CN205061622U - Efficient membrane distillation plant - Google Patents
Efficient membrane distillation plant Download PDFInfo
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- CN205061622U CN205061622U CN201520610335.5U CN201520610335U CN205061622U CN 205061622 U CN205061622 U CN 205061622U CN 201520610335 U CN201520610335 U CN 201520610335U CN 205061622 U CN205061622 U CN 205061622U
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Abstract
The utility model provides an efficient membrane distillation plant. Including running through in the way setting of raw materials liquid stream: preheating device for preheat former feed liquid, an equalizing basin, multiple -effect membrane distillation system, with a steam flow path of the steam outlet intercommunication of multiple -effect membrane distillation system, the steam flow path with preheating device connects. Adopt multiple -effect vacuum membrane distillation, be equipped with percolating water and collect recovery system, can effectively avoid percolating water to pollute and produce water, ensure to produce water quality of water. The with a system of multiple effective membrane distillation simultaneously three -section heat recovery system can improve system's heat utilization efficiency, reduces system energy consumption, improves vacuum membrane distillation's practicality.
Description
Technical field
The utility model relates to water-treatment technology field, is specifically related to a kind of distillation device efficiently.
Background technology
Film distillation technology take hydrophobic film as separating medium, by carrying out heat temperature raising to hot side solution, the water in feed liquid is made to evaporate into water vapour and enter fenestra, water vapour arrives the opposite side of film under the promotion of film both sides vapour pressure deficit through fenestra, then through certain type of cooling, water vapour is condensed into liquid water again.Due to the hydrophobicity of film, the liquid water in solution and other water-soluble substanceses are trapped, thus realize the concentration process of feed liquid.When adopting membrane distillation concentration desalination, have most salt and other non-volatile substances and retain efficiency close to 100%, and membrane distillation operational condition is gentle, do not need solution to be heated to boiling.In addition, in solution, the change of saltiness is less on membrane flux impact, and membrane distillation normally can run when high saltiness (saltiness can be greater than 25%), and membrane distillation can run at ambient pressure, does not need condition of high voltage.Due to stalling characteristic and the many merits of membrane distillation, this technology has in wastewater treatment, sea water desaltination, chemical separating, concentration of juices etc. studies application widely.
At present, the shortcoming of the membrane distillation technique of prior art is mainly reflected in energy consumption and crosses high aspect:
Membrane distillation is different according to the operation scheme of cold side, and membrane distillation can be divided into direct contact membrane distillation, sweep gas membrane disillation, gap field orientation and vacuum membrane distillation, these four kinds of membrane distillation modes respectively have relative merits.
Vacuum membrane distillation (VMD) adopts the mode vacuumized to make the condensation side of membrane module keep certain negative pressure, after water in the solution of hot side enters the opposite side of film in vapour form, extracted out membrane module by the effect of vacuum pump, and be condensed into liquid water in condenser beyond membrane module.Because film both sides vapour pressure deficit in VMD is larger, have larger impellent, the membrane distillation form that therefore VMD compares other has larger membrane flux.Owing to needing to provide extra cooling working medium in traditional vacuum membrane distillation vapour condensation process, not only limit its application prospect, also cause energy consumption higher simultaneously.Therefore, develop that to have more high-throughout membrane distillation technique significant for the industrial applications of film distillation technology.
Patent of invention CN101797479A disclose a kind of utilize open steam compressing hot pump to carry out vacuum membrane distillation method and device.By adopting a vapour compressor directly to compress the steam of membrane module through side, by the high temperature and high pressure steam after compression successively by a well heater and a preheater, simultaneously by raw material also by well heater and preheater.But this invention maintains system cloud gray model mainly through vapour compression heat, but because flux of membrane distillation is lower in actual production, be difficult to ensure enough heats and maintain system stable operation, and the heat in the dense water of high temperature produced in this invention does not reclaim, and causes serious heat loss.In addition, what adopt in this invention is single-action membrane distillation, does not also arrange leakage water collecting system and vacuum pump, because percolating water is very large to Influence of production, therefore must carry out independent collection and treatment.
Utility model content
For above-mentioned prior art Problems existing, the purpose of this utility model overcomes the shortcoming that in existing vacuum membrane distillation technique, energy consumption is higher, proposes a kind of distillation device efficiently.Heated low temperature feedstock liquid by vapour compression and Multi-stage heating, heat exchange efficiency is higher.
For achieving the above object, the technical scheme that the utility model is taked is:
A kind of distillation device efficiently, comprises and arranging through stock liquid stream:
Primary heater unit, in order to carry out preheating to stock liquid;
One equalizing tank, remains on a preset temp in order to make the stock liquid after preheating and ensures that pool inner water matter is even;
One multiple-effect membrane distillation system, in order to carry out multiple-effect membrane distillation to the stock liquid being in preset temp;
The vapor flow path be communicated with the vapour outlet of described multiple-effect membrane distillation system, described vapor flow path is connected with described primary heater unit, in order to primary heater unit heat supply.
Further, described primary heater unit comprises and being communicated with successively: one or two sections of interchanger, one or two sections of condensation storage tanks, one or three sections of interchanger, one or three sections of water of condensation storage tanks; Also comprise the interchanger of section one by one be simultaneously communicated with two sections of water of condensation storage tanks and three sections of water of condensation storage tanks; Described one section of interchanger, two sections of interchanger and three sections of interchanger are set in turn in and are communicated on the stock liquid stream of equalizing tank.
Further, in described equalizing tank, heating unit is set, in order to guarantee that in equalizing tank, stock liquid temperature remains on setting range.
Further, described multiple-effect membrane distillation system comprises: what be communicated with successively is no less than 2 membrane modules; The tail end of the solution side of preceding membrane module is communicated with successively with the head end of the solution side of posterior membrane module; In described membrane module, the head end of the solution side of first membrane module is communicated with described equalizing tank, and the tail end of the solution side of last membrane module is communicated with described equalizing tank.
Further, the effusion storage tank be communicated with the effusion discharge outlet of the inlet side of multiple membrane module is also comprised; Described effusion storage tank is communicated with described equalizing tank.
By taking technique scheme, the utility model has following beneficial effect: adopt multiple-effect vacuum membrane distillation, be provided with leakage water collecting recovery system, percolating water effectively can be avoided to pollute and produce water, guarantees to produce water water quality.The membrane distillation system of multiple-effect coordinates three sections of heat recovery systems simultaneously, can improve systematic heat utilization rate, reduces system energy consumption, improves the practicality of vacuum membrane distillation.
Accompanying drawing explanation
Fig. 1 is efficient distillation device of the present utility model technological principle schematic diagram in one embodiment.
In figure: 1, equalizing tank; 2, well heater; 3, feed pump; 4, the first effect membrane module; 5, hydrophobic membrane; 6, the second effect membrane module; 7, triple effect membrane module; 8, N imitates membrane module; 9, vacuum pump; 10, two sections of interchanger; 11, two sections of water of condensation storage tanks; 12, air compressor; 13, three sections of interchanger; 14, three sections of water of condensation storage tanks; 15, liquid heat pump; 16, one section of interchanger; 17, water storage tank is produced; 18, raw material liquid pump; 19, stock liquid storage tank; 20, effusion storage tank; A1, the first effect membrane module vapour outlet; A2, the second effect membrane module vapour outlet; A3, triple effect membrane module vapour outlet; A4, N imitate membrane module vapour outlet; B1, the first effect membrane module vacuum tightness variable valve; B2, the second effect membrane module vacuum tightness variable valve; B3, triple effect membrane module vacuum tightness variable valve; B4, N imitate membrane module vacuum tightness variable valve; C1, the first effect membrane module effusion discharge outlet; C2, the second effect membrane module effusion discharge outlet; C3, triple effect membrane module effusion discharge outlet; C4, N imitate membrane module effusion discharge outlet.
Embodiment
Below in conjunction with the drawings and specific embodiments, the utility model is described further.
As shown in Figure 1, efficient distillation device of the present utility model, comprise through stock liquid stream arrange: primary heater unit, in order to carry out preheating to stock liquid; Well heater 2 and equalizing tank 1, in order to make the stock liquid after preheating remain on a preset temp, ensure that in pond, feed liquid is even simultaneously; Multiple-effect membrane distillation system, in order to carry out multiple-effect membrane distillation to the stock liquid being in preset temp; The vapor flow path be communicated with the vapour outlet of described multiple-effect membrane distillation system, described vapor flow path is connected with described primary heater unit, in order to primary heater unit heat supply; Vacuum pump 9, in order to provide negative pressure, and extracts out water vapor in membrane module; Vapour compressor 12, in order to compressed vapour, and then improves vapor temperature; Liquid heat pump 15, in order to improve fluid temperature.Also comprise the stock liquid storage tank 19 storing stock liquid, in order to collect the effusion storage tank 20 of the effusion of multiple-effect membrane distillation system, be connected with the end of primary heater unit, in order to collect the finished fluid storage tank 17 of finished fluid; And be arranged in stock liquid stream, vapor flow path and primary heater unit in order to many covers regulated valve of auxiliary heat-exchanging and pump.
Wherein, primary heater unit comprises: two sections of interchanger, 10, two sections of water of condensation storage tanks, 11, three sections of interchanger, 13, three sections of water of condensation storage tanks 14; Be connected with cryogenic liquid heat pump 15 entrance after two sections of water of condensation storage tanks 11 and three sections of water of condensation storage tanks 13 mix, after liquid heat pump 15 heats up, liquid is exported by liquid heat pump 15 and enters into one section of interchanger 16, carries out one section of preheating to stock liquid.As can be seen from Figure 1, before stock liquid enters equalizing tank 1, one section of interchanger, 16, two sections of interchanger 10 and three sections of interchanger 13 are successively set on stock liquid stream.
By the decoration form of above-mentioned primary heater unit, steam is first through two sections of interchanger 10, can be tentatively liquid water by water vapor condensation, on the one hand heat exchange is carried out to stock liquid, can effectively reduce the quantity of steam entering vapour compressor 12 on the other hand, and then reduce follow-up load, because after two sections and three sections of preheatings, stock liquid temperature raises, with two sections of water of condensation storage tanks 11 and three sections of water of condensation storage tank 14 mixed mixing liquid temperature difference less, heat exchange efficiency is low, therefore two sections of water of condensation storage tanks 11 and three sections of mixed mixing liquids of water of condensation storage tank 14 are entered one section of interchanger 16 after liquid heat pump 15 heats up, realize higher heat exchange efficiency, also be more conducive to reducing the product water temp produced in tank 17 simultaneously, be conducive to reuse.
Be provided with well heater 2 in equalizing tank 1, when feed temperature is lower than set(ting)value in equalizing tank 1, starts well heater 2 pairs of feed liquid heating, remain on a temperature preset in order to make the stock liquid in equalizing tank 1.
Multiple-effect membrane distillation system comprises: the multiple membrane modules be communicated with successively, comprise first effect membrane module 4, second imitate membrane module 6, triple effect membrane module 7 to N imitate membrane module 8, N be less than or equal to 14 integer; The tail end of the solution side of preceding membrane module is communicated with successively with the head end of the solution side of posterior membrane module.In fact, the utility model is not limited to the multiple-effect membrane module shown in Fig. 1, as long as membrane module quantity is more than or equal to 2 all can be applicable to method of the present utility model and device; For different applied environments, the quantity of membrane module remains on less than 14 and can obtain good technique effect.
In FIG, the form of multiple membrane module is hollow fiber form membrane module, and membrane module solution side is the tube side of hollow fiber form membrane module, and membrane module inlet side is the shell side of hollow fiber form membrane module; Or membrane module solution side is the shell side of hollow fiber form membrane module, membrane module inlet side is the tube side of hollow fiber form membrane module.In fact, in other examples, also can adopt the other forms of membrane module such as rolled membrane module or plate type membrane component, at this only in order to a kind of embodiment of the present utility model to be described, the form for membrane module does not limit.One hydrophobic membrane 5 is provided with in each membrane module.Hydrophobic membrane 5 can be polytetrafluoroethylmaterial material, polypropylene material, polyvinylidene difluoride (PVDF) or stupalith.In addition, thermal insulation layer (figure does not illustrate) can be provided with in the outside of membrane module.
The head end of the solution side of the first effect membrane module 4 is communicated with described equalizing tank 1; From then on stock liquid is pressed into by the second raw material liquid pump 3, and the tail end that N imitates the solution side of membrane module 8 is communicated with equalizing tank 1, and from then on stock liquid is back to equalizing tank 1 after multiple-effect membrane module.
Multiple membrane module is communicated with a vacuum pump 9 jointly, and the side that vacuumizes of each membrane module is provided with vacuum tightness variable valve: comprise the first effect membrane module vacuum tightness variable valve b1, the second effect membrane module vacuum tightness variable valve b2, triple effect membrane module vacuum tightness variable valve b3 ... until N imitates membrane module vacuum tightness variable valve b4, for controlling the vacuum tightness in different membrane module.
Also comprise the effusion storage tank 20 be communicated with the effusion discharge outlet of multiple membrane module; Effusion storage tank 20 is also communicated with equalizing tank 1, and effusion is back to equalizing tank 1 equally.Effusion is collected into effusion storage tank 20 and is back to equalizing tank 1, avoids normally running because local fenestra seepage affects membrane module or polluting product water.
Efficient distillation device of the present utility model operationally, when namely implementing efficient membrane distillation method of the present utility model, first by raw material liquid pump 18, stock liquid is pumped into equalizing tank 1 by stock liquid storage tank 19, period, raw material feed liquid was successively by one section of interchanger, 16, two sections of interchanger, 10, three sections of interchanger 13, when in equalizing tank 1, the water yield reaches set(ting)value, heater 2, is heated to design temperature (being generally 30 ~ 95 DEG C) by feed liquid in equalizing tank 1.Then feed pump 3 is opened, feed liquid is pumped into the first effect membrane module 4 from equalizing tank 1, entered by one end of the tube side of the first effect membrane module 4, the second effect membrane module 6 is entered after the other end of the tube side of the first effect membrane module 4 flows out, entered by one end of the tube side of the second effect membrane module 6, flow out from the other end of the tube side of the second effect membrane module 6, then triple effect membrane module 7 is entered, class is broken successively, feed liquid enters one end that N imitates membrane module 8 tube side, imitate the other end outflow of membrane module 8 tube side from N after, again flow back into equalizing tank 1.
Open vacuum pump 9, then different according to difference effect membrane module temperature, slowly regulate the first effect membrane module vacuum tightness variable valve b1, the second effect membrane module vacuum tightness variable valve b2, triple effect membrane module vacuum tightness variable valve b3 until N imitates membrane module vacuum tightness variable valve b4.First the steam that vacuum pump 9 is extracted out carry out preheating by two sections of interchanger, 10 pairs of stock liquids, collected by two sections of condensation storage tanks 11 after some vapor condensation, all the other uncooled steam enter three sections of interchanger, 13 pairs of stock liquids after compressing intensification by Pistonless compressor 12 and carry out three sections of heating, and the water of condensation simultaneously generated is collected by three sections of condensation storage tanks 14.
Enter heat of liquid pump 15 by after the feed liquid mixing in two sections of condensation storage tanks 11 and three sections of condensation storage tanks 14, enter one section of heat exchanger 16 after being heated up by liquid heat pump 15, produce water storage tank 17 with entering after stock liquid heat exchange, be back to other technique.Open the first effect membrane module effusion discharge outlet c1, the second effect membrane module effusion discharge outlet c2, triple effect membrane module effusion discharge outlet c3 until N imitates membrane module effusion discharge outlet c4, if there is effusion, by each discharge outlet, effusion is collected into effusion storage tank 20, is then back to equalizing tank 1.
Due to the operation of multiple-effect membrane distillation, in equalizing tank 1, material liquid volume reduces gradually, controls raw material liquid pump 18 by controller, constantly supplements feed liquid to equalizing tank 1 by stock liquid storage tank 19.Equalizing tank 1 set temperature automatic control device simultaneously, ensure homo(io)thermism in equalizing tank 1, because stock liquid temperature after three grades of preheatings raises, if feed temperature has reached in equalizing tank 1 and has required temperature after preheating, then do not need to start well heater 2, if feed temperature does not reach in equalizing tank 1 temperature required after preheating, then heater 2 is heated to design temperature automatically.
As mentioned above, efficient distillation device of the present utility model and method are compared to prior art, guarantee have enough heats to maintain system stable operation, improve systematic heat utilization rate to 80%-85%, comparatively prior art, its heat utilization efficiency can improve 50%-80%, reduces system energy consumption, improves the practicality of vacuum membrane distillation.
The utility model may be used for the concentration of the aqueous solution, also can be applied to other purposes such as gas delivery in concentration of juices, the aqueous solution.Not only can be applicable to inner pressed membrane distillation, also can be applicable to external-compression type membrane distillation and immersion vacuum membrane distillation.
Above-described embodiment is only embodiment of the present utility model; but protection domain of the present utility model is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the utility model discloses; change can be expected easily or replace, all should be encompassed within protection domain of the present utility model.
Claims (5)
1. an efficient distillation device, is characterized in that, comprise through stock liquid stream arrange:
Primary heater unit, in order to carry out preheating to stock liquid;
One equalizing tank, remains on a preset temp in order to make the stock liquid after preheating and ensures that pool inner water matter is even;
One multiple-effect membrane distillation system, in order to carry out multiple-effect membrane distillation to the stock liquid being in preset temp;
The vapor flow path be communicated with the vapour outlet of described multiple-effect membrane distillation system, described vapor flow path is connected with described primary heater unit, in order to primary heater unit heat supply.
2. distillation device efficiently as claimed in claim 1, is characterized in that, described primary heater unit comprises and being communicated with successively: one or two sections of interchanger, one or two sections of water of condensation storage tanks, one or three sections of interchanger, one or three sections of water of condensation storage tanks; Also comprise the interchanger of section one by one be simultaneously communicated with two sections of water of condensation storage tanks and three sections of water of condensation storage tanks; Described one section of interchanger, two sections of interchanger and three sections of interchanger are set in turn in and are communicated on the stock liquid stream of equalizing tank.
3. distillation device efficiently as claimed in claim 1, is characterized in that, be provided with a heating unit in described equalizing tank, in order to guarantee that in equalizing tank, stock liquid temperature remains on setting range.
4. distillation device efficiently as claimed in claim 1, it is characterized in that, described multiple-effect membrane distillation system comprises: what be communicated with successively is no less than 2 membrane modules; The tail end of the solution side of preceding membrane module is communicated with successively with the head end of the solution side of posterior membrane module; In described membrane module, the head end of the solution side of first membrane module is communicated with described equalizing tank, and the tail end of the solution side of last membrane module is communicated with described equalizing tank.
5. distillation device efficiently as claimed in claim 1, is characterized in that, also comprise the effusion storage tank be communicated with the effusion discharge outlet of the inlet side of multiple membrane module; Described effusion storage tank is communicated with described equalizing tank.
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| CN201520610335.5U CN205061622U (en) | 2015-08-13 | 2015-08-13 | Efficient membrane distillation plant |
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| CN201520610335.5U CN205061622U (en) | 2015-08-13 | 2015-08-13 | Efficient membrane distillation plant |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105084445A (en) * | 2015-08-13 | 2015-11-25 | 大唐环境产业集团股份有限公司 | Efficient membrane distillation method and device |
| CN108147485A (en) * | 2016-12-04 | 2018-06-12 | 中国科学院大连化学物理研究所 | A kind of fresh-water generator |
| CN110404411A (en) * | 2019-07-22 | 2019-11-05 | 珠海格力电器股份有限公司 | Membrane distillation system and method with waste heat recovery coupling MVR |
-
2015
- 2015-08-13 CN CN201520610335.5U patent/CN205061622U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105084445A (en) * | 2015-08-13 | 2015-11-25 | 大唐环境产业集团股份有限公司 | Efficient membrane distillation method and device |
| CN108147485A (en) * | 2016-12-04 | 2018-06-12 | 中国科学院大连化学物理研究所 | A kind of fresh-water generator |
| CN110404411A (en) * | 2019-07-22 | 2019-11-05 | 珠海格力电器股份有限公司 | Membrane distillation system and method with waste heat recovery coupling MVR |
| CN110404411B (en) * | 2019-07-22 | 2024-04-19 | 珠海格力电器股份有限公司 | Membrane distillation system and method with waste heat recovery coupling MVR |
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