit hot water line, in vaporizer in generator Unit cold water pipeline is provided with, unit cooling water pipeline in condenser and absorber, has been arranged in series, heat exchanger is internally provided with First pipeline and the second pipeline, it is characterised in that:Ammonia circulation main pipeline is provided with tie point and the second branch road, tie point And second be respectively arranged with flow regulating equipment on branch road, flow regulating equipment is electrically connected with control device, and tie point connects Pick group hot water line's import, and the second branch road connects the first pipeline import, unit hot water line outlet and the first tube outlet point It is not connected with ammonia circulation main pipeline;Under cooling condition, unit cold water pipeline is connected with outer cold water pipe road;Outside cooling water pipe Road connection unit cooling water pipeline and the second pipeline;Under heat pump working condition, unit cold water pipeline and primary cooler cooling circulating water pipeline Connection, heating hot water pipeline connection unit cooling water pipeline and the second pipeline.
2. cyclic ammonia water waste heat recovery unit according to claim 1, it is characterised in that:The outside cooling water pipeline or Heating hot water pipeline connects unit cooling water pipeline and the second pipeline respectively using parallel way.
3. cyclic ammonia water waste heat recovery unit according to claim 1, it is characterised in that:The outside cooling water pipeline or Heating hot water pipeline is sequentially connected unit cooling water pipeline and the second pipeline using series system.
4. according to the arbitrary described cyclic ammonia water waste heat recovery unit of claim 1-3, it is characterised in that:The generator and change The carft of construction corroded using resistance to cyclic ammonia water inside hot device.
5. according to the arbitrary described cyclic ammonia water waste heat recovery unit of claim 1-3, it is characterised in that:The lithium bromide absorption Formula unit is with heat exchanger using integral structure or split-type structural.
CN201620847282.3U 2016-08-08 2016-08-08 A kind of cyclic ammonia water waste heat recovery unit Active CN206019055U (en)

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Application Number Priority Date Filing Date Title
CN201620847282.3U CN206019055U (en) 2016-08-08 2016-08-08 A kind of cyclic ammonia water waste heat recovery unit

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110081636A (en) * 2019-04-19 2019-08-02 东南大学 A kind of solution chiasma type ammonium hydroxide absorbs, reabsorbs formula heat pump system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110081636A (en) * 2019-04-19 2019-08-02 东南大学 A kind of solution chiasma type ammonium hydroxide absorbs, reabsorbs formula heat pump system

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