CN205682365U - A kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment - Google Patents
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment Download PDFInfo
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- CN205682365U CN205682365U CN201620262125.6U CN201620262125U CN205682365U CN 205682365 U CN205682365 U CN 205682365U CN 201620262125 U CN201620262125 U CN 201620262125U CN 205682365 U CN205682365 U CN 205682365U
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Abstract
nullThe utility model discloses a kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment，Including magnetization electrolysis Aquatic product generating apparatus and degraded equipment body，Described degraded equipment body includes chaining conveyer、The equidistant multiple fruit and vegerable being placed in below described chaining conveyor rail place cage、And it is set in turn in the acidic potential tank group below track、Alkaline potential water groove group and pure water groove，Described magnetization electrolysis Aquatic product generating apparatus is connected with described acidic potential tank group and described alkaline potential water groove group respectively by tube for transfusion，Multiple and described acidic potential tank group it is additionally provided with on described track、The slow fall platform that described alkaline potential water groove group is corresponding with described pure water groove group，This utility model utilizes the characteristic of magnetization electrolysis water to degrade the pesticide residues on fruit and vegerable quickly and efficiently，Degradation process environmental protection、Reliably，It is highly suitable for the degraded of extensive garden stuff pesticide residue.
Description
Technical field
This utility model relates to a kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment.
Background technology
World, in agricultural production, for ensureing, promoting plant and the growth of crops, uses anti-the most in a large number
The pesticide of worm and weeding and the coordinate plant growth etc. of curing the disease.Pesticide is in prevention and elimination of disease and pests, weeding and coordinate plant growth
Meanwhile, also remain in organism, agricultural byproducts and environment, cause pesticide residues.After so-called pesticide residues refer to Pesticide use
Remain in trace pesticide substance toxic metabolite, degradation product and the general name of impurity in organism, agricultural byproducts and environment.Pesticide
It is short that the time of residual has length to have, and quantity has to be had less more.Owing to the chemical constitution of pesticide is different, toxicity difference is very big, in the environment
Katabolism speed have very big difference, same pesticide different application methods and different formulation rates, its residual quantity is also
There is the biggest big difference.Pesticide residues the most directly have impact on the quality of agricultural byproducts, and is directly connected to the people's
Healthy.To this end, FAO (Food and Agriculture Organization of the United Nation) (FAO) and World Health Organization (WHO) (WHO) have organized pesticide residues joint council specially
View (JMPR), and formulated by Codex Alimentary Commission (CAC) and promulgate various pesticide residual in different agricultural product
Limit standard, i.e. maximum residual license amount (MRLs), to guarantee that people eat the safety of agricultural byproducts.At present, China makes the most
Determine 79 kinds of pesticide national standard of 197 maximum residue limits for pesticides (MRL) in 32 kinds of (class) agricultural byproducts.
Utility model content
This utility model aims to overcome that above-mentioned the deficiencies in the prior art, it is provided that a kind of large-scale based on magnetization electrolysis
Pesticide residues on fruit and vegerable are degraded by the garden stuff pesticide residue degraded equipment of water technology quickly and efficiently, and degradation process
Environmental protection, reliable.
The technical solution of the utility model is: a kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment,
Including magnetization electrolysis Aquatic product generating apparatus and degraded equipment body, described degraded equipment body includes chaining conveyer, equidistant extension
It is placed in the multiple fruit and vegerable below described chaining conveyor rail place cage and be set in turn in the electrolyzed-oxidizing water below track
Groove group, alkaline potential water groove group and pure water groove, described magnetization electrolysis Aquatic product generating apparatus is acid electric with described respectively by tube for transfusion
Position tank group is connected with described alkaline potential water groove group, described track is additionally provided with multiple with described acidic potential tank group,
The slow fall platform that described alkaline potential water groove group is corresponding with described pure water groove group.
Further, described track is arranged ringwise, and the upstream of described acidic potential tank group is additionally provided with dress dish workbench,
The downstream of described pure water groove is additionally provided with sacker's station, and described dress dish workbench and described sacker's station are all arranged at described rail
The lower section in road.
Further, described dress dish workbench includes selecting dish workbench and dress cage workbench.
Specifically, described sacker's station include sterilizing room and arrange in sterilizing room air air-dry vibration dehydration platform and
Vacuum packaging platform.
Preferably, described air air-dries vibration dehydration platform two groups.
Specifically, described acidic potential tank group includes the first acidic potential tank and the second acidic potential tank, described
The length of the second acidic potential tank is more than the length of described first acidic potential tank, and described alkaline potential water groove group includes the
One alkaline potential water groove, the second alkaline potential water groove and the 3rd alkaline potential water groove, described first alkaline potential water groove and second
The length of alkaline potential water groove is equal, and the length of described 3rd alkaline potential water groove is more than the first alkaline potential water groove and the second alkali
The length of property current potential tank.
Preferably, described first acidic potential tank, described second acidic potential tank, described first alkaline potential water
Groove, length ratio between described second alkaline potential water groove and described 3rd alkaline potential water groove are 1: 4: 1: 1: 5.
Preferably, each cell body of described acidic potential tank group, described alkaline potential water groove group and described pure water groove is deep
Spend the most equal.
Further, each cell body of described acidic potential tank group, described alkaline potential water groove group and described pure water groove it
Between gap in be also designed with secondary groove.
Preferably, described chaining conveyer is closed type track chaining conveyer.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment Methods of Degrading Pesticide Residues, including with
Lower step:
(1) detection fruit and vegerable containing pesticide residues, record the kind of its pesticide residues, and are loaded into placing cage, successively
It is carried out with tap water, pure water；
(2) work of magnetization electrolysis Aquatic product generating apparatus produces electrolyzed-oxidizing water and alkaline potential water and is injected separately into acidic potential
In tank group and alkaline potential water groove group, wherein, the pH value of electrolyzed-oxidizing water is 2.0～3.0, ORP value is 1000-1200mV,
Alkaline potential water value is pH11～12, ORP value is 800-900mV；
(3) track utilizing chaining conveyer will be equipped with the placement cage of fruit and vegerable and immerses acidic potential tank group and alkalescence successively
Current potential tank group, according to different vegetables and fruits kinds and the kind of pesticide residues, utilizes the speed of service placing cage to control to place
The soak time of cage, wherein, the soak time in acidic potential tank group is 15 minutes～30 minutes, in alkaline potential water groove group
Soak time be 20～30 minutes；
Wherein, in step (2), (3), in soak time, electrolysis bath, electrolyte current potential and the net basket speed of service are in accordance with agriculture
The kind of medicine residual sets and regulates and controls in good time；
(4) fruit and vegerable of soaking degraded, then dewatering, air-dried, packaging is cleaned with pure water.
The principle that this utility model utilizes magnetization electrolysis water technology to degrade garden stuff pesticide residue is:
Light water is made pure water through purified treatment, uses micropore surface filter method, utilize randomness absorption side
Formula is detained granule, the suspended solid in removable fruit and vegerable, go the removal of impurity, microorganism, float, Organic substance, antibacterial, colloid and
Microorganism etc..
Pure water enters water magnetizing appts and generates magnetic water, and water magnetizes through magnetic field, and physicochemical property to change, moisture subchain
Shortening, the specific surface area of water increases, and surface tension diminishes, and activity improves, and osmotic pressure increases, and dissolubility and oxygen content increase, table
Surface tension coefficient significantly improves.
Pure water, after magnetization, adds the content of dissolubility, ionization degree, mobility and oxygen, pH value rising, osmotic pressure,
Dissolved oxygen content changes, and degree of association reduces, and after especially degree of association reduces, moisture is more easy to the semipermeable membrane through cell.
Magnetic water enters electrolysis bath, defines have the electrolyte of high electrical conductivity by adding 0.05% sodium chloride (salt)
Solution, under the effect of electrode, can be broken down into OH root and H ion, these ions again with containing the chlorine in sodium-chloride water solution
Ion and sodium ion reaction generate sub-hypochlorous acid and sodium hydroxide, this process need under the effect of anion and cation exchange membrane ability
Realize, thus the sub-hypochlorite ion allowing chemical reaction be formed is rich in collection on the sunny side, and hydroxide ion is to cathodic enrichment, so
The Strong oxdiative highly basic onium hydroxide solution with high potential, wherein, the pH value of electrolyzed-oxidizing water is defined the most respectively in two grooves
Be 2.0～3.0, ORP value 1000-1200mV, alkaline potential water value is pH11～12, ORP value is 800-900mV；
After negative electrode and anode surface generate hydrogen and oxygen, the water of electrode surrounding, will be inclined to alkalescence and acidity, oxidoreduction electricity
Position (ORP) changes the most therewith.
Insert between the two poles of the earth and can allow the selective ceramic membrane passed through of zwitterion, can from cathode collector hydrogen-oxygen from
The alkaline reduction electric potential water of sub-concentration height tool reducing power, anode collects the electrolyzed oxidizing water that hydrogen ion concentration is high.
Oxidation-reduction potential water character:
With saturated common salt (NaCI) solution as electrolyte:
Anode reaction: H2O=2H+ → 1/2O2+2e-
H2O+2Cl-→HCl+HClO+2e-
Cathode reaction: 2H2O+2e-→2OH-+H2O
Chemical characteristic is that water electrolysis forms hypochlorous acid, and hypochlorous acid is further decomposed to form nascent oxygen [O], nascent oxygen
Strong oxidizing property make the material degeneration such as the protein in thalline and virus, thus lethal sex pheromone.
According to chemical assay, being almost in water of PPM level concentration is electrolyzed to produce hypochlorous acid completely, and its efficiency is higher than
99.99%.Its process simply can be expressed as follows with chemical equation:
NaCIO+H2O=HCIO+NaOH；HCIO→HCI+[O]
Secondly, hypochlorous acid, during sterilization, killing the virus, not only may act on cell wall, virus coat, and dimension chlorine
Acid molecule is little, neutral, also can penetrate into bacterium (viral) internal, with organic high scores such as bacterium (viral) body protein, nucleic acid and enzymes
There is oxidation reaction in son, thus kills pathogenic microorganism.
R-NH-R+HCIO→R2NCI+H2O
Meanwhile, the chloride ion that hypochlorous acid produces can also significantly change the osmotic pressure of antibacterial and virion so that it is cell loses
Devitalized and dead；Furthermore it is possible to decompose trace pesticide remaining on the agricultural byproducts such as veterinary antibiotics；Most pesticide
All being made up of Organic substance, the new state oxygen energy oxidation Decomposition discharged falls these materials；Also it is appreciated that, by
Including that orthene is many containing P=S and C=O double bond in organophosphorus pesticide, nucleophilic easily makes its pair under acid or alkaline conditions
Key ruptures, nucleophilic substitution；Acidic oxidized electric potential water has low pH and high ORP value, and alkaline reduction electric potential water has height
PH and good emulsibility, acidic oxidized electric potential water and alkaline reduction electric potential water, special physicochemical property makes it to organophosphor agriculture
Medicine has good eradicating efficacy；During immersion treatment 60min, acephate pesticide residual eliminating rate is reached by acidic oxidized electric potential water
82%, the elimination factor of alkaline reduction electric potential water reaches more than 90%.
Utilize magnetization electrolysis water to process, can effectively remove fruit and vegerable epidermis and be partially into the pesticide within fruit and vegerable, chemical fertilizer, killing
The reluctant antibacterial of the fruit and vegetable surfaces that goes out, fungus, pathogen, extend fresh keeping time, it is ensured that the green of fruit and vegerable, safety.
Owing to the magnetization electrolysis water of production producing free chlorine not as the disinfectant such as chlorine, chlorine dioxide in water, so
Typically it is difficult to be formed and generates the carcinogen being unfavorable for health because there is free chlorine；If also air not as ozone
Life will be caused damage and poison by the faintest amount (0.001mg/m3) of middle existence；And, also will not be anti-with water as chlorine
Should eventually form and catch the such heavy corrosion that causes metallic conduit of acid, the mode of removal pesticide residues is more environmentally-friendly reliably.
Finally, magnetization electrolysis water physical characteristic is to have high oxidation potential containing hypochlorous aqueous solution, once with antibacterial
Or after viruses contact, it forcibly obtains electronics from biomembrane, and changes normal current potential and the permeability of cell membrane, makes fat
Film oxidization and infiltration destroys, and just as having worn individual hole on cell membrane, causes cellular content to leak and lethal, and this process belongs to
Physical process, can just reach good effect within 1-10 minute, so the ratio speed of chemical sterilization on using, and not
Pathogenic bacteria can be made to produce any Drug resistance.
Accompanying drawing explanation
Fig. 1 is the top view of garden stuff pesticide residue based on magnetization electrolysis water technology of the present utility model degraded equipment；
Fig. 2 is the structural representation in the A portion of Fig. 1；
Fig. 3 is the structural representation in the B portion of Fig. 1；
The workflow diagram of Fig. 4 garden stuff pesticide residue based on magnetization electrolysis water technology of the present utility model degraded equipment；
Fig. 5 is the contrast schematic diagram using this utility model and other processing modes to affect Cypermethrin Residues rate；
The schematic diagram that Fig. 6 is different soak time electrolyzed-oxidizing water and Cypermethrin Residues rate is affected by alkaline potential water；
Fig. 7 is the schematic diagram using this utility model and other processing modes to affect Bravo residual rate；
The schematic diagram that Fig. 8 is different soak time electrolyzed-oxidizing water and Bravo residual rate is affected by alkaline potential water.
Detailed description of the invention
Below by embodiment, and combine accompanying drawing, the technical solution of the utility model is described in further detail.
Shown in Fig. 1-4, a kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment, including magnetization electricity
Solving Aquatic product generating apparatus and degraded equipment body, described degraded equipment body includes chaining conveyer, equidistant is placed in described extension
Multiple fruit and vegerable below chain conveyor rail 1 place cage 2 and be set in turn in the acidic potential tank group 3 below track 1,
Alkaline potential water groove group 4 and pure water groove 5, described magnetization electrolysis Aquatic product generating apparatus by tube for transfusion 6 respectively with described acidic potential
Tank group 3 is connected with described alkaline potential water groove 4 groups, and described track 1 is additionally provided with multiple and described acidic potential tank group
3, the slow fall platform 6 that described alkaline potential water groove group 4 is corresponding with described pure water groove group.
Further, described track 1 is arranged ringwise, and the upstream of described acidic potential tank group 3 is additionally provided with dress dish work
Platform 7, the downstream of described pure water groove 5 is additionally provided with sacker's station 8, and described dress dish workbench 7 and described sacker's station 8 are all arranged
Lower section in described track 1.
Further, described dress dish workbench 7 includes selecting dish workbench 71 and dress cage workbench 72.
Specifically, described sacker's station 8 includes that sterilizing room 81 and the air arranged in sterilizing room 81 air-dry vibration dehydration
Platform 82 and vacuum packaging platform 83.
Preferably, described air air-dries vibration dehydration platform 82 two groups.
Specifically, described acidic potential tank group 3 includes the first acidic potential tank 31 and the second acidic potential tank 32,
The length of described second acidic potential tank 32 is more than the length of described first acidic potential tank 31, described alkaline potential water groove
Group 4 includes the first alkaline potential water groove the 41, second alkaline potential water groove 42 and the 3rd alkaline potential water groove 43, described first alkalescence
The length of current potential tank 41 and the second alkaline potential water groove 42 is equal, and the length of described 3rd alkaline potential water groove 43 is more than first
Alkaline potential water groove 41 and the length of the second alkaline potential water groove 42.
Preferably, described first acidic potential tank 31, described second acidic potential tank 32, described first alkalescence current potential
Tank 41, length ratio between described second alkaline potential water groove 42 and described 3rd alkaline potential water groove 43 are 1: 4: 1: 1: 5.
Preferably, each cell body of described acidic potential tank group 3, described alkaline potential water groove group 4 and described pure water groove 5
The degree of depth is the most equal.
Further, described acidic potential tank group 3, described alkaline potential water groove group 4 and each cell body of described pure water groove 5
Between gap in be also designed with secondary groove 9.
Preferably, described chaining conveyer is closed type track chaining conveyer.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment Methods of Degrading Pesticide Residues, including with
Lower step:
(1) detection fruit and vegerable containing pesticide residues, record the kind of its pesticide residues, and are loaded into placing cage, successively
It is carried out with tap water, pure water；
(2) work of magnetization electrolysis Aquatic product generating apparatus produces electrolyzed-oxidizing water and alkaline potential water and is injected separately into acidic potential
In tank group and alkaline potential water groove group, wherein, the pH value of electrolyzed-oxidizing water is 2.0～3.0, ORP value is 1000-1200mV,
Alkaline potential water value is pH11～12, ORP value is 800-900mV；
Wherein, magnetization electrolysis water generation technological process is: light water or tap water → purified treatment are made pure water and (removed
Miscellaneous and Organic substance and antibacterial) → water magnetizing appts make magnetic water (physicochemical property of water to change, and makes moisture subchain shorten,
Become micromolecular water group) generate magnetization electrolysis water (acidic electrolytic water and electrolyzed alkaline water) after → electrolytic tank electrolysis.
(3) track utilizing chaining conveyer will be equipped with the placement cage of fruit and vegerable and immerses acidic potential tank group and alkalescence successively
Current potential tank group, according to different vegetables and fruits kinds and the kind of pesticide residues, utilizes the speed of service placing cage to control to place
The soak time of cage, wherein, wherein, the soak time in acidic potential tank group is 15 minutes～30 minutes, alkaline potential water
Soak time in groove group is 20～30 minutes；
Wherein, in step (2), (3), in soak time, electrolysis bath, electrolyte current potential and the net basket speed of service are in accordance with agriculture
The kind of medicine residual sets and regulates and controls in good time；
(4) fruit and vegerable of soaking degraded, then dewatering, air-dried, packaging is cleaned with pure water.
Choose representative Herba Spinaciae pesticide residues cypermethrin and Fructus Cucumidis sativi pesticide residues Bravo as subjects,
Result of the test is as follows:
Impact on Herba Spinaciae pesticide residues cypermethrin:
As it is shown in figure 5, the residual rate through tap water and the Herba Spinaciae cypermethrin of detergent immersion is 65-75%, and acid
Electric potential water and alkaline potential water soak the Bravo residual rate after 30min all below 43%；Illustrate that electric potential water eliminates with agriculture
The mode of washing used by effect daily life to be considerably better than of the Herba Spinaciae of medicine residual.
As shown in Figure 6, either electrolyzed-oxidizing water or alkaline potential water soak Herba Spinaciae, and the residual rate of pesticide all can be along with
The prolongation of soak time and reduce, especially at the front 5min soaked, pesticide residues rate declines rapidly, to 15min reduction of speed at present
Degree gradually slows down.
Impact on Fructus Cucumidis sativi pesticide residues Bravo:
As it is shown in fig. 7, the residual rate of Bravo is 30.2% after acidic potential water soaking 30min；Alkaline potential water soaks
Bravo residual rate after 30min is 26.7%；And tap water and detergent the most only soak after 30min the residual rate of Bravo
It is 79.1% and 47%；Illustrate that electric potential water eliminates the mode of washing used by effect daily life to be considerably better than of pesticide residues,
May be used for daily life and remove vegetable pesticide residue.
As shown in Figure 8, it can be seen that either electrolyzed-oxidizing water or alkaline potential water immersion Fructus Cucumidis sativi, its Bravo is residual
Allowance all reduces with the prolongation of soak time；However, to ensure that the organoleptic quality of Fructus Cucumidis sativi should not be soaked for a long time；Before immersion
The residual rate dramatic decrease of 5min Bravo, before soaking, the residual rate of 20min alkaline potential water Bravo is significantly less than acid electricity
Position water.
The foregoing is only preferred embodiment of the present utility model, not in order to limit this utility model, all at this
Within the spirit of utility model and principle, any modification, equivalent substitution and improvement etc. made, should be included in this utility model
Protection domain within.
Claims (9)
1. garden stuff pesticide residue based on a magnetization electrolysis water technology degraded equipment, including magnetization electrolysis Aquatic product generating apparatus and fall
Solve equipment body, it is characterised in that: described degraded equipment body include chaining conveyer, equidistant be placed in described chaining conveying
Multiple fruit and vegerable below machine track are placed cage and are set in turn in the acidic potential tank group below track, alkaline potential water
Groove group and pure water groove, described magnetization electrolysis Aquatic product generating apparatus by tube for transfusion respectively with described acidic potential tank group and described alkali
Property current potential tank group be connected, described track is additionally provided with multiple with described acidic potential tank group, described alkaline potential water groove
Organize the slow fall platform corresponding with described pure water groove group.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 1 degraded equipment, its feature
Being: described track is arranged ringwise, the upstream of described acidic potential tank group is additionally provided with dress dish workbench, described pure water groove
Downstream is additionally provided with sacker's station, and described dress dish workbench and described sacker's station are all arranged at the lower section of described track.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 2 degraded equipment, its feature
It is: described dress dish workbench includes selecting dish workbench and dress cage workbench.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 2 degraded equipment, its feature
It is: described sacker's station includes that sterilizing room and the air arranging in sterilizing room air-dry vibration dehydration platform and vacuum packaging is flat
Platform.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 4 degraded equipment, its feature
It is: described air air-dries vibration dehydration platform two groups.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 1 degraded equipment, its feature
It is: described acidic potential tank group includes the first acidic potential tank and the second acidic potential tank, the described second acid electricity
The length of position tank is more than the length of described first acidic potential tank, and described alkaline potential water groove group includes the first alkalescence current potential
Tank, the second alkaline potential water groove and the 3rd alkaline potential water groove, described first alkaline potential water groove and the second alkaline potential water
The length of groove is equal, and the length of described 3rd alkaline potential water groove is more than the first alkaline potential water groove and the second alkaline potential water groove
Length.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 6 degraded equipment, its feature
Be: described first acidic potential tank, described second acidic potential tank, described first alkaline potential water groove, described second
Length ratio between alkaline potential water groove and described 3rd alkaline potential water groove is 1: 4: 1: 1: 5.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 1 and 2 degraded equipment, it is special
Levy and be: the degree of depth of each cell body of described acidic potential tank group, described alkaline potential water groove group and described pure water groove is the most equal.
A kind of garden stuff pesticide residue based on magnetization electrolysis water technology the most according to claim 1 and 2 degraded equipment, it is special
Levy and be: in described acidic potential tank group, gap between described alkaline potential water groove group and each cell body of described pure water groove
Also it is designed with secondary groove.
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| CN201620262125.6U CN205682365U (en) | 2016-04-01 | 2016-04-01 | A kind of garden stuff pesticide residue based on magnetization electrolysis water technology degraded equipment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077010A (en) * | 2018-07-18 | 2018-12-25 | 苏州千层茧农业科技有限公司 | The remove device of remains of pesticide, hormone in a kind of aquaculture object |
| CN113040318A (en) * | 2021-03-18 | 2021-06-29 | 北京首创纳米科技有限公司 | A electro-catalysis water installation for fruit vegetables dewaxing gets rid of incomplete farming |
-
2016
- 2016-04-01 CN CN201620262125.6U patent/CN205682365U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077010A (en) * | 2018-07-18 | 2018-12-25 | 苏州千层茧农业科技有限公司 | The remove device of remains of pesticide, hormone in a kind of aquaculture object |
| CN109077010B (en) * | 2018-07-18 | 2021-03-02 | 苏州千层茧农业科技有限公司 | Device for removing residual pesticide and hormone in aquaculture material |
| CN113040318A (en) * | 2021-03-18 | 2021-06-29 | 北京首创纳米科技有限公司 | A electro-catalysis water installation for fruit vegetables dewaxing gets rid of incomplete farming |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161116 Termination date: 20200401 |