CN205700176U - A kind of online decision maker of reverse osmosis membrane apparatus pollution situation - Google Patents
A kind of online decision maker of reverse osmosis membrane apparatus pollution situation Download PDFInfo
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- CN205700176U CN205700176U CN201620544984.4U CN201620544984U CN205700176U CN 205700176 U CN205700176 U CN 205700176U CN 201620544984 U CN201620544984 U CN 201620544984U CN 205700176 U CN205700176 U CN 205700176U
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- reverse osmosis
- osmosis membrane
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- pollution
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- 238000001223 reverse osmosis Methods 0.000 title claims abstract description 107
- 239000012528 membrane Substances 0.000 title claims abstract description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229910001868 water Inorganic materials 0.000 claims abstract description 52
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 23
- 231100000719 pollutant Toxicity 0.000 claims abstract description 23
- 230000008859 change Effects 0.000 claims abstract description 7
- 230000000694 effects Effects 0.000 claims abstract description 6
- 238000003860 storage Methods 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 22
- 230000008569 process Effects 0.000 abstract description 4
- 230000035800 maturation Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 238000003911 water pollution Methods 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000001728 nano-filtration Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 210000003484 anatomy Anatomy 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 102000010637 Aquaporins Human genes 0.000 description 1
- 108010063290 Aquaporins Proteins 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 108091006146 Channels Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
This utility model provides the online decision maker of the pollution situation of a kind of reverse osmosis membrane apparatus.This device mainly selects the household reverse osmosis membrane component of existing maturation to judge carrier as reverse osmosis unit dense water pollution situation;By household reverse osmosis membrane component, household reverse osmosis putamina, be equipped with corresponding inlet and outlet pipe lines, pressure-regulating valve, pressure instrumentation, flow instrumentation composition pollute decision maker online;Then this is polluted online decision maker and is connected in parallel on the dense water side of large-scale reverse osmosis membrane apparatus.Utilize the enriching pollutants effect again of household reverse osmosis membrane component, be can be determined that the pollution tendencies of reverse osmosis unit by the pressure change of online pollution decision maker, changes in flow rate.This device constitutes simple, using method fast and flexible, it is possible to reduce the impact of reverse osmosis unit is run in scene by pollutant judge process, and can find out reverse osmosis membrane pollutant classification and solution accurately, possesses preferable industrial applicability prospect.
Description
Technical field
This utility model belongs to application field of water treatment, relates to industrial large-sized reverse osmosis membrane apparatus operation maintenance and pollutes control
System, especially a kind of Industrial reverse osmosis film device pollution situation judges online, completes pollutants identification and pollutant cleaning program
The device judged.
Background technology
Reverse osmosis membrane apparatus is a kind of wide variety of feed separation, solution purification method.Especially in desalinization, hardship
The softening of desalination, bitter, surface water treatment, Industrial Wastewater Treatment, urban sewage recycling process, industrial pure water process, work
The fields such as industry material concentration are widely used.Typically, this system selects the membrane component of rolled structure, uses single hop, multistage in design
Or multistage system configuration.In order to ensure the properly functioning of system, coagulant precipitation, more medium filter, activity typically can be selected
Carbon filter, ultrafiltration, cartridge filter, disinfection system etc. carry out pretreatment, and its technique core is to prevent reverse osmosis membrane or nanofiltration
There is serious fouling membrane in film.Even if but using above-mentioned technique or equipment, reverse osmosis membrane system or nanofiltration membrane system because originally
The highly enriched characteristic of body, still can polluting by the pollutant in water body.Therefore in reverse osmosis membrane or the reality of nanofiltration membrane system
Border application in, prevention and cure of pollution remain its heavy among.
In the pollution problem of general reverse osmosis membrane, the most all can relate to two big classes: the first kind is reversible fouling membrane shape
Condition, such as, retain for ion component due to reverse osmosis membrane, and forms concentration polarization layer in the boundary region on film surface.This
Pollution type generally can be promoted by surface velocity, the hydromechanical condition optimizing of degradation or run and control to come under the response rate
Controlled or improved;Equations of The Second Kind is irreversible fouling membrane situation, such as because of film surface electric charge or the Van der Waals of molecule
Power and form film surface contamination deposition etc., this pollution situation is generally all the most different owing to the condition of water quality changes.Reverse osmosis membrane
The a lot of preposition processing equipment that device is equipped with is provided to cut down the formation of this kind of pollution.This two classes pollution situation is difficult to strict district
Separate, it is common that synergism.
A lot of scholar and the engineering of water treatment teacher pollution situation all for reverse osmosis membrane is had to give the biggest attention at present,
And studied for conditions associated and thought deeply.Chinese Patent Application No. 201110424602.6 discloses a kind of reverse osmosis membrane
The decision method that microorganism is polluted.The method utilize plate count away from, use Petrifilm paper disk method accurately, quickly examine
The microbial biomass survey reverse osmosis membrane system water inlet, producing in water and dense water, in conjunction with total plate count in dense water and sodium ion or chloride ion
Between the ratio of concentration rate can judge accurately, rapidly reverse osmosis membrane microorganism pollution level.Chinese Patent Application No.
201210517285.7 disclose and a kind of evaluate the method that reverse osmosis membrane is polluted by organic matter.First pass through configuration standard and pollute molten
Liquid, obtains when Pn value is test natural law n when 0.5;The repeated contamination test of actual water source is used to obtain the Pn ' when testing natural law n
Value, judges the contaminated trend of reverse osmosis membrane by the size of the Pn ' judged and 0.5 value.
These methods have all inquired into the method how obtaining reverse osmosis membrane apparatus pollution situation, but all concentrate on laboratory
Water quality diagnosis work, the operation instruction for reverse osmosis membrane apparatus has indirect sense.But the reverse osmosis of large-scale actual motion
Device in running it is difficult to ensure that only by the other pollution of unitary class, be the most all compound pollution.And operator
Concerned about content for reverse osmosis membrane apparatus more concentrates on operational factor and clean-in-place recovers.Said method is used relatively to be difficult to reality
These targets existing.
Should be used for from actual at present, fouling membrane determination methods based on on-the-spot running gear is concentrated mainly on two kinds: one
It is with on-the-spot large reverse osmosis device as references object, is judged pollution tendencies and the pollution of film by the service data of device
Situation.Solve once the mode occurring fouling membrane just to use concentrated chemical to clean, or need on-the-spot reality 4 cun or 8
Very little membrane component carries out dismantling, having dissected pollutants identification and the judgement of pollutant cleaning program.This method has some shortcomings:
Cleaning every time or pollute and all have to stop normally producing water when judging, reduce system obtains water rate;Meanwhile, to dismantle every time
Mounted membrane component in system, delivers to Large components Special experimental room and detects, spend costly.
Another kind is that scene installs the extraction of side line pollutant and method for decomposing additional.Chinese Patent Application No. 201110340055.3
Disclose a kind of Industrial reverse osmosis film device pollutant On-line testing and method for decomposing, select commercial reverse osmosis membrane to make side line film
Assembly, the carrier extracted as key pollutants;Side line membrane module is parallel in Industrial reverse osmosis film device, regulates side line film
The Inlet and outlet water valve opening size of assembly, to control the crossflow velocity of water inlet;Time recording side line membrane module in running
Aquifer yield changes, when the relatively initial aquifer yield of aquifer yield declines 50~95%, then it is assumed that contaminated reverse osmosis membrane reaches to dissect to be wanted
Ask;Take out contaminated reverse osmosis membrane and carry out observation and the anatomy of pollutant;Bronsted lowry acids and bases bronsted lowry is used respectively contaminated reverse osmosis membrane to be entered
Row soaking and washing, the content size of specific pollutants in detection cleanout fluid.This method reduces some drawbacks of first method,
But yet suffer from deficiency: side line pollutant and original system start parallel work-flow from former water, but due to large-scale membrane component with
The HYDRODYNAMIC CONDITION RELATING TO of small-sized side line diaphragm element is not quite similar, and therefore pollutes asynchronous.The most large-scale membrane component has polluted ten
Divide serious, but parallel Miniature film disc element but pollutes lighter.
Relevant deficiency in above-mentioned reverse osmosis commercial Application causes the actual application of reverse osmosis to nevertheless suffer from the tired of pollutant
Disturbing, a lot of large scale systems are even forced to shorten the service life of film, cause operating cost significantly to rise.
Therefore, what those skilled in the art was devoted to develop a kind of reverse osmosis membrane apparatus pollution situation judges dress online
Put, it is judged that the pollution of reverse osmosis membrane apparatus, extend the life-span of film, improve the water-yielding capacity of membranous system.
Utility model content
Because the drawbacks described above of prior art, technical problem to be solved in the utility model is at large reverse osmosis film
Under the conditions of device actual motion, how to complete the online judgement of reverse osmosis membrane apparatus pollution situation.
For achieving the above object, this utility model provide a kind of reverse osmosis membrane apparatus pollution situation judge online dress
Put, including household reverse osmosis membrane component, household reverse osmosis putamina, inlet and outlet pipe lines and pipe fitting, cut-off valve, pressure-regulating valve,
Pressure instrumentation, flow instrumentation, described online decision maker is connected in parallel on large-scale by described inlet and outlet pipe lines and pipe fitting
The dense water side of reverse osmosis membrane apparatus, using the dense water of large reverse osmosis device that runs as water inlet, produce water and the dense water of secondary respectively
Enter original dense water storage tank or exhausting pipeline.
Further, the described online pollution decision maker response rate selects 8%~15%.
Further, described online pollution decision maker is configured to, with the pollution again of household reverse osmosis membrane component
By pressure change, the changes in flow rate of online pollution decision maker, thing enrichment, can be determined that the pollution of reverse osmosis unit becomes
Gesture.
Further, described household reverse osmosis membrane component is configurable for identifying pollutant and pollutant cleaning program
Judge.
Further, described household reverse osmosis membrane component is rolled film structure.
Further, described household reverse osmosis membrane component is 1812 types or 2012 types.
Technical solution of the present utility model is:
(1) the household reverse osmosis membrane component selecting existing maturation judges to carry as reverse osmosis unit dense water pollution situation
Body;
(2) by household reverse osmosis membrane component, household reverse osmosis putamina, be equipped with inlet channel, water production pipeline, dense waterpipe,
Water inlet stop valve, influent pressure force regulating valve, dense hydraulic pressure force regulating valve, pressure instrumentation, flow instrumentation composition are online dirty
Dye decision maker;
(3) this is polluted online decision maker and be connected in parallel on the dense water side of large-scale reverse osmosis membrane apparatus.Pollute judgement online
The pipeline before large reverse osmosis film device dense water relief valve is taken from device water inlet;If large reverse osmosis film device is equipped with pressure
Power retracting device, before large reverse osmosis film device dense water feeding pressure recovery devices is taken from the water inlet of pollution decision maker the most online
Pipeline.The online decision maker product water that pollutes enters dense water storage tank or the exhausting pipeline of original big system.Online pollution judges dress
The original dense water storage tank of the dense water of secondary put or exhausting pipeline.
(4) the online decision maker that pollutes uses cross-flow operation.The online decision maker that pollutes is carried out data tracking, analyzes pressure
Power change and product discharge change.Determine that the cycles of concentration of large reverse osmosis membranous system is the most suitable, if pressure reduction significantly rises, example
As risen more than 15% in the short time, or produce discharge decay substantially, such as in the short time, decline more than 15%, then it is believed that big
There is Heavy Pollution Conditions in type reverse osmosis membrane apparatus.Need large reverse osmosis film device is regulated and controled, reduce the system response rate
Or check RO pre-treatment system treatment effect.
(5) when pollutant are analyzed judging by needs, the online water inlet stop valve polluting decision maker is closed, to family
Pass in and out outspoken interface with pressure vessel for reverse osmosis to dismantle, then household reverse osmosis film is taken out from putamina, change new replacement
Use household reverse osmosis film.Then installing, former state is recovered.
(6) the household reverse osmosis membrane component taken off is carried out Anatomical Structure, then carry out pollutants identification and the dirt of diaphragm
Dye thing cleaning program judges, thus ensures, on the basis of the reverse osmosis membrane apparatus not affecting existing operation, to complete pollutant and exist
Line judges.
(7) according to judging that conclusion carries out directiveness work to large reverse osmosis system, as pre-in Chemical cleaning scheme, reverse osmosis
Treatment process is strengthened, reverse osmosis operating condition correction etc..
Below with reference to accompanying drawing, the technique effect of design of the present utility model, concrete structure and generation is made furtherly
Bright, to be fully understood from the purpose of this utility model, feature and effect.
Accompanying drawing explanation
Fig. 1 is the system schematic polluting decision maker online;Including: device inlet channel 1, the dense waterpipe of device secondary
2, device water production pipeline 3, water inlet stop valve 4, feed water flow gauge 5, influent pressure force regulating valve 6, household reverse osmosis putamina 7, domestic
Reverse-osmosis membrane element 8, product water ga(u)ge 9, household reverse osmosis differential manometer 10, secondary dense hydraulic pressure force regulating valve 11.
Fig. 2 is to pollute the decision maker installation system schematic diagram at common large reverse osmosis film device online;Including: film
System water inlet storage tank 1, booster pump 2, security personnel's filter 3, high-pressure pump 4, reverse osmosis membrane apparatus 5, reverse osmosis membrane apparatus produce tank 6, anti-
The dense tank of permeable membrane device 7;Reverse osmosis concentrated water regulating valve 8, online pollution decision maker 9.
Fig. 3 is to pollute decision maker online to illustrate at the installation system of the large reverse osmosis film device of band energy recycle device
Figure;Including: membranous system water inlet storage tank 1, booster pump 2, security personnel filter 3, high-pressure pump 4, pressure recovery devices 5, pressure recovery secondary
Booster pump 6, reverse osmosis membrane apparatus 7;Reverse osmosis membrane apparatus produces tank 8, the dense tank of reverse osmosis membrane apparatus 9, online pollution judgement dress
Put 10.
Detailed description of the invention
Below by an embodiment and combine accompanying drawing this utility model is described further.
As shown in Figure 1, Figure 2 and Figure 3, it is one-level two-part reverse osmosis membrane apparatus 5 that the present embodiment relates to reverse osmosis membrane apparatus,
Reverse osmosis membrane apparatus uses 6 core dress putamina, totally 30 membrane components.Water inlet is provided with into water storage tank 1, and membranous system water inlet is provided with booster pump
2, security personnel's filter 3 and high-pressure pump 4.Reverse osmosis unit 5 produces current multiparity tank 6, and reverse osmosis concentrated waterpipe cuts equipped with manually regulation
Only valve 8, controls valve opening in running.After pressure release, reverse osmosis concentrated water gravity flow enters dense tank 7.At manual adjustable cut-off valve
Weld opening on dense waterpipe before 8, introduce one stream of water water inlet online pollution decision maker 9.
In normal course of operation, high pressure pump outlet pressure 15bar, film initially produce discharge 25 vertical/time, reverse osmosis concentrated hydraulic pressure
Power 13.5bar.Online pollution decision maker intake pressure regulation controls at 3bar, and flow of inlet water controls as 5L/h, initial reclamation
Rate controls 12%.After 30d runs, online decision maker product discharge of polluting drops to 0.45L/h.The biggest device system
Not yet there is significant change in system.Again after 15d runs, online decision maker product discharge of polluting drops to 0.35L/h, this
Time, big apparatus system produce discharge decay to 20 vertical/time.Pollute decision maker membrane component by dismounting is online, be carried out behaviour
Making, use the hydrochloric acid of 0.1% to clean invalid, the caustic dip using pH to be 10 is effective, and the alkali liquor according to pH10 combines
The surfactant combined cleaning of 0.02% is better.After this cleaning program is applied in large scale system, reverse osmosis after cleaning
Permeable membrane device produce discharge recover to 24.5 vertical/time.
Preferred embodiment of the present utility model described in detail above.Should be appreciated that the ordinary skill of this area without
Need creative work just can make many modifications and variations according to design of the present utility model.Therefore, all in the art
Technical staff on the basis of existing technology can by logical analysis, reasoning, or a limited experiment according to design of the present utility model
With the technical scheme obtained, all should be in the protection domain being defined in the patent claims.
Claims (6)
1. the online decision maker of the pollution situation of a reverse osmosis membrane apparatus, it is characterised in that include household reverse osmosis membrane element
Part, household reverse osmosis putamina, inlet and outlet pipe lines and pipe fitting, cut-off valve, pressure-regulating valve, pressure instrumentation, flow detection
Instrument, described online decision maker is connected in parallel on the dense water of large-scale reverse osmosis membrane apparatus by described inlet and outlet pipe lines and pipe fitting
Side, enters original dense water storage tank using the dense water of large reverse osmosis device run respectively as water inlet, product water and the dense water of secondary or puts
Vacant duct.
2. the online decision maker of the pollution situation of reverse osmosis membrane apparatus as claimed in claim 1, it is characterised in that described
Line pollutes the decision maker response rate and selects 8%~15%.
3. the online decision maker of the pollution situation of reverse osmosis membrane apparatus as claimed in claim 1, it is characterised in that described
Line pollutes decision maker and is configured to, with the enriching pollutants effect again of household reverse osmosis membrane component, is polluted by online
The pressure change of decision maker, changes in flow rate can be determined that the pollution tendencies of reverse osmosis unit.
4. the online decision maker of the pollution situation of reverse osmosis membrane apparatus as claimed in claim 1, it is characterised in that described family
It is configurable for identifying pollutant and the judgement of pollutant cleaning program with reverse-osmosis membrane element.
5. the online decision maker of the pollution situation of reverse osmosis membrane apparatus as claimed in claim 1, it is characterised in that described family
It is rolled film structure with reverse-osmosis membrane element.
6. the online decision maker of the pollution situation of reverse osmosis membrane apparatus as claimed in claim 1, it is characterised in that described family
It is 1812 types or 2012 types with reverse-osmosis membrane element.
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CN201620544984.4U CN205700176U (en) | 2016-06-06 | 2016-06-06 | A kind of online decision maker of reverse osmosis membrane apparatus pollution situation |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109187311A (en) * | 2018-10-23 | 2019-01-11 | 清华大学 | A kind of device and method of the dirty stifled potentiality of evaluation counter-infiltration system water inlet |
CN111185093A (en) * | 2019-12-27 | 2020-05-22 | 湖南军信环保股份有限公司 | Online detection method and sampling device for membrane element of nanofiltration or reverse osmosis membrane unit |
-
2016
- 2016-06-06 CN CN201620544984.4U patent/CN205700176U/en active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109187311A (en) * | 2018-10-23 | 2019-01-11 | 清华大学 | A kind of device and method of the dirty stifled potentiality of evaluation counter-infiltration system water inlet |
CN109187311B (en) * | 2018-10-23 | 2024-05-28 | 清华大学 | Device and method for evaluating water inlet blocking potential of reverse osmosis system |
CN111185093A (en) * | 2019-12-27 | 2020-05-22 | 湖南军信环保股份有限公司 | Online detection method and sampling device for membrane element of nanofiltration or reverse osmosis membrane unit |
CN111185093B (en) * | 2019-12-27 | 2022-06-21 | 湖南军信环保股份有限公司 | Online detection method and sampling device for membrane element of nanofiltration or reverse osmosis membrane unit |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191227 Address after: 625000 4 Binhe East Road, economic development zone, Ya'an City, Sichuan Province Patentee after: YAAN WAKLIN ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD. Address before: 200052 No. 900, Changning District, Shanghai, West Yan'an Road Patentee before: Wang Xia |
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TR01 | Transfer of patent right |