CN207019036U - The ultra-clean cold-heat combined system of discharge in coke-oven plant - Google Patents
The ultra-clean cold-heat combined system of discharge in coke-oven plant Download PDFInfo
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Abstract
本实用新型提供了一种焦化厂超净排放冷热联产系统,包括脱硝装置、余热锅炉、吸收塔、再生器,脱硝装置用于对烟气进行脱硝处理,余热锅炉用于回收烟气的余热,余热锅炉的烟气通过换热器为吸收式制冷机组提供热源,吸收塔、再生器用于对烟气进行深度脱硫、除尘及脱气溶胶处理。该焦化厂超净排放冷热联产系统,通过配置脱硝装置、余热锅炉、吸收塔、再生器等装置,深度回收及高效利用焦化炉烟气的余热,同时分级处理烟气,实现烟气超净排放,保证全年的节能环保收益。
The utility model provides a cogeneration system for ultra-clean discharge of coking plants, including a denitrification device, a waste heat boiler, an absorption tower, and a regenerator. Waste heat, the flue gas of the waste heat boiler provides heat source for the absorption refrigeration unit through the heat exchanger, and the absorption tower and regenerator are used for deep desulfurization, dust removal and degassing of the flue gas. The ultra-clean emission cooling and heating cogeneration system of the coking plant, through the configuration of denitrification devices, waste heat boilers, absorption towers, regenerators and other devices, deeply recovers and efficiently utilizes the waste heat of the coking furnace flue gas, and simultaneously treats the flue gas in stages to achieve ultra-thin flue gas Net emissions to ensure annual energy saving and environmental protection benefits.
Description
技术领域technical field
本实用新型涉及一种焦化厂超净排放冷热联产系统。The utility model relates to an ultra-clean discharge cooling and heating combined production system in a coking plant.
背景技术Background technique
能源是社会发展的重要物质基础,我国面对的能源问题主要体现在能源利用效率低、经济效益差、能源消费迅速增长、生态环境压力明显等方面。国家在“十一五”发展规划中,明确提出将节能减排作为一项长期的战略任务,在后续的发展规划中,不断提高和量化节能减排指标及加大财政投入。Energy is an important material basis for social development. The energy problems my country faces are mainly reflected in low energy utilization efficiency, poor economic benefits, rapid growth in energy consumption, and obvious pressure on the ecological environment. In the "Eleventh Five-Year" development plan, the country clearly stated that energy conservation and emission reduction should be regarded as a long-term strategic task. In the follow-up development plan, energy conservation and emission reduction indicators should be continuously improved and quantified, and financial investment should be increased.
焦炉是能量转换装置中高效率的热工设备,净效率高达87%~89%。这是因为炼焦过程不仅是一个较完善的能量转换过程,能产生优质的二次能源,而且焦炉本体设备经过一百余年的不断改进,在煤气燃烧、烟气热量利用、绝热等方面均较完善。但这并不能说明它没有节能的余地了。The coke oven is a high-efficiency thermal equipment in the energy conversion device, with a net efficiency as high as 87% to 89%. This is because the coking process is not only a relatively complete energy conversion process that can produce high-quality secondary energy, but also the coke oven itself has been continuously improved for more than 100 years, and has excellent performance in gas combustion, flue gas heat utilization, and heat insulation. more perfect. But this does not mean that it has no room for energy saving.
高效回收利用在炼焦过程中产生的余热资源是资源节约、环境友好的绿色焦化厂节能的主要方向和潜力所在,也是提高效率的主要途径之一。目前,已有的节能措施主要有:1、充分回收利用焦炉输出热;2、深入推广干熄焦技术,充分回收利用红焦余热;3、研发荒煤气余热的回收利用;4、焦炉烟道气余热的回收利用。Efficient recovery and utilization of waste heat resources generated in the coking process is the main direction and potential of energy conservation in resource-saving and environmentally friendly green coking plants, and it is also one of the main ways to improve efficiency. At present, the existing energy-saving measures mainly include: 1. Fully recycle and utilize the output heat of coke ovens; 2. In-depth promotion of CDQ technology and fully recycle and utilize red coke waste heat; 3. Research and development of waste gas waste heat recovery and utilization; 4. Coke oven Recycling of flue gas waste heat.
以上措施,均从某一方面,对焦炉的余热回收进行了研究,没有深入研究焦化厂能源的优化配置,因此不能实现节能的最大化和全面化。另外,现有的节能措施,对环保方面的研究有所欠缺,且目前环保产品往往增加耗能,不具备节能特性。The above measures are all from a certain aspect, the waste heat recovery of the coking oven has been studied, and the optimal allocation of energy in the coking plant has not been studied in depth, so the maximum and comprehensive energy saving cannot be realized. In addition, existing energy-saving measures lack research on environmental protection, and current environmental protection products often increase energy consumption and do not have energy-saving features.
实用新型内容Utility model content
本实用新型所要解决的技术问题是为了克服现有技术中的焦炉的余热回收措施的节能效率低且不兼具环保效果的缺陷,而提供一种焦化厂超净排放冷热联产系统。The technical problem to be solved by the utility model is to provide an ultra-clean emission combined cooling and heating system for a coking plant to overcome the defects of low energy saving efficiency and no environmental protection effect of the coke oven waste heat recovery measures in the prior art.
本实用新型通过以下技术方案解决上述技术问题:The utility model solves the above technical problems through the following technical solutions:
本实用新型提供了一种焦化厂超净排放冷热联产系统,包括:The utility model provides an ultra-clean discharge cooling and heating cogeneration system in a coking plant, comprising:
脱硝装置,所述脱硝装置具有脱硝烟气进口、脱硝烟气出口,烟气从所述脱硝烟气进口进入所述脱硝装置内并从所述脱硝烟气出口排出;A denitration device, the denitration device has a denitration flue gas inlet and a denitration flue gas outlet, and the flue gas enters the denitration device from the denitration flue gas inlet and is discharged from the denitration flue gas outlet;
余热锅炉,所述余热锅炉具有锅炉烟气进口、锅炉烟气出口、锅炉冷源进口、锅炉冷源出口,所述锅炉烟气进口、锅炉烟气出口之间通过锅炉烟气管道相连通,所述锅炉冷源进口、锅炉冷源出口之间通过锅炉冷源管道相连通,所述锅炉烟气管道中的烟气与所述锅炉冷源管道中的工质进行热交换,锅炉烟气进口与脱硝烟气出口相连通;Waste heat boiler, the waste heat boiler has a boiler flue gas inlet, a boiler flue gas outlet, a boiler cold source inlet, and a boiler cold source outlet, and the boiler flue gas inlet and boiler flue gas outlet are connected through boiler flue gas pipes, so The inlet of the boiler cold source and the outlet of the boiler cold source are connected through the boiler cold source pipeline, the flue gas in the boiler flue gas pipeline exchanges heat with the working medium in the boiler cold source pipeline, and the boiler flue gas inlet and The denitrification flue gas outlet is connected;
吸收塔,所述吸收塔具有吸收塔烟气进口、吸收塔烟气出口、吸收塔溶液进口、吸收塔溶液出口,所述吸收塔烟气进口与所述锅炉烟气出口相连通,所述吸收塔烟气进口位于所述吸收塔的下部并排放所述烟气进入所述吸收塔的内部,所述吸收塔烟气出口位于所述吸收塔的上部并排放所述烟气至外部,所述吸收塔溶液进口位于所述吸收塔的上部并向所述吸收塔内喷射吸湿溶液,所述吸收塔溶液出口位于所述吸收塔的下部并排出所述吸湿溶液;An absorption tower, the absorption tower has an absorption tower flue gas inlet, an absorption tower flue gas outlet, an absorption tower solution inlet, and an absorption tower solution outlet, the absorption tower flue gas inlet is connected with the boiler flue gas outlet, and the absorption tower The flue gas inlet of the absorption tower is located at the lower part of the absorption tower and discharges the flue gas into the interior of the absorption tower, the flue gas outlet of the absorption tower is located at the upper part of the absorption tower and discharges the flue gas to the outside, the The absorption tower solution inlet is located at the upper part of the absorption tower and sprays the hygroscopic solution into the absorption tower, and the absorption tower solution outlet is located at the lower part of the absorption tower and discharges the hygroscopic solution;
再生器,所述再生器具有再生器溶液进口、再生器溶液出口、二次蒸汽出口,所述再生器溶液进口与所述吸收塔溶液出口相连通,所述再生器溶液出口与所述吸收塔溶液进口相连通,所述二次蒸汽出口将所述吸湿溶液加热蒸发出的二次蒸汽排出。A regenerator, the regenerator has a regenerator solution inlet, a regenerator solution outlet, and a secondary steam outlet, the regenerator solution inlet is connected to the absorption tower solution outlet, and the regenerator solution outlet is connected to the absorption tower The solution inlet is connected, and the secondary steam outlet discharges the secondary steam generated by heating and evaporating the hygroscopic solution.
较佳地,所述焦化厂超净排放冷热联产系统还包括至少一个换热器,所述锅炉烟气出口和/或所述二次蒸汽出口与至少一个所述换热器相连通并热交换。Preferably, the ultra-clean emission cogeneration system of the coking plant further includes at least one heat exchanger, and the boiler flue gas outlet and/or the secondary steam outlet are connected to at least one of the heat exchangers and heat exchange.
较佳地,所述吸收塔还具有吸收塔冷源进口、吸收塔冷源出口,所述吸收塔冷源进口、吸收塔冷源出口之间通过吸收塔冷源管道相连通,所述吸收塔冷源管道内的工质与所述吸收塔的内部的工质进行热交换。Preferably, the absorption tower also has an absorption tower cold source inlet and an absorption tower cold source outlet, and the absorption tower cold source inlet and the absorption tower cold source outlet are connected through the absorption tower cold source pipeline, and the absorption tower The working fluid in the cold source pipeline exchanges heat with the working fluid inside the absorption tower.
较佳地,所述吸收塔冷源出口与至少一个换热器相连通并热交换。Preferably, the cold source outlet of the absorption tower communicates with at least one heat exchanger for heat exchange.
较佳地,所述再生器还具有再生器热源进口、再生器热源出口,所述再生器热源进口与所述再生器热源出口之间通过再生器热源管道相连通,所述再生器热源管道内的工质与所述再生器的内部的工质进行热交换,所述再生器热源进口与所述锅炉冷源出口相连通。Preferably, the regenerator also has a regenerator heat source inlet and a regenerator heat source outlet, and the regenerator heat source inlet and the regenerator heat source outlet are connected through a regenerator heat source pipeline, and the regenerator heat source pipeline The working fluid in the regenerator performs heat exchange with the working fluid inside the regenerator, and the heat source inlet of the regenerator is connected with the cold source outlet of the boiler.
较佳地,所述再生器热源出口与至少一个换热器相连通并热交换。Preferably, the heat source outlet of the regenerator communicates with at least one heat exchanger for heat exchange.
较佳地,所述焦化厂超净排放冷热联产系统还包括吸收式制冷机组,所述吸收式制冷机组与至少一个所述换热器相连通并热交换。Preferably, the ultra-clean emission combined cooling and heating system of the coking plant further includes an absorption refrigerating unit, and the absorption refrigerating unit communicates with at least one of the heat exchangers for heat exchange.
较佳地,所述焦化厂超净排放冷热联产系统还包括:Preferably, the ultra-clean emission combined cooling and heating system of the coking plant also includes:
第一换热器,所述第一换热器位于所述锅炉烟气出口与所述吸收塔烟气进口之间,所述第一换热器具有第一烟气进口、第一烟气出口、第一冷源进口、第一冷源出口,所述第一烟气进口、第一烟气出口之间通过第一烟气管道相连通,所述第一冷源进口、第一冷源出口之间通过第一冷源管道相连通,所述第一烟气管道内的烟气与所述第一冷源管道内的工质进行热交换,所述锅炉烟气出口与所述第一烟气进口相连通,所述第一烟气出口与所述吸收塔烟气进口相连通;The first heat exchanger, the first heat exchanger is located between the boiler flue gas outlet and the absorption tower flue gas inlet, the first heat exchanger has a first flue gas inlet and a first flue gas outlet , the first cold source inlet, the first cold source outlet, the first flue gas inlet and the first flue gas outlet are connected through the first flue gas pipe, the first cold source inlet, the first cold source outlet The flue gas in the first flue gas pipe exchanges heat with the working fluid in the first cold source pipe, and the boiler flue gas outlet and the first flue gas The gas inlet is connected, and the first flue gas outlet is connected with the flue gas inlet of the absorption tower;
第二换热器,所述第二换热器具有第二冷源进口、第二冷源出口、第二热源进口、第二热源出口,所述第二冷源进口、第二冷源出口之间通过第二冷源管道相连通,所述第二热源进口、第二热源出口之间通过第二热源管道相连通,所述第二冷源管道内的工质与所述第二热源管道内的工质进行热交换,所述第二热源进口与所述二次蒸汽出口相连通,所述第二热源出口与外部管路相连通,所述第二冷源进口、第二冷源出口、第一冷源出口之间相互连通;The second heat exchanger, the second heat exchanger has a second cold source inlet, a second cold source outlet, a second heat source inlet, and a second heat source outlet, the second cold source inlet, the second cold source outlet The two are connected through the second cold source pipeline, the second heat source inlet and the second heat source outlet are connected through the second heat source pipeline, and the working medium in the second cold source pipeline is connected with the second heat source pipeline. The working medium is used for heat exchange, the second heat source inlet is connected with the secondary steam outlet, the second heat source outlet is connected with the external pipeline, the second cold source inlet, the second cold source outlet, The outlets of the first cold source are connected to each other;
第三换热器,所述第三换热器具有第三冷源进口、第三冷源出口、第三热源进口、第三热源出口,所述第三冷源进口、第三冷源出口之间通过第三冷源管道相连通,所述第三热源进口、第三热源出口之间通过第三热源管道相连通,所述第三冷源管道内的工质与所述第三热源管道内的工质进行热交换,所述第三热源进口与所述二次蒸汽出口相连通,所述第三热源出口与所述第二热源出口相连通,所述第三冷源进口、第三冷源出口均与所述外部管路相连通。The third heat exchanger, the third heat exchanger has a third cold source inlet, a third cold source outlet, a third heat source inlet, and a third heat source outlet, and the third cold source inlet and the third cold source outlet The third heat source inlet and the third heat source outlet are connected through the third heat source pipeline, and the working medium in the third heat source pipeline is connected with the third heat source pipeline. The working medium is used for heat exchange, the third heat source inlet is connected with the secondary steam outlet, the third heat source outlet is connected with the second heat source outlet, the third cold source inlet, the third cold source The source outlets are all in communication with the external pipeline.
较佳地,所述吸收塔还具有吸收塔冷源进口、吸收塔冷源出口,所述吸收塔冷源进口、吸收塔冷源出口之间通过吸收塔冷源管道相连通,所述吸收塔冷源管道的工质与所述吸收塔的内部的工质进行热交换;Preferably, the absorption tower also has an absorption tower cold source inlet and an absorption tower cold source outlet, and the absorption tower cold source inlet and the absorption tower cold source outlet are connected through the absorption tower cold source pipeline, and the absorption tower The working fluid of the cold source pipeline exchanges heat with the internal working fluid of the absorption tower;
所述再生器还具有再生器热源进口、再生器热源出口,所述再生器热源进口与所述再生器热源出口之间通过再生器热源管道相连通,所述再生器热源管道内的工质与所述再生器的内部的工质进行热交换,所述再生器热源进口与所述锅炉冷源出口相连通;The regenerator also has a regenerator heat source inlet and a regenerator heat source outlet, and the regenerator heat source inlet and the regenerator heat source outlet are connected through a regenerator heat source pipeline, and the working fluid in the regenerator heat source pipeline and the The working fluid inside the regenerator performs heat exchange, and the heat source inlet of the regenerator is connected with the boiler cold source outlet;
所述焦化厂超净排放冷热联产系统还包括第四换热器,所述第四换热器具有第四冷源进口、第四冷源出口、第四热源进口、第四热源出口,所述第四冷源进口、第四冷源出口之间通过第四冷源管道相连通,所述第四热源进口、第四热源出口之间通过第四热源管道相连通,所述第四冷源管道内的工质与所述第四热源管道内的工质进行热交换,所述第四热源进口与所述再生器热源出口相连通,所述第四热源出口与所述外部管路相连通,所述第四冷源进口与所述吸收塔冷源出口相连通,所述第四冷源出口与所述第三冷源进口相连通。The ultra-clean emission cogeneration system of the coking plant also includes a fourth heat exchanger, the fourth heat exchanger has a fourth cold source inlet, a fourth cold source outlet, a fourth heat source inlet, and a fourth heat source outlet, The fourth cold source inlet and the fourth cold source outlet are connected through a fourth cold source pipeline, the fourth heat source inlet and the fourth heat source outlet are connected through a fourth heat source pipeline, and the fourth cold source The working fluid in the source pipeline exchanges heat with the working medium in the fourth heat source pipeline, the inlet of the fourth heat source is connected with the heat source outlet of the regenerator, and the outlet of the fourth heat source is connected with the external pipeline The inlet of the fourth cold source is connected with the outlet of the absorption tower cold source, and the outlet of the fourth cold source is connected with the inlet of the third cold source.
较佳地,所述焦化厂超净排放冷热联产系统还包括吸收式制冷机组,所述吸收式制冷机组具有制冷机组热源进口、制冷机组热源出口、制冷机组冷冻水进口、制冷机组冷冻水出口,所述制冷机组热源进口、制冷机组热源出口之间通过制冷机组热源管道相连通,所述制冷机组冷冻水进口、制冷机组冷冻水出口之间通过冷冻水管道相连通,所述冷冻水管道内的冷冻水与所述制冷机组热源管道内的工质进行热交换,所述制冷机组冷冻水进口、制冷机组冷冻水出口与所述外部管道相连接,所述制冷机组热源进口与所述第一冷源出口相连通,所述制冷机组热源出口与所述第一冷源进口相连通。Preferably, the ultra-clean emission combined cooling and heating system of the coking plant also includes an absorption refrigeration unit, and the absorption refrigeration unit has a heat source inlet of the refrigeration unit, a heat source outlet of the refrigeration unit, a chilled water inlet of the refrigeration unit, and a chilled water supply of the refrigeration unit. Outlet, the heat source inlet of the refrigeration unit and the heat source outlet of the refrigeration unit are connected through the heat source pipeline of the refrigeration unit, the chilled water inlet of the refrigeration unit and the chilled water outlet of the refrigeration unit are connected through a chilled water pipeline, and the inside of the chilled water pipeline The chilled water of the refrigeration unit exchanges heat with the working medium in the heat source pipeline of the refrigeration unit. The chilled water inlet of the refrigeration unit and the chilled water outlet of the refrigeration unit are connected to the external pipeline. The cold source outlet is connected, and the heat source outlet of the refrigerating unit is connected with the first cold source inlet.
较佳地,所述焦化厂超净排放冷热联产系统还包括脱硝装置,所述脱硝装置具有脱硝烟气进口、脱硝烟气出口,所述脱硝烟气出口与所述锅炉烟气进口相连通,所述烟气从所述脱硝烟气进口进入所述脱硝装置内并从所述脱硝烟气出口排出。Preferably, the ultra-clean emission cooling and heating cogeneration system of the coking plant also includes a denitration device, the denitration device has a denitration flue gas inlet and a denitration flue gas outlet, and the denitration flue gas outlet is connected to the boiler flue gas inlet The flue gas enters the denitration device from the denitration flue gas inlet and is discharged from the denitration flue gas outlet.
较佳地,所述焦化厂超净排放冷热联产系统还包括加热器,所述加热器包括焦炉烟气进口、焦炉烟气出口、加热源进口、加热源出口,所述焦炉烟气进口、焦炉烟气出口之间通过焦炉烟气管道相连通,所述加热源进口、加热源出口之间通过加热源管道相连通,所述焦炉烟气管道内的烟气与所述加热源管道内的工质进行热交换,所述焦炉烟气出口与所述脱硝烟气进口相连通。Preferably, the ultra-clean emission combined cooling and heating system of the coking plant further includes a heater, the heater includes a coke oven flue gas inlet, a coke oven flue gas outlet, a heating source inlet, and a heating source outlet, and the coke oven The flue gas inlet and the coke oven flue gas outlet are connected through a coke oven flue gas pipeline, the heating source inlet and the heating source outlet are connected through a heating source pipeline, and the flue gas in the coke oven flue gas pipeline is connected to the The working medium in the heating source pipeline performs heat exchange, and the coke oven flue gas outlet communicates with the denitration flue gas inlet.
在符合本领域常识的基础上,上述各优选条件,可任意组合,即得本实用新型各较佳实例。On the basis of conforming to common knowledge in the field, the above-mentioned preferred conditions can be combined arbitrarily to obtain the preferred examples of the present utility model.
本实用新型的积极进步效果在于:The positive progressive effect of the present utility model is:
该焦化厂超净排放冷热联产系统,通过配置余热锅炉、吸收塔、再生器等装置,深度回收并高效利用焦化炉烟气的余热,还兼具烟气超净排放的环保效益,保证了全年的节能环保收益。The ultra-clean emission cooling and heating cogeneration system of the coking plant, through the configuration of waste heat boilers, absorption towers, regenerators and other devices, deeply recovers and efficiently utilizes the waste heat of coking furnace flue gas, and also has the environmental protection benefits of ultra-clean emission of flue gas, ensuring The annual energy saving and environmental protection benefits.
附图说明Description of drawings
图1为本实用新型焦化厂超净排放冷热联产系统的示意图。Fig. 1 is a schematic diagram of an ultra-clean emission combined cooling and heating system of a coking plant of the present invention.
附图标记说明Explanation of reference signs
余热锅炉1Waste heat boiler 1
锅炉烟气进口11Boiler flue gas inlet 11
锅炉烟气出口12Boiler flue gas outlet 12
锅炉冷源进口13Boiler cold source inlet 13
锅炉冷源出口14Boiler cold source outlet 14
吸收塔2Absorption tower 2
吸收塔烟气进口21Absorption tower flue gas inlet 21
吸收塔烟气出口22Absorption tower flue gas outlet 22
吸收塔溶液进口23Absorption tower solution inlet 23
吸收塔溶液出口24Absorption tower solution outlet 24
吸收塔冷源进口25Absorption tower cold source inlet 25
吸收塔冷源出口26Absorption tower cold source outlet 26
再生器3regenerator 3
再生器溶液进口31Regenerator solution inlet 31
再生器溶液出口32Regenerator solution outlet 32
二次蒸汽出口33Secondary steam outlet 33
再生器热源进口34Regenerator heat source inlet 34
再生器热源出口35Regenerator heat source outlet 35
吸收式制冷机组4Absorption refrigeration unit 4
制冷机组热源进口41Refrigeration unit heat source inlet 41
制冷机组热源出口42Refrigeration unit heat source outlet 42
制冷机组冷冻水进口43Refrigeration unit chilled water inlet 43
制冷机组冷冻水出口44第一换热器5Refrigeration unit chilled water outlet 44 first heat exchanger 5
第一烟气进口51The first flue gas inlet 51
第一烟气出口52The first flue gas outlet 52
第一冷源进口53The first cold source import 53
第一冷源出口54The first cold source outlet 54
第二换热器6Second heat exchanger 6
第二冷源进口61Second cold source inlet 61
第二冷源出口62Second cold source outlet 62
第二热源进口63Second heat source inlet 63
第二热源出口64Second heat source outlet 64
第三换热器7The third heat exchanger 7
第三冷源进口71The third cold source inlet 71
第三冷源出口72The third cold source outlet 72
第三热源进口73The third heat source import 73
第三热源出口74The third heat source outlet 74
第四换热器8Fourth heat exchanger 8
第四冷源进口81The fourth cold source import 81
第四冷源出口82The fourth cold source outlet 82
第四热源进口83The fourth heat source import 83
第四热源出口84The fourth heat source outlet 84
脱硝装置9Denitration device 9
脱硝烟气进口91Denitrification flue gas inlet 91
脱硝烟气出口92Denitration flue gas outlet 92
加热器10Heater 10
焦炉烟气进口101Coke oven flue gas inlet 101
焦炉烟气出口102Coke oven flue gas outlet 102
加热源进口103Heating source import 103
加热源出口104Heating source outlet 104
具体实施方式detailed description
下面通过实施例的方式进一步说明本实用新型,但并不因此将本实用新型限制在所述的实施例范围之中。The utility model is further illustrated below by means of examples, but the utility model is not limited to the scope of the examples.
如图1所示为本实用新型所提供的焦化厂超净排放冷热联产系统,包括余热锅炉1、吸收塔2、再生器3,余热锅炉1具有锅炉烟气进口11、锅炉烟气出口12、锅炉冷源进口13、锅炉冷源出口14,锅炉烟气进口11、锅炉烟气出口12之间通过锅炉烟气管道相连通,锅炉冷源进口13、锅炉冷源出口14之间通过锅炉冷源管道相连通,锅炉烟气管道中的烟气与锅炉冷源管道中的工质进行热交换;吸收塔2具有吸收塔烟气进口21、吸收塔烟气出口22、吸收塔溶液进口23、吸收塔溶液出口24,吸收塔烟气进口21与锅炉烟气出口12相连通,吸收塔烟气进口21位于吸收塔2的下部并排放烟气进入吸收塔2的内部,吸收塔烟气出口22位于吸收塔2的上部并排放烟气至外部,吸收塔溶液进口23位于吸收塔2的上部并向吸收塔2内喷射吸湿溶液,吸收塔溶液出口24位于吸收塔2的下部并排出吸湿溶液;再生器3具有再生器溶液进口31、再生器溶液出口32、二次蒸汽出口33,再生器溶液进口31与吸收塔溶液出口24相连通,再生器溶液出口32与吸收塔溶液进口23相连通,二次蒸汽出口33将吸湿溶液加热蒸发出的二次蒸汽排出。As shown in Figure 1, the ultra-clean exhaust cogeneration system of coking plant provided by the present invention includes a waste heat boiler 1, an absorption tower 2, and a regenerator 3, and the waste heat boiler 1 has a boiler flue gas inlet 11 and a boiler flue gas outlet 12. Boiler cold source inlet 13, boiler cold source outlet 14, boiler flue gas inlet 11, boiler flue gas outlet 12 are connected through boiler flue gas pipes, boiler cold source inlet 13, boiler cold source outlet 14 are connected through boiler The cold source pipeline is connected, and the flue gas in the boiler flue gas pipeline exchanges heat with the working medium in the boiler cold source pipeline; the absorption tower 2 has an absorption tower flue gas inlet 21, an absorption tower flue gas outlet 22, and an absorption tower solution inlet 23 , the absorption tower solution outlet 24, the absorption tower flue gas inlet 21 is connected with the boiler flue gas outlet 12, the absorption tower flue gas inlet 21 is located at the bottom of the absorption tower 2 and discharges the flue gas into the inside of the absorption tower 2, the absorption tower flue gas outlet 22 is located at the upper part of the absorption tower 2 and discharges flue gas to the outside, the absorption tower solution inlet 23 is located at the upper part of the absorption tower 2 and sprays the hygroscopic solution into the absorption tower 2, and the absorption tower solution outlet 24 is located at the lower part of the absorption tower 2 and discharges the hygroscopic solution Regenerator 3 has regenerator solution inlet 31, regenerator solution outlet 32, secondary steam outlet 33, regenerator solution inlet 31 is connected with absorption tower solution outlet 24, and regenerator solution outlet 32 is connected with absorption tower solution inlet 23 , the secondary steam outlet 33 discharges the secondary steam produced by heating and evaporating the hygroscopic solution.
余热锅炉1将焦化炉烟气的余热进行回收后,烟气进入吸收塔2中,烟气的余热传递给锅炉冷源管道内的工质,比如冬季供暖水、全年锅炉用水、生活用水及生产用水等。烟气从吸收塔烟气进口21进入吸收塔2内,从下向上运行,与从吸收塔溶液进口23进入并从上方下落的吸湿溶液逆流传热传质,吸湿溶液起到深度除尘、脱气溶胶的作用。烟气经吸收塔烟气出口22排出系统,此时排出的烟气的余热已回收且已通过吸湿溶液深度净化,实现了超净排放的同时,也实现了余热回收。吸湿溶液经过烟气后,吸收了烟气中的水蒸气,浓溶液被稀释为稀溶液,并从吸收塔溶液出口24、再生器溶液进口31流入再生器3中。稀溶液在再生器3中加热并蒸发出二次蒸汽,稀溶液再次变成浓溶液,并从再生器溶液出口32、吸收塔溶液进口23进入吸收塔2中,实现了吸湿溶液的循环。After the waste heat boiler 1 recovers the waste heat of the coking furnace flue gas, the flue gas enters the absorption tower 2, and the waste heat of the flue gas is transferred to the working medium in the cold source pipeline of the boiler, such as heating water in winter, boiler water throughout the year, domestic water and Production water, etc. The flue gas enters the absorption tower 2 from the flue gas inlet 21 of the absorption tower, runs from bottom to top, and conducts heat and mass transfer countercurrently with the hygroscopic solution that enters from the solution inlet 23 of the absorption tower and falls from above. The hygroscopic solution plays a role in deep dust removal and degassing The role of sol. The flue gas is discharged from the system through the flue gas outlet 22 of the absorption tower. At this time, the waste heat of the discharged flue gas has been recovered and deeply purified by the hygroscopic solution, which realizes ultra-clean emission and waste heat recovery at the same time. After the hygroscopic solution passes through the flue gas, it absorbs the water vapor in the flue gas, and the concentrated solution is diluted into a dilute solution, which flows into the regenerator 3 from the solution outlet 24 of the absorption tower and the solution inlet 31 of the regenerator. The dilute solution is heated in the regenerator 3 and evaporates secondary steam, and the dilute solution becomes a concentrated solution again, and enters the absorption tower 2 from the solution outlet 32 of the regenerator and the solution inlet 23 of the absorption tower, realizing the circulation of the hygroscopic solution.
余热锅炉1采用翅片管和热管相结合的翅片管-热管式余热锅炉,即在露点温度以上用翅片管换热(一次换热),在容易发生露点腐蚀温度的部位用热管(二次换热),合理的换热设计和壁温设计,可提高换热系数,同时解决低温露点腐蚀的问题。Waste heat boiler 1 adopts a finned tube-heat tube type waste heat boiler that combines finned tubes and heat pipes, that is, finned tubes are used for heat exchange above the dew point temperature (primary heat exchange), and heat pipes are used for parts prone to dew point corrosion temperature (secondary heat exchange) Secondary heat transfer), reasonable heat transfer design and wall temperature design can improve the heat transfer coefficient and solve the problem of low temperature dew point corrosion.
在烟气进入余热锅炉1之前,还需要进行脱硝处理,因此,在余热锅炉1之前还设置了脱硝装置9,烟气先经过脱硝装置9脱硝后再进入余热锅炉1中。具体而言,脱硝装置9具有脱硝烟气进口91、脱硝烟气出口92,脱硝烟气出口92与锅炉烟气进口11相连通,烟气从脱硝烟气进口91进入脱硝装置9内并从脱硝烟气出口92排出。Before the flue gas enters the waste heat boiler 1, denitration treatment is required. Therefore, a denitrification device 9 is installed before the waste heat boiler 1, and the flue gas passes through the denitrification device 9 before entering the waste heat boiler 1. Specifically, the denitrification device 9 has a denitrification flue gas inlet 91 and a denitrification flue gas outlet 92. The denitrification flue gas outlet 92 is connected to the boiler flue gas inlet 11. The flue gas enters the denitrification device 9 from the denitrification flue gas The flue gas outlet 92 is discharged.
烟气在进行脱硝处理时需达到较高的温度,为了保证脱硝效果,在烟气进入脱硝装置9前,需先在加热器10中进行加热。具体而言,加热器10包括焦炉烟气进口101、焦炉烟气出口102、加热源进口103、加热源出口104,焦炉烟气进口101、焦炉烟气出口102之间通过焦炉烟气管道相连通,加热源进口103、加热源出口104之间通过加热源管道相连通,焦炉烟气管道内的烟气与加热源管道内的工质进行热交换,焦炉烟气出口102与脱硝烟气进口91相连通。为了节能及综合利用,可利用焦化炉荒煤气余热加热烟气,即焦化炉荒煤气从加热源进口103进入加热源管道中,并加热源出口104排出,加热源管道中的荒煤气与焦炉烟气管道内的烟气进行热交换,将烟气的温度提升。加热器10可为板翅式换热器、热管换热器或板式换热器等。The flue gas needs to reach a higher temperature during the denitrification treatment. In order to ensure the denitrification effect, the flue gas needs to be heated in the heater 10 before entering the denitrification device 9 . Specifically, the heater 10 includes a coke oven flue gas inlet 101, a coke oven flue gas outlet 102, a heating source inlet 103, and a heating source outlet 104. The coke oven flue gas inlet 101 and the coke oven flue gas outlet 102 pass through the The flue gas pipes are connected, the heating source inlet 103 and the heating source outlet 104 are connected through the heating source pipes, the flue gas in the coke oven flue gas pipe exchanges heat with the working medium in the heating source pipe, and the coke oven flue gas outlet 102 communicates with the denitrification flue gas inlet 91. For energy saving and comprehensive utilization, waste heat of coking furnace raw gas can be used to heat the flue gas, that is, coking furnace raw gas enters the heating source pipeline from the heating source inlet 103, and is discharged from the heating source outlet 104, and the raw gas in the heating source pipeline and the coke oven The flue gas in the flue gas pipe conducts heat exchange to increase the temperature of the flue gas. The heater 10 can be a plate-fin heat exchanger, a heat pipe heat exchanger, or a plate heat exchanger.
上述系统可根据实际需求,在各个位置设置多个换热器,如在锅炉烟气出口12与吸收塔烟气进口21之间可设置换热器,如在二次蒸汽出口33处可设置一个或多个换热器。换热器可为板翅式换热器、热管换热器、板式换热器等。The above-mentioned system can be equipped with multiple heat exchangers at various positions according to actual needs. For example, a heat exchanger can be installed between the boiler flue gas outlet 12 and the absorption tower flue gas inlet 21. For example, a heat exchanger can be installed at the secondary steam outlet 33. or multiple heat exchangers. The heat exchanger can be a plate-fin heat exchanger, a heat pipe heat exchanger, a plate heat exchanger, and the like.
进入吸收塔2中的烟气仅仅释放了显热,实际上烟气内还有汽化潜热可以回收,为了进一步提高余热回收率,可在吸收塔2内设置换热设施,使烟气的潜热也得以回收。具体而言,吸收塔2还具有吸收塔冷源进口25、吸收塔冷源出口26,吸收塔冷源进口25、吸收塔冷源出口26之间通过吸收塔冷源管道相连通,吸收塔冷源管道内的工质与吸收塔2的内部的工质进行热交换。除在吸收塔2内设置换热设施,还可将吸收塔冷源出口26与一个或多个换热器相连通并热交换,实现余热的全方位回收。The flue gas entering the absorption tower 2 only releases sensible heat. In fact, there is still latent heat of vaporization in the flue gas that can be recovered. In order to further improve the recovery rate of waste heat, heat exchange facilities can be installed in the absorption tower 2 to make the latent heat of the flue gas also be recycled. Specifically, the absorption tower 2 also has an absorption tower cold source inlet 25, an absorption tower cold source outlet 26, and the absorption tower cold source inlet 25 and the absorption tower cold source outlet 26 are connected through the absorption tower cold source pipeline, and the absorption tower cooling The working fluid in the source pipeline exchanges heat with the working fluid inside the absorption tower 2 . In addition to setting heat exchange facilities in the absorption tower 2, the cold source outlet 26 of the absorption tower can also be connected with one or more heat exchangers for heat exchange, so as to realize comprehensive recovery of waste heat.
同时,吸湿溶液进入再生器3中,再生器3内也设置换热设施,使经余热锅炉1换热后产生的蒸汽进入再生器3中并与再生器3内的溶液进行热交换。具体而言,再生器3还具有再生器热源进口34、再生器热源出口35,再生器热源进口34与再生器热源出口35之间通过再生器热源管道相连通,再生器热源管道内的工质与再生器3的内部的工质进行热交换,再生器热源进口34与锅炉冷源出口14相连通。除在再生器3内设置换热设施,还可将再生器热源出口35与一个或多个换热器相连通并热交换,实现余热的全方位回收。At the same time, the hygroscopic solution enters the regenerator 3, and heat exchange facilities are also installed in the regenerator 3, so that the steam generated after heat exchange by the waste heat boiler 1 enters the regenerator 3 and exchanges heat with the solution in the regenerator 3. Specifically, the regenerator 3 also has a regenerator heat source inlet 34 and a regenerator heat source outlet 35. The regenerator heat source inlet 34 and the regenerator heat source outlet 35 are connected through a regenerator heat source pipeline. It exchanges heat with the working fluid inside the regenerator 3 , and the heat source inlet 34 of the regenerator communicates with the boiler cold source outlet 14 . In addition to setting heat exchange facilities in the regenerator 3, the heat source outlet 35 of the regenerator can also be connected with one or more heat exchangers for heat exchange, so as to realize all-round recovery of waste heat.
余热锅炉1的产生的蒸汽具有较高品位,可直接用作再生器3的再生热源,因此,将再生器热源进口34与锅炉冷源出口14相连通,可进一步提高能源利用率。The steam produced by the waste heat boiler 1 is of high grade and can be directly used as the regeneration heat source of the regenerator 3. Therefore, connecting the heat source inlet 34 of the regenerator with the boiler cold source outlet 14 can further improve the energy utilization rate.
换热器的冷源经加热后可用于冬季供暖水、全年锅炉用水、生活用水及生产用水等。除此以外,换热器还可与吸收式制冷机组4相连通,主要用于满足厂区夏季制冷的需求。After being heated, the cold source of the heat exchanger can be used for heating water in winter, boiler water, domestic water and production water all year round. In addition, the heat exchanger can also be connected with the absorption refrigeration unit 4, which is mainly used to meet the cooling demand of the factory area in summer.
上述换热器的组合的一种具体方案如下:A kind of specific scheme of the combination of above-mentioned heat exchanger is as follows:
焦化厂超净排放冷热联产系统包括第一换热器5、第二换热器6、第三换热器7,第一换热器5位于锅炉烟气出口12与吸收塔烟气进口21之间,第一换热器5具有第一烟气进口51、第一烟气出口52、第一冷源进口53、第一冷源出口54,第一烟气进口51、第一烟气出口52之间通过第一烟气管道相连通,第一冷源进口53、第一冷源出口54之间通过第一冷源管道相连通,第一烟气管道内的烟气与第一冷源管道内的工质进行热交换,锅炉烟气出口12与第一烟气进口51相连通,第一烟气出口52与吸收塔烟气进口21相连通;The ultra-clean emission cogeneration system of the coking plant includes the first heat exchanger 5, the second heat exchanger 6, and the third heat exchanger 7. The first heat exchanger 5 is located at the boiler flue gas outlet 12 and the absorption tower flue gas inlet Between 21, the first heat exchanger 5 has a first flue gas inlet 51, a first flue gas outlet 52, a first cold source inlet 53, a first cold source outlet 54, a first flue gas inlet 51, a first flue gas The outlets 52 are connected through the first flue gas pipe, the first cold source inlet 53 and the first cold source outlet 54 are connected through the first cold source pipe, and the flue gas in the first flue gas pipe is connected to the first cold source. The working medium in the source pipeline is heat-exchanged, the boiler flue gas outlet 12 is connected with the first flue gas inlet 51, and the first flue gas outlet 52 is connected with the absorption tower flue gas inlet 21;
第二换热器6具有第二冷源进口61、第二冷源出口62、第二热源进口63、第二热源出口64,第二冷源进口61、第二冷源出口62之间通过第二冷源管道相连通,第二热源进口63、第二热源出口64之间通过第二热源管道相连通,第二冷源管道内的工质与第二热源管道内的工质进行热交换,第二热源进口63与二次蒸汽出口33相连通,第二热源出口64与外部管路相连通,第二冷源进口61、第二冷源出口62、第一冷源出口54之间相互连通;The second heat exchanger 6 has a second cold source inlet 61, a second cold source outlet 62, a second heat source inlet 63, and a second heat source outlet 64, and the second cold source inlet 61 and the second cold source outlet 62 pass through the second The two cold source pipelines are connected, the second heat source inlet 63 and the second heat source outlet 64 are connected through the second heat source pipeline, the working fluid in the second cold source pipeline and the working fluid in the second heat source pipeline perform heat exchange, The second heat source inlet 63 is connected to the secondary steam outlet 33, the second heat source outlet 64 is connected to the external pipeline, and the second cold source inlet 61, the second cold source outlet 62, and the first cold source outlet 54 are connected to each other. ;
第三换热器7具有第三冷源进口71、第三冷源出口72、第三热源进口73、第三热源出口74,第三冷源进口71、第三冷源出口72之间通过第三冷源管道相连通,第三热源进口73、第三热源出口74之间通过第三热源管道相连通,第三冷源管道内的工质与第三热源管道内的工质进行热交换,第三热源进口73与二次蒸汽出口33相连通,第三热源出口74与第二热源出口64相连通,第三冷源进口71、第三冷源出口72均与外部管路相连通。The third heat exchanger 7 has a third cold source inlet 71, a third cold source outlet 72, a third heat source inlet 73, and a third heat source outlet 74, and the third cold source inlet 71 and the third cold source outlet 72 pass through the third The three cold source pipelines are connected, the third heat source inlet 73 and the third heat source outlet 74 are connected through the third heat source pipeline, the working fluid in the third cold source pipeline and the working medium in the third heat source pipeline perform heat exchange, The third heat source inlet 73 communicates with the secondary steam outlet 33 , the third heat source outlet 74 communicates with the second heat source outlet 64 , the third cold source inlet 71 and the third cold source outlet 72 communicate with external pipelines.
通过第一换热器5、第二换热器6、第三换热器7,对锅炉烟气出口12、二次蒸汽出口33的位置的余热进行了全面回收,且换热器之间相互连通,使每个换热器均设有旁路,增加了系统的安全性。Through the first heat exchanger 5, the second heat exchanger 6, and the third heat exchanger 7, the waste heat at the position of the boiler flue gas outlet 12 and the secondary steam outlet 33 is fully recovered, and the heat exchangers are mutually Connected, so that each heat exchanger is equipped with a bypass, increasing the safety of the system.
第四换热器8用于回收吸收塔2、再生器3内的热量,第四换热器8具有第四冷源进口81、第四冷源出口82、第四热源进口83、第四热源出口84,第四冷源进口81、第四冷源出口82之间通过第四冷源管道相连通,第四热源进口83、第四热源出口84之间通过第四热源管道相连通,第四冷源管道内的工质与第四热源管道内的工质进行热交换,第四热源进口83与再生器热源出口35相连通,第四热源出口84与外部管路相连通,第四冷源进口81与吸收塔冷源出口26相连通,第四冷源出口82与第三冷源进口71相连通。The fourth heat exchanger 8 is used to recover the heat in the absorption tower 2 and the regenerator 3. The fourth heat exchanger 8 has a fourth cold source inlet 81, a fourth cold source outlet 82, a fourth heat source inlet 83, and a fourth heat source. The outlet 84, the fourth cold source inlet 81, and the fourth cold source outlet 82 are connected through the fourth cold source pipeline, and the fourth heat source inlet 83 and the fourth heat source outlet 84 are connected through the fourth heat source pipeline. The working fluid in the cold source pipeline exchanges heat with the working fluid in the fourth heat source pipeline, the fourth heat source inlet 83 is connected with the heat source outlet 35 of the regenerator, the fourth heat source outlet 84 is connected with the external pipeline, and the fourth heat source The inlet 81 is connected with the outlet 26 of the absorption tower cold source, and the fourth cold source outlet 82 is connected with the third cold source inlet 71 .
通过第一换热器5、第二换热器6、第三换热器7、第四换热器8,高效回收利用焦炉烟气余热,充分利用厂内其他余热,无一次能源投入,实现烟气超低排放环保效益,保证了全年节能环保收益。Through the first heat exchanger 5, the second heat exchanger 6, the third heat exchanger 7, and the fourth heat exchanger 8, the coke oven flue gas waste heat can be efficiently recycled and other waste heat in the plant can be fully utilized without primary energy input. Realize the environmental benefits of ultra-low emission of flue gas, and ensure the benefits of energy saving and environmental protection throughout the year.
吸收式制冷机组4与上述其中一个或多个换热器相连通,可满足厂区夏季制冷的需求。吸收式制冷机组4的一种具体方案如下:吸收式制冷机组4具有制冷机组热源进口41、制冷机组热源出口42、制冷机组冷冻水进口43、制冷机组冷冻水出口44,制冷机组热源进口41、制冷机组热源出口42之间通过制冷机组热源管道相连通,制冷机组冷冻水进口43、制冷机组冷冻水出口44之间通过冷冻水管道相连通,冷冻水管道内的冷冻水与制冷机组热源管道内的工质进行热交换,制冷机组冷冻水进口43、制冷机组冷冻水出口44与外部管道相连接,制冷机组热源进口41与第一冷源出口54相连通,制冷机组热源出口42与第一冷源进口53相连通。吸收式制冷机组4实际上不局限于与第一换热器5、第二换热器6相连通,也可以与其它换热器相连通。The absorption refrigerating unit 4 is connected with one or more of the heat exchangers mentioned above, which can meet the cooling requirements of the factory area in summer. A specific scheme of absorption refrigeration unit 4 is as follows: absorption refrigeration unit 4 has refrigeration unit heat source inlet 41, refrigeration unit heat source outlet 42, refrigeration unit chilled water inlet 43, refrigeration unit chilled water outlet 44, refrigeration unit heat source inlet 41, The heat source outlets 42 of the refrigeration unit are connected through the heat source pipeline of the refrigeration unit, the chilled water inlet 43 of the refrigeration unit and the chilled water outlet 44 of the refrigeration unit are connected through a chilled water pipeline, and the chilled water in the chilled water pipeline is connected with the heat source pipeline of the refrigeration unit. The working medium performs heat exchange, the chilled water inlet 43 of the refrigeration unit, the chilled water outlet 44 of the refrigeration unit are connected with external pipes, the heat source inlet 41 of the refrigeration unit is connected with the first cold source outlet 54, and the heat source outlet 42 of the refrigeration unit is connected with the first cold source The entrance 53 is connected. Actually, the absorption refrigerating unit 4 is not limited to communicate with the first heat exchanger 5 and the second heat exchanger 6, and may also communicate with other heat exchangers.
本实用新型不局限于上述实施方式,不论在其形状或结构上作任何变化,均落在本实用新型的保护范围之内。本实用新型的保护范围是由所附权利要求书限定的,本领域的技术人员在不背离本实用新型的原理和实质的前提下,可以对这些实施方式做出多种变更或修改,但这些变更和修改均落入本实用新型的保护范围。The utility model is not limited to the above-mentioned embodiments, and no matter any changes are made in its shape or structure, all fall within the protection scope of the utility model. The protection scope of the utility model is defined by the appended claims, and those skilled in the art can make various changes or modifications to these embodiments without departing from the principle and essence of the utility model, but these Changes and modifications all fall within the protection scope of the present utility model.
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| CN108131656B (en) * | 2017-07-10 | 2024-03-15 | 昊姆(上海)节能科技有限公司 | Ultra-clean emission cold and hot co-production system of coking plant |
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Effective date of registration: 20250430 Address after: No. 33A, North Second East Road, Tiexi District, Shenyang City, Liaoning Province (7-1) Patentee after: Liaoning Zhijing Haomu Energy saving Technology Co.,Ltd. Country or region after: China Address before: Room 132, Building 19, Siping South Road, Tinglin Town, Jinshan District, Shanghai, 201505 Patentee before: HAOMU (SHANGHAI) ENERGY SAVING TECHNOLOGY CO.,LTD. Country or region before: China |