CN105347440A - Backwashing system and process for cleaning filter membrane - Google Patents
Backwashing system and process for cleaning filter membrane Download PDFInfo
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- 239000012528 membrane Substances 0.000 title claims abstract description 77
- 238000011001 backwashing Methods 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 31
- 238000004140 cleaning Methods 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 238
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 120
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 68
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 239000012267 brine Substances 0.000 claims description 17
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 17
- 238000005342 ion exchange Methods 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 238000010979 pH adjustment Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000013327 media filtration Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims 1
- 239000006227 byproduct Substances 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000008235 industrial water Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000014459 Cation Transport Proteins Human genes 0.000 description 1
- 108010078140 Cation Transport Proteins Proteins 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/04—Backflushing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/12—Use of permeate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/14—Use of concentrate
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
技术领域technical field
本发明涉及水处理技术领域,尤其涉及一种清洗滤膜的反洗系统及其工艺。The invention relates to the technical field of water treatment, in particular to a backwashing system for cleaning a filter membrane and a process thereof.
背景技术Background technique
随着水资源的日益紧缺和工业生产用水量的日益增大,水的回收利用技术一直是重点研究方向,近年来有很多水处理技术问世,常见如微生物处理法、膜技术处理法、反渗透处理法、离子交换处理等,但是缺少针对特定区域特定水质的个性化处理方案,因此处理效果不尽如人意。With the increasing shortage of water resources and the increasing water consumption of industrial production, water recycling technology has always been a key research direction. In recent years, many water treatment technologies have come out, such as microbial treatment, membrane technology treatment, reverse osmosis treatment, ion exchange treatment, etc., but there is a lack of personalized treatment solutions for specific water quality in specific areas, so the treatment effect is not satisfactory.
水质在地域、时间的不同下差别很大,在现有水处理技术发展的基础上,寻找到一种组合处理工艺,能够符合当地水质情况,得到符合条件的工业用水,是一个值得探讨的课题。Water quality varies greatly depending on the region and time. On the basis of the development of existing water treatment technologies, it is a topic worth exploring to find a combined treatment process that can meet the local water quality conditions and obtain qualified industrial water. .
一般工业用水,尤其是石化领域的用水,需要水质达到一级除盐水的需求,多数企业采取使用新鲜的地下水经过处理得到一级除盐水。这种方法对自然水的需求极大,而且需要进一步处理,浪费极大的人力物力。采用生活污水制备一级除盐水是一种成本低的工业用水来源方法。然而在这种工艺中,因生活污水中的杂质较多,各个处理的模组需要进行定期清理才能保持原有的处理效率。对模组尤其是超滤模组进行反洗处理是一种有效的清理方式。现有的制备一级除盐水的系统中,对膜组的清理不完善,对滤膜是否洗净不能及时判断,清理系统不能配套整个系统的使用。General industrial water, especially the water used in the petrochemical field, needs water quality to meet the needs of first-class desalinated water. Most enterprises use fresh groundwater to obtain first-class desalinated water after treatment. This method has a great demand for natural water and requires further treatment, which wastes a lot of manpower and material resources. The preparation of primary demineralized water from domestic sewage is a low-cost method for industrial water sources. However, in this process, due to the large amount of impurities in domestic sewage, each treatment module needs to be cleaned regularly to maintain the original treatment efficiency. Backwashing the module, especially the ultrafiltration module, is an effective cleaning method. In the existing system for preparing first-level desalinated water, the cleaning of the membrane group is not perfect, and whether the filter membrane is cleaned cannot be judged in time, and the cleaning system cannot be used with the entire system.
发明内容Contents of the invention
本发明要解决的问题是现有的制备一级除盐水的系统中,对膜组的清理不完善,对滤膜是否洗净不能及时判断,不能配套系统的使用。The problem to be solved by the present invention is that in the existing system for preparing the first-stage desalinated water, the cleaning of the membrane group is not perfect, the cleaning of the filter membrane cannot be judged in time, and the matching system cannot be used.
本发明的第一个目的在于提供一种设置在制备一级除盐水系统中的清洗滤膜的反洗系统,与现有的一级除盐水系统配合,利用系统中的水作为反洗水对装置进行反洗或其他处理。The first object of the present invention is to provide a backwashing system for cleaning the filter membrane installed in the first-stage desalinated water system, which can cooperate with the existing one-stage desalinated water system, and use the water in the system as the backwash water to device for backwashing or other treatment.
所述清洗滤膜的反洗系统分别与超滤系统和反渗透系统相连通,包括反洗水泵、存放使用过的反洗水的反洗水池和添加器。所述反洗水泵的入水口通过管路和阀门与反渗透系统中的粗盐水池相连通,反洗水泵的出水口通过管路和阀门与超滤系统中的超滤膜组相连通。反洗水池与超滤膜组相连通。所述添加器用于添加指示超滤膜组是否洗净的指示剂,其通过管路与连接反洗水泵和超滤膜组的管路相连通。The backwashing system for cleaning the filter membrane is respectively connected with the ultrafiltration system and the reverse osmosis system, including a backwashing water pump, a backwashing water tank for storing used backwashing water, and an adder. The water inlet of the backwash water pump is connected with the crude brine pool in the reverse osmosis system through pipelines and valves, and the water outlet of the backwash water pump is connected with the ultrafiltration membrane group in the ultrafiltration system through pipelines and valves. The backwash pool is connected with the ultrafiltration membrane group. The adder is used to add an indicator indicating whether the ultrafiltration membrane group is cleaned, and it communicates with the pipeline connecting the backwash water pump and the ultrafiltration membrane group through a pipeline.
进一步地,所述反洗水泵的进水口还通过管路和阀门与超滤系统中的超滤产水池相连通。Further, the water inlet of the backwash water pump is also communicated with the ultrafiltration produced water pool in the ultrafiltration system through pipelines and valves.
优选地,所述反洗水泵的出水口还通过管路和阀门与超滤系统中的多介质过滤器相连通,反洗水池通过管路和阀门与多介质过滤器相连通。Preferably, the water outlet of the backwash water pump is also connected to the multimedia filter in the ultrafiltration system through pipelines and valves, and the backwash water pool is connected to the multimedia filter through pipelines and valves.
优选地,所述反洗水泵的出水口还通过管路和阀门与反渗透系统中的保安过滤器的进料口相连通。Preferably, the water outlet of the backwash water pump is also connected to the feed inlet of the security filter in the reverse osmosis system through pipelines and valves.
本发明的第二个目的在于提供一种包含上述反洗系统的制备一级除盐水系统。所述制备一级除盐水系统,包括上述的清洗滤膜的反洗系统,还包括顺次连接的超滤系统、反渗透系统和离子交换系统,所述反洗系统分别与超滤系统和反渗透系统相连通。The second object of the present invention is to provide a preparative primary desalination system comprising the above-mentioned backwashing system. The preparation of the primary desalinated water system includes the above-mentioned backwashing system for cleaning the filter membrane, and also includes an ultrafiltration system, a reverse osmosis system and an ion exchange system connected in sequence, and the backwashing system is connected with the ultrafiltration system and the reverse osmosis system respectively. The osmotic system is connected.
超滤系统包括依次连接的下述设备:集水池、集水池提升泵、调节池、多介质给水泵、多介质过滤器、自清洗过滤器、超滤膜组、超滤产水池。反渗透系统包括依次连接的反渗透增压泵、保安过滤器、高压泵、反渗透膜组、反渗透产水池。所述反渗透增压泵与超滤产水池相连通。The ultrafiltration system includes the following equipment connected in sequence: sump, sump lift pump, regulating pool, multi-media feed pump, multi-media filter, self-cleaning filter, ultrafiltration membrane group, and ultrafiltration water production pool. The reverse osmosis system includes a reverse osmosis booster pump, a security filter, a high-pressure pump, a reverse osmosis membrane group, and a reverse osmosis production tank connected in sequence. The reverse osmosis booster pump communicates with the ultrafiltration water production pool.
所述反洗系统包括反洗水泵、存放使用过的反洗水的反洗水池和用于添加指示超滤膜组是否洗净的指示剂的添加器。所述反洗水泵的入水口通过管路和阀门与粗盐水池相连通,反洗水泵的出水口通过管路和阀门与超滤膜组相连通,反洗水泵中的水在超滤膜组中流动方向与超滤系统中水的流动方向相反。反洗水池与超滤膜组相连通,收集储存使用过的反洗水。所述添加器通过管路与连接反洗水泵和超滤膜组的管路相连通。The backwash system includes a backwash water pump, a backwash water tank for storing used backwash water, and an adder for adding an indicator indicating whether the ultrafiltration membrane group is cleaned. The water inlet of the backwash water pump is connected with the crude brine pool through pipelines and valves, the water outlet of the backwash water pump is connected with the ultrafiltration membrane group through pipelines and valves, and the water in the backwash water pump is in the ultrafiltration membrane group The direction of flow in the middle is opposite to the flow direction of water in the ultrafiltration system. The backwash water tank is connected with the ultrafiltration membrane group to collect and store the used backwash water. The adder communicates with the pipeline connecting the backwash water pump and the ultrafiltration membrane group through pipelines.
优选地,所述反洗水泵的进水口还通过管路和阀门与超滤产水池相连通。Preferably, the water inlet of the backwash water pump is also communicated with the ultrafiltration produced water pool through pipelines and valves.
优选地,所述反洗水泵的出水口还通过管路和阀门分别与保安过滤器的进料口和多介质过滤器相连通,反洗水池通过管路和阀门与多介质过滤器相连通。Preferably, the water outlet of the backwash water pump is also connected to the feed port of the security filter and the multimedia filter through pipelines and valves, and the backwash water tank is connected to the multimedia filter through pipelines and valves.
进一步地,所述超滤膜组上设有超滤错流管路,其出水口通过管路和阀门与调节池相相连通。Further, the ultrafiltration membrane group is provided with an ultrafiltration cross-flow pipeline, and its water outlet communicates with the regulating tank through pipelines and valves.
本发明的第三个目的在于提供一种清洗滤膜的反洗工艺,设置在整个制备一级除盐水的工艺中。所述反洗工艺,利用反渗透工艺中得到的粗盐水和一部分超滤工艺中的超滤水作为反洗水,在反洗水中加入指示剂后对超滤模组的滤膜进行反洗。The third object of the present invention is to provide a backwashing process for cleaning the filter membrane, which is arranged in the entire process for preparing primary desalinated water. In the backwashing process, the crude brine obtained in the reverse osmosis process and a part of the ultrafiltration water in the ultrafiltration process are used as backwashing water, and an indicator is added to the backwashing water to backwash the filter membrane of the ultrafiltration module.
所述指示剂为酸或碱,反洗水在超滤膜组中的流动方向与超滤工艺中水的流动方向相反。The indicator is acid or alkali, and the flow direction of the backwash water in the ultrafiltration membrane group is opposite to the flow direction of water in the ultrafiltration process.
本发明的第四个目的在于提供一种制备一级除盐水的工艺。所述制备一级除盐水的工艺中,原水依次经过超滤工艺、反渗透工艺和离子交换工艺处理,得到一级除盐水。The fourth object of the present invention is to provide a process for preparing primary desalinated water. In the process for preparing the primary desalinated water, the raw water is sequentially treated by an ultrafiltration process, a reverse osmosis process and an ion exchange process to obtain the primary desalinated water.
所述超滤工艺中,原水经pH调节后进行多介质过滤、自清洗过滤,之后在超滤膜组中进行超滤,得到超滤水。超滤膜组中还设有超滤错流管路,超滤错流的水与原水混合进行pH调节。In the ultrafiltration process, the raw water is subjected to multi-media filtration and self-cleaning filtration after pH adjustment, and then ultrafiltration is performed in an ultrafiltration membrane group to obtain ultrafiltration water. The ultrafiltration membrane group is also provided with an ultrafiltration cross-flow pipeline, and the ultrafiltration cross-flow water is mixed with the raw water for pH adjustment.
反渗透工艺中,超滤水经增压后进行保安过滤,之后继续增压进入反渗透膜组进行反渗透处理,分别得到粗盐水和反渗透水。反渗透水经过离子交换工艺处理得到一级除盐水。In the reverse osmosis process, the ultrafiltration water is pressurized and then filtered for security, and then continues to be pressurized and enters the reverse osmosis membrane group for reverse osmosis treatment to obtain coarse brine and reverse osmosis water respectively. Reverse osmosis water is treated by ion exchange process to obtain primary desalinated water.
原水在经上述三级工艺处理的同时,还进行反洗工艺处理。反洗工艺中,粗盐水和一部分的超滤水作为反洗水。一部分反洗水加入指示剂后对超滤膜组进行处理,所述指示剂为酸或碱。一部分的反洗水对多介质过滤装置进行清洗。一部分反洗水加入阻垢剂和还原剂后作为反渗透药剂加入到反渗透处理中。While the raw water is treated by the above-mentioned three-stage process, it is also treated by the backwash process. In the backwashing process, coarse brine and a part of ultrafiltration water are used as backwashing water. A part of the backwash water is added with an indicator to process the ultrafiltration membrane group, and the indicator is acid or alkali. Part of the backwash water cleans the multimedia filter device. Part of the backwash water is added to the reverse osmosis treatment as a reverse osmosis agent after adding antiscalant and reducing agent.
本发明具有的优点和积极效果是:(1)本发明提供的反洗系统,巧妙地设置在制备一级除盐水系统中,利用制备一级除盐水的副产水经过调配作为反洗水,对制备一级除盐水系统中的装置进行清理、反洗,配合良好,设置方便,提高了水资源的利用率。(2)本发明提供的反洗系统中,设置有添加器,用于添加指示剂,使得反洗水清洗超滤膜组时,根据是否产生沉淀判断是否对超滤膜组清洗干净,提高了反洗效率。(3)本发明提供的反洗系统中,反洗水还可以对超滤系统中的多介质过滤器进行清洗,也可以作为反渗透药剂的溶剂进入反渗透系统,进一步提高了副产水的利用率。The advantages and positive effects of the present invention are: (1) The backwashing system provided by the present invention is cleverly arranged in the system for preparing the first-stage desalinated water, and the by-product water used for preparing the first-stage desalinated water is prepared as backwashing water, Cleaning and backwashing the devices in the first-level desalinated water system are well coordinated, easy to set up, and improve the utilization rate of water resources. (2) in the backwashing system provided by the present invention, adder is provided with, is used for adding indicator, when making backwash water cleans ultrafiltration membrane group, judges whether to clean ultrafiltration membrane group according to whether to produce precipitation, has improved Backwash efficiency. (3) In the backwash system provided by the present invention, the backwash water can also clean the multi-media filter in the ultrafiltration system, and also can enter the reverse osmosis system as a solvent of the reverse osmosis agent, further improving the efficiency of by-product water. utilization rate.
附图说明Description of drawings
图1是本发明中一级除盐水系统的示意图。Fig. 1 is a schematic diagram of the first-stage desalinated water system in the present invention.
具体实施方式detailed description
为了更好的理解本发明,下面结合具体实施例和附图对本发明进行进一步的描述。In order to better understand the present invention, the present invention will be further described below in conjunction with specific embodiments and accompanying drawings.
如图1所示,一种制备一级除盐水系统,包括清洗滤膜的反洗系统,顺次连接的超滤系统、反渗透系统和离子交换系统,反洗系统分别与超滤系统和反渗透系统相连通。As shown in Figure 1, a system for preparing primary desalinated water includes a backwashing system for cleaning the filter membrane, an ultrafiltration system, a reverse osmosis system, and an ion exchange system connected in sequence, and the backwashing system is connected to the ultrafiltration system and the reverse osmosis system respectively. The osmotic system is connected.
超滤系统包括依次连接的下述设备:集水池、集水池提升泵、调节池、多介质给水泵、多介质过滤器、自清洗过滤器、超滤膜组、超滤产水池。超滤膜组上设有超滤错流管路,其出水口通过管路和阀门与调节池相相连通,减少了水的外排,节约水资源。自清洗过滤器是一种利用滤网直接拦截水中的杂质,去除水体悬浮物、颗粒物,降低浊度,净化水质,减少系统污垢、菌藻、锈蚀等产生,以净化水质及保护系统其他设备正常工作的精密设备。The ultrafiltration system includes the following equipment connected in sequence: sump, sump lift pump, regulating pool, multi-media feed pump, multi-media filter, self-cleaning filter, ultrafiltration membrane group, and ultrafiltration water production pool. The ultrafiltration membrane group is equipped with an ultrafiltration cross-flow pipeline, and its water outlet is connected to the regulating tank through pipelines and valves, which reduces the discharge of water and saves water resources. Self-cleaning filter is a kind of filter that directly intercepts impurities in water, removes suspended solids and particulate matter in water, reduces turbidity, purifies water quality, reduces system dirt, bacteria and algae, rust, etc., to purify water quality and protect other equipment in the system. Working precision equipment.
反渗透系统包括依次连接的反渗透增压泵、保安过滤器、高压泵、反渗透膜组、反渗透产水池。反渗透增压泵与超滤产水池相连通。保安过滤器的作用是截留来自前级产水泄漏的或外界带入的大于5μm的颗粒,防止其进入反渗透系统,此类颗粒经高压泵加速后可能击穿反渗透膜组件,造成大量漏盐的情况,同时划伤高压泵的叶轮。The reverse osmosis system includes a reverse osmosis booster pump, a security filter, a high-pressure pump, a reverse osmosis membrane group, and a reverse osmosis production tank connected in sequence. The reverse osmosis booster pump is connected with the ultrafiltration water production tank. The function of the security filter is to intercept the particles larger than 5 μm from the leakage of the pre-product water or from the outside to prevent them from entering the reverse osmosis system. Such particles may break through the reverse osmosis membrane components after being accelerated by the high-pressure pump, causing a large amount of leakage. Salt situation while scratching the impeller of the high pressure pump.
离子交换系统包括依次连接的下述设备:离子交换给水泵、阳床、弱阴床、阴床、除盐水池,离子交换给水泵与反渗透产水池相连通。通过除盐水池获得的一级除盐水通过外供泵供给给用户。The ion exchange system includes the following equipment connected in sequence: ion exchange feedwater pump, cation bed, weak yin bed, yin bed, desalinated water tank, and the ion exchange feed water pump is connected with the reverse osmosis production water tank. The primary desalted water obtained from the desalinated water pool is supplied to users through external pumps.
反洗系统包括反洗水泵、存放使用过的反洗水的反洗水池和用于添加指示超滤膜组是否洗净的指示剂的添加器。The backwash system includes a backwash water pump, a backwash water tank for storing used backwash water, and an adder for adding an indicator indicating whether the ultrafiltration membrane group is cleaned.
反洗水泵的入水口通过管路和阀门分别与粗盐水池和超滤产水池相连通,反洗水泵的出水口通过管路和阀门分别与超滤膜组、多介质过滤器、保安过滤器的进料口相连通。反洗水泵中的水在超滤膜组中流动方向与超滤系统中水的流动方向相反。反洗水池与超滤膜组相连通。添加器通过管路与连接反洗水泵和超滤膜组的管路相连通。The water inlet of the backwash water pump is respectively connected with the crude brine pool and the ultrafiltration water production pool through pipelines and valves, and the water outlet of the backwash water pump is respectively connected with the ultrafiltration membrane group, multi-media filter and security filter through pipelines and valves. The feed port is connected. The flow direction of the water in the backwash water pump in the ultrafiltration membrane group is opposite to the flow direction of the water in the ultrafiltration system. The backwash pool is connected with the ultrafiltration membrane group. The adder communicates with the pipeline connecting the backwash water pump and the ultrafiltration membrane group through pipelines.
一种制备一级除盐水的工艺,原水依次经过超滤工艺、反渗透工艺和离子交换工艺处理,得到一级除盐水。A process for preparing primary desalinated water. Raw water is sequentially treated by an ultrafiltration process, a reverse osmosis process and an ion exchange process to obtain a primary desalinated water.
超滤工艺中,原水经pH调节后进行多介质过滤、自清洗过滤,之后在超滤膜组中进行超滤,得到超滤水。超滤膜组中还设有超滤错流管路,超滤错流的水与原水混合进行pH调节。In the ultrafiltration process, the raw water is subjected to multi-media filtration and self-cleaning filtration after pH adjustment, and then ultrafiltration is performed in the ultrafiltration membrane group to obtain ultrafiltered water. The ultrafiltration membrane group is also provided with an ultrafiltration cross-flow pipeline, and the ultrafiltration cross-flow water is mixed with the raw water for pH adjustment.
反渗透工艺中,超滤水经增压后进行保安过滤,之后继续增压进入反渗透膜组进行反渗透处理,分别得到粗盐水和反渗透水。反渗透水经过离子交换处理得到一级除盐水。In the reverse osmosis process, the ultra-filtered water is pressurized and then subjected to security filtration, and then continues to be pressurized and enters the reverse osmosis membrane group for reverse osmosis treatment to obtain coarse brine and reverse osmosis water respectively. Reverse osmosis water undergoes ion exchange treatment to obtain primary desalinated water.
原水在经上述三级处理的同时,还进行反洗工艺处理。反洗工艺中,粗盐水和一部分的超滤水作为反洗水。一部分反洗水加入指示剂后对超滤膜组进行处理,指示剂为酸或碱。一部分的反洗水对多介质过滤装置进行清洗。一部分反洗水加入阻垢剂和还原剂后作为反渗透药剂加入到反渗透处理中。While the raw water undergoes the above-mentioned three-stage treatment, it is also subjected to backwashing process. In the backwashing process, coarse brine and a part of ultrafiltration water are used as backwashing water. A part of the backwash water is added with an indicator to treat the ultrafiltration membrane group, and the indicator is acid or alkali. Part of the backwash water cleans the multimedia filter device. Part of the backwash water is added to the reverse osmosis treatment as a reverse osmosis agent after adding antiscalant and reducing agent.
具体而言,原水进入集水池,经过集水池提升泵,提升至调节池,调节至合适pH值,然后进入多介质给水泵,经由给水泵的作用,进入多介质过滤器,过滤掉80%的悬浮杂质,然后进入自清洗过滤器,再进入超滤膜组,得到超滤水。超滤错流水回收进入调节池,再次利用。Specifically, the raw water enters the sump, passes through the sump lifting pump, lifts to the regulating pool, adjusts to a suitable pH value, and then enters the multi-media feed water pump. Through the action of the feed water pump, it enters the multi-media filter to filter out 80% of the Suspended impurities, then enter the self-cleaning filter, and then enter the ultrafiltration membrane group to obtain ultrafiltered water. The ultrafiltration cross-flow water is recycled into the regulating tank for reuse.
超滤水进入超滤产水池,再经过反渗透增压泵,进入保安过滤器,经高压泵加压,进入反渗透膜组,得到反渗透水。The ultrafiltration water enters the ultrafiltration water production pool, then passes through the reverse osmosis booster pump, enters the security filter, is pressurized by the high pressure pump, enters the reverse osmosis membrane group, and obtains reverse osmosis water.
反渗透水进入反渗透产水池,再经离子给水泵加压后,分别进入阳床、弱阴床、阴床,去除水中的阴阳离子,得到一级除盐水,进入除盐水池,然后经外供泵供给给用户。阳床、弱阴床、阴床分别设置有再生水池,对产出的水进行再生后,重复利用。The reverse osmosis water enters the reverse osmosis water production tank, and after being pressurized by the ion feed water pump, it enters the cation bed, weak yin bed, and yin bed respectively to remove anions and cations in the water to obtain first-level desalinated water, enters the desalinated water pool, and then passes through the external The supply pump is supplied to the user. The positive bed, weak shade bed, and shade bed are respectively provided with regeneration pools, and the produced water is regenerated and reused.
反渗透处理中得到反渗透处理水的同时副产浓盐水,进入浓盐水池。浓盐水池中的浓盐水和超滤产水池中的超滤水通过管路和阀门的控制与反洗水泵的进水口连通,阀门可调配二者的比例,反洗水泵的出口处得到反洗水。In the reverse osmosis treatment, the reverse osmosis treated water is obtained and concentrated brine is produced by-product, which enters the concentrated brine pool. The concentrated brine in the concentrated brine tank and the ultrafiltered water in the ultrafiltration water production tank are connected to the water inlet of the backwash water pump through the control of pipelines and valves. The valve can adjust the ratio of the two, and the outlet of the backwash water pump can be backwashed water.
一部分的反洗水作为反渗透药剂的溶剂,加入阻垢剂和还原剂后进入保安过滤器。一部分的反洗水也可作为多介质过滤器的清洗用水。一部分的反洗水加入指示剂后对超滤膜组的滤膜进行反洗。指示剂为酸或碱,指示剂与滤膜上残存的杂质反应,生成沉淀,因此,观察流出超滤膜组的反洗水是否有沉淀即可判断超滤膜组的滤膜是否清洗干净,判断方式简单快捷,节省反洗水的用量,节省反洗时间。Part of the backwash water is used as a solvent for the reverse osmosis agent, and after adding antiscalant and reducing agent, it enters the security filter. Part of the backwash water can also be used as cleaning water for the multi-media filter. A part of the backwash water is added with the indicator to backwash the filter membrane of the ultrafiltration membrane group. The indicator is acid or alkali, and the indicator reacts with the remaining impurities on the filter membrane to form a precipitate. Therefore, it can be judged whether the filter membrane of the ultrafiltration membrane group is cleaned by observing whether there is precipitation in the backwash water flowing out of the ultrafiltration membrane group. The judgment method is simple and fast, which saves the amount of backwash water and saves backwash time.
以上对本发明的实施例进行了详细说明,但所述内容仅为本发明的较佳实施例,不能被认为用于限定本发明的实施范围。凡依本发明范围所作的均等变化与改进等,均应仍归属于本专利涵盖范围之内。The embodiments of the present invention have been described in detail above, but the content described is only a preferred embodiment of the present invention, and cannot be considered as limiting the implementation scope of the present invention. All equivalent changes and improvements made according to the scope of the present invention should still belong to the scope of this patent.
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