CN205205197U - Concentrate desulfurization reduces device of magnesium oxide content - Google Patents

Concentrate desulfurization reduces device of magnesium oxide content Download PDF

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Publication number
CN205205197U
CN205205197U CN201520938422.3U CN201520938422U CN205205197U CN 205205197 U CN205205197 U CN 205205197U CN 201520938422 U CN201520938422 U CN 201520938422U CN 205205197 U CN205205197 U CN 205205197U
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concentrate
caustic soda
liquid caustic
sloptank
sulfur dioxide
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CN201520938422.3U
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孙治忠
路八智
史万敬
唐照勇
马旻锐
魏占鸿
何春文
裴英鸽
瞿尚君
邵志超
李燕梅
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Jinchuan Group Nickel Cobalt Co ltd
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Jinchuan Group Co Ltd
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Abstract

The utility model discloses a concentrate desulfurization reduces device of magnesium oxide content, it mainly includes concentrate thick liquid underground tank, absorb back concentrate thick liquid underground tank, the desulfurizing tower, liquid caustic soda security personnel absorption tower, alkali preparation tank, the concentrator, thick stock underground tank and clear solution pH adjustment tank, its concentrate thick liquid of picking out the ore dressing regards as the desulfurizer to absorb the sulfur dioxide in the flue gas, it detects sulfur dioxide content to absorb the back, it discharges to detect qualified back, if detect unqualifiedly, discharge again after continuing to absorb sulfur dioxide through the liquid caustic soda in the liquid caustic soda security personnel absorption tower, and simultaneously, ore pulp dense one -tenth supernatant and thick stock two parts of low -concentration sulfur dioxide will be absorbed through the concentrator, thick stock emits into thick stock underground tank, the supernatant is through adjusting the pH value, accord with after the ore dressing water distribution requirement supernatant carry to the ore dressing system as the water distribution retrieval and utilization. The utility model discloses can smelt the sulfur dioxide desorption in the flue gas with low -concentration sulfur dioxide effectively to reduce the content of concentrate self magnesium oxide, reduced ore dressing system moisturizing volume.

Description

A kind of concentrate desulfurization reduces the device of content of magnesia
Technical field
The utility model belongs to smelting, chemical field, is specifically related to the device that a kind of concentrate desulfurization reduces content of magnesia.
Background technology
In the smelting process of sulphide ores, smelt the height of the content of magnesia in nickel ore concentrate, pyrometallurgical smelting slag making is had a significant impact, content of magnesia is high, and slag melting point can be caused to increase, and energy consumption increases, and be unfavorable for that slag nickel is separated, cause the nickeliferous rising of slag, therefore adopt effective ways to reduce Magnesia Content of Nickel Concentrate, the index request to Magnesia Content of Nickel Concentrate can be relaxed.
In the smelting process of sulphide ores, usually can produce a large amount of containing SO 2flue gas during smelting, serious pollution is caused to surrounding enviroment, low concentration SO 2flue gas during smelting has large-minded, SO 2concentration is low, and the feature such as fluctuate larger, the environmental protection gas collection mainly in smelt production, and current traditional treatment method is relatively more extensive, comprises lime method, ionic liquid method, activated coke method, alkali absorb method etc., technical maturity.But because flue gas during smelting amount is large, desired raw material amount is large, and processing cost is higher, and produce new solid waste in treating processes, liquid gives up.
Utility model content
The purpose of this utility model is to solve the technical problem existed in prior art, and provide a kind of energy scrubbing CO_2 and can reduce content of magnesia in concentrate, the concentrate desulfurization that desulfuration efficiency is high, cost is low reduces the device of content of magnesia.
In order to achieve the above object, the utility model is by the following technical solutions: a kind of concentrate desulfurization reduces the device of content of magnesia, comprise concentrate slurry sloptank, concentrate slurry sloptank after absorbing, thionizer, liquid caustic soda security personnel absorption tower, alkali-prepared tank, thickener, underflow sloptank and clear liquid pH regulator groove, described concentrate slurry sloptank is connected with the concentrate slurry entrance being positioned at thionizer bottom, the bottom of described thionizer is also connected with the top spray equipment in thionizer by recycle pump, the concentrate slurry outlet of described thionizer is connected with concentrate slurry sloptank after absorption, after described absorption, concentrate slurry sloptank is also connected with thickener, the bottom of described thickener is connected with underflow sloptank, the top of described thickener is connected with clear liquid pH regulator groove, the middle part of described thionizer is provided with the import of low-concentration sulfur dioxide flue gas during smelting, the lower entrances on the top of described thionizer is provided with venting port and venting port is ensured public security with exhaust emission pipeline and liquid caustic soda respectively absorption tower is connected, the lower entrances on described liquid caustic soda security personnel absorption tower and exhaust emission pipeline are respectively equipped with chain trip valve, described chain trip valve is connected with the outlet sulfur dioxide concentration detector being arranged on exhaust ports, the bottom on described liquid caustic soda security personnel absorption tower is also connected with the top liquid caustic soda spray equipment that liquid caustic soda is ensured public security in absorption tower by liquid caustic soda recycle pump, described liquid caustic soda security personnel absorption tower is connected with alkali-prepared tank, the top on described liquid caustic soda security personnel absorption tower is connected with exhaust emission pipeline, described exhaust emission pipeline is connected with blower fan.
Further, described low-concentration sulfur dioxide flue gas during smelting ingress is provided with entrance sulfur dioxide concentration detector.
Further, whipping appts is provided with in described clear liquid pH regulator groove.
Further, the pipeline that the bottom of described thickener is connected with underflow sloptank is provided with underflow valve.
Further, described alkali-prepared tank be provided with concentration be 30% liquid caustic soda add entrance and water distribution adds entrance.
Further, described clear liquid pH regulator groove is provided with concentration is that the liquid caustic soda of 9-11% adds entrance.
Further, described underflow sloptank is connected with raw materials for metallurgy storehouse by slush pump.
Further, after described absorption, concentrate slurry sloptank is connected with thickener by pump.
Further, described recycle pump and liquid caustic soda recycle pump are respectively two groups.
The utility model hinge structure has following beneficial effect: concentrate desulfurization of the present utility model reduces the device of content of magnesia, comprise concentrate slurry sloptank, absorb rear concentrate slurry sloptank, thionizer, liquid caustic soda ensure public security absorption tower, alkali-prepared tank, thickener, underflow sloptank and clear liquid pH regulator groove, its concentrate slurry ore dressing selected is delivered to as sweetening agent in thionizer, and concentrate slurry contains a certain amount of MgO, CaO, Al 2o 3, Fe 2o 3in basic oxide (being mainly MgO), instead of traditional sweetening agent, the basic oxide in concentrate slurry (being mainly MgO) are utilized to absorb sour gas sulfurous gas in low-concentration sulfur dioxide flue gas during smelting, after absorption, the content of sulfur dioxide in flue gas is detected, detect qualified rear discharge, if detect defective, discharge again after continuing to absorb the sulfurous gas in flue gas by the liquid caustic soda in liquid caustic soda security personnel absorption tower, simultaneously, the dense one-tenth supernatant liquor of ore pulp and underflow two portions of low-concentration sulfur dioxide will be absorbed by thickener, be delivered in raw materials for metallurgy storehouse through slush pump after underflow enters underflow sloptank, supernatant liquor regulates the pH value of supernatant liquor by adding liquid caustic soda, after meeting ore dressing water distribution requirement, supernatant liquor is delivered to ore-sorting system as water distribution reuse.The utility model can effectively by the sulfur dioxide removal in low-concentration sulfur dioxide flue gas during smelting, and reduce the content of concentrate autoxidation magnesium, achieve the comprehensive utilization of waste water, decrease ore-sorting system rate of water make-up, sweetening effectiveness is obvious, while guaranteeing flue gas qualified discharge, can significantly reduce traditional doctor solution consumption, reduce system operation cost, avoid the discharge that solid waste new in sweetening process, liquid are useless, finally achieve lower concentration flue gas during smelting sulfur dioxide treatment and the object reducing concentrate content of magnesia.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
The utility model Reference numeral implication is as follows: 1, concentrate slurry sloptank; 2, concentrate slurry sloptank after absorbing; 3, recycle pump; 4, thionizer; 5, liquid caustic soda recycle pump; 6, blower fan; 7, alkali-prepared tank; 8, liquid caustic soda security personnel absorption tower; 9, chain trip valve; 10, sulfur dioxide concentration detector is exported; 11, entrance sulfur dioxide concentration detector; 12, underflow sloptank; 13, clear liquid pH regulator groove; 14, thickener; 15, top spray equipment; 16, low-concentration sulfur dioxide flue gas during smelting import; 17, venting port; 18, exhaust emission pipeline; 19, top liquid caustic soda spray equipment; 20, whipping appts; 21, underflow valve; 22, concentration be 30% liquid caustic soda add entrance; 23, water distribution adds entrance; 24, concentration is that the liquid caustic soda of 9-11% adds entrance.
Embodiment
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Embodiment 1
As shown in Figure 1, a kind of concentrate desulfurization reduces the device of content of magnesia, comprise concentrate slurry sloptank 1, concentrate slurry sloptank 2 after absorbing, thionizer 4, liquid caustic soda security personnel absorption tower 8, alkali-prepared tank 7, thickener 14, underflow sloptank 12 and clear liquid pH regulator groove 13, concentrate slurry sloptank 1 is connected with the concentrate slurry entrance being positioned at thionizer 4 bottom, the bottom of thionizer 4 is also connected with the top spray equipment 15 in thionizer 4 by two groups of recycle pumps 3, the concentrate slurry outlet of thionizer 4 is connected with concentrate slurry sloptank 2 after absorption, after absorbing, concentrate slurry sloptank 2 is also connected with thickener 14 by pump, the bottom of thickener 14 is connected with underflow sloptank 12, underflow sloptank 12 is connected with raw materials for metallurgy storehouse by slush pump, the pipeline that the bottom of thickener 14 is connected with underflow sloptank 12 is provided with underflow valve 21, the top of thickener 14 is connected with clear liquid pH regulator groove 13, it is that the liquid caustic soda of 9-11% adds entrance 24 that clear liquid pH regulator groove 13 is provided with concentration, whipping appts 20 is provided with in clear liquid pH regulator groove 13, the middle part of thionizer 4 is provided with low-concentration sulfur dioxide flue gas during smelting import 16, low-concentration sulfur dioxide flue gas during smelting import 16 place is provided with entrance sulfur dioxide concentration detector 11, the lower entrances on the top of thionizer 4 is provided with venting port 17 and venting port 17 is ensured public security with exhaust emission pipeline 18 and liquid caustic soda respectively absorption tower 8 is connected, the lower entrances on liquid caustic soda security personnel absorption tower 8 and exhaust emission pipeline 18 are respectively equipped with chain trip valve 9, chain trip valve 9 is connected with the outlet sulfur dioxide concentration detector 10 being arranged on venting port 17 place, the top liquid caustic soda spray equipment 19 also ensured public security in absorption tower 8 by two groups of liquid caustic soda recycle pumps 5 and liquid caustic soda in the bottom on liquid caustic soda security personnel absorption tower 8 is connected, liquid caustic soda security personnel absorption tower 8 is connected with alkali-prepared tank 7, alkali-prepared tank 7 be provided with concentration be 30% liquid caustic soda add entrance 22 and water distribution adds entrance 23, the top on liquid caustic soda security personnel absorption tower 8 is connected with exhaust emission pipeline 18, exhaust emission pipeline 18 is connected with blower fan 6.
The device above-mentioned concentrate desulfurization being reduced content of magnesia is used in certain mining and metallurgy refining unit normal productive process, specifically comprise the following steps: after the concentrate slurry (solid content is 20%, and pH value is 9.5) ore dressing selected is delivered to concentrate slurry sloptank 1, concentrate slurry is delivered to thionizer 4 by concentrate slurry entrance; ON cycle pump 3, by recycle pump 3 by concentrate slurry the top spray equipment 15 be delivered in thionizer 4 spray and under, concentrate slurry and low-concentration sulfur dioxide flue gas during smelting (sulfur dioxide concentration: 266mg/Nm from bottom to top from thionizer 4 3-2076mg/Nm 3, mean concns is 1314mg/Nm 3, exhaust gas volumn: 61423Nm 3/ h-91156Nm 3/ h, average tolerance is 70000Nm 3/ h) counter current contact, the sulfurous gas in flue gas absorbs by the basic activated component in concentrate slurry; (pH value is 6.4 to concentrate slurry after absorption, magnesium oxide mass percentage is less than 6.5%, meet pyrometallurgical smelting requirement) be delivered to the rear concentrate slurry sloptank 2 of absorption, and through pump delivery in thickener 14, after thickener 14 is dense, open underflow valve 21, underflow enters underflow sloptank 12, and is delivered in raw materials for metallurgy storehouse through slush pump; Supernatant liquor after thickener 14 is dense flows in clear liquid pH regulator groove 13, by adding the pH value that concentration is the liquid caustic soda adjustment supernatant liquor of 10.5% in clear liquid pH regulator groove 13, stirred by whipping appts 20, the pH value of supernatant liquor reaches ore dressing water distribution and requires rear as ore-sorting system water distribution reuse; Detected by the sulfur dioxide concentration exported in the low-concentration sulfur dioxide flue gas during smelting of sulfur dioxide concentration detector 10 pairs of venting port 17 places after concentrate slurry absorbs, detected result is SO 2concentration remains on 100mg/Nm substantially 3below, meet qualified discharge standard, chain trip valve 9 opens to the pipeline of exhaust emission pipeline 18, and flue gas is directly discharged from exhaust emission pipeline 18.
Embodiment 2
The concentrate desulfurization of the present embodiment reduces the device of content of magnesia with embodiment 1, use it for that the fluctuation of certain mining and metallurgy refining unit flue gas during smelting is comparatively large, sulfurous gas exceeds in the situation of concentration for the treatment of, specifically comprise the following steps: after the concentrate slurry (solid content is 20%, and pH value is 9.64) ore dressing selected is delivered to concentrate slurry sloptank 1, concentrate slurry is delivered to thionizer 4 by concentrate slurry entrance, ON cycle pump 3, by recycle pump 3 by concentrate slurry the top spray equipment 15 be delivered in thionizer 4 spray and under, concentrate slurry and low-concentration sulfur dioxide flue gas during smelting (sulfur dioxide concentration: 1682mg/Nm from bottom to top from thionizer 4 3-7859mg/Nm 3, mean concns: 3803mg/Nm 3, exhaust gas volumn: 51834Nm 3/ h-85692Nm 3/ h, average tolerance: 69523Nm 3/ h) counter current contact, the sulfurous gas in flue gas absorbs by the basic activated component in concentrate slurry, (pH value is 6.0 to concentrate slurry after absorption, magnesium oxide mass percentage is less than 6.5%, meet pyrometallurgical smelting requirement) be delivered to the rear concentrate slurry sloptank 2 of absorption, and through pump delivery in thickener 14, after thickener 14 is dense, open underflow valve 21, underflow enters underflow sloptank 12, and is delivered in raw materials for metallurgy storehouse through slush pump, supernatant liquor after thickener 14 is dense flows in clear liquid pH regulator groove 13, by adding the pH value that concentration is the liquid caustic soda adjustment supernatant liquor of 10.5% in clear liquid pH regulator groove 13, stirred by whipping appts 20, the pH value of supernatant liquor reaches ore dressing water distribution and requires rear as ore-sorting system water distribution reuse, by exporting the low-concentration sulfur dioxide flue gas during smelting of sulfur dioxide concentration detector 10 pairs of venting port 17 places after concentrate slurry absorbs, (flue gas concentration is more than 3500mg/Nm 3) in sulfur dioxide concentration detect, detected result is SO 2concentration is more than 400mg/Nm 3below, do not meet qualified discharge standard, chain trip valve 9 is cut to the pipeline of exhaust emission pipeline 18, open to the pipeline of liquid caustic soda security personnel absorption tower 8 lower entrances, it (is that the liquid caustic soda pump delivery of 32% is to alkali-prepared tank 7 by concentration in advance that flue gas enters in liquid caustic soda security personnel absorption tower 8 by the lower entrances on liquid caustic soda security personnel absorption tower 8, adding water and being mixed with concentration is enter into after the liquid caustic soda of 10.6% in liquid caustic soda security personnel absorption tower 8), open liquid caustic soda recycle pump 5, liquid caustic soda from top liquid caustic soda spray equipment 19 spray and, with ensure public security absorption tower 8 from liquid caustic soda in flue gas adverse current from bottom to top contact and continue to absorb the sulfurous gas in flue gas, (flue gas concentration remains on 60mg/Nm to flue gas after absorbing by liquid caustic soda 3below, qualified discharge requirement is met) discharge from exhaust emission pipeline 18 through the top on liquid caustic soda security personnel absorption tower 8.

Claims (9)

1. the device of a concentrate desulfurization reduction content of magnesia, it is characterized in that: comprise concentrate slurry sloptank (1), concentrate slurry sloptank (2) after absorbing, thionizer (4), liquid caustic soda security personnel absorption tower (8), alkali-prepared tank (7), thickener (14), underflow sloptank (12) and clear liquid pH regulator groove (13), described concentrate slurry sloptank (1) is connected with the concentrate slurry entrance being positioned at thionizer (4) bottom, the bottom of described thionizer (4) is also connected with the top spray equipment (15) in thionizer (4) by recycle pump (3), the concentrate slurry outlet of described thionizer (4) is connected with concentrate slurry sloptank (2) after absorption, after described absorption, concentrate slurry sloptank (2) is also connected with thickener (14), the bottom of described thickener (14) is connected with underflow sloptank (12), the top of described thickener (14) is connected with clear liquid pH regulator groove (13), the middle part of described thionizer (4) is provided with low-concentration sulfur dioxide flue gas during smelting import (16), the lower entrances on the top of described thionizer (4) is provided with venting port (17) and venting port (17) is ensured public security with exhaust emission pipeline (18) and liquid caustic soda respectively absorption tower (8) is connected, the lower entrances of described liquid caustic soda security personnel absorption tower (8) and exhaust emission pipeline (18) are respectively equipped with chain trip valve (9), described chain trip valve (9) is connected with the outlet sulfur dioxide concentration detector (10) being arranged on venting port (17) place, the bottom of described liquid caustic soda security personnel absorption tower (8) is also connected with top liquid caustic soda spray equipment (19) that liquid caustic soda is ensured public security in absorption tower (8) by liquid caustic soda recycle pump (5), described liquid caustic soda security personnel absorption tower (8) is connected with alkali-prepared tank (7), the top of described liquid caustic soda security personnel absorption tower (8) is connected with exhaust emission pipeline (18), described exhaust emission pipeline (18) is connected with blower fan (6).
2. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: described low-concentration sulfur dioxide flue gas during smelting import (16) place is provided with entrance sulfur dioxide concentration detector (11).
3. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: be provided with whipping appts (20) in described clear liquid pH regulator groove (13).
4. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: the pipeline that the bottom of described thickener (14) is connected with underflow sloptank (12) is provided with underflow valve (21).
5. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: described alkali-prepared tank (7) be provided with concentration be 30% liquid caustic soda add entrance (22) and water distribution adds entrance (23).
6. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: it is that the liquid caustic soda of 9-11% adds entrance (24) that described clear liquid pH regulator groove (13) is provided with concentration.
7. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: described underflow sloptank (12) is connected with raw materials for metallurgy storehouse by slush pump.
8. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: after described absorption, concentrate slurry sloptank (2) is connected with thickener (14) by pump.
9. a kind of concentrate desulfurization according to claim 1 reduces the device of content of magnesia, it is characterized in that: described recycle pump (3) and liquid caustic soda recycle pump (5) are respectively two groups.
CN201520938422.3U 2015-11-23 2015-11-23 Concentrate desulfurization reduces device of magnesium oxide content Active CN205205197U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105349772A (en) * 2015-11-23 2016-02-24 金川集团股份有限公司 Device and method for reducing magnesium oxide content for concentrate desulfurization
CN107185385A (en) * 2017-07-07 2017-09-22 金川集团股份有限公司 A kind of spuious flue gas during smelting wet dedusting of atm number, sulfur method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105349772A (en) * 2015-11-23 2016-02-24 金川集团股份有限公司 Device and method for reducing magnesium oxide content for concentrate desulfurization
CN105349772B (en) * 2015-11-23 2018-04-10 金川集团股份有限公司 A kind of concentrate desulfurization reduces the device and method of content of magnesia
CN107185385A (en) * 2017-07-07 2017-09-22 金川集团股份有限公司 A kind of spuious flue gas during smelting wet dedusting of atm number, sulfur method

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Effective date of registration: 20240220

Address after: 737100 No. 2 Lanzhou Road, Beijing Road Street, Jinchuan District, Jinchang City, Gansu Province

Patentee after: Jinchuan Group Nickel Cobalt Co.,Ltd.

Country or region after: China

Address before: 737103 No. 98, Jinchuan Road, Jinchang, Gansu

Patentee before: JINCHUAN GROUP Co.,Ltd.

Country or region before: China