CN205050704U - High voltage piece formula conductive polymer tantalum electrolytic capacitor - Google Patents
High voltage piece formula conductive polymer tantalum electrolytic capacitor Download PDFInfo
- Publication number
- CN205050704U CN205050704U CN201520417645.5U CN201520417645U CN205050704U CN 205050704 U CN205050704 U CN 205050704U CN 201520417645 U CN201520417645 U CN 201520417645U CN 205050704 U CN205050704 U CN 205050704U
- Authority
- CN
- China
- Prior art keywords
- tantalum
- layer
- capacitor
- zinc
- negative electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Abstract
The utility model discloses a high voltage piece formula conductive polymer tantalum electrolytic capacitor, include: epoxy encapsulates the shell, is packaged with tantalum granule condenser base member, the brass zinc -plated cathode extraction piece of base and the zinc -plated positive pole of brass base through epoxy in it and draws forth the piece, the inside positive pole that is of tantalum granule condenser base member, this positive pole briquet that piece formula tantalum powder was suppressed into for the raw materials of serving as reasons, the positive pole outside is equipped with the dielectric layer that thickness was not less than 3000 nanometers or 3500 nanometers, the outside of dielectric layer is equipped with gathers 3 as the nanometer of negative pole, 4 ethylene dioxy thiophene particle deposition layer, the negative pole outside is equipped with the negative pole and draws forth the layer, be equipped with in the positive pole and draw forth the tantalum silk lead -out wire that chip bonding formation electricity is connected with the zinc -plated positive pole of brass base, the negative pole and the zinc -plated cathode extraction piece of the brass base electricity of tantalum granule condenser base member are connected. This electric capacity is withstand voltage to reach 50V or 63V, has widened piece formula tantalum electrolytic capacitor's range of application, satisfies the requirement of circuit reliability.
Description
Technical field
The utility model relates to the preparation field of tantalum capacitor, particularly relates to a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor.
Background technology
When the capacity of tantalum capacitor and test or frequency of utilization are increased to certain value, the capacity of product can reduce with the increase of frequency, and when frequency is increased to the same with the resonance frequency of product, the capacity of product will be lost, and become an inductance.The root of this inevitable physical phenomenon is that the inductance of product and impedance can become capacitive reactance with the increase of frequency, causes the capacity of product to decline.Impedance as fruit product is lower, and particularly high-frequency resistance is lower, and so the induction reactance of product is also lower, so the capacity of product also by higher frequencies maintenance to a certain extent.Like this, this product just can be used in the higher circuit of frequency and there will not be the phenomenon that cannot use with the decline of capacity.
Well falling low-impedance a kind of mode is at present that negative electrode uses polythiophene [3,4 ethene dioxythiophenes, English abbreviation PEDT], this kind of organic polymer conductance is 10 ~ 100 times of manganese dioxide, can condensance be effectively reduced, make electric capacity have better capacity frequency characteristics, and this kind of material can not discharge oxygen when high temperature, electric capacity combustion explosion when losing efficacy would not be caused, there is better fail safe.
The use circuit of chip tantalum capacitor is all the switching power circuit of high surge height ripple substantially, particularly highly reliable military circuit, the tantalum capacitor that manganese dioxide does negative electrode uses voltage can only reach 1/3 of rated voltage, the tantalum electric capacity that macromolecule tantalum electric capacity and manganese dioxide do negative electrode has the low advantage of derate voltage in use, and rated voltage and use voltage-contrast see the following form:
In circuit in the raising of voltage and circuit device to the increase of high power requirements, use voltage more and more higher in circuit, as LED circuit, the 35V high-voltage CMOS integrated circuit of 36V, be used in the tantalum capacitor of high voltage circuit like this, the tantalum capacitor that manganese dioxide does negative electrode needs rated voltage 100V (this kind of solid capacitor there is no ripe technology both at home and abroad), and the tantalum capacitor that macromolecule does negative electrode needs rated voltage to reach 50V just to meet the demands.If voltage is at 40 ~ 50V in circuit, the High-Polymer Capacitance rated voltage of needs reaches 63V.But existing macromolecule tantalum electric capacity rated voltage can only accomplish 35V, and rated voltage is one piece of blank at the Serial capacitance of 50V and 63V, and the macromolecule tantalum electric capacity of existing 35V rated voltage can not meet the requirement of this high-tension circuit.
Existing mesolow macromolecule tantalum electric capacity adopts the method for polymerization to form negative electrode, no matter be two step method or one-step method, all by EDT monomer [3 of single molecule level, 4 ethene dioxythiophenes and butanol solution] and be with and conduct electricity the higher polymeric coating layer of a kind of conductivity of being formed after the p-methyl benzenesulfonic acid iron of iron ion carries out electrochemistry or chemical polymerization, as shown in the reaction equation of Fig. 1.This kind of polymerization process can be divided into dipping, polymerization, cleaning, mend the steps such as formation, impregnated monomer EDT (3 of single molecule level, 4 ethene dioxythiophenes) and oxidant p-methyl benzenesulfonic acid iron after, in an oven after uniform temperature and time aggregation, form cathode polymer, wherein iron ion is washed off in matting, then mends in p-methyl benzenesulfonic acid solution and is formed, to reduce leakage current.Repeatedly increase capacity through operations such as dipping several times, polymerization, cleaning, benefit formation draw and form certain outer layer copolymer thickness.The cathode layer that this polymerization is formed, after impregnated monomer and oxidant, because tantalum anode block is loose structure, iron ion unnecessary in oxidant and reacted ferrous ion can not be washed in cleaning process, cause the withstand voltage reduction of cathode polymer, the puncture voltage of cathode polymer only has 40V to 50V, so the load voltage value of finished product tantalum electric capacity is the highest can only accomplish 35V.
Utility model content
Based on the problem existing for above-mentioned prior art, the utility model provides a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor, its rated insulation voltage reaches 50V or 63V, solve existing chip conducting polymer solid electrolyte Ta capacitor rated insulation voltage and only can reach 35V, the problem used in some high-tension circuit cannot be met.
For solving the problems of the technologies described above, the utility model provides a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor, and this capacitor comprises:
Molded plastic shell, has tantalum particle capacitor matrix, the zinc-plated negative pole of brass base and the zinc-plated positive pole of brass base through epoxy encapsulation in it, described tantalum particle capacitor matrix inside is anode, this anode is 6000 ~ 10000UuF.v/g by specific volume, the chip tantalum powder that puncture voltage reaches 250V or 300V is raw material, the tantalum core briquet be pressed into by the pressed density of 6.0 ~ 8.0 grams/CC, the outside of described tantalum core briquet is provided with the dielectric layer that thickness is not less than 3000 nanometers or 3500 nanometers, the outside of described dielectric layer is provided with the nanometer poly-3 as negative electrode, 4 ethene dioxythiophene particle deposition layer, graphite linings is coated with successively and silver slurry layer goes out layer as negative electrode silver outside negative electrode, tantalum wire lead-out wire is provided with in described tantalum core briquet, described tantalum wire lead-out wire welds to be formed with the zinc-plated positive pole of described brass base and is electrically connected, the negative electrode of described tantalum particle capacitor matrix is connected with the zinc-plated negative electricity of described brass base.
The beneficial effects of the utility model are: by adopting specific volume to be 6000 ~ 10000uF.v/g, the chip tantalum powder that puncture voltage reaches 250V (correspond to and manufacture rated voltage 50V capacitor) or 300V (correspond to and manufacture rated voltage 63V capacitor) is raw material, the size of allowing according to standard shell capacitance shell under the pressed density of 6.0 ~ 8.0 grams/CC carries out anode compact formation, then to briquet 1600 ~ 1800 DEG C of temperature, vacuum degree carries out high-temperature vacuum sintering under reaching 5 × 0.0004Pa condition, and use passivation technology when coming out of the stove, then in phosphoric acid ethylene glycol electrolyte, the direct voltage of 4 × 50V or 4 × more than 63V is pressed as coating-forming voltage, and ensure that current density is 20 ~ 50 milliamperes/gram, the electrochemistry of briquet being carried out to dielectric layer is formed, the dielectric layer that thickness is not less than 3000 nanometers (correspond to and manufacture rated voltage 50V capacitor) or 3500 nanometers (correspond to and manufacture rated voltage 63V capacitor) is formed on briquet surface, and by adopting nanoscale poly-3, 4 ethene dioxythiophene particle deposition layer are as cathode layer, its purity is high, good stability, puncture voltage reaches 120V to 150V, technique coordinates with follow-up plastic packaging is shaping etc., make the rated insulation voltage of the chip-type solid tantalum electrolytic capacitor prepared and leakage current all can reach the requirement of 50V or 63V, fill up the blank of macromolecule tantalum electric capacity rated insulation voltage higher than 35V series, extend the range of application of solid sheet type tantalum electrolyte capacitor greatly, meet the demand of electronic circuit high voltage appearance.
Accompanying drawing explanation
In order to be illustrated more clearly in the technical scheme of the utility model embodiment, below the accompanying drawing used required in describing embodiment is briefly described, apparently, accompanying drawing in the following describes is only embodiments more of the present utility model, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the reaction equation that prior art manufactures the polymerization of mesolow macromolecule tantalum capacitance cathode;
Fig. 2 is the structural representation of the solid sheet type tantalum electrolyte capacitor of the utility model embodiment;
Fig. 3 is the manufacture method flow chart of the solid sheet type tantalum electrolyte capacitor of the utility model embodiment;
In Fig. 2: 1-molded plastic shell; The zinc-plated negative pole of 2-brass base; 3-tantalum particle capacitor matrix; 30-tantalum core; 31-nanometer gathers 3,4 ethene dioxythiophene particle deposition layer; 32-graphite linings; 33-silver slurry layer; 4-silver paste; 5-packing ring; 6-tantalum wire lead-out wire; 7-pad; The zinc-plated positive pole of 8-brass base; 9-polarity bar; 10-epoxy resin.
Embodiment
Be clearly and completely described the technical scheme in the utility model embodiment below, obviously, described embodiment is only the utility model part embodiment, instead of whole embodiments.Based on embodiment of the present utility model, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to protection range of the present utility model.
The utility model embodiment provides a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor, and this capacitor can be obtained by above-mentioned manufacture method, and as shown in Figure 2, this capacitor comprises:
Molded plastic shell, has tantalum particle capacitor matrix, the zinc-plated negative pole of brass base and the zinc-plated positive pole of brass base through epoxy encapsulation in it, tantalum particle capacitor matrix is inner as anode, this anode is 6000 ~ 10000UuF.v/g by specific volume, the chip tantalum powder that puncture voltage reaches 250V or 300V is raw material, the tantalum core briquet be pressed into by the pressed density of 6.0 ~ 8.0 grams/CC, the outside of tantalum core briquet (i.e. anode) is provided with the dielectric layer that thickness is not less than 3000 nanometers or 3500 nanometers, the outside of dielectric layer is provided with the nanometer poly-3 as negative electrode, 4 ethene dioxythiophene particle deposition layer, graphite linings is coated with successively and silver slurry layer goes out layer as negative electrode silver outside negative electrode, tantalum wire lead-out wire is provided with in tantalum core briquet (i.e. anode), the packing ring that layer contact position has arranged insulating effect can be drawn at tantalum wire lead-out wire and negative electrode and negative electrode, tantalum wire lead-out wire welds to be formed with the zinc-plated positive pole of brass base and is electrically connected, the negative electrode of tantalum particle capacitor matrix is connected with the zinc-plated negative electricity of brass base.
In above-mentioned capacitor, as the nanometer poly-3 of negative electrode, 4 ethene dioxythiophene particle deposition layer are: to be 20 ~ 50 nanometer solid contents by particle diameter be 0.8% ~ 3.0% nanoscale poly-3,4 ethene dioxythiophene particle solution penetrate in the anode interior space and dielectric layer generating dielectric layer, the operation of drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, repeat poly-3, the 4 ethene dioxythiophene particle deposition layer of nanometer formed for 16 ~ 26 times.
The above-mentioned nanometer as negative electrode poly-3,4 ethene dioxythiophene particle deposition layer are inside and outside two-layer, internal layer is poly-3 of 20 ~ 30nm with particle diameter, the capacity that 4 ethene dioxythiophene particle solution are coated to formation draws layer, skin increases layer with the thickness that poly-3,4 ethene dioxythiophenes that particle diameter is 30 ~ 50nm are coated to.
Above-mentioned high voltage chip conducting polymer solid electrolyte Ta capacitor, by following methods manufacture, as shown in Figure 3, the method comprises:
Be 6000 ~ 10000UuF.v/g by the pressed density of 6.0 ~ 8.0 grams/CC by specific volume, the puncture voltage chip tantalum powder raw material that reaches 250V or 300V is pressed into the tantalum core briquet of band tantalum wire lead-out wire, 1600 ~ 1800 DEG C of temperature, vacuum degree carries out vacuum-sintering to described briquet under reaching the condition of 5 × 0.0004Pa, carries out Passivation Treatment to the briquet after sintering;
At 60 ~ 85 DEG C of temperature, described briquet after sintering is put into the electrochemistry formation that the formation groove that phosphoric acid ethylene glycol electrolyte is housed carries out dielectric layer, adopt the direct voltage being not less than 4 × 50V or 4 × 63V as coating-forming voltage, the dielectric layer being not less than 3000 nanometers or 3500 nanometers with the current density of 20 ~ 50 milliamperes/gram at described briquet surface formation thickness;
The described briquet of dielectric layer will be generated, adopt repeatedly infusion process by nanoscale poly-3,4 ethene dioxythiophene particle solution penetrate into described briquet internal voids and deposition forms nanometer poly-3 on briquet surface media, 4 ethene dioxythiophene particle deposition layer are as negative electrode, and on the negative electrode that briquet surface media is formed, coated graphite layer and silver slurry layer draw layer as negative electrode;
The tantalum wire lead-out wire of described briquet is welded on the outer cover metal support lead of corresponding shell number, by epoxy encapsulation, i.e. obtained high voltage chip conducting polymer solid electrolyte Ta capacitor.
In said method, Passivation Treatment is carried out to the briquet after sintering and comprises:
To the briquet after sintering when coming out of the stove, point reduce vacuum degree gradually four times, each vacuum degree reduces amplitude and is not more than 0.25Ma, and make described briquet can not excessively oxygenation through transpassivation, after making sintering, on briquet, the folding silk number of times of tantalum wire be not less than 4 times.
In above-mentioned manufacture method, described briquet after sintering is put into the electrochemistry formation that the formation groove that phosphoric acid ethylene glycol electrolyte is housed carries out dielectric layer, be by sintering after described briquet be welded on stainless steel strip, then put into the formation groove that phosphoric acid ethylene glycol electrolyte is housed carry out dielectric layer electrochemistry formed.
In said method, in phosphoric acid ethylene glycol electrolyte, the concentration of phosphoric acid is 0.2 ~ 0.5% by volume, and the concentration of ethylene glycol is 20 ~ 50% by volume.
In said method, adopt repeatedly infusion process that poly-for nanoscale 3,4 ethene dioxythiophene particle solution are penetrated into described briquet internal voids and on briquet surface media, deposit formation high polymer layer and comprise as negative electrode:
Adopt repeatedly infusion process to be 20 ~ 50 nanometer solid contents by particle diameter to be the nanoscale poly-3 of 0.8% ~ 3.0%, 4 ethene dioxythiophene particle solution penetrate in the described briquet internal voids and dielectric layer generating dielectric layer, drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, make the nanoscale after oven dry poly-3,4 ethene dioxythiophene particles deposit and form poly-3, the 4 ethene dioxythiophene particle deposition layer of nanometer as negative electrode on described dielectric layer.
Above-mentioned manufacture method comprises further: to be 20 ~ 50 nanometer solid contents by particle diameter be 0.8% ~ 3.0% poly-3,4 ethene dioxythiophene particle solution penetrate in the described briquet internal voids and dielectric layer generating dielectric layer, under temperature is 120 ~ 150 DEG C of conditions, carries out the operation of drying and processing, repeats 16 ~ 26 times.
In said method, comprise by epoxy encapsulation: use fire-retardant epoxy resin at 150 ~ 180 DEG C of temperature, by transfer moulding press in precision die the dimensions that described briquet plastic packaging becomes profile to meet standard to specify.
Said method also comprises: carry out franking to obtained described high voltage chip conducting polymer solid electrolyte Ta capacitor, the process of shaping, the aging rear detection that goes between, and namely obtains final high voltage chip conducting polymer solid electrolyte Ta capacitor after process.
In said method, adopt ad hoc fashion carry out the design of anode, the formation of dielectric layer and cathode polymer coating, wherein, the design of anode comprises the control of the selection of tantalum powder, the design of pressed density and sintering shrinkage.Tantalum powder selects electronics bombardment powder or the chip powder of extra low impurity content, specific volume is 6000 ~ 10000uF.v/g, 50V tantalum electric capacity selects tantalum powder puncture voltage to need more than 250V, 63V tantalum electric capacity puncture voltage needs more than 300V, the size of allowing according to standard shell capacitance shell under the pressed density of 6.0 ~ 8.0 grams/CC carries out anode compact formation, then by briquet 1600 ~ 1800 DEG C of temperature, vacuum degree carries out high-temperature vacuum sintering under reaching 5 × 0.0004Pa condition, and shrinkage reaches 10 ~ 14%.Dielectric layer to be formed in phosphoric acid ethylene glycol electrolyte by direct voltage more than 4 × 50V (rated voltage is at the tantalum electric capacity of 50V) or 4 × 63V (rated voltage is at the tantalum electric capacity of 63V) as coating-forming voltage, and ensure that current density is 20 ~ 50 milliamperes/gram, the electrochemistry of briquet being carried out to dielectric layer is formed, and forms the dielectric layer that thickness is not less than 3000 nanometers or 3500 nanometers on briquet surface.The coating of cathode polymer needs the nanoscale poly-3 adopting different-grain diameter; 4 ethene dioxythiophene particle solution and then form the double-decker of inside and outside layer; internal layer first with particle diameter little poly-3; 4 ethene dioxythiophene particle solution form the capacity of being drawn by capacity and draw layer; what outer use particle diameter was large gathers 3; the thickness that 4 ethene dioxythiophenes are formed increases outer layer thickness increases layer, to protect anodic wick and to reduce condensance.Poly-3, the 4 ethene dioxythiophene particles of nanoscale are 20 ~ 50 nano particles, can adopt poly-3, the 4 ethene dioxythiophene particles of the nanoscale being widely used in the fields such as antistatic.Cathode polymer coating in, owing to using the nanoscale poly-3 be polymerized, 4 ethene dioxythiophene particles, its impurity content is low, inside is not containing iron ion, good stability, breakdown potential pressure energy reaches 120V ~ 150V, can be the cathode material of the tantalum electric capacity of 50V and 63V completely as rated voltage.
Embodiment one
The present embodiment provides a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor, and be the chip conducting polymer solid electrolyte Ta capacitor that a kind of rated insulation voltage can reach 50v, the structure of this capacitor as shown in Figure 2, specifically comprises:
Capacitor tantalum core matrix 3 is set in molded plastic shell 1, the zinc-plated negative pole of brass base 2 and the zinc-plated positive pole 8 of brass base, each several part is by epoxy encapsulation, capacitor tantalum core matrix 3 inside is the tantalum core as anode, anode surface is negative electrode, the dielectric layer that thickness is not less than 3500 nanometers is provided with between anode and negative electrode, tantalum wire lead-out wire 6 is provided with in anode, cathode surface is coated with graphite linings 32 successively and silver slurry layer goes out layer 33 as negative electrode silver, negative electrode and the zinc-plated negative pole of brass base 2 of capacitor tantalum core matrix 3 use bonding formation of silver paste 4 to be electrically connected, tantalum wire lead-out wire 6 in capacitor tantalum core matrix 3 is welded on the zinc-plated positive pole 8 of brass base and forms electrical connection, wherein, the chip tantalum powder that the anode of described tantalum particle capacitor matrix is take specific volume as 10000UuF.v/g, puncture voltage reaches more than 250V is raw material, the tantalum core briquet suppressed by the pressed density of 7.0 grams/CC, negative electrode is poly-3, the 4 ethene dioxythiophene particle deposition layer 31 of nanometer, can draw the packing ring 5 that layer contact position has arranged insulating effect at tantalum wire lead-out wire 6 and negative electrode and negative electrode.
As the nanometer poly-3 of negative electrode, 4 ethene dioxythiophene particle deposition layer are: to be 20 ~ 50 nanometer solid contents by particle diameter be 0.8% ~ 3.0% nanoscale poly-3,4 ethene dioxythiophene particle solution penetrate in the described anode interior space and dielectric layer generating dielectric layer, the operation of drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, repeat poly-3, the 4 ethene dioxythiophene particle deposition layer of nanometer formed for 16 ~ 26 times.The nanometer poly-3 of negative electrode; 4 ethene dioxythiophene particle deposition layer can be two-layer; internal layer is poly-3 of 20 ~ 30nm with particle diameter; the capacity that 4 ethene dioxythiophene particle solution are coated to formation draws layer; skin is poly-3 of 30 ~ 50nm with particle diameter; the thickness increase layer that 4 ethene dioxythiophenes are coating, the negative electrode of this structure can be protected anodic wick and reduce condensance.Outside the molded plastic shell 1 of capacitor, positive pole place can arrange the polarity bar 9 of mark positive pole.
The manufacture method of above-mentioned solid sheet type tantalum electrolyte capacitor can be shown in Figure 3 flow chart, can prepare the highest withstand voltage high pressure solid organic polymer sheet type tantalum electrolyte capacitor reaching 50V by the method, example specifications is 50V15uF, and concrete steps are as follows:
(1) specific volume is used to be 10000UuF.v/g, the chip tantalum powder that puncture voltage reaches more than 250V is raw material, the anode briquet with tantalum wire lead-out wire is pressed into according to the pressed density of 7.0 grams/CC, the compressing of anode briquet is carried out according to being of a size of 5.0 × 3.30 × 3.30mm (corresponding capacitance shell model is E shell), by the temperature of compressing anode briquet at 1600 DEG C, vacuum degree carries out high-temperature vacuum sintering under reaching the condition of 5 × 0.0004Pa, and use passivation technology passivation when coming out of the stove after sintering, time-division of coming out of the stove reduces vacuum degree four times gradually, each guarantee vacuum degree reduces amplitude and is not more than 0.25Ma, ensure that tantalum briquet can not excessively oxygenation through transpassivation, thus ensure that the folding silk number of times of tantalum wire on the rear briquet of sintering is not less than 4 times.To ensure that (the folding silk of tantalum wire shows that degree of oxidation is low often in acceptable degree in the oxidation of tantalum block and tantalum wire, the folding silk number of times of tantalum wire shows that degree of oxidation is high less, and the high leakage current of product that can directly cause of degree of oxidation cannot be reduced to the grade of 50V product needed);
(2) the anode briquet by above-mentioned sintering and after Passivation Treatment is welded on stainless steel strip according to certain required precision, putting it into and temperature is housed is 80 degree, resistivity is at 800 ~ 850 ohm. centimetre phosphoric acid ethylene glycol electrolyte (phosphoric acid concentration in electrolyte is 0.2% by volume, glycol concentration is 50% by volume) formation groove in, use the DC power supply that voltage can raise automatically, according to coating-forming voltage 235V (being generally the voltage of the withstand voltage more than 4 times that manufactures a product as coating-forming voltage), and press the current density of 40 milliamperes/gram, the electrochemistry of carrying out the dielectric layer of anode briquet is formed, the thickness of the dielectric layer of generation is made to reach more than 3760 nanometers, this thickness of dielectric layers can reach the designing requirement of 50V rated voltage, dielectric layer forms rear fuse capacity and reaches 15uF,
(3) macromolecule negative electrode manufactures: use repeatedly infusion process by nanoscale poly-3, 4 ethene dioxythiophene particle solution infiltrations are at described briquet internal voids and form high polymer layer at briquet surface deposition and comprise as negative electrode: use repeatedly infusion process particle diameter to be 20 ~ 50 nanometer solid contents be 0.8% ~ 3.0% nanoscale poly-3, 4 ethene dioxythiophene particle solution penetrate into and generate in the described briquet internal voids of dielectric layer, drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, make poly-3 after oven dry, as negative electrode on 4 ethene dioxythiophene particle depositions to the dielectric layer formed.Handled process need 16 ~ 26 times, can make the thickness of polymer cathode layer reach the thickness of regulation like this;
(4) when the thickness of polymer cathode layer reaches the thickness of regulation, on the cathode surface of product, coated graphite layer and silver slurry layer are as the excessive layer of negative electrode;
(5) the product of coated silver slurry layer from after stainless steel strip cuts down, the macromolecule elargol of conduction is used to be bonded on metal framework, using formation electrical connection welded together for the positive pole on the tantalum wire lead-out wire and capacitance shell framework of anode lead wire;
(6) use fire-retardant epoxy resin at 160 DEG C, in the mould of precision, become overall dimension to be 7.3 × 4.30 × 4.10mm (tolerance is ± 0.3mm) product plastic packaging by transfer moulding press, namely obtain the withstand voltage solid sheet type tantalum electrolyte capacitor product reaching 50V.
On obtained tantalum electrolytic capacitor product, following operation can also be carried out successively:
(1) use laser printing specification and positive pole mark;
(2) excise anode side, product is applied to aging 2 ~ 40 hours of rated voltage in the baking oven of 85 ~ 125 degree;
(3) specify to carry out test automatically to the product after aging according to standard and waste product removing simultaneously;
(4) the shaping and braid of lead-in wire that standard specifies is carried out to the both positive and negative polarity of product.
In actual production, after finishing above-mentioned process, the product be up to the standards can be dropped into actual use.
Embodiment two
The present embodiment provides a kind of high voltage chip conducting polymer solid electrolyte Ta capacitor, it is the chip conducting polymer solid electrolyte Ta capacitor that a kind of rated insulation voltage can reach 63v, example specifications is 63V4.7uF, the structure of this capacitor as shown in Figure 2, can see the explanation of embodiment a pair capacitor arrangement, difference is, the thickness as the dielectric layer on anode briquet is 4400 nanometers, no longer repeat at this, the step of its manufacture method is as follows:
(1) specific volume is used to be 8000UuF.v/g, the electronics bombardment tantalum powder that puncture voltage reaches more than 300V is raw material, the anode briquet with tantalum wire lead-out wire is pressed into according to the pressed density of 7.5 grams/CC, the compressing of anode briquet is carried out according to being of a size of 5.0 × 3.50 × 1.70mm (corresponding capacitance shell model is D shell), by the temperature of compressing anode briquet at 1700 DEG C, vacuum degree carries out high-temperature vacuum sintering under reaching the condition of 5 × 0.0004Pa, and use passivation technology passivation when coming out of the stove after sintering, after ensureing sintering, on briquet, the folding silk number of times of tantalum wire is not less than 4 times, in acceptable degree, (the folding silk of tantalum wire shows that degree of oxidation is low often in the oxidation of guarantee tantalum block and tantalum wire, the folding silk number of times of tantalum wire shows that degree of oxidation is high less, the high leakage current of product that can directly cause of degree of oxidation cannot be reduced to the grade of 63V product needed),
(2) the tantalum block after sintering is spoted weld on steel bar, putting it into and temperature is housed is 80 degree, resistivity is at 800 ~ 850 ohm. centimetre phosphoric acid ethylene glycol electrolyte (phosphoric acid concentration in electrolyte is 0.2% by volume, glycol concentration is 50% by volume) formation groove in, according to coating-forming voltage 275V (being generally the voltage of the withstand voltage more than 4 times that manufactures a product as coating-forming voltage), and press the current density of 40 milliamperes/gram, the electrochemistry of carrying out the dielectric layer of anode briquet is formed, the thickness of the dielectric layer of generation is made to reach more than 4400 nanometers, this thickness of dielectric layers can reach the designing requirement of 63V rated voltage, capacity reaches 4.7uF,
(3) use repeatedly infusion process particle diameter to be 20 ~ 50 nanometer solid contents be 0.8% ~ 3.0% nanoscale poly-3,4 ethene dioxythiophene particle solution penetrate into and generate in the described briquet internal voids of dielectric layer, drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, make poly-3 after oven dry, as negative electrode on 4 ethene dioxythiophene particle depositions to the described dielectric layer formed, handled process need repeats 16 ~ 26 times, reaches the object of drawing internal capacity and forming certain outer layer thickness; On cathode surface, coated graphite layer and silver slurry layer are as the excessive layer of negative electrode; After be assembled on metal framework, in the mould of precision, become overall dimension to be 7.3 × 4.30 × 2.80mm (tolerance for ± 0.3mm) product plastic packaging, namely obtain the withstand voltage solid sheet type tantalum electrolyte capacitor product reaching 63V.
Follow-up through printing, cut muscle trimming, aging, test, go between the operation such as shaping, the product that can be up to the standards drops into actual use.
Above two embodiments meet following test stone and test requirements document, can be used for the military circuit of high reliability.
In the utility model embodiment, when preparation rated voltage is the organic polymer sheet type tantalum electrolyte capacitor of 50V and 63V, use specific volume is 6000 ~ 10000uF.v/g, the chip tantalum powder that puncture voltage reaches 250V (rated voltage 50V capacitor) or 300V (rated voltage 63V capacitor) is raw material, the size of allowing according to standard shell capacitance shell under the pressed density of 6.0 ~ 8.0 grams/CC carries out anode compact formation, then to briquet 1600 ~ 1800 DEG C of temperature, vacuum degree carries out high-temperature vacuum sintering under reaching 5 × 0.0004Pa condition, and adopt passivation technology when coming out of the stove, ensure that anode briquet is not subject to over oxidation when coming out of the stove, when dielectric layer is formed, use concentration be by volume 20 ~ 50% the phosphoric acid ethylene glycol electrolyte that formed of ethylene glycol and the concentration by volume phosphoric acid that is 0.2 ~ 0.5%, and ensure that the outer layer thickness of the dielectric layer formed is not less than the dielectric layer of 3000 nanometers (rated voltage 50V capacitor) or 3500 nanometers (rated voltage 63V capacitor), when macromolecule negative electrode manufactures, use repeatedly infusion process particle diameter to be 20 to 50 nanometer solid contents be 0.8% ~ 3.0% poly-3,4 ethene dioxythiophene particle solution penetrate into and generate in the described briquet internal voids of dielectric layer, drying and processing is carried out under temperature is 120 ~ 150 DEG C of conditions, make poly-3 after oven dry, as negative electrode on 4 ethene dioxythiophene particle depositions to the described dielectric layer formed, handled process need repeats 16 ~ 26 times.Based on the difference of above-mentioned these and traditional mesolow organic polymer sheet type tantalum electrolyte capacitor production technology, especially specific volume is used to be 6000 ~ 10000UuF.v/g, the electronics bombardment powder that puncture voltage is higher or chip tantalum powder are raw material, and in phosphoric acid ethylene glycol electrolyte, use the direct voltage of 4 × 50V or 4 × more than 63V as coating-forming voltage, the dielectric layer that thickness is not less than 3000 nanometers (rated voltage 50V capacitor) or 3500 nanometers (rated voltage 63V capacitor) is formed on briquet surface, use repeatedly the better nanoscale of immersion stability poly-3 on this basis, after the method formation negative electrode of 4 ethene dioxythiophene particle solution, can make that last obtained electric capacity is withstand voltage reaches 50V and 63V, fill up the blank of high withstand voltage organic polymer tantalum capacitance series, widen the range of application of solid organic polymer sheet type tantalum electrolyte capacitor greatly, can meet and be applied in multiple circuit, meet the requirement of circuit reliability.
The above; be only the utility model preferably embodiment; but protection range of the present utility model is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the utility model discloses; the change that can expect easily or replacement, all should be encompassed within protection range of the present utility model.Therefore, protection range of the present utility model should be as the criterion with the protection range of claims.
Claims (2)
1. a high voltage chip conducting polymer solid electrolyte Ta capacitor, is characterized in that, this capacitor comprises:
Molded plastic shell, has tantalum particle capacitor matrix, the zinc-plated negative pole of brass base and the zinc-plated positive pole of brass base through epoxy encapsulation in it; Described tantalum particle capacitor matrix is inner as anode, the outside of described anode is provided with the dielectric layer that thickness is not less than 3000 nanometers or 3500 nanometers, the outside of described dielectric layer is provided with the nanometer poly-3 as negative electrode, 4 ethene dioxythiophene particle deposition layer, graphite linings is coated with successively and silver slurry layer goes out layer as negative electrode silver outside negative electrode, tantalum wire lead-out wire is provided with in described anode, described tantalum wire lead-out wire welds to be formed with the zinc-plated positive pole of described brass base and is electrically connected, and the negative electrode of described tantalum particle capacitor matrix is connected with the zinc-plated negative electricity of described brass base.
2. high voltage chip conducting polymer solid electrolyte Ta capacitor according to claim 1, it is characterized in that, the described nanometer as negative electrode poly-3,4 ethene dioxythiophene particle deposition layer are inside and outside two-layer, internal layer is poly-3 of 20 ~ 30nm with particle diameter, the capacity that 4 ethene dioxythiophene particle solution are coated to formation draws layer, and skin increases layer with the thickness that poly-3,4 ethene dioxythiophenes that particle diameter is 30 ~ 50nm are coated to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520417645.5U CN205050704U (en) | 2015-06-16 | 2015-06-16 | High voltage piece formula conductive polymer tantalum electrolytic capacitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520417645.5U CN205050704U (en) | 2015-06-16 | 2015-06-16 | High voltage piece formula conductive polymer tantalum electrolytic capacitor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205050704U true CN205050704U (en) | 2016-02-24 |
Family
ID=55344255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520417645.5U Active CN205050704U (en) | 2015-06-16 | 2015-06-16 | High voltage piece formula conductive polymer tantalum electrolytic capacitor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205050704U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105792420A (en) * | 2016-03-31 | 2016-07-20 | 中山市中广科研技术服务有限公司 | LED driving device with stable performance |
| CN108054010A (en) * | 2017-12-15 | 2018-05-18 | 株洲中电电容器有限公司 | A kind of hermetically sealed Metal Packaging high molecular polymer tantalum capacitor of axial direction |
| CN110706927A (en) * | 2019-08-20 | 2020-01-17 | 深圳云容新能源有限公司 | High-reliability solid-state aluminum electrolytic capacitor and preparation method thereof |
-
2015
- 2015-06-16 CN CN201520417645.5U patent/CN205050704U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105792420A (en) * | 2016-03-31 | 2016-07-20 | 中山市中广科研技术服务有限公司 | LED driving device with stable performance |
| CN108054010A (en) * | 2017-12-15 | 2018-05-18 | 株洲中电电容器有限公司 | A kind of hermetically sealed Metal Packaging high molecular polymer tantalum capacitor of axial direction |
| CN110706927A (en) * | 2019-08-20 | 2020-01-17 | 深圳云容新能源有限公司 | High-reliability solid-state aluminum electrolytic capacitor and preparation method thereof |
| CN110706927B (en) * | 2019-08-20 | 2022-04-01 | 深圳云容新能源有限公司 | High-reliability solid-state aluminum electrolytic capacitor and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104916443B (en) | High voltage chip conducting polymer solid electrolyte Ta capacitor and its manufacture method | |
| CN101404213B (en) | Solid sheet type tantalum electrolyte capacitor and its manufacturing method | |
| TW201117244A (en) | Solid electrolytic capacitor and method of manufacturing thereof | |
| TW201023220A (en) | Method of manufacturing solid electrolytic capacitor | |
| CN101983409A (en) | Capacitor with sacrificial lead wire configuration and improved manufacturing method thereof | |
| CN205050704U (en) | High voltage piece formula conductive polymer tantalum electrolytic capacitor | |
| CN203456311U (en) | Stack type solid electrolytic capacitor packaging structure | |
| CN103426643A (en) | Stack type solid electrolytic capacitor packaging structure with multiple negative electrode lead-out pins and manufacturing method thereof | |
| CN102800480A (en) | Preparation method for cathode of Nb capacitor | |
| CN101404214A (en) | Polymer solid sheet type tantalum electrolyte capacitor and its manufacturing method | |
| CN106971851B (en) | A method of preparing the chip-type laminated solid aluminum electrolytic capacitor of polymer | |
| CN103632847B (en) | A kind of axially mold pressing tantalum capacitor and manufacture method thereof | |
| CN203456293U (en) | Single-surface aluminum-and-zinc metalized film with single reserved edge | |
| CN107039185B (en) | A kind of preparation method of the chip-type laminated solid aluminum electrolytic capacitor of polymer | |
| CN207602404U (en) | Stacked capacitor | |
| CN203826222U (en) | Sheet type ultra-small high voltage heavy current capacitor | |
| CN102074383B (en) | Stack solid electrolytic capacitor with multi-end pins | |
| CN105788865A (en) | Production technology of patch-type aluminum electrolytic capacitor | |
| CN204189622U (en) | A kind of trapezoidal evaporated metallized polypropylene film capacitor | |
| CN106783177A (en) | A kind of method for preparing the chip-type laminated solid aluminum electrolytic capacitor of thin polymeric | |
| CN206059180U (en) | A kind of double tantalum core solid electrolyte Ta capacitors of high-voltage large-capacity | |
| CN201725692U (en) | Complex electrolytic capacitor capable of resisting high-frequency ripple current | |
| CN101916672B (en) | Solid tantalum electrolytic capacitor and preparation method thereof | |
| CN206595158U (en) | Low impedance at high frequency electrochemical capacitor | |
| CN216528462U (en) | Solid electrolytic capacitor with groove on surface of anode |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |