CN205199294U - Device for low concentration SO2 flue gas desulfurization with basicity waste liquid - Google Patents

Device for low concentration SO2 flue gas desulfurization with basicity waste liquid Download PDF

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Publication number
CN205199294U
CN205199294U CN201520938585.1U CN201520938585U CN205199294U CN 205199294 U CN205199294 U CN 205199294U CN 201520938585 U CN201520938585 U CN 201520938585U CN 205199294 U CN205199294 U CN 205199294U
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flue gas
ore pulp
tower
active
low concentration
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CN201520938585.1U
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Inventor
孙治忠
路八智
史万敬
方永水
马俊
王晖
张宏昌
毛艳丽
李平德
马莹
张雪峰
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Jinchuan Group Nickel Cobalt Co ltd
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Jinchuan Group Co Ltd
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Abstract

The utility model discloses a device for low concentration SO2 flue gas desulfurization with basicity waste liquid, the device mainly includes SO2 flue gas absorption tower, electric demister, active ore pulp buffer tank, active ore pulp absorption liquid buffer tank, the spent electrolyte buffer tank, spent electrolyte circulating slot and the tail chimney of discharging fume, at first utilize twice absorption of alkaline composition in the active ore pulp to smelt the acid gas SO2 in the flue gas, then utilize the alkaline composition among the spent electrolyte further to absorb the acid gas SO2 who smelts in the flue gas, detach the mine dust of smelting in the flue gas simultaneously, two kinds of waste lyes of active ore pulp and spent electrolyte have greatly been utilized, simple technical process, and reliable in operation, desulfurization effect is showing and the investment is hanged down, small occupation area, the operation is thus simple, only need less cost can accomplish the desulfurization to the low concentration SO2 flue gas of huge tolerance, desulphurization process's raw materials cost is reduced, and can not produce new discarded object, environmental protection gas collection SO2 up to standard economic standard treatment's mesh is realized through waste control by waste.

Description

One utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization
Technical field
The utility model belongs to ore dressing, smelting and chemical technology field, is specifically related to one and utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization.
Background technology
Ambrose alloy pyrometallurgical smelting factory can produce a large amount of SO in smelt production 2flue gas during smelting.High concentration SO 2flue gas generally adopts the mode of extracting sulfuric acid to reclaim, but the environmental protection gas collection of metallurgical furnace kiln generation disperses owing to producing, exhaust gas volumn is large, SO 2the factors such as concentration is low, fluctuation is large, recycling and administration difficulty is large.Conventional administering method has lime method, activated coke method, Novel carbon catalysis method, ionic liquid round-robin method, sodium alkali, citrate absorption process, ammonia process etc., but the problems such as the new discarded object of high, the easy generation of ubiquity production cost.
Utility model content
The purpose of this utility model is to solve the technical problem existed in prior art, provides that a kind of desulfurization degree is high, operating cost is low, the alkaline waste liquor that utilizes that is pollution-free, the treatment of wastes with processes of wastes against one another carries out low concentration SO 2the device of flue gas desulfurization.
In order to achieve the above object, the utility model by the following technical solutions: one utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, comprises SO 2smoke absorption tower, electrostatic precipitator, active ore pulp surge tank, active ore pulp absorbing liquid surge tank, waste electrolyte surge tank, waste electrolyte circulating slot and tail smoke evacuation chimney, described SO 2the reverse jet tube end of smoke absorption tower is connected with relay air blower through flue, described SO 2circulating slot at the bottom of the tower of smoke absorption tower is connected with active ore pulp surge tank by active pulp conveying pump, described SO 2circulating slot at the bottom of the tower of smoke absorption tower is connected with the active ore pulp shower nozzle of reverse jet tube shower nozzle and Ta Nei middle and lower part respectively by active ore pulp circulating pump, described SO 2circulating slot at the bottom of the tower of smoke absorption tower is connected with active ore pulp absorbing liquid surge tank by active ore pulp absorbing liquid circulating pump, described SO 2the distribution device bottom land of smoke absorption tower is connected with waste electrolyte circulating slot by pipeline, described waste electrolyte circulating slot is connected with tower internal upper part waste electrolyte shower nozzle by waste electrolyte circulating pump, described waste electrolyte circulating slot is connected with waste electrolyte surge tank, described SO 2the top of smoke absorption tower is connected with electrostatic precipitator, and described electrostatic precipitator is connected with tail smoke evacuation chimney.
Further, described waste electrolyte circulating slot is provided with waste electrolyte delivery pipe.
Further, described active pulp conveying pump is two groups.
Further, described active ore pulp circulating pump is three groups.
Further, described active ore pulp absorbing liquid delivery pump is two groups.
Further, described waste electrolyte circulating pump is two groups.
Further, described SO 2smoke absorption tower is that Two-way Cycle rapids rushes desulfurizing tower.
The utility model hinge structure has following beneficial effect: the alkaline waste liquor that utilizes of the present utility model carries out low concentration SO 2the device of flue gas desulfurization mainly comprises SO 2smoke absorption tower, electrostatic precipitator, active ore pulp surge tank, active ore pulp absorbing liquid surge tank, waste electrolyte surge tank, waste electrolyte circulating slot and tail smoke evacuation chimney, its waste liquid adopting the active ore pulp that produces in nickel, copper ore dressing process and nickel, copper metal electrolysis processes to produce is as desulfurizing agent, and wherein active ore pulp contains a certain amount of MgO, CaO, Al 2o 3, Fe 2o 3in basic anhydride, pH is about 9-10, and waste electrolyte is the waste liquid that potroom produces when removing the heavy metal elements such as Ni, Cu, Co in electrolyte, and main component is Na 2cO 3, NaHCO 3, pH value is 7.5-8.5.First the utility model utilizes the alkaline components in active ore pulp to absorb sour gas SO in flue gas during smelting for twice 2, then utilize the alkaline components in waste electrolyte to absorb sour gas SO in flue gas during smelting further 2, remove the mine dust in flue gas during smelting simultaneously, greatly make use of active ore pulp and waste electrolyte two kinds of spent lyes, technological process is simple, reliable, significant desulfurization effect and invest low, and floor space is little, simple to operate, only the less cost of need can complete the low concentration SO to huge tolerance 2the desulfurization of flue gas, reduces the cost of material of sweetening process, and can not produce new discarded object, realizes environmental protection gas collection SO by the treatment of wastes with processes of wastes against one another 2the object of economy up to standard process up to standard.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
The utility model Reference numeral implication is as follows: 1, relay air blower; 2, SO 2smoke absorption tower; 3, electrostatic precipitator; 4, active ore pulp surge tank; 5, active pulp conveying pump; 6, active ore pulp circulating pump; 7, active ore pulp absorbing liquid surge tank; 8, active ore pulp absorbing liquid circulating pump; 9, waste electrolyte surge tank; 10, waste electrolyte circulating slot; 11, waste electrolyte circulating pump; 12, tail smoke evacuation chimney; 13, reverse jet tube; 14, reverse jet tube shower nozzle; 15, the active ore pulp shower nozzle in middle and lower part in tower; 16, tower internal upper part waste electrolyte shower nozzle; 17, waste electrolyte delivery pipe.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Embodiment 1
As shown in Figure 1, one utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, comprises SO 2smoke absorption tower 2, electrostatic precipitator 3, active ore pulp surge tank 4, active ore pulp absorbing liquid surge tank 7, waste electrolyte surge tank 9, waste electrolyte circulating slot 10 and tail smoke evacuation chimney 12, SO 2smoke absorption tower 2 rushes desulfurizing tower for Two-way Cycle rapids, comprise reverse jet tube 13 and absorption tower body, reverse jet tube 13 is made up of changeover portion, inverse spray section and straight length, play a part to connect flue and absorption tower tower body, absorption tower body comprises the active ore pulp shower nozzle 15 in middle and lower part in circulating slot at the bottom of tower body, tower, reverse jet tube shower nozzle 14, tower, distribution device, tower internal upper part waste electrolyte shower nozzle 16, SO 2reverse jet tube 13 end of smoke absorption tower 2 is connected with relay air blower 1, SO through flue 2circulating slot at the bottom of the tower of smoke absorption tower 2 is opened one standby by two groups of active pulp conveying pump 5(mono-) be connected with active ore pulp surge tank 4, SO 2circulating slot at the bottom of the tower of smoke absorption tower 2 is opened one standby by three groups of active ore pulp circulating pump 6(two) be connected with the active ore pulp shower nozzle 15 of reverse jet tube shower nozzle 14 and Ta Nei middle and lower part respectively, SO 2circulating slot at the bottom of the tower of smoke absorption tower 2 is opened one standby by two groups of active ore pulp absorbing liquid circulating pump 8(mono-) be connected with active ore pulp absorbing liquid surge tank 7, SO 2the distribution device bottom land of smoke absorption tower 2 is connected with waste electrolyte circulating slot 10 by pipeline, waste electrolyte circulating slot 10 is opened one standby by two groups of waste electrolyte circulating pump 11(mono-) be connected with tower internal upper part waste electrolyte shower nozzle 16, waste electrolyte circulating slot 10 is connected with waste electrolyte surge tank 9, waste electrolyte circulating slot 10 is provided with waste electrolyte delivery pipe 17, SO 2the top of smoke absorption tower 2 is connected with electrostatic precipitator 3, and electrostatic precipitator 3 is connected with tail smoke evacuation chimney 12.
The above-mentioned alkaline waste liquor that utilizes is carried out low concentration SO 2application of installation low concentration SO when normal production of flue gas desulfurization 2flue gas (SO 2concentration: 1950mg/Nm 3-5270mg/Nm 3, mean concentration is 2860mg/Nm 3, exhaust gas volumn: 48520Nm 3/ h-165130Nm 3/ h, average tolerance is 106825Nm 3/ h) desulfurization in, due to SO 2concentration is lower, only adopts active ore pulp desulfurization can make flue gas qualified discharge, specifically comprises the following steps: active pulp conveying ore dressing produced to active ore pulp surge tank 4, and is delivered to SO through active pulp conveying pump 5 2circulating slot at the bottom of the tower of smoke absorption tower 2, SO 2active ore pulp in circulating slot at the bottom of the tower of smoke absorption tower 2 is delivered to the active ore pulp shower nozzle 15 of reverse jet tube shower nozzle 14 and Ta Nei middle and lower part respectively through active ore pulp circulating pump 6; Low concentration SO 2flue gas is delivered to SO by relay air blower 1 2the reverse jet tube 13 of smoke absorption tower 2, the active ore pulp counter current contacting sprayed with reverse jet tube shower nozzle 14, to the SO in flue gas 2carry out first time absorption, entered SO by the flue gas after absorbing for the first time 2in smoke absorption tower 2, the active ore pulp counter current contacting sprayed with the active ore pulp shower nozzle 15 in middle and lower part in tower, to the SO in flue gas 2carry out second time to absorb; SO 2concentration remains on 100mg/Nm substantially 3below, meet qualified discharge standard, pass through SO 2the top of smoke absorption tower 2 enters in electrostatic precipitator 3, and the acid mist in removing flue gas, enters in tail smoke evacuation chimney 12 and discharge.Absorb saturated after active ore pulp absorbing liquid (pH value is down to 7.5 by 9.8) be settled down to SO 2circulating slot at the bottom of the tower of smoke absorption tower 2, is delivered to active ore pulp absorbing liquid surge tank 7 through active ore pulp absorbing liquid circulating pump 8.
Embodiment 2
The alkaline waste liquor that utilizes in the present embodiment carries out low concentration SO 2the device of flue gas desulfurization, with embodiment 1, is applied to that the fluctuation of certain flue gas during smelting is comparatively large, SO 2exceed certain low concentration SO when concentration for the treatment of 2flue gas (SO 2concentration: 4500mg/Nm 3-9000mg/Nm 3, mean concentration: 6570mg/Nm 3; Exhaust gas volumn: 82850Nm 3/ h-171190Nm 3/ h, average tolerance: 127020Nm 3/ h) desulfurization in, specifically comprise the following steps: active pulp conveying ore dressing produced to active ore pulp surge tank 4, and is delivered to SO through active pulp conveying pump 5 2circulating slot at the bottom of the tower of smoke absorption tower 2, SO 2active ore pulp in circulating slot at the bottom of the tower of smoke absorption tower 2 is delivered to the active ore pulp shower nozzle 15 of reverse jet tube shower nozzle 14 and Ta Nei middle and lower part respectively through active ore pulp circulating pump 6; Waste electrolyte from nickel, copper, cobalt potroom is delivered to waste electrolyte surge tank 9, and flows in waste electrolyte circulating slot 10, is delivered to tower internal upper part waste electrolyte shower nozzle 16 through waste electrolyte circulating pump 11; Low concentration SO 2flue gas is delivered to SO by relay air blower 1 2the reverse jet tube 13 of smoke absorption tower 2, the active ore pulp counter current contacting sprayed with reverse jet tube shower nozzle 14, to the SO in flue gas 2carry out first time absorption, entered SO by the flue gas after absorbing for the first time 2in smoke absorption tower 2, the active ore pulp counter current contacting sprayed with the active ore pulp shower nozzle 15 in middle and lower part in tower, to the SO in flue gas 2carry out second time to absorb; Absorb saturated after active ore pulp absorbing liquid (pH value is down to 6.5 by 9.8) be settled down to SO 2circulating slot at the bottom of the tower of smoke absorption tower 2, is delivered to active ore pulp absorbing liquid surge tank 7 through active ore pulp absorbing liquid circulating pump 8; SO is passed through by the flue gas after absorbing for the second time 2the distribution device of smoke absorption tower 2 enters waste electrolyte security personnel absorber portion, the waste electrolyte counter current contacting sprayed with tower internal upper part waste electrolyte shower nozzle 16, utilizes waste electrolyte to carry out security personnel to flue gas and absorbs, guarantee the SO in tail smoke discharging 2concentration is up to standard; Waste electrolyte after absorption is deposited on SO 2the distribution device bottom land of smoke absorption tower 2, flow into waste electrolyte circulating slot 10 Inner eycle to use, discharge from waste electrolyte delivery pipe 17 when in waste electrolyte circulating slot 10, waste electrolyte pH value is reduced to 7.1, (flue gas concentration remains on 110mg/Nm to the flue gas after waste electrolyte absorbs 3below, qualified discharge standard is met) pass through SO 2the top of smoke absorption tower 2 enters in electrostatic precipitator 3, and the acid mist in removing flue gas, enters in tail smoke evacuation chimney 12 and discharge.

Claims (7)

1. one kind utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: comprise SO 2smoke absorption tower (2), electrostatic precipitator (3), active ore pulp surge tank (4), active ore pulp absorbing liquid surge tank (7), waste electrolyte surge tank (9), waste electrolyte circulating slot (10) and tail smoke evacuation chimney (12), described SO 2reverse jet tube (13) end of smoke absorption tower (2) is connected with relay air blower (1) through flue, described SO 2circulating slot at the bottom of the tower of smoke absorption tower (2) is connected with active ore pulp surge tank (4) by active pulp conveying pump (5), described SO 2circulating slot at the bottom of the tower of smoke absorption tower (2) is connected with middle and lower part activity ore pulp shower nozzle (15) in reverse jet tube shower nozzle (14) and tower respectively by active ore pulp circulating pump (6), described SO 2circulating slot at the bottom of the tower of smoke absorption tower (2) is connected with active ore pulp absorbing liquid surge tank (7) by active ore pulp absorbing liquid circulating pump (8), described SO 2the distribution device bottom land of smoke absorption tower (2) is connected with waste electrolyte circulating slot (10) by pipeline, described waste electrolyte circulating slot (10) is connected with tower internal upper part waste electrolyte shower nozzle (16) by waste electrolyte circulating pump (11), described waste electrolyte circulating slot (10) is connected with waste electrolyte surge tank (9), described SO 2the top of smoke absorption tower (2) is connected with electrostatic precipitator (3), and described electrostatic precipitator (3) is connected with tail smoke evacuation chimney (12).
2. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described waste electrolyte circulating slot (10) is provided with waste electrolyte delivery pipe (17).
3. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described active pulp conveying pump (5) is two groups.
4. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described active ore pulp circulating pump (6) is three groups.
5. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described active ore pulp absorbing liquid delivery pump (8) is two groups.
6. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described waste electrolyte circulating pump (11) is two groups.
7. one according to claim 1 utilizes alkaline waste liquor to carry out low concentration SO 2the device of flue gas desulfurization, is characterized in that: described SO 2smoke absorption tower (2) rushes desulfurizing tower for Two-way Cycle rapids.
CN201520938585.1U 2015-11-23 2015-11-23 Device for low concentration SO2 flue gas desulfurization with basicity waste liquid Active CN205199294U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105268307A (en) * 2015-11-23 2016-01-27 金川集团股份有限公司 Device and method for carrying out low-concentration SO2 smoke desulfurization through alkaline waste liquid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105268307A (en) * 2015-11-23 2016-01-27 金川集团股份有限公司 Device and method for carrying out low-concentration SO2 smoke desulfurization through alkaline waste liquid

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C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20240201

Address after: 737100 No. 2 Lanzhou Road, Beijing Road Street, Jinchuan District, Jinchang City, Gansu Province

Patentee after: Jinchuan Group Nickel Cobalt Co.,Ltd.

Country or region after: China

Address before: 737103 No. 98, Jinchuan Road, Jinchang, Gansu

Patentee before: JINCHUAN GROUP Co.,Ltd.

Country or region before: China

TR01 Transfer of patent right