CN206109125U - Spent acid concentration and recycling system that contain heavy metal and particulate matter - Google Patents

Spent acid concentration and recycling system that contain heavy metal and particulate matter Download PDF

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Publication number
CN206109125U
CN206109125U CN201620985518.XU CN201620985518U CN206109125U CN 206109125 U CN206109125 U CN 206109125U CN 201620985518 U CN201620985518 U CN 201620985518U CN 206109125 U CN206109125 U CN 206109125U
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heavy metal
concentration
pond
sour
acid
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韩全
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Guangdong Yeanovo Environmental Protection Co Ltd
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Guangdong Yeanovo Environmental Protection Co Ltd
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Abstract

The utility model provides a spent acid concentration and recycling system that contain heavy metal and particulate matter, including ultrafiltration system (100), heavy metal ion piece -rate system (200), sour concentrated system (300) and evaporation concentration system (400), its characterized in that, ultrafiltration system (100) intercommunication heavy metal ion piece -rate system (200), heavy metal ion piece -rate system (200) intercommunication sour concentrated system (300), the intercommunication evaporation concentration system (400) of sour concentrated system (300), through the utility model discloses a special membrane concentration device of spent acid, it is used for the concentrated of acid waste water to handle, because the special membrane concentration device of spent acid need not the heating, the energy consumption is few, the operation process is stable in succession, equipment area is little, full automatic operation, easy operation, and easy the maintenance.

Description

A kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter
Technical field
This utility model is related to the technical field that acid waste water is processed produced in commercial production, especially a kind of containing a huge sum of money The waste acid concentration and reclaiming system of category and particulate matter.
Background technology
Energy-saving and emission-reduction have become me and have crossed the great state basic policy of industrial development.Industrial undertaking early has started to be absorbed in energy-saving and emission-reduction work Make, under the requirement of policy, in addition it is also necessary to enhance the capacity for independent innovation energetically, and seek a kind of energy-efficient mode strengthening energy-conservation Work.This is also one of direction of economic development of China's Industrial Economic Development from now on.Industrial undertaking is resource consumption and pollution The rich and influential family of thing discharge, for energy-saving and emission-reduction, there is bigger social responsibility in industrial undertaking.Most enterprise is in order to pursue economic benefit So as to have ignored the problem of environmental pollution, how to allow industrial undertaking while keeping profit to increase and reduce the consumption of resource, Just into government and the focus of enterprise.
Existing domestic many chemical enterprises need to use sulphuric acid and carry out surface clean, metal to metal as the cleanout fluid of product The consumption of sulphuric acid very big and metal ion can be constantly run up in the middle of acid solution during cleaning, when the metal in acid solution reaches one After determining concentration, because treatment effect does not reach technological requirement, acid solution is caused to need to match somebody with somebody again after the certain number of times of wash cycles Put and change, in this process, substantial amounts of acid pickle is produced.Acid containing higher concentration and metal and outstanding in these spent acid Floating particles thing, causes certain threat, needs to be processed to environment.
At present many enterprises use Neutralisation treatment method, and the method is simple and easy to do, and general technique is:Acid-bearing wastewater → regulating reservoir → PH regulating reservoirs → coagulative precipitation tank → PH readjustment pond → qualified discharges.Acid-bearing wastewater enters regulating reservoir equilibrium water quality Afterwards PH regulating reservoirs are promoted to by elevator pump, PH regulating reservoirs are the critical processes of whole technique, and the medicament for mainly adding is Calx, PH value is adjusted to 8 or so, mud-water separation is being realized into sedimentation tank through coagulating basin, clear water flows into PH and adjusts back pond heel row to factory River outside area, due to the characteristic of Calx itself, mix to occur that after chemical reaction substantial amounts of mud can be produced with acid and causes Produce very high treatment of sludge expense.
Existing method processes that spent acid is although effective and feasible, but processing mode is extensive, there are problems that it is a lot, such as:Management is numerous Trivial, wayward, floor space is big, and wastewater treatment capacity is restricted;Sulphuric acid, water in waste water, metal ion fail to utilize;Place The gas diffusion generated during reason, causes secondary pollution;Sludge quantity is big, and remaining salt residue treatment is difficult, Treatment of Sludge High cost.From enterprise development angle, the method for traditional neutralisation treatment spent acid not only causes acid and a large amount of wastes of water resource, Also so that the cost of product increases, the survival and development of enterprise are had a strong impact on and constrained.
Utility model content
To overcome the defect of prior art, the utility model proposes a kind of waste acid concentration containing heavy metal and particulate matter and returning Use system.
A kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter, including ultrafiltration system, separation of heavy metal ions System, sour concentration systems and evaporation concentration system, the ultrafiltration system connects the separation of heavy metal ions system;Heavy metal from Sub- piece-rate system connects the sour concentration systems;The sour concentration systems connect evaporation concentration system.
Ultrafiltration system includes regulating reservoir, heat-exchange system, disc filter, ultrafiltration intake pool and acidproof ultra-filtration membrane device, its In, the regulating reservoir connects heat-exchange system, heat-exchange system connection disc filter, and disc filter is by ultrafiltration intake pool and resistance to Sour ultra-filtration membrane device is to connection.
Separation of heavy metal ions system includes that separation of heavy metal ions device, first produce pond and the first concentrated water pond, wherein, The separation of heavy metal ions device is respectively communicated with the first product pond and the first concentrated water pond.
Sour concentration systems include that sour enrichment facility, second produce pond and the second concentrated water pond, wherein, the sour enrichment facility point Lian Tong not the second product pond and the second concentrated water pond.
Evaporation concentration system includes the sour pond of vaporising device, storage and distillation pond, wherein, the vaporising device is respectively communicated with storage Sour pond and distillation pond.
Separation of heavy metal ions device in ultrafiltration system in acidproof ultra-filtration membrane device connection separation of heavy metal ions system, First produces the sour enrichment facility in the sour concentration systems of pond connection in separation of heavy metal ions system, and second is dense in sour concentration systems Vaporising device in pond connection evaporation concentration system.
By a kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter of the present utility model, containing heavy metal and The pigment waste acid concentrator of grain thing is recycled to spent acid, is reduced enterprise's spent acid processing cost and is more reduced the dirt to environment Dye, while effectively reclaiming to spent acid, to enterprise larger economic benefit, social benefit and environmental benefit is brought
Description of the drawings
Fig. 1 is the embodiment schematic diagram of waste acid concentration and reclaiming system containing heavy metal and particulate matter.
Fig. 2 is the special film condensing device workflow diagram of spent acid.
Specific embodiment
A kind of spent acid containing heavy metal and particulate matter below in conjunction with the accompanying drawings this utility model provided with specific embodiment Concentration and reclaiming system are described in detail.
Embodiment
The characteristics of pigment waste acid concentrator containing heavy metal and particulate matter is directed to acid waste water, with reference to different enterprises to acid concentration Requirement, can be oriented concentration to acid waste water, the pure water of output and middle and high concentration acid enterprise recycle.Whole device point For four systemses, i.e.,:Ultrafiltration system, separation of heavy metal ions membranous system, sour concentration systems, vapo(u)rization system.Acid waste water is first Preprocessing system is promoted to by elevator pump and filters out larger particles in acid waste water, filtered subsequently into ultrafiltration system tiny Particulate matter, acid waste water enters separation of heavy metal ions membranous system by one-level booster pump, one-level high-pressure pump again, separates a huge sum of money Category, eventually pass two-stage supercharging pump, two grades of high-pressure pumps enter be recycled after sour concentration systems and vapo(u)rization system the acid that utilizes and Pure water.
Shown in Fig. 1 containing heavy metal and particulate matter waste acid concentration and reuse special purpose device schematic diagram, including ultrafiltration system 100th, separation of heavy metal ions system 200, sour concentration systems 300 and evaporation concentration system 400,
Wherein, the acid waste water from plant area's production line enters regulating reservoir 1 after collecting, and carries out water quality and quantity regulation.Adjust Heat-exchange system 2, the outlet of heat-exchange system 2 and the inlet communication of disc filter 3 are entered after the waste water of pond 1 is boosted, is filtered through disc type Device removes the larger float of particle diameter in waste water.
The outlet of disc filter 3 accesses ultrafiltration intake pool 4, is surpassed the waste water lifting of ultrafiltration intake pool 4 to acidproof using pump Filter membrane device 5, ultrafilter membrane removes the serosity reuse containing titanium dioxide granule being rejected by after the float in waste water to titanium dioxide Production line, the acid waste water without float is lifted into again separation of heavy metal ions device 6 after ultrafiltration membrance filter.
Separation of heavy metal ions film device 6 separates the iron ion in waste water from spent acid, and iron content waste liquid enters One concentrated water pond 8, the acid waste water of metal ion is not into the first product pond 7.Iron content devil liquor recovery is used as Polyferric Sulfate product, totally Acid enters sour enrichment facility 9.
In sour enrichment facility 9, concentration can be concentrated into 11% or so after the clean concentrated film of dilute spent acid.Device produces water Clean water enter second and produce pond 10 and reuse to plant area, the concentrated acid to 11% enters the second concentrated water pond 11.
Spent acid in second concentrated water pond 11 enters back into vaporising device 12, and sulfuric acid concentration is promoted to 70% from 11%, high concentration Acid is stored in sour pond 13 and reuse is to plant area, is evaporated the distilled water for producing and is entered distillation pond 14.
Ultrafiltration system adopts new acidproof ultrafiltration PPSV films, and the film has that treatment effeciency is high, filtration flow-rate is big, membrane flux Greatly, highly acid can be born, alkalescence, bleaching and oxidating chemicals cleaning the characteristics of.Ultra-filtration membrane device can substitute traditional materialization and sink Shallow lake technique, reduces processing links, save space, investment cost and operating cost;
Separation of heavy metal ions system adopts novel heavy metal ion seperation film, and seperation film has that flux is big, acid resistance strong, The characteristics of removal rate is high.The molecular weight of seperation film retention is between 200~1000, it is adaptable to which molecular size is the dissolving group of 1nm The separation for dividing, it is most effective to the metal ion removal effect in waste water;
Acid concentration membranous system due to the special film condensing device of spent acid without the need for heating, less energy consumption, running continuous-stable, if Standby floor space is little, and fully automatic operation is simple to operate, and easy care.
The special film condensing device strong adaptability of spent acid, not only can apply to conventional common film condensing device field, also right The low-down acid waste water of pH value has very strong adaptability, so as to compensate for the domestic deficiency to spent acid embrane method recovery technology.It is special Requirement of the safety pin to the pollutant property in acid waste water and cycles of concentration, from extraordinary dedicated film as enrichment facility infiltration Element, the pH value range of adaptation can as little as less than 0.1, anti-pollution characteristic is good;
Spent acid special evaporator special materials steel makes molding, can operate with the various spent acid of variety classes, variable concentrations Raw material, it is applied widely.The hyperthermal distilled water that system is produced is recycled as pre- heat exchanger thermal source, without waste hot steam discharge, With good energy-conservation and characteristic of environmental protection.Vaporising device is without the need for condenser, and structure is very simple with flow process, and full automatic working can Continuous operation, it is safe and reliable.
It is few that whole waste acid concentration recycles simple technological process, high degree of automation, floor space.Acid waste water is entered The recyclable effective ingredient therein of suspended particle that Jing ultrafiltration is produced after system, separation of heavy metal ions membrance separation weight out Metal ion is recyclable to be used, acid concentration and evaporate output clean water also can reuse to plant area, it is final Jing after evaporation and concentration The clean acid of high concentration be recycled.Whole system does not have waste water to discharge, and obtains after the various components in waste water are separated Effectively recycle, the real unification for realizing environmental benefit, economic benefit and social benefit.
As shown in Fig. 2 because the acid waste water that enterprise discharges typically all contains various polluters, it is impossible to be directly entered film Concentration systems, can otherwise cause the irreversible membrane fouling of film.Therefore, before membrance concentration process, necessary Jing is effective for acid waste water Physical reaction, precipitation, and Jing after ultrafiltration pretreatment removes particulate matter of the particle diameter more than 5 microns, follow-up spent acid of being allowed for access is special Film condensing device carries out concentration.
Due to the high problem of acid waste water generally existing salinity, to reach the cycles of concentration of design, it is therefore necessary to adopt Feed pump of the high-pressure pump of elevated pressures as the special film condensing device of spent acid.The special film condensing device concentrations of acid waste water Jing Afterwards, middle and high concentration acid can be recycled by enterprise, and film produces water because electrical conductivity is very low, also can return to workshop as clean water Use.
After normal operation a period of time, the special membrane component of spent acid can be polluted by indissoluble material present in waste water, Calcium carbonate scale, calcium sulfate scale, metal-oxide dirt, silicon deposits and organic or biogenic deposit are the most common are in these pollutant Thing etc..The property and pollution speed of pollutant is relevant with raw water condition, and pollution slowly develops, if do not take in early stage arranged Apply, pollution will damage the performance of membrane component within the relatively short time.During cleaning by cleaning solution with low pressure and mass flow in film High-pressure side circulation, now membrane component be still mounted in pressure vessel and need to complete the work with special cleaning device.
High high expense, spent acid and water resource waste are produced in change existing spent acid processing system processing procedure serious Situation, it is new containing heavy metal and particulate matter waste acid concentration and reuse special purpose device that enterprise employs this.The spent acidic that enterprise produces Water is entered containing heavy metal and particulate matter waste acid concentration and reuse special purpose device Jing after preliminary pretreatment, and the material of this new device is defeated Enter and output situation such as table 1:
Sequence number Project Material is input into Remarks
1 Flow (t/h) 140
2 Run time (h/t) 20
3 Proportion (g/ml) 1.09 In terms of 25 DEG C
4 Sulfuric acid concentration (%) 5%
5 Iron ion (g/ml) 5000
6 TDS(mg/l) 62000
Table 1
Material is entered containing heavy metal and particulate matter waste acid concentration and reuse special purpose device, output material feelings Jing after pre- heat exchanger Condition such as table 2:
Table 2
By data above as can be seen that after containing heavy metal and particulate matter waste acid concentration and reuse special purpose device, obtaining High concentrated acid, clean recycle-water, iron content waste liquid and particulate slurry containing titanium dioxide, sulfuric acid concentration brings up to 70% from 6%, so as to Enterprise is met to the requirement using acid concentration.While waste water is reused, the ring that discharge of wastewater is caused is it also avoid Pollute in border.
By the special film condensing device of spent acid of the present utility model, it is used for the concentration of acid waste water, due to spent acid , without the need for heating, less energy consumption, running continuous-stable, occupation area of equipment is little, fully automatic operation for special film condensing device, operation Simply, and easy care.
The special film condensing device strong adaptability of spent acid, not only can apply to conventional common film condensing device field, also right The low-down acid waste water of pH value has very strong adaptability, so as to compensate for the domestic deficiency to spent acid embrane method recovery technology.
Particular for the requirement of the pollutant property in acid waste water and cycles of concentration, from extraordinary dedicated film as concentration The osmotic component of device, the pH range of adaptation can as little as less than 0.1, anti-pollution characteristic is good.
In order that the special film device of spent acid can safely and reliably run, and the supervision being easy in running, should install must The instrument wanted and control device.Generally requiring the meter of installing has thermometer, pressure gauge, flow meter, PH tables, electric conductive meter, oxygen Change reduction potential table etc..
The special film condensing device of spent acid is for processing cost is too high in solution industrial acidic wastewater processing procedure and avoids The waste problem of industrial waste acid and water resource, acid waste water realizes the concentration of acid after the special concentration film device of spent acid is processed Recycling and the separation of pure water, concentrated solution and pure water are finally back to enterprise, change original acid waste water and add at a large amount of alkali Mistake high cost and spent acid produced by discharging after reason is wasted, the situation of water resource waste.
Finally it should be noted that above example is only to describe the technical solution of the utility model rather than to this technology Method is limited, and this utility model can extend to other modifications, change in application, apply and embodiment, and because This thinks all such modifications, change, application, embodiment all in the range of spirit or teaching of the present utility model.

Claims (6)

1. a kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter, including ultrafiltration system (100), heavy metal ion point From system (200), sour concentration systems (300) and evaporation concentration system (400), it is characterised in that the ultrafiltration system (100) is even Lead to the separation of heavy metal ions system (200);Separation of heavy metal ions system (200) connects the sour concentration systems (300); The sour concentration systems (300) connection evaporation concentration system (400).
2. waste acid concentration and reclaiming system containing heavy metal and particulate matter according to claim 1, it is characterised in that described Ultrafiltration system (100) includes regulating reservoir (1), heat-exchange system (2), disc filter (3), ultrafiltration intake pool (4) and acidproof ultrafiltration Film device (5), wherein, the regulating reservoir (1) connection heat-exchange system (2), heat-exchange system (2) connection disc filter (3), disc type Filter (3) is by ultrafiltration intake pool (4) and acidproof ultra-filtration membrane device (5) to connecting.
3. waste acid concentration and reclaiming system containing heavy metal and particulate matter according to claim 1, it is characterised in that described Separation of heavy metal ions system (200) produces pond (7) and the first concentrated water pond including separation of heavy metal ions device (6), first (8), wherein, the separation of heavy metal ions device (6) is respectively communicated with the first product pond (7) and the first concentrated water pond (8).
4. waste acid concentration and reclaiming system containing heavy metal and particulate matter according to claim 1, it is characterised in that described Sour concentration systems (300) produce pond (10) and the second concentrated water pond (11) including sour enrichment facility (9), second, wherein, the acid is dense Compression apparatus (9) are respectively communicated with the second product pond (10) and the second concentrated water pond (11).
5. waste acid concentration and reclaiming system containing heavy metal and particulate matter according to claim 1, it is characterised in that described Evaporation concentration system (400) includes vaporising device (12), the sour pond (13) of storage and distillation pond (14), wherein, the vaporising device (12) the sour pond (13) of storage and distillation pond (14) are respectively communicated with.
6. waste acid concentration and reclaiming system containing heavy metal and particulate matter according to claim 1, it is characterised in that described Separation of heavy metal ions in ultrafiltration system (100) in acidproof ultra-filtration membrane device (5) connection separation of heavy metal ions system (200) Device (6), first produces the acid concentration dress in the sour concentration systems (300) of pond (7) connection in separation of heavy metal ions system (200) Put (9), the vaporising device (12) in sour concentration systems (300) in the second concentrated water pond (11) connection evaporation concentration system (400).
CN201620985518.XU 2016-08-30 2016-08-30 Spent acid concentration and recycling system that contain heavy metal and particulate matter Active CN206109125U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107792981A (en) * 2016-08-30 2018-03-13 广东益诺欧环保股份有限公司 A kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107792981A (en) * 2016-08-30 2018-03-13 广东益诺欧环保股份有限公司 A kind of waste acid concentration and reclaiming system containing heavy metal and particulate matter

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Denomination of utility model: Condensation and recovery system of waste acid containing heavy metal and particulate matters

Effective date of registration: 20190521

Granted publication date: 20170419

Pledgee: China Co. truction Bank Corp Guangzhou branch

Pledgor: GUANGDONG YEANOVO ENVIRONMENTAL PROTECTION Co.,Ltd.

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Denomination of utility model: A waste acid concentration and reuse system containing heavy metals and particles

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Pledgee: China Co. truction Bank Corp Guangzhou branch

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