CN108328836A - A kind of water inflow control system based on high slat-containing wastewater minimizing process - Google Patents

A kind of water inflow control system based on high slat-containing wastewater minimizing process Download PDF

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Publication number
CN108328836A
CN108328836A CN201810189542.6A CN201810189542A CN108328836A CN 108328836 A CN108328836 A CN 108328836A CN 201810189542 A CN201810189542 A CN 201810189542A CN 108328836 A CN108328836 A CN 108328836A
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water
reverse osmosis
level
waste water
sent
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CN108328836B (en
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张建飞
权秋红
赵庆
元西方
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Bgt International Environment Technology Co Ltd
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Bgt International Environment Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

A kind of water inflow control system during the minimizing based on high slat-containing wastewater, the parameter index of high slat-containing wastewater by minimizing processing is monitored in real time by water inlet adjustment monitoring device and the water inlet index according to back segment process is adjusted parameter index, and high slat-containing wastewater minimizing process includes at least:Waste water is adjusted to alkaline environment based on the preprocessing process carried out using dosing method, dosage is adjusted according to the practical each ion concentration situation of change of water inlet of the high slat-containing wastewater;And pass through the middle press mold element that width of flow path is 1.524~1.778mm and the high pressure membrane component progress minimizing processing that width of flow path is 1.905~2.159mm successively by pretreated high slat-containing wastewater;High slat-containing wastewater of the water inlet adjustment monitoring device by hygrosensor, chlorion detection, heavy metal ion detector and fine particle detector monitors by minimizing processing is to obtain parameter index.The water inflow control system of the present invention can effectively prevent the pollution of membrane component.

Description

A kind of water inflow control system based on high slat-containing wastewater minimizing process
The present invention is application No. is 201510980936.X, and the applying date is on December 23rd, 2015, and applying type is invention, Apply for a kind of divisional application of the minimizing processing method of entitled high slat-containing wastewater.
Technical field
The present invention relates to industrial wastewater treatment device fields, more particularly to one kind is based on during high slat-containing wastewater minimizing Water inflow control system.
Background technology
In recent years, it with the fast development of the industries such as petrochemical industry, electric power, metallurgy, coal chemical industry, is generated in industrial processes The sewage quantity of the saliferous complicated components such as reverse osmosis concentrated water, trade effluent, circulating sewage and some processes draining increases year by year, this How the sewage of a little saliferous complicated components finally handles and using receiving extensive attention.As country is to enterprise's sewage discharge Control dynamics are increasingly stringent, and especially in water resources shortage area, it is multiple containing salt component how rationally to handle and make good use of this part Miscellaneous sewage is realized wastewater zero discharge, the surrounding enviroment and natural water that we depend on for existence to protection, and is further increased The comprehensive utilization ratio of water resource alleviates water resource pressure and is of great significance.Currently, in waste water treating and reutilizing technology, instead Infiltration embrane method has been increasingly becoming a kind of extremely important processing in the fields such as industrial circulation water treatment, waste water recycling, minimizing Means.
Reverse osmosis technology development ratio currently used for handling waste water is very fast, but existing for the technical finesse complicated ingredient waste water Problem is increasingly prominent, and main problem shows two aspects:
First, reverse-osmosis membrane element has equipment with high desalinization to brine waste, reverse-osmosis membrane element can reach under normal conditions Salt rejection rate 98% or more so that do not undergo phase transition 98% or more salt and impurity in water be trapped in system generation concentrated water In.The recovery utilization rate of the reverse osmosis general water of water manufacturing system can only achieve 75% or so, and water manufacturing system still has about 25% concentrated water It cannot recycle and need to discharge.Due in the concentrated water of these saliferous complexity waste water containing including a large amount of calcium ions, magnesium ion, again Metal ion, silicon ion and colloid substance, also, some wastewater from chemical industry contain a fairly large number of nondegradable organic matter The closely related complicated ingredient with inorganic salts and with production technology, direct emission can cause water pollution to the river being discharged into. Although reverse-osmosis treated realizes a degree of minimizing processing, the salts substances of concentration remain in the concentrated water of exclusion, Such wastewater treatment method influences surrounding enviroment increasingly tight generally using outer row or direct emission after simple process at present The disposition of weight, this final part reverse osmosis concentrated water is a problem.
Second is that the saliferous complexity waste water by low pressure, medium and high pressure reverse osmosis concentration, recycles reverse-osmosis treated mode There are the organic pollutions of membrane component when processing easily asks in film surface generation fouling with the inorganic salts calcium and magnesium compound for tending to saturation Topic.To lead to the problems such as salt separating difficulty increases and separating energy consumption increases, and economy is bad and reliability is relatively low.
Such as Chinese patent CN 102923876A disclose a kind of tube microfiltration membrane method processing heavy metal wastewater thereby heavy metal time Receipts and waste water reuse system.The system by carrying out pH adjustings to waste water, tubular type micro-filtration pre-processes, using reverse osmosis unit into Row Sewage treatment.It realizes and filters out waste particles polluter, and will not there is a phenomenon where divulge mud particle;Microfiltration membranes can be with Acid, alkaline, bleaching and oxidating chemicals cleaning is born, the microfiltration membranes membrane tube through over cleaning has longer validity period.The hair Bright process CIMS is simple, operates more convenient, automation control easy to implement;Floor space is small, can save basis The investment of construction period, but also medicament input can be saved.But the system only carries out pretreatment and reverse osmosis place to waste water Reason, the water resource recovery utilization rate of waste water is relatively low, and there are larger water resource waste problems, while pending tail washings accounts for waste water Large percentage increases the energy consumption of processing tail washings, increases cost for wastewater treatment and environmental issue.
The patent (documents 1) of Publication No. CN103508602A disclose a kind of film integrated with evaporative crystallization it is with high salt The technique for spending zero discharge of industrial waste water.It specifically notes that traditional chemical precipitation method, oxidation-reduction method, membrane separation process and ion are handed over Change the requirement that the techniques such as method are unable to reach zero-emission after wastewater treatment, be based on the technical background, propose integrated application UF membrane, Solid impurity in waste water is concentrated into very high concentration, big portion by the physics such as evaporative crystallization and/or drying, chemistry and biochemical process Divide water to return to recycle, the water of remaining a small amount of adjoint solid waste passes through evaporation/crystallization, evaporation/drying, solid fertilizer Material the approach processing such as absorbs and recycles technological means to not discharge system.It is not directed to the parameter index of waste water into The technological means for the problems such as row is monitored and adjusted to solve the fouling membrane and low producing water ratio in waste water actual process in real time.Into One step, it is also not directed to dosage and is adjusted and the wide reverse osmosis membrane element of super large runner into water concentration dynamic according to reality The technological means of part.
The patent (documents 2) of Publication No. CN102030397A disclose a kind of architectural intermediate water online test method and Device, and specifically note and architectural intermediate water detection device is arranged at the middle water feed pipe towards middle water user to detect into confession The contents of residual chlorine and turbidity situation of middle water in water pipe.It is not particularly suited for the processing of the high slat-containing wastewater of the present invention, meanwhile, Under conditions of documents 1 and documents 2 are combined, those skilled in the art are only capable of accessing, and water inlet detecting device is arranged At the water inlet line of the recycle-water of user with detection process after the obtained water quality of reuse water purification, cannot obtain detection device Technological means applied to monitoring wastewater parameter index and dynamic adjustment to improve fouling membrane with improve producing water ratio.
The patent (documents 3) of Publication No. CN103319042A discloses one kind complicated waste water recycling with high salt and zero-emission Put integrated equipment and technique.It, which is specifically disclosed, carries out complicated waste water with high salt after homogeneous amount is handled by the way that hydroxide is added Sodium, sodium carbonate etc. adjust waste water to the Wastewater Pretreatment process of alkalinity.It is not directed to practical dense into water ion according to water inlet Spend the technological means for being adjusted into Mobile state to dosage and to wastewater parameter index monitor in real time and dynamic adjusts.
Invention content
For the deficiency of the prior art, the present invention provides a kind of minimizing processing method of high slat-containing wastewater, the sides Method is to carry out preliminary minimizing processing and depth concentration after being pre-processed to high slat-containing wastewater again, at the depth concentration The water inflow control system of reason be will pass through preliminary minimizing processing generate the reverse osmosis concentrated solution of high pressure in chlorine residue, heavy metal from Son and colloid are after active carbon filter and resin container absorption, through third cartridge filter by small suspended matter and gel filtration Fall, and filtered waste water is sent to water inlet and adjusts monitoring device, based on level-one electrically-driven ion during depth concentration The filtered waste water information of film unit water inlet index and the water inlet adjustment monitoring device monitoring, monitoring is adjusted in water inlet Under the control of device, at least one of thermostat, active carbon filter, resin container and third cartridge filter place is used It manages device and circular treatment at least once is carried out to filtered waste water, until the filtered waste water reaches the level-one electricity and drives Dynamic ion film unit water inlet index.
According to a preferred embodiment, the water inlet adjustment monitoring device includes:Temperature for monitoring waste water temperature Detector, the chlorion detector for monitoring waste water chlorine ion concentration, for monitor the heavy metal of concentration of heavy metal ion from Sub- detector, the fine particle detector for monitoring colloid and small suspension content;Water temperature for adjusting waste water temperature Adjuster, the first drain valve that level-one electrically-driven ion film unit is flowed into for controlling waste water, for controlling waste water flowing water activity Second drain valve of carbon filter, the third drain valve that resin container is flowed into for controlling waste water flow into third for controlling waste water 4th drain valve of cartridge filter;Distributed A/D acquisition modules for receiving monitoring data), for the list of data processing The distributed digital input/output module of piece machine, the PC terminals for controlling the microcontroller and feedback control information.
According to a preferred embodiment, the water inlet adjustment monitoring device will be described by distributed A/D acquisition modules The information that hygrosensor, chlorion detector, heavy metal ion detector and fine particle detector detect is transmitted to The microcontroller, the inflow requirement of the level-one electrically-driven ion film unit inputted based on PC terminals by the microcontroller is to the prison Measurement information carry out data processing, and by handling result through distributed digital input/output module feed back to the thermostat, First drain valve, the second drain valve, third drain valve, the 4th drain valve.
According to a preferred embodiment, the level-one electrically-driven ion film unit water inlet index is:Inflow temperature 5~40 ℃;Contents of residual chlorine is not more than 0.05mg/L;Heavy metal ion content is not more than 0.1mg/L;Sewage quality index S DI is not more than 3.0。
According to a preferred embodiment, the preliminary minimizing processing includes the following steps:By pretreated waste water Medium pressure reverse osmosis unit is sent into after being filtered by the first cartridge filter;Waste water is after the processing of medium pressure reverse osmosis unit Obtain middle pressure reverse osmosis produced water and the middle reverse osmosis concentrated solution of pressure, wherein medium pressure reverse osmosis produced water is sent into two-pass reverse osmosis dress It sets, the reverse osmosis concentrated solution of medium pressure is sent after the filtering of the second cartridge filter to the high pressure reverse osmosis unit;The process The reverse osmosis concentrated solution of middle pressure of filter obtains high pressure reverse osmosis produced water after high pressure reverse osmosis unit processing and high pressure is reverse osmosis Concentrated solution, wherein the high pressure reverse osmosis produced water is sent into second level reverse osmosis apparatus, and the reverse osmosis concentrated solution of high pressure carries out depth Concentration.
According to a preferred embodiment, the depth concentration includes the following steps:The high pressure is reverse osmosis concentrated molten Liquid send to level-one electrically-driven ion film unit after water inflow control system is handled and carries out depth concentration;It is driven through the level-one electricity The dense saline solution of level-one electric drive and level-one electric drive production water are obtained after dynamic ionic membrane cell processing, wherein the level-one electric drive production Water enters second level reverse osmosis apparatus, and the dense saline solution of level-one electric drive is sent into two level electrically-driven ion film list through third booster water pump Member;The dense saline solution of two level electric drive is obtained after two level electrically-driven ion film unit processing and two level electric drive produces water, it is described Two level electric drive production water presses pond, the two level electric drive dense saline solution to be sent into the second strong brine case in being sent into.
According to a preferred embodiment, the production water for being sent into the second level reverse osmosis apparatus obtains two level reverse osmosis after processing Production water and the dense saline solution of two-pass reverse osmosis thoroughly, wherein the two-pass reverse osmosis production water is sent into fresh water tanks, and the two-pass reverse osmosis is dense Saline solution is sent to the first intermediate pool.
According to a preferred embodiment, medium pressure reverse osmosis unit uses width of flow path for 1.524~1.778mm Middle press mold element, the high pressure reverse osmosis unit uses width of flow path for the high pressure membrane component of 1.905~2.159mm.
According to a preferred embodiment, the active carbon filter is used to adsorb what preliminary minimizing did not removed in the process Chlorine, while adsorbing small organic molecule, colloid and heavy metal ion;The resin container has ion exchange resin, for adsorbing Heavy metal ion after active carbon filter processing in solution;The third cartridge filter is used in filtering solution Small suspended matter and colloid.
According to a preferred embodiment, the Wastewater Pretreatment, preliminary minimizing processing and depth concentration include Following steps:High slat-containing wastewater is carried out be added after homogeneous amount processing lime or sodium hydroxide, sodium carbonate, aluminium polychloride and The coagulant and softening agent of one or more of polyacrylamide are precipitated, and it is alkaline environment, sediment row to adjust waste water Enter sludge-tank, waste water after precipitation, which is sent into tubular type microstrainer, to be filtered;
Sediment in the sludge-tank obtains mud cake and brine waste after sludge dehydration device carries out mud-water separation, institute It states mud cake and carries out dewatered sludge processing, the brine waste is sent into regulating reservoir and is mixed with waste water stoste;
It is sent into candle filter through the filtered supernatant of the tubular type microstrainer, it is filtered through the tubular type microstrainer Chemical precipitates is discharged into highly dense pond;The first intermediate pool is sent into carry out minimizing through the filtered production water of the candle filter Processing;
In first intermediate pool by pretreated waste water by the first cartridge filter filter out waste water suspension and Medium pressure reverse osmosis unit is sent into after colloid;
Waste water obtains middle pressure reverse osmosis produced water and the middle reverse osmosis concentrated solution of pressure after the processing of medium pressure reverse osmosis unit, In, medium pressure reverse osmosis produced water is sent into second level reverse osmosis apparatus, and the reverse osmosis concentrated solution of medium pressure is through the second cartridge filter It is sent after filtering to the high pressure reverse osmosis unit;
It is reverse osmosis that the filtered middle reverse osmosis concentrated solution of pressure obtains high pressure after high pressure reverse osmosis unit processing Produce water and the reverse osmosis concentrated solution of high pressure, wherein the high pressure reverse osmosis produced water is sent into second level reverse osmosis apparatus, the high pressure reverse osmosis Saturating concentrated solution, which is sent to depth, concentrates water inflow control system;
The depth concentration water inflow control system is the reverse osmosis concentrated solution of high pressure that will pass through preliminary minimizing processing and generate In chlorine residue, heavy metal ion and colloid through active carbon filter and resin container absorption after, will be small through third cartridge filter Suspended matter and gel filtration fall, and filtered waste water is sent to water inlet and adjusts monitoring device;
Based on level-one electrically-driven ion film unit water inlet index during depth concentration and water inlet adjustment monitoring Device monitoring was ensured public security to the filtered waste water information, then through thermostat, active carbon filter, resin container and third The realization of at least one of filter processing unit handles the filtered waste water of the process at least once, until described filtered Waste water reaches the level-one electrically-driven ion film unit water inlet index;
The reverse osmosis concentrated solution of high pressure is sent after depth concentration water inflow control system processing to level-one electrically-driven ion film Unit carries out depth concentration;The dense saline solution of level-one electric drive and one are obtained after level-one electrically-driven ion film unit processing Grade electric drive produces water, wherein the level-one electric drive production water enters second level reverse osmosis apparatus, the dense saline solution warp of level-one electric drive Third booster water pump is sent into two level electrically-driven ion film unit;
The dense saline solution of two level electric drive is obtained after two level electrically-driven ion film unit processing and two level electric drive produces water, The two level electric drive production water presses pond, the two level electric drive dense saline solution to be sent into the second strong brine case in being sent into;
The production water for being sent into the second level reverse osmosis apparatus obtains two-pass reverse osmosis production water after processing and two-pass reverse osmosis is dense Saline solution, wherein the two-pass reverse osmosis production water is sent into fresh water tanks, and the dense saline solution of two-pass reverse osmosis is sent to the first intermediate water Pond;
The high slat-containing wastewater (after the pretreatment, preliminary minimizing processing and depth concentration, can recycle described in The 95% of waste water solution is with up to fresh water tanks, the production water that the fresh water tanks are collected is sent into reuse water tank to realize that waste water is sharp again With.
The present invention has the following advantages:
(1) during the preliminary minimizing of waste water of the invention, waste water is under alkaline condition, can be inhibited under this condition The fouling of film surface silicon and organic contamination problem.
(2) high-pressure membrane original paper of the present invention has the characteristics that super large runner, special runner and structure design make reverse osmosis System is less susceptible to that the pollution problem of ion fouling and organic matter occurs.
(3) water inlet adjusting apparatus of the invention can effectively adjust waste water temperature, realize level-one electrically-driven ion film unit It works under optimum temperature, improves its producing water ratio.
(4) water inlet adjusting apparatus of the invention can effectively avoid electrically-driven ion film calcium ions and magnesium ions pollution problem and a huge sum of money Belong to ion in film surface scale problems.
(5) it is handled by this wastewater reduction processing method, recyclable 95% or more high-quality desalted water is back to production dress It sets, is that significantly decrement treatment creates favorable conditions follow-up water.
Description of the drawings
Fig. 1 is the high slat-containing wastewater process chart of the present invention;
Fig. 2 is that the high slat-containing wastewater of the present invention handles a preferred embodiment flow chart;With
Fig. 3 is the water inlet adjusting apparatus module diagram of the present invention.
Reference numerals list
101:High slat-containing wastewater 102:Regulating reservoir 103:Elevator pump
104:Highly dense pond 105:First booster pump 106:Tubular type microstrainer
107:Candle filter 108:First intermediate pool 109:Second booster pump
110:First cartridge filter 111:Middle pressure reverse osmosis unit 112:Middle pressure pond
113:Third booster pump 114:Second cartridge filter 115:High pressure reverse osmosis unit
116:Second intermediate pool 117:First booster water pump 118:Active carbon filter
119:Resin container 120:Intermediate water tank 121:Second booster water pump
122:Third cartridge filter 123:Level-one electrically-driven ion film unit 124:First strong brine case
125:Third booster water pump 126:Two level electrically-driven ion film unit 127:Second strong brine case
128:Second level reverse osmosis apparatus 129:Fresh water tanks 130:Reuse water tank
131:Salt evaporated crystallization device 132:Crystal salt 133:Sludge-tank
134:Sludge dehydration device 135:Mud cake 136:Chemicals dosing plant
200:Water inlet adjustment monitoring device 201:Hygrosensor 202:Chlorion detector
203:Heavy metal ion detector 204:Fine particle detector 205:Thermostat
206:First drain valve 207:Second drain valve 208:Third drain valve
209:4th drain valve 210:Distributed A/D acquisition modules 211:Distributed digital input is defeated Go out module
212:Microcontroller 213:PC terminals
Specific implementation mode
It is described in detail with reference to the accompanying drawings and examples.
Fig. 1 shows the wastewater treatment process figure of the present invention.As shown in Figure 1, the high slat-containing wastewater processing of the present invention includes Wastewater Pretreatment stage, waste water preliminary minimizing processing stage, waste water advanced enriching stage and waste water evaporative crystallization stage.
Referring to Fig. 1, Wastewater Pretreatment stage apparatus of the present invention includes regulating reservoir 102, elevator pump 103, highly dense pond 104, and One booster pump 105, tubular type microstrainer 106, candle filter 107, the first intermediate pool 108, sludge-tank 133, sludge dewatering dress 134 are set, chemicals dosing plant 136.Regulating reservoir 102 is connected with elevator pump 103, for being carried out at homogeneous amount to high slat-containing wastewater 101 Reason.Elevator pump 103 will carry out homogeneous and measure that treated high slat-containing wastewater be sent to highly dense pond 104.Chemicals dosing plant 136 with it is highly dense Pond 104 is connected, and coagulant and softening agent is added for the waste water into highly dense pond 104, while waste water is adjusted to alkaline environment, Alkaline environment has the trend for inhibiting film surface that silicon fouling and organic contamination occurs.Highly dense pond 104 also with the first booster pump 105 and Sludge-tank 133 is connected.Highly dense pond 104 is for realizing the coagulation of waste water, softening process and the turbid precipitation process of drop for completing waste water. The chemical sludge of precipitation is discharged into sludge-tank 133, remaining exhausted water is sent through the first booster pump 105 to tubular type microstrainer 106.Sludge-tank 133 are connected with sludge dehydration device 134.Sludge-tank 133 is sent into being discharged into after chemical sludge therein carries out sludge adjustment processing Sludge dehydration device 134 is handled.Sludge dehydration device 134 is connected with regulating reservoir 102.Sludge dehydration device 134 is to being sent into Sludge therein carries out mud-water separation processing.The waste water that the separation of sludge dehydration device 134 generates is sent into regulating reservoir 102 and raw wastewater Mixing reprocessing.The mud cake 135 that the separation of sludge dehydration device 134 generates finally carries out dewatered sludge processing.Tubular type microstrainer 106 It is connected with candle filter 107 and highly dense pond 104.Tubular type microstrainer 106 is sent for filtering out the coagulation colloidal substance in waste water To highly dense pond 104, waste water is sent to candle filter 107 after filtering.Candle filter 107 is connected with the first intermediate pool 108, filter Core filter 107, which will be fed into after waste water therein is filtered, to be sent to the first intermediate pool 108.
Referring again to Fig. 1, the preliminary minimizing processing stage device of waste water of the present invention includes the second booster pump 109, and first protects Pacify filter 110, middle pressure divides permeability apparatus 111, middle pressure pond 112, third booster pump 113, the second cartridge filter 114, height Pressure divides permeability apparatus 115, the second intermediate pool 116, second level reverse osmosis apparatus 128, fresh water tanks 129, reuse water tank 130.The Two booster pumps 109 are connected with the first cartridge filter 110.Second booster pump 109 is used for the waste water of the first intermediate pool 108 is defeated It send to the first cartridge filter 110.First cartridge filter 110 is connected with middle pressure reverse osmosis unit 111.First security personnel's filtering Device 110 send filtered waste water to middle pressure reverse osmosis unit 111 for filtering out small suspended matter in waste water.Middle pressure reverse osmosis Saturating device 111 is connected with middle pressure pond 112 and second level reverse osmosis apparatus 128.It is middle pressure it is reverse osmosis fill 111 use width of flow path for The middle press mold element of 1.524~1.778mm.Middle pressure reverse osmosis unit 111 is used to pressurize to waste water, and carries out reverse-osmosis treated. Pressure reverse osmosis produced water enters second level reverse osmosis apparatus 128 during treated, and the middle reverse osmosis concentrated solution of pressure is sent to middle pressure water after processing Pond 112.Middle pressure pond 112 is connected with third booster pump 113.Third booster pump 113 is connected with the second cartridge filter 114.The Three booster pumps 113 are used to send the reverse osmosis concentrated solution of middle pressure in middle pressure pond 112 to the second cartridge filter 114.Second protects Peace filter 114 is connected with high pressure reverse osmosis unit 115.Second cartridge filter 114 is for filtering out small suspension in waste water Object, and waste water after filtering is sent to high pressure reverse osmosis unit 115.High pressure reverse osmosis unit 115 and the second intermediate pool 116 and two Grade reverse osmosis unit 128 is connected.High pressure reverse osmosis unit 115 uses width of flow path for the high pressure membrane element of 1.905~2.159mm Part.High pressure reverse osmosis unit 115 pressurizes to being sent into waste water therein, and completes waste-water high-pressure reverse-osmosis treated, after processing High pressure reverse osmosis produced water is sent to second level reverse osmosis apparatus 128, and the reverse osmosis concentrated solution of high pressure is sent into the second intermediate pool after processing 116.Second level reverse osmosis apparatus 128 is connected with fresh water tanks 129.Second level reverse osmosis apparatus 128 is used for entering production water therein Secondary reverse-osmosis treated is carried out, gained two-pass reverse osmosis production water is sent through fresh water tanks 129 to reuse water tank 130 after processing, is realized Water resource recycles, and the dense saline solution of two-pass reverse osmosis send to the first intermediate pool 108 and mixed with raw wastewater after processing.
Referring again to Fig. 1, the waste water advanced concentration stage apparatus of the present invention includes the first booster water pump 117, activated carbon Filter 118, resin container 119, intermediate water tank 120, the second booster water pump 121, third cartridge filter 122, level-one electric drive Ion film unit 123, the first strong brine case 124, third booster water pump 125, two level electrically-driven ion film unit 126, second is dense Brine tank 127, second level reverse osmosis apparatus 128, fresh water tanks 129, reuse water tank 130.First booster water pump 117 and activated carbon mistake Filter 118 is connected.First booster water pump 117 is for sending the reverse osmosis concentrated solution of high pressure of the second intermediate pool 116 to activated carbon Filter 118.Active carbon filter 118 is connected with resin container 119.Active carbon filter 118 is for adsorbing preliminary minimizing Chlorine residue in journey prevents oxygen poisoning pollution more than ion exchange resin free state, while also adsorbing small organic molecule, colloid and again Metal ion, and the concentrated solution after absorption is sent to resin container 119.Resin container 119 is connected with intermediate water tank 120.Resin Tank 119 is used to adsorb the heavy metal ion through in treated the solution of active carbon filter 118, and will treated solution feeding Intermediate water tank 120.Intermediate water tank 120 is connected with the second booster water pump 121.Second booster water pump 121 and third cartridge filter 122 are connected.Second booster water pump 121 is for sending the solution of intermediate water tank 120 to third cartridge filter 122.Third is ensured public security Filter 122 is connected with level-one electrically-driven ion film unit 123.Third cartridge filter 122 is small in solution for filtering out Suspended matter, and waste water after filtering is sent to level-one electrically-driven ion film unit 123.Level-one electrically-driven ion film unit 123 and One strong brine case 124 is connected with second level reverse osmosis apparatus 128.Level-one electrically-driven ion film unit 123 is used to enter waste water and follow The processing of ring desalination and concentration obtains level-one electric drive production water and is sent into second level reverse osmosis apparatus 128, level-one electricity is obtained after processing after processing Dense saline solution is driven to enter the first strong brine case 124.Second level reverse osmosis apparatus 128 is connected with fresh water tanks 129.Two-pass reverse osmosis fills 128 are set for carrying out secondary reverse-osmosis treated to entering production water therein, gained two-pass reverse osmosis produces water through fresh water water after processing Case 129 send to reuse water tank 130 and realizes that water resource recycles, and the dense saline solution of two-pass reverse osmosis is sent to the first intermediate pool after processing 108 mix with raw wastewater.First strong brine case 124 is connected with third booster water pump 125.Third booster water pump 125 and two level electricity Ion film unit 126 is driven to be connected.Third booster water pump 125 is used for the dense salt of level-one electric drive in the first strong brine case 124 Liquid is sent to two level electrically-driven ion film unit 126.Two level electrically-driven ion film unit 126 and the second strong brine case 127 and middle pressure Pond 112 is connected.Two level electrically-driven ion film unit 126 is used to carry out cycle desalination and concentration wastewater treatment to waste water, after processing It obtains pressure pond 112 during two level electric drive production water is sent into mix with the middle reverse osmosis concentrated solution of pressure in pond, two level electricity is obtained after processing Dense saline solution is driven to enter the second strong brine case 127.Second strong brine case 127 is connected with salt evaporated crystallization device 131.Second dense salt Water tank 127 is used to the dense saline solution of two level electric drive being sent into evaporated crystallization device 131.
Referring to Fig. 2, for a preferred embodiment in the present invention waste water advanced concentration stage, which includes First booster water pump 117, active carbon filter 118, resin container 119, intermediate water tank 120, the second booster water pump 111, third are protected Pacify filter 122, water inlet adjustment monitoring device 200, level-one electrically-driven ion film unit 123, the first strong brine case 124, third Booster water pump 125, two level electrically-driven ion film unit 126, the second strong brine case 127, second level reverse osmosis apparatus 128, fresh water water Case 129, reuse water tank 130.In conjunction with shown in Fig. 3, water inlet adjustment monitoring device 200 includes:Hygrosensor 201, chlorion are visited Survey device 202, heavy metal ion detector 203, fine particle detector 204, thermostat 205, the first drain valve 206, the Two drain valves 207, third drain valve 208, the 4th drain valve 209, distributed A/D acquisition modules 210, distributed digital input Output module 211, microcontroller 212, PC terminals 213.
First booster water pump 117 is connected with active carbon filter 118.First booster water pump 117 is used for the second intermediate water The reverse osmosis concentrated solution of high pressure in pond 116 is sent to active carbon filter 118.Active carbon filter 118 is connected with resin container 119.It is living Property carbon filter 118 be used to adsorb chlorine residue during preliminary minimizing, prevent oxygen poisoning more than ion exchange resin free state dirty Dye, while small organic molecule, colloid and heavy metal ion are also adsorbed, and the concentrated solution after absorption is sent to resin container 119.Resin container 119 is connected with intermediate water tank 120.Resin container 119 is for adsorbing through treated the solution of active carbon filter 118 In heavy metal ion, and treated solution is sent into intermediate water tank 120.Intermediate water tank 120 and 121 phase of the second booster water pump Even.Second booster water pump 121 is connected with third cartridge filter 122.Second booster water pump 121 is used for intermediate water tank 120 Solution is sent to third cartridge filter 122.Third cartridge filter 122 is connected with water inlet adjustment monitoring device 200.Third is protected Waste water after filtering is sent to water inlet for filtering out small suspended matter in solution and adjusts monitoring device 200 by peace filter 122. Water inlet adjustment monitoring device 200 is connected by the first drain valve 206 with level-one electrically-driven ion film unit 123.Water inlet adjustment prison Device 200 is surveyed by the second drain valve 207 to be connected with active carbon filter 118.Water inlet adjustment monitoring device 200 is arranged by third Water valve 208 is connected with resin container 119.Water inlet adjustment monitoring device 200 passes through the 4th drain valve 209 and third cartridge filter 122 are connected.Water inlet adjustment monitoring device 200 is collected the hygrosensor 201 by distributed A/D acquisition modules 210 Waste water solution temperature information be transmitted to microcontroller.Water inlet adjustment monitoring device 200 will by distributed A/D acquisition modules 210 202 collected waste water solution chlorine ion concentration information of chlorion detector is transmitted to microcontroller 212.Water inlet adjustment monitoring device 200 is dense by 203 collected waste water solution heavy metal ion of heavy metal ion detector by distributed A/D acquisition modules 210 Degree information is transmitted to microcontroller 212.Water inlet adjustment monitoring device 200 is by distributed A/D acquisition modules 210 by fine particle 204 collected waste water solution concentration of heavy metal ion information of detector is transmitted to microcontroller 212.From PC terminals 213 to monolithic Machine 212 inputs the water inlet index of level-one electrically-driven ion film unit 123.The level-one electricity that microcontroller 212 is inputted based on PC terminals 213 Drive the inflow requirement of ion film unit 123 to waste water solution temperature, chloride ion content, the heavy metal ion monitored Content and fine particle content information carry out data processing.Microcontroller 212 inputs data processed result through distributed digital defeated Go out module 211 and feed back to the thermostat 205, and waste water solution temperature is controlled by thermostat 205.Microcontroller Data processed result is fed back to the second drain valve 207 by 212 through distributed digital input/output module 211, and passes through control the Two drain valves 207 are to control whether that waste water solution, which is drained into active carbon filter 118, carries out dechlorination process again.Microcontroller Data processed result is fed back to third drain valve 208 by 212 through distributed digital input/output module 211, and passes through control the Three drain valves 208 are to control whether that waste water solution, which is discharged into resin container 119, to carry out removing metal ion treatment again.Microcontroller Data processed result is fed back to the 4th drain valve 209 by 212 through distributed digital input/output module 211, and passes through control the Four drain valves 209 are to control whether that waste water solution, which is flowed into third cartridge filter 122, carries out the processing of removal of impurities again.Until into The waste water that water adjustment monitoring device 200 monitors reaches the water inlet index of level-one electrically-driven ion film unit 123, microcontroller 212 Data processed result is fed back into the first drain valve 206 through distributed digital input/output module 211, and passes through the first drain valve 206 control waste water solutions flow into level-one electrically-driven ion film unit 123.Level-one electrically-driven ion film unit 123 and the first dense salt Water tank 124 is connected with second level reverse osmosis apparatus 128.Level-one electrically-driven ion film unit 123 to waste water for entering cycle desalination Concentration obtains level-one electric drive production water and is sent into second level reverse osmosis apparatus 128, it is dense that level-one electric drive is obtained after processing after processing Saline solution enters the first strong brine case 124.Second level reverse osmosis apparatus 128 is connected with fresh water tanks 129.Second level reverse osmosis apparatus 128 For carrying out secondary reverse-osmosis treated to entering production water therein, gained two-pass reverse osmosis produces water through fresh water tanks 129 after processing It send to reuse water tank 130 and realizes that water resource recycles, the dense saline solution of two-pass reverse osmosis is sent to the first intermediate pool 108 and original after processing Waste water mixes.First strong brine case 124 is connected with third booster water pump 125.Third booster water pump 125 and two level electric drive from Sub- film unit 126 is connected.Third booster water pump 125 be used for by the dense saline solution of level-one electric drive in the first strong brine case 124 send to Two level electrically-driven ion film unit 126.Two level electrically-driven ion film unit 126 and the second strong brine case 127 and middle pressure pond 112 It is connected.Two level electrically-driven ion film unit 126 is used to carry out cycle desalination and concentration wastewater treatment to waste water, and two level is obtained after processing Pressure pond 112 is mixed with the middle reverse osmosis concentrated solution of pressure in pond during electric drive production water is sent into, and the dense salt of two level electric drive is obtained after processing Liquid enters the second strong brine case 127.Second strong brine case 127 is connected with salt evaporated crystallization device 131.Second strong brine case 127 For the dense saline solution of two level electric drive to be sent into evaporated crystallization device 131.
Referring to Fig. 2, wastewater treatment of the invention further includes the waste water evaporative crystallization stage, and waste water evaporated crystallization device includes salt Evaporated crystallization device 131, fresh water tanks 129, reuse water tank 130.Salt evaporated crystallization device 131 is connected with fresh water tanks 129.With In being evaporated crystallization treatment to being sent into the dense saline solution of two level electric drive therein, the production water for handling generation is sent through fresh water tanks 129 Enter reuse water tank 130 for realizing water resource reuse, the crystal salt 132 for handling generation carries out salt integrated treatment again.
Embodiment 1
It is illustrated with reference to Fig. 1 the Wastewater Pretreatment process of the present invention.High slat-containing wastewater 101 is carried out by regulating reservoir 102 Matter measures adjusting processing.High slat-containing wastewater 101 comes from water in water circulating system with water and production technology draining in Industrial Waste Water Treatments. Processed waste water, which will be adjusted, by elevator pump 103 is sent into highly dense pond 104.It is added successively to highly dense pond 104 by chemicals dosing plant 136 Lime or sodium hydroxide, sodium carbonate, aluminium polychloride, polyacrylamide, and waste water is adjusted to alkaline environment.The hydrogen-oxygen of addition Change sodium and sodium carbonate is used to carry out sofening treatment to waste water, sodium hydroxide is configured to the solution of 20% concentration, dosage 1.5g/ L, sodium carbonate are configured to the solution of 15% concentration, dosage 3g/L, the aluminium polychloride and polyacrylamide of addition for pair Waste water carries out coagulating treatment, and aluminium polychloride is made into the solution of 20% concentration, and dosing, polyacrylamide are carried out according to the amount of 30mg/L Amine is made into the solution of 0.3% concentration, and dosing is carried out according to the amount of 3mg/L, and sodium hydroxide, sodium carbonate, aluminium polychloride, poly- The dosage of acrylamide should not be too large, and need to be adjusted according to the practical each ion concentration situation of change of water inlet of waste water, otherwise easily Reverse osmosis membrane and electrically-driven ion fouling membrane are caused, the service life of film is influenced.It is added to the waste water stoste in the highly dense pond 104 It after coagulant and softening agent, is precipitated, sediment is discharged into sludge-tank 133.Waste water stoste is sent into tubular type microstrainer after precipitating 106 are filtered.Waste water residence time in tubular type microstrainer 106 is 2.5 hours, and under natural subsidence effect, supernatant is logical It crosses tubular type microstrainer 106 and enters candle filter 107, the highly dense pond of chemical precipitates feeding carries out sedimentation and is discharged into sludge-tank 133. Production water is sent into the first intermediate pool 108 by waste water stoste by filtering in the candle filter 107, is so far completed waste water and is located in advance Reason process.
Embodiment 2
Illustrate the wastewater reduction processing procedure of the present invention in conjunction with Fig. 2 and Fig. 3.To realize that Sewage treatment recycles, waste water Minimizing process includes the preliminary minimizing processing of waste water and waste water advanced concentration process.
Second booster pump 109 will complete pretreated waste water in first intermediate pool 108 and be delivered to the first cartridge filter 110.First cartridge filter 110 presses reverse osmosis unit for filtering out small suspended matter in waste water in being sent into waste water after filtering 111。
According to a preferred embodiment, middle pressure reverse osmosis unit 111 uses membrane material compound for aromatic polyamide Material runner width is the middle press mold element of 1.651mm, is carried out to waste water under the conditions of operating pressure is 2.0~3.5MPa anti- Infiltration is handled, special runner and structure design so that middle pressure reverse osmosis unit 111 is not susceptible to ion fouling and organic matter Dirt is stifled.Middle its Sewage treatment rate of pressure reverse-osmosis treated process is more than 70%, can retain 97.5% salts substances, can will be averaged The raw water that TDS is 6500mg/L is concentrated to TDS and is more than 21600mg/L.The middle pressure reverse osmosis produced water of recycling is sent into two-pass reverse osmosis Device 128, the middle reverse osmosis concentrated solution of pressure are sent to middle pressure pond 112, and middle pressure reverse osmosis produced water is handled through two-pass reverse osmosis, and two level is anti- Infiltration production water enters fresh water tanks 129, and two-pass reverse osmosis concentrated solution is sent again to the first intermediate pool 8.
The middle reverse osmosis concentrated solution of pressure is filtered through the second cartridge filter 114, is sent to high pressure reverse osmosis unit 115.According to one A preferred embodiment, high pressure reverse osmosis unit 115 use the membrane material to be for aromatic polyamide composite material width of flow path The high pressure membrane component of 2.032mm, it is reverse osmosis concentrated molten to filtered middle pressure under conditions of operating pressure is 3.5~4.5MPa Liquid is into horizontal high voltage reverse-osmosis treated, special runner and structure design so that high pressure reverse osmosis unit 111 is not susceptible to ion knot The dirt of dirt and organic matter is stifled.Its Sewage treatment rate of high pressure reverse-osmosis treated process is more than 65%, can retain 97.2% or more salt The raw water that average TDS is 21600mg/L can be concentrated to TDS and be more than 50000mg/L by substance.The high pressure of recycling is reverse osmosis produced Water is sent into second level reverse osmosis apparatus 28 and carries out two-pass reverse osmosis processing, and two-pass reverse osmosis production water enters fresh water tanks 129, and two level is anti- Infiltration concentrated solution is sent again to the first intermediate pool 108, and the reverse osmosis concentrated solution of high pressure send to the second intermediate pool 116 and waits for Depth concentration.
According to a kind of preferred embodiment, the reverse osmosis concentrated solution of high pressure through active carbon filter 118 and resin container 119 at Reason is sent to water inlet after the filtering of security filter 122 and adjusts monitoring device 200.
According to high-quality preferred embodiment, the water inlet of level-one electrically-driven ion film unit 123 index is:Inflow temperature 5~ 40℃;Contents of residual chlorine is not more than 0.05mg/L;Heavy metal ion content is not more than 0.1mg/L;Sewage quality index S DI is little In 3.0.
Water inlet adjustment monitoring device 200 is visited hygrosensor 201, chlorion by distributed A/D acquisition modules 210 Survey device 202, the information that heavy metal ion detector 203 and fine particle detector 204 detect is transmitted to the microcontroller 212, the inflow requirement of the level-one electrically-driven ion film unit 123 inputted based on PC terminals 213 by the microcontroller 212 is to institute It states monitoring information and carries out data processing.
Data processed result is fed back to the lower water temperature by microcontroller 212 through distributed digital input/output module 211 Device 205, and waste water solution temperature is controlled by thermostat 205.Microcontroller 212 is by data processed result through distributed number Word input and output module 211 feeds back to the second drain valve 207, and by controlling the second drain valve 207 to control whether to give up Aqueous solution drains into active carbon filter 118 and carries out dechlorination process again.Microcontroller 212 is by data processed result through distributed number Word input and output module 211 feeds back to third drain valve 208, and by controlling third drain valve 208 to control whether to give up Aqueous solution is discharged into resin container 119 and carries out removing metal ion treatment again.Microcontroller 212 is by data processed result through distributed digital Input/output module 211 feeds back to the 4th drain valve 209, and by controlling the 4th drain valve 209 to control whether waste water Solution flows into third cartridge filter 122 and carries out the processing of removal of impurities again.Up to what water inlet adjustment monitoring device 200 monitored gives up Water reaches the water inlet index of level-one electrically-driven ion film unit 123, and microcontroller 212 is defeated through distributed digital by data processed result Enter output module 211 and feed back to the first drain valve 206, and waste water solution inflow level-one is controlled by controlling the first drain valve 206 Electrically-driven ion film unit 123 carries out depth concentration.
Level-one electrically-driven ion film unit 123 further concentrates the reverse osmosis concentrated solution of high pressure using electrically-driven ion film, The Halite water that TDS is 50000mg/L can be concentrated to 120000mg/L, production water enters second level reverse osmosis apparatus 128, dense Solution enters the first strong brine case 124.Level-one electric drive produces water after two-pass reverse osmosis is handled, and two-pass reverse osmosis production water enters light Water tank 129, two-pass reverse osmosis concentrated solution are sent again to the first intermediate pool 108.Dense saline solution passes through in first strong brine case 124 Third booster water pump 125 is sent into two level electrically-driven ion film unit 126, using electrically-driven ion film to the reverse osmosis concentrated solution of high pressure The Halite water that TDS is 120000mg/L can be concentrated to 200000mg/L, two level electrically-driven ion film by further concentration Pressure pond 112 is mixed with the middle reverse osmosis concentrated solution of pressure during production water is sent into, the two level electrically-driven ion film unit residue concentrated solution It is sent into the second strong brine case 127.
High slat-containing wastewater 101 can recycle the 95% of waste water solution after preliminary minimizing processing and depth concentration Up to fresh water tanks 129, to realize waste water reuse.
It should be noted that above-mentioned specific embodiment is exemplary, those skilled in the art can disclose in the present invention Various solutions are found out under the inspiration of content, and these solutions also belong to disclosure of the invention range and fall into this hair Within bright protection domain.It will be understood by those skilled in the art that description of the invention and its attached drawing are illustrative and are not Constitute limitations on claims.Protection scope of the present invention is limited by claim and its equivalent.

Claims (10)

1. the water inflow control system during a kind of minimizing based on high slat-containing wastewater, which is characterized in that described into water management system System adjusts the parameter index and foundation of high slat-containing wastewater of monitoring device (200) monitoring in real time by minimizing processing by water inlet The water inlet index of back segment process is adjusted the parameter index, wherein
High slat-containing wastewater minimizing process includes at least:Waste water is adjusted to based on the preprocessing process carried out using dosing method Alkaline environment, wherein dosage is adjusted according to the practical each ion concentration situation of change of water inlet of the high slat-containing wastewater;With And by pretreated high slat-containing wastewater successively by using width of flow path in the middle press mold element of 1.524~1.778mm It presses reverse osmosis unit (111) and uses width of flow path for the high pressure reverse osmosis unit of the high pressure membrane component of 1.905~2.159mm (115) minimizing processing is carried out;
The water inlet adjustment monitoring device (200) passes through hygrosensor (201), chlorion detector (202), heavy metal ion Detector (203) and fine particle detector (204) the monitoring high slat-containing wastewater by minimizing processing are described to obtain Parameter index.
2. water inflow control system as described in claim 1, which is characterized in that the hygrosensor (201) is useless for monitoring Coolant-temperature gage, the chlorion detector (202) is for monitoring waste water chlorine ion concentration, the heavy metal ion detector (203) For monitoring concentration of heavy metal ion, the fine particle detector (204) is for monitoring colloid and small suspension content;
The water inflow control system further includes:For adjusting the thermostat (205) of waste water temperature, being flowed into for controlling waste water The first drain valve (206) of level-one electrically-driven ion film unit (123) flows into active carbon filter (118) for controlling waste water The second drain valve (207), for control waste water flow into resin container (119) third drain valve (208), for controlling waste water stream Enter the 4th drain valve (209) of third cartridge filter (122);
For receiving the distributed A/D acquisition modules (210) of monitoring data, for the microcontroller (212) of data processing, for controlling Make the PC terminals (213) of the microcontroller (212) and the distributed digital input/output module (211) of feedback control information.
3. water inflow control system as claimed in claim 2, which is characterized in that the water inlet adjustment monitoring device (200) passes through Distributed A/D acquisition modules (210) detect the hygrosensor (201), chlorion detector (202), heavy metal ion The information that device (203) and fine particle detector (204) detect is transmitted to the microcontroller (212), by the microcontroller (212) be based on PC terminals (213) input level-one electrically-driven ion film unit (123) inflow requirement to the monitoring information into Row data processing, and handling result is fed back into the thermostat through distributed digital input/output module (211) (205), the first drain valve (206), the second drain valve (207), third drain valve (208), the 4th drain valve (209).
4. water inflow control system as claimed in claim 3, which is characterized in that high slat-containing wastewater obtains height by minimizing process Press reverse osmosis concentrated solution, the back segment process be based on successively level-one electrically-driven ion film unit (123) and two level electric drive from The depth concentration that sub- film unit (126) carries out the reverse osmosis concentrated solution of the high pressure, wherein
Chlorine residue, heavy metal ion and colloid in the reverse osmosis concentrated solution of high pressure is through the active carbon filter (118) and the tree After fat tank (119) absorption, small suspended matter and gel filtration are fallen through third cartridge filter (122), and will be filtered useless Water is sent to water inlet adjustment monitoring device (200),
What water inlet index and the water inlet adjustment monitoring device (200) based on level-one electrically-driven ion film unit (123) monitored The parameter index uses thermostat (205), active carbon filter under the control of water inlet adjustment monitoring device (200) (118), at least one of resin container (119) and third cartridge filter (122) processing unit are to the filtered waste water Carry out circular treatment at least once, until the filtered waste water reach the level-one electrically-driven ion film unit (123) into Water index.
5. water inflow control system as claimed in claim 4, which is characterized in that the level-one electrically-driven ion film unit (123) Water inlet index be:5~40 DEG C of inflow temperature;Contents of residual chlorine is not more than 0.05mg/L;Heavy metal ion content is not more than 0.1mg/L;Sewage quality index S DI is not more than 3.0.
6. water inflow control system as described in claim 1, which is characterized in that the minimizing process further includes following steps:
It is sent into medium pressure reverse osmosis unit after the waste water of preprocessing process is filtered by the first cartridge filter (110) (111);
Waste water obtains middle pressure reverse osmosis produced water and the middle reverse osmosis concentrated solution of pressure after medium pressure reverse osmosis unit (111) processing, Wherein, medium pressure reverse osmosis produced water is sent into second level reverse osmosis apparatus (128), and the reverse osmosis concentrated solution of medium pressure is through the second security personnel It is sent to the high pressure reverse osmosis unit (115) after filter (114) filtering;
It is reverse osmosis that the filtered middle reverse osmosis concentrated solution of pressure obtains high pressure after the high pressure reverse osmosis unit (115) is handled Produce water and the reverse osmosis concentrated solution of high pressure, wherein the high pressure reverse osmosis produced water is sent into second level reverse osmosis apparatus (128), the height Reverse osmosis concentrated solution is pressed to carry out depth concentration.
7. water inflow control system as claimed in claim 4, which is characterized in that the depth concentration includes the following steps:
The reverse osmosis concentrated solution of high pressure is sent after water inflow control system processing to level-one electrically-driven ion film unit (123);
The dense saline solution of level-one electric drive and the production of level-one electric drive are obtained after the level-one electrically-driven ion film unit (123) is handled Water, wherein the level-one electric drive production water enters second level reverse osmosis apparatus (128), and the dense saline solution of level-one electric drive is through third Booster water pump (125) is sent into two level electrically-driven ion film unit (126);
The dense saline solution of two level electric drive and the production of two level electric drive are obtained after the two level electrically-driven ion film unit (126) is handled Water, the two level electric drive production water press pond (112) in being sent into, and the two level electric drive dense saline solution is sent into the second strong brine case (127)。
8. water inflow control system as claimed in claims 6 or 7, which is characterized in that be sent into the second level reverse osmosis apparatus (128) Production water obtain the two-pass reverse osmosis production water and dense saline solution of two-pass reverse osmosis after processing, wherein the two-pass reverse osmosis production water is sent Enter fresh water tanks (129), the dense saline solution of two-pass reverse osmosis is sent to the first intermediate pool (108).
9. water inflow control system as claimed in claim 4, which is characterized in that the active carbon filter (118) is for adsorbing The chlorine not removed during minimizing, while adsorbing small organic molecule, colloid and heavy metal ion;The resin container (119) With ion exchange resin, for adsorbing the heavy metal ion after the active carbon filter (118) processing in solution;It is described Third cartridge filter (122) is used for small suspended matter and colloid in filtering solution.
10. a kind of minimizing processing method of high slat-containing wastewater, which is characterized in that the minimizing processing method includes that waste water is pre- Processing procedure, wastewater reduction processing procedure and waste water advanced concentration process, wherein
Lime or sodium hydroxide, carbonic acid is added after high slat-containing wastewater is carried out homogeneous amount processing in the Wastewater Pretreatment process The coagulant and softening agent of one or more of sodium, aluminium polychloride and polyacrylamide are precipitated, and it is alkali to adjust waste water Property environment, wherein dosage is adjusted according to each ion concentration situation of change of the practical water inlet of the high slat-containing wastewater;
The wastewater reduction processing procedure will pass through pretreated high slat-containing wastewater successively by using width of flow path for 1.524 The middle pressure reverse osmosis unit (111) of the middle press mold element of~1.778mm and use width of flow path for the height of 1.905~2.159mm The high pressure reverse osmosis unit (115) of press mold element carries out minimizing processing;
The waste water advanced concentration process is based on level-one electrically-driven ion film unit (123) and two level electrically-driven ion successively Film unit (126) handles the waste water through the Wastewater Pretreatment process and the wastewater reduction processing procedure, wherein By water inflow control system by chlorine residue, heavy metal ion and the colloid of the waste water during will entering waste water advanced concentration After active carbon filter (118) and resin container (119) absorption, through third cartridge filter (122) by small suspended matter and glue Body filters out, and filtered waste water is sent to water inlet adjustment monitoring device (200),
Based on level-one electrically-driven ion film unit (123) water inlet index during depth concentration and water inlet adjustment monitoring The filtered waste water information of device (200) monitoring uses water temperature under the control of water inlet adjustment monitoring device (200) At least one of adjuster (205), active carbon filter (118), resin container (119) and third cartridge filter (122) place It manages device and circular treatment at least once is carried out to filtered waste water, until the filtered waste water reaches the level-one electricity and drives Dynamic ion film unit (123) water inlet index.
CN201810189542.6A 2015-12-23 2015-12-23 Water inlet control system based on high-salt-content wastewater reduction process Active CN108328836B (en)

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