CN207324498U - With the desulfurizer of lime/lime stone slurry absorbing sulfur dioxide in flue - Google Patents

With the desulfurizer of lime/lime stone slurry absorbing sulfur dioxide in flue Download PDF

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Publication number
CN207324498U
CN207324498U CN201720840572.XU CN201720840572U CN207324498U CN 207324498 U CN207324498 U CN 207324498U CN 201720840572 U CN201720840572 U CN 201720840572U CN 207324498 U CN207324498 U CN 207324498U
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flue gas
slurries
flue
lime
slurry
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杨春明
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Jiangsu New Chunxing Resource Recycling Co Ltd
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Jiangsu New Chunxing Resource Recycling Co Ltd
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Abstract

A kind of desulfurizer and method with lime/lime stone slurry absorbing sulfur dioxide in flue, belongs to the desulfurizer and method of sulfur dioxide in flue gas.Device:In gas inlet, manhole, flue gas and device, exhanst gas outlet, neutralize slurries manifold and smoke chamber;There are gas inlet and manhole on smoke chamber, have the hole of flue gas swirl cylinder in smoke chamber, be connected with hole in flue gas and device;In flue gas and there is an exhanst gas outlet in the upper end of device, has in flue gas and on device and neutralizes slurries delivery pipe and be connected with neutralization slurries manifold;From the gas inlet of smoke chamber into flue gas and the exhanst gas outlet of device is closed exhaust gases passes.Method:(1)It is prepared by lime white or lime stone slurry;(2) desulfurization of flue gas desulfurization device;(3)Detection neutralizes the pH value and concentration of slurries.Advantage:The device operation and maintenance are convenient, flue gas is changed it is adaptable, can safe, reliable, efficient desulfurization, desulfurization degree more than 99.9%, the content of sulfur dioxide in flue gas after desulfurization is less than 30mg/Nm3

Description

With the desulfurizer of lime/lime stone slurry absorbing sulfur dioxide in flue
Technical field
A kind of sulfur dioxide in flue gas desulfurizer is the utility model is related to, more particularly to one kind is starched with lime/lime stone The desulfurizer of absorbing sulfur dioxide in flue.
Background technology
At present, the wet process of FGD equipment industrially applied is mainly spray absorber, uses void tower technology more, interior Portion is simple in structure, and the slurries that flue gas enters behind absorption tower directly with top spray are reacted, some flue gases are not in time for instead Absorption tower should be just have left, gas residence time is short, and desulfuration efficiency is relatively low, is usually only capable of processing content of sulfur dioxide and is less than 3000 mg/Nm3Following flue gas.
In lead-acid accumulator reclaiming smelting process, closed in lead plaster containing substantial amounts of lead sulfate and other Containing Sulfurs Thing, though through pre- desulfurization process, but still there is considerable amount of sulphur-containing substance to be difficult to removing totally, it can usually be produced in smelting process a large amount of The concentration of flue gas during smelting containing sulfur dioxide, wherein sulfur dioxide is generally 3000~60000mg/Nm3, and concentration, flow pole It is unstable, while the content of this sulfur dioxide in flue gas does not reach the concentration requirement of extracting sulfuric acid again, relieving haperacidity is of high cost, it is difficult to Economic utilization, surrounding enviroment can be caused serious pollution by directly being discharged such as without desulfurization process, be handled using conventional desulfurization It is extremely difficult to GB 31574-2015《Reclaimed copper, aluminium, lead, Zn Cr coating pollutant emission standard》Middle sulfur dioxide is less than 150mg/ m3Requirement.Therefore, the processing of such flue gas also just becomes the task of top priority, good there is an urgent need to find a kind of adaptability, desulfurization effect Rate is high, simple flue gas desulfurization device is safeguarded, to solve resulting problem of environmental pollution.
Utility model content
It is good that the purpose of this utility model is to provide for a kind of adaptability, and desulfuration efficiency is high, and maintenance simply uses lime/lime Stone starches the desulfurizer of absorbing sulfur dioxide in flue, solves in lead-acid accumulator reclaiming smelting process, containing titanium dioxide The flue gas during smelting of sulphur directly discharges, and surrounding enviroment are caused with serious pollution problem.
What the purpose of this utility model was realized in:Desulfurizer includes:In gas inlet, manhole, flue gas and fill Put, exhanst gas outlet, neutralize slurries manifold and smoke chamber;There are gas inlet and manhole on smoke chamber, have flue gas in smoke chamber The hole of swirl cylinder, is connected with flue gas and device on hole;In flue gas and there is an exhanst gas outlet in the upper end of device, in flue gas and fills Neutralization slurries delivery pipe is put and has been connected with neutralizing slurries manifold;From the gas inlet of smoke chamber into flue gas and device flue gas Export as closed exhaust gases passes.
In the flue gas and device has a multilayer, and each layer is superimposed installation up and down, in all flue gases and device neutralization slurry Liquid delivery pipe is connected with neutralizing slurries manifold;It is corresponding with the neutralization slurries delivery pipe of first layer and neutralizes slurry inlet pipe, in It is connected to and is neutralized on slurries manifold with slurry inlet pipe;The neutralization slurry inlet pipe includes:In first layer and slurry inlet Pipe, the second layer neutralize in slurry inlet pipe, third layer and slurry inlet pipe and the 4th layer of neutralization slurry inlet pipe more than two layers.
Include in the flue gas with device:Neutralization bucket, neutralize distribution of slurry pipe, neutralize slurries dashpot, neutralize slurries Delivery pipe, flue gas eddy flow bore and flue gas swirl cylinder;Multiple flue gas swirl cylinders are uniformly connected with the bottom surface of neutralization bucket, in With the hole that multiple flue gas swirl cylinders are evenly equipped with the top surface of bucket, in the end face center of neutralization bucket is connected with and slurries dashpot, In and slurries dashpot on be connected with it is multiple in and distribution of slurry pipe, each neutralize Guan Yuyi flue gas eddy flow of distribution of slurry Cylinder is corresponding, neutralizes the outlet of distribution of slurry pipe positioned at the upper end of flue gas swirl cylinder.
The flue gas swirl cylinder includes:Deflector, water conservancy diversion sheet-pile, spray frustum and eddy flow barrel shell;Water conservancy diversion sheet-pile is located at In eddy flow barrel shell, deflector is connected between water conservancy diversion sheet-pile and eddy flow barrel shell, the deflector is no less than two layers;Leading The upper end of flowing plate column is connected with spray frustum.
In the multilayer flue gas and device has 2 to 8 layers;Multiple flue gas swirl cylinders are 4 to 16.
The deflector tilts installation, and angle of inclination is:10 ~ 45 degree of angles;Deflector is 12-48.
Beneficial effect, as a result of such scheme, the flue gas shunting mouth of the utility model is that one kind carries double-deck water conservancy diversion The circular apparatus of harden structure, deflector angle 10 to 45 spend angle, its effect is to make rising flue gas and the lime white or lime of downlink Stone slurries form rotational flow, so that flue gas comes into full contact with lime white or limestone slurry liquid energy, make sulfur dioxide in flue gas Fully reacted with calcium hydroxide in lime white or lime stone slurry or calcium carbonate, with remove sulfur dioxide in flue gas and sulfuric acid mist and Other sour gas, by the absorbing and removing of the higher sulfur dioxide of content in pyrometallurgy flue gas and produce qualified gypsum product, Suitable for content of sulfur dioxide 60000mg/Nm is arrived 30003Industrial smoke in carry out Absorption Desulfurization, desulfurization degree 99.9% with On.Solve in lead-acid accumulator reclaiming smelting process, the flue gas during smelting containing sulfur dioxide directly discharges, to peripheral ring Serious pollution problem is caused in border, has reached the purpose of this utility model.
Advantage:1st, it is reasonable to set, it is possible to achieve the quickly de- high-efficiency desulfurization of flue gas, shortens flow, reduce Process configuration.2、 With dependable performance, adaptability is good, and operation is easy, safeguards simple, can be to avoid the fouling and clogging of desulfurizer the features such as, and 3, outstanding It is suitable for the high flue gas of sulfur dioxide concentration in pollutant, the sulfur dioxide that can effectively remove in flue gas realizes that environment protection standard is arranged Put;4th, whole set process apparatus structure is compact, and operating cost is low, and floor space is small, and accessory substance gypsum can be used as the raw material of industry to carry out Recycling, meets the environmental protection policy of current " green, circulation, economy ".
The device operation and maintenance are convenient, adaptable to flue gas change, can reliably and securely realize flue gas desulfurization, take off Sulphur efficiency is high, desulfurization degree more than 99.9%, and the content of sulfur dioxide in flue gas after desulfurization is less than 30mg/Nm3, far below national cigarette Gas discharge standard.
Brief description of the drawings
Fig. 1 is the structure chart of the utility model.
Fig. 2 be the utility model flue gas in and structure drawing of device.
Fig. 3 is the A line of vision structure charts of Fig. 2.
Fig. 4 is the B-B line of vision structure charts of Fig. 2.
Fig. 5 is the structure chart with flue gas swirl cylinder in device in the utility model flue gas.
Fig. 6 is the structure chart of guide plate in the utility model flue gas swirl cylinder.
In figure, 1, gas inlet;2nd, flue gas swirl cylinder;2-1, deflector;2-2, water conservancy diversion sheet-pile;2-3, spray frustum;2- 4;Eddy flow barrel shell;3rd, manhole;4th, in flue gas and device;4-1, neutralization bucket;4-2, neutralize distribution of slurry pipe;4-3, neutralize slurries Dashpot;4-4;Neutralize slurries delivery pipe;4-5, flue gas eddy flow bore;5th, in first layer and slurry inlet pipe;6th, the second layer or More than two layers neutralization slurry inlet pipes;7th, in third layer and slurry inlet pipe;8th, the 4th layer of neutralization slurry inlet pipe;9th, flue gas goes out Mouthful;10th, slurries manifold is neutralized;11st, smoke chamber.
Embodiment
The technical solution of the utility model is further illustrated below in conjunction with the accompanying drawings:
Embodiment 1:The desulfurizer of the utility model includes:In gas inlet 1, manhole 3, flue gas and device 4, flue gas Outlet 9, neutralize slurries manifold 10 and smoke chamber 11;There are gas inlet 1 and manhole 3 on smoke chamber 11, have in smoke chamber 11 The hole of flue gas swirl cylinder 2, is connected with flue gas and device 4 on hole;There are exhanst gas outlet 9, cigarette in upper end with device 4 in flue gas Gas, which neutralizes, has neutralization slurries delivery pipe 4-4 to be connected with neutralizing slurries manifold 10 on device 4;From the gas inlet 1 of smoke chamber 11 to Exhanst gas outlet 9 in flue gas with device 4 is closed exhaust gases passes.
In the flue gas and device 4 has a multilayer, and each layer is superimposed installation up and down, the neutralization in all flue gases with device 4 Slurries delivery pipe 4-4 is connected with neutralizing slurries manifold 10;Neutralization slurries are corresponding with the neutralization slurries delivery pipe 4-4 of first layer Inlet tube, neutralizes slurry inlet pipe and is connected on neutralization slurries manifold 10;The neutralization slurry inlet pipe 5 includes:First layer Neutralize slurry inlet pipe 5, the second layer or neutralized more than two layers in slurry inlet pipe 6, third layer and slurry inlet pipe 7 and the 4th layer Neutralize slurry inlet pipe 8.
Include in the flue gas with device 4:Neutralization bucket 4-1, neutralize distribution of slurry pipe 4-2, neutralize slurries dashpot 4- 3rd, slurries delivery pipe 4-4, flue gas eddy flow bore 4-5 and flue gas swirl cylinder 2 are neutralized;Uniformly connected on the bottom surface of neutralization bucket 4-1 There are multiple flue gas swirl cylinders 2, the hole of multiple flue gas swirl cylinders 2 is evenly equipped with the top surface of neutralization bucket 4-1, neutralization bucket 4-1's End face center be connected with neutralize slurries dashpot 4-3, in and slurries dashpot 4-3 on be connected with it is multiple in and distribution of slurry pipe 4-2, each is neutralized, and distribution of slurry pipe 4-2 is corresponding with a flue gas swirl cylinder 2, and the outlet for neutralizing distribution of slurry pipe 4-2 is located at The upper end of flue gas swirl cylinder 2.
The flue gas swirl cylinder 2 includes:Deflector 2-1, water conservancy diversion sheet-pile 2-2, spray frustum 2-3 and eddy flow barrel shell 2-4; Water conservancy diversion sheet-pile 2-2 is located in eddy flow barrel shell 2-4, and deflector 2-1, institute are connected between water conservancy diversion sheet-pile 2-2 and eddy flow barrel shell 2-4 The deflector 2-1 stated is no less than two layers;Spray frustum 2-3 is connected with the upper end of deflector 2-1.
Sulfur method comprises the following steps:
(1)It is prepared by lime white or lime stone slurry
Lime or lime stone are introduced into the lime or agstone that wet ball mill is milled to 150 to 200 mesh, by lime or Agstone mixes with water, stirs neutralization slurries are made, and then inserts slurry pool;The lime or agstone is mixed with water Mass percent concentration be 0.1-5%.
(2) sulfur method of flue gas desulfurization device
The sulfur-containing smoke gas produced from lead-acid accumulator reclaiming smelting process, by exhaust fan from smoke chamber 11 Gas inlet 1 enter flue gas desulfurization device, sulfur-containing smoke gas respectively by each flue gas and device 4 flue gas swirl cylinder 2 on Rise;
Under the action of 2 deflector of flue gas swirl cylinder, sulfur-containing smoke gas rotation rises;
Slurry inlet pipe, the second layer or neutralize from first layer and more than two layers in slurry inlet pipe, third layer and slurries Inlet tube and the 4th layer of neutralization slurries for neutralizing the entrance of slurry inlet pipe, the corresponding neutralization slurries dashpot for entering each layer, in Slurries delivery pipe downlink outflow neutralized with slurries;
Neutralize slurries to flow directly out to the spray frustum of flue gas swirl cylinder, under the action of frustum is sprayed, form umbrella shape Neutralize serosa;
Rotate the sulfur-containing smoke gas risen to be come into full contact with neutralizing slurries by neutralizing serosa, sulfur-containing smoke gas, make cigarette Sulfur dioxide in gas is fully reacted with neutralizing calcium hydroxide or calcium carbonate in slurries, removes sulfur dioxide in flue gas and sulfuric acid mist And other sour gas.
(3)Detection neutralizes the pH value and concentration of slurries
Detection neutralizes the pH value of the neutralization slurries of slurry inlet pipe and neutralizes the concentration of slurries, according to titanium dioxide in flue gas The grade of the content of sulphur, flow and desulfurization product gypsum, in time adjustment neutralize the flow and concentration of slurries.
In the multilayer flue gas and device has 2 to 8 layers;Multiple flue gas swirl cylinders are 4 to 16.
The deflector tilts installation, and angle of inclination is:10 ~ 45 degree of angles.Deflector is 12-48.
The neutralization slurries are lime white or lime stone slurry.

Claims (6)

1. a kind of desulfurizer with lime/lime stone slurry absorbing sulfur dioxide in flue, it is characterized in that:Desulfurizer includes: In gas inlet, manhole, flue gas and device, exhanst gas outlet, neutralize slurries manifold and smoke chamber;Have on smoke chamber flue gas into Mouthful and manhole, have the hole of flue gas swirl cylinder in smoke chamber, be connected with hole in flue gas and device;In flue gas and device There is an exhanst gas outlet in upper end, has in flue gas and on device and neutralizes slurries delivery pipe and be connected with neutralization slurries manifold;From the cigarette of smoke chamber Gas import is closed exhaust gases passes with the exhanst gas outlet of device into flue gas.
2. a kind of desulfurizer with lime/lime stone slurry absorbing sulfur dioxide in flue according to claim 1, it is special Sign is:In the flue gas and device has a multilayer, and each layer is superimposed installation up and down, defeated with the neutralization slurries of device in all flue gases Send in Guan Junyu and connected with slurries manifold;It is corresponding with the neutralization slurries delivery pipe of first layer and neutralizes slurry inlet pipe, neutralizes slurry Liquid inlet tube, which is connected to, to be neutralized on slurries manifold;The neutralization slurry inlet pipe includes:In first layer and slurry inlet pipe, the Two layers or neutralized more than two layers in slurry inlet pipe, third layer and slurry inlet pipe and the 4th layer of neutralization slurry inlet pipe.
3. a kind of desulfurizer with lime/lime stone slurry absorbing sulfur dioxide in flue according to claim 1, it is special Sign is:Include in the flue gas with device:Neutralization bucket, neutralize distribution of slurry pipe, neutralize slurries dashpot, neutralize slurries conveying Pipe, flue gas eddy flow bore and flue gas swirl cylinder;Multiple flue gas swirl cylinders are uniformly connected with the bottom surface of neutralization bucket, in neutralization bucket Top surface on be evenly equipped with the holes of multiple flue gas swirl cylinders, in the end face center of neutralization bucket is connected with and slurries dashpot, in Be connected with slurries dashpot it is multiple neutralization distribution of slurry pipes, each neutralize Guan Yuyi flue gas swirl cylinder pair of distribution of slurry Should, the outlet of distribution of slurry pipe is neutralized positioned at the upper end of flue gas swirl cylinder.
4. a kind of desulfurizer with lime/lime stone slurry absorbing sulfur dioxide in flue according to claim 3, it is special Sign is:Multiple flue gas swirl cylinders are 4 to 16;The flue gas swirl cylinder includes:Deflector, water conservancy diversion sheet-pile, spray Frustum and eddy flow barrel shell;Water conservancy diversion sheet-pile is located in eddy flow barrel shell, and deflector is connected between water conservancy diversion sheet-pile and eddy flow barrel shell, institute The deflector stated is no less than two layers;Spray frustum is connected with the upper end of deflector.
5. the desulfurizer according to claim 2 with lime/lime stone slurry absorbing sulfur dioxide in flue, its feature It is:In the multilayer flue gas and device has 2 to 8 layers.
6. the desulfurizer according to claim 4 with lime/lime stone slurry absorbing sulfur dioxide in flue, its feature It is:The deflector tilts installation, and angle of inclination is:10 ~ 45 degree of angles;Deflector is 12-48.
CN201720840572.XU 2017-07-12 2017-07-12 With the desulfurizer of lime/lime stone slurry absorbing sulfur dioxide in flue Active CN207324498U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158922A (en) * 2017-07-12 2017-09-15 江苏新春兴再生资源有限责任公司 The desulfurizer and method of absorbing sulfur dioxide in flue are starched with lime/lime stone

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158922A (en) * 2017-07-12 2017-09-15 江苏新春兴再生资源有限责任公司 The desulfurizer and method of absorbing sulfur dioxide in flue are starched with lime/lime stone

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