CN204778810U - Methanol -water reformation hydrogen manufacturing machine - Google Patents
Methanol -water reformation hydrogen manufacturing machine Download PDFInfo
- Publication number
- CN204778810U CN204778810U CN201520449838.9U CN201520449838U CN204778810U CN 204778810 U CN204778810 U CN 204778810U CN 201520449838 U CN201520449838 U CN 201520449838U CN 204778810 U CN204778810 U CN 204778810U
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- reformer
- water
- methanol
- reformer chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
The utility model discloses a methanol -water reformation hydrogen manufacturing machine, including methanol -water reservoir, delivery pump, heat exchanger and reformer, wherein: the reformer is equipped with reformation room, electromagnetic heater and hydrogen purification device, electromagnetic heater includes that solenoid and metal receive the magnet, can produce the high frequency magnetic field after the solenoid circular telegram, makes the metal receive the magnet to receive the magnetic field response and generate heat, provides heat energy for the reformation room, the reformation room is used for methyl alcohol and water emergence reformation hydrogen generation, makes the high temperature mist of giving first place to with carbon dioxide and hydrogen, the temperature of following the high temperature mist of reformation room output is held from the product gas of hydrogen purification device and is obtained hydrogen through hydrogen purification device after -separating. The utility model discloses long service life, maintenance volume is little, the thermo -lag is less, control is accurate, and the reformer toggle speed is fast, the thermal efficiency is high, the heating evenly.
Description
Technical field
The utility model relates to hydrogen Preparation equipment technical field, particularly a kind of methanol-water reformation hydrogen production machine.
Background technology
Hydrogen is one of the optimal energy of a kind of 21 century, and when the coal of identical weight of burning, gasoline and hydrogen, the energy that hydrogen produces is maximum, and the product of its burning is water, does not have lime-ash and waste gas, does not pollute the environment; And the mainly CO that coal and oil combustion generate
2and SO
2, Greenhouse effect and acid rain can be produced respectively.Coal and reserves are limited, and hydrogen is mainly stored in water, and after burning, unique product is also water, can produce hydrogen continuously, be finished never.The distribution of hydrogen is very extensive, and water is exactly large " warehouse " of hydrogen, wherein contains the hydrogen of 11%.There is the hydrogen of 1.5% earth Rio; All contain hydrogen in oil, coal, Sweet natural gas, animal and plant body etc.The main body of hydrogen exists with the form of compound water, and earth surface about 70% is covered for water, and very greatly, therefore can say, hydrogen is the energy of " inexhaustible, nexhaustible " to moisture storage capacity.If can by suitable method from preparing hydrogen, so hydrogen also will be the energy that a kind of price is quite cheap.
At present, the annual production of hydrogen is about 3,600 ten thousand tons in the world, and hydrogen production process mainly contains two kinds: one, most hydrogen produce from oil, coal and Sweet natural gas, and this method needs to consume mineral fuel natively very in short supply; Two, about have the hydrogen of 4% to be produce by the method for brine electrolysis, it is large that this method consumes electric energy, do not calculate very much.Along with the progress of technology, adopt the technology of first alcohol and water reformation hydrogen production to be gradually developed, it can reduce the energy consumption in Chemical Manufacture and reduce costs, and is expected to alternative electric energy and consumes king-sized electrolysis hydrogen producing process.Advanced methanol steam reforming technology is utilized to produce H
2with CO
2mixed gas, then through palladium membrane separation apparatus be separated, H can be obtained respectively
2and CO
2.
With reference to Chinese invention application 201310340475.0(applicant: Shanghai Hejide Dynamic Hydrogen Machine Co., Ltd.), which disclose a kind of Methanol water hydrogen production system, the reformer chamber of methyl alcohol and steam reformer, at 350-409 DEG C of temperature 1-5MPa pressure condition under pass through catalyzer, under the effect of catalyzer, the transformationreation of methanol decomposition reaction and carbon monoxide occurs, generates hydrogen and carbonic acid gas, this is the gas solid catalytic reaction system of component more than, many reactions.Reactional equation is as follows: (1) CH
3oH → CO+2H
2; (2) H
2o+CO → CO
2+ H
2; (3) CH
3oH+H
2o → CO
2+ 3H
2, the H that reforming reaction generates
2and CO
2, then the palladium membrane separation apparatus through separate chamber is by H
2and CO
2be separated, obtain high-purity hydrogen.In reformer, be also provided with vaporizer and combustion chamber, vaporizer is gasificated into steam before being used for that methyl alcohol and water are entered reformer, and combustion chamber is used for passing through H
2combustion heat release, for reformer chamber provides the reforming reaction temperature of 350-409 DEG C, and provides heat for vaporizer.
But, also there is following disappearance in above-mentioned Methanol water hydrogen production system: one, needs to arrange combustion chamber due to reformer, therefore, reformer also needs to arrange the air inlet fan for oxygen in fan-in air and air intake passage, and for discharging the smokestack of the rear waste gas produced of burning, high-temp waste gas is discharged from smokestack, not only wastes heat energy, and easily affects hydrogen generating system each several part equipment operation; Two, in combustion chamber, combustion of hydrogen temperature often soars to more than 1000 DEG C in the short period of time, easily burns out reformer, and, the mode of combustion of hydrogen heat release is difficult to control, the temperature stability difference (temperature of combustion chamber requires between 405-570 DEG C usually) of combustion chamber; Three, reformer arranges the parts such as the chamber such as vaporizer, combustion chamber, air inlet fan, air intake passage and smokestack, increases structural complexity and the maintenance difficulty of reformer.
In view of this, on November 7th, 2014, the applicant (Guangdong He Ji get Energy Science Co., Ltd) has applied for that a key name is called a kind of methanol-water hydrogen making machine and hydrogen production process thereof, application number is 201410622141.7 patents of invention, the reformer of this patent of invention is provided with reformer chamber and electric heater, electric heater provides heat energy for reformer chamber, reformer chamber is provided with catalyzer, first alcohol and water reacts at the reformation hydrogen production of reformer chamber generation first alcohol and water, obtains the high-temperature gas mixture body based on carbonic acid gas and hydrogen; Particularly, this electric heater comprises resistance heater and metal founding heat conductor.Reformer due to this hydrogen making machine is provided with the electric heater into reformer chamber heating, therefore reformer is without the need to arranging combustion chamber, air inlet fan, air intake passage and smokestack, be a reformer closed on the whole, high-temp waste gas can not be discharged, avoid thermal waste, avoid because high-temp waste gas affects hydrogen generating system each several part equipment operation, avoid because of the destruction problem of burning to reformer, and reducing structural complexity and the maintenance difficulty of reformer, the Heating temperature of electric heater is also easier to control.
But, the electric heater that this methanol-water hydrogen making machine adopts is resistance heater and metal founding heat conductor, also there is following defect: one, work-ing life is short, maintenance capacity is large, electric heater is owing to adopting resistance heater heating, the heat conduction of metal founding heat conductor, when temperature reaches between 405-570 DEG C, the easy Yin Gaowen of resistance wire and aging and blow, the life-span of conventional resistance heater, thus maintenance load was relatively large on average less than half a year; Two, adopt the mode of resistance heater heating, the heat conduction of metal founding heat conductor, its thermal hysteresis is comparatively large, and control device not easily accurately controls reformer chamber temperature; Three, adopt the mode of resistance heater heating, the heat conduction of metal founding heat conductor, reformer toggle speed is slow, and start time is usually more than 3 minutes; Four, the thermo-efficiency of resistance heater self-heating is low, usually can only utilize 50% of electric energy, and heats uneven.
Utility model content
The technical problems to be solved in the utility model is for above-mentioned deficiency of the prior art, a kind of methanol-water reformation hydrogen production machine is provided, the reformer of this hydrogen making machine not only without the need to arranging combustion chamber, air inlet fan, air intake passage and smokestack, structure are comparatively simple, and long service life, a little repair, thermal hysteresis is less, control is accurate, reformer toggle speed is fast, and thermo-efficiency is high, homogeneous heating.
For solving the problems of the technologies described above, the technical solution of the utility model is: a kind of methanol-water reformation hydrogen production machine, comprises methanol-water storage vessel, transferpump, interchanger and reformer, wherein:
Methanol-water storage vessel, stores liquid first alcohol and water in it;
Transferpump, for being delivered to the reformer chamber of reformer by the first alcohol and water in methanol-water storage vessel;
Interchanger, is installed on the transport pipe between transferpump and reformer, and the first alcohol and water of low temperature is in interchanger, and the high-temperature hydrogen exported with reformer carries out heat exchange, and methyl alcohol and water temp raise, and hydrogen temperature reduces;
Reformer, is provided with reformer chamber, electromagnetic heater and hydrogen purification apparatus, and described electromagnetic heater comprises solenoid and metal is subject to magnet, can produce high frequency magnetic field, metal is generated heat by magnet is subject to magnetic field induction, for reformer chamber provides heat energy after solenoid energising; Described reformer chamber is provided with catalyzer, and first alcohol and water reacts at the reformation hydrogen production of reformer chamber generation first alcohol and water, obtains the high-temperature gas mixture body based on carbonic acid gas and hydrogen; Described reformer chamber is connected by connecting pipeline with hydrogen purification apparatus, and all or part of of connecting pipeline is arranged at reformer chamber, and the high temperature by reformer chamber continues the high-temperature gas mixture body that heating exports from reformer chamber; Described connecting pipeline, as the buffering between reformer chamber and hydrogen purification apparatus, makes the temperature of the high-temperature gas mixture body exported from reformer chamber identical with the temperature of hydrogen purification apparatus or close; Obtain hydrogen from the aerogenesis end of hydrogen purification apparatus, this hydrogen exports after interchanger.
As to further elaboration of the present utility model:
Described methanol-water reformation hydrogen production machine also comprises gas diverter, fuel cell and alternating current-direct current power conversion device, and described gas diverter is for shunting the hydrogen exported from interchanger, and after gas diverter shunting, hydrogen partial enters fuel cell; The oxygen generation electrochemical reaction that described fuel cell is used in hydrogen and air produces electric energy; Produce electric energy through alternating current-direct current power conversion device conversion after, for the electromagnetic heater of described transferpump and reformer is powered.Further, described alternating current-direct current power conversion device flows to the electricity of electromagnetic heater is the high-frequency high-voltage of 20-40KHZ.Described methanol-water reformation hydrogen production machine is also provided with hydrogen storage bottle, and this hydrogen storage bottle in reformer start-up course, can be fuel cell inputting hydrogen, make operation of fuel cells, produces electric energy, for the electromagnetic heater of transferpump and reformer is powered.
Described reformer comprises insulation shell, reformer chamber and hydrogen purification apparatus from outside to inside successively, and the solenoid of described electromagnetic heater is arranged between insulation shell and reformer chamber, and described metal is arranged at reformer chamber by magnet.Further, described metal is provided with single or multiple lift by magnet, and metal is tubular structure or reticulated structure by magnet.The outside of described reformer chamber and inner side are also provided with vaporization coil pipe, and first alcohol and water first passed through vaporization coil pipe before entering reformer chamber, so that methyl alcohol and water vapor.
Described hydrogen purification apparatus is the membrane separation unit at porous ceramic surface Vacuum Deposition palladium-silver alloy, and coatings is palladium-silver alloy, and the mass percent palladium of palladium-silver alloy accounts for 75%-78%, and silver accounts for 22%-25%.
The beneficial effects of the utility model are: one, due to reformer of the present utility model be provided with into reformer chamber heating electromagnetic heater, therefore reformer is without the need to arranging combustion chamber, air inlet fan, air intake passage and smokestack, be a reformer closed on the whole, high-temp waste gas can not be discharged, avoid thermal waste, avoid because high-temp waste gas affects hydrogen generating system each several part equipment operation, avoid because of the destruction problem of burning to reformer; Two, the utility model adopts electromagnetic heater to reformer chamber, and because solenoid itself can not produce heat substantially, thus the life-span is long, and without the need to maintenance, without safeguarding replacement cost, work-ing life, the later stage was substantially without maintenance cost up to more than 10 years; Three, can produce high frequency magnetic field after solenoid energising, metal is generated heat rapidly by magnet is subject to magnetic field induction, and for reformer chamber provides heat energy, the thermal hysteresis of this type of heating is less, and control device is easy to precisely control reformer temperature; The mode four, adopting metal to generate heat rapidly by magnetic field induction by magnet, reformer toggle speed is very quick, and efficiency is very high, the experiment proved that, can be reduced to 10 seconds the start time of reformer; Five, the thermo-efficiency of electromagnetic heater is very high, can utilize more than 95% of electric energy, and homogeneous heating.In addition, in the further technical scheme of the utility model, the electric energy of electromagnetic heater and transferpump is provided by fuel cell, and the hydrogen required for fuel cell comes from the obtained hydrogen of the utility model, therefore, the utility model, without the need to external civil power, can realize the work of electromagnetic heater and transferpump, thus make the utility model adaptability extremely strong, be not subject to the restriction of regional condition and civil power.
Accompanying drawing explanation
Fig. 1 is one-piece construction skeleton diagram of the present utility model.
Fig. 2 is reformer of the present utility model and interchanger external structure schematic diagram.
Fig. 3 is the cross-sectional TV structure schematic diagram of reformer of the utility model one preferred embodiment.
Fig. 4 is a kind of preferred structure schematic diagram that metal is subject to magnet.
Fig. 5 is the another kind of preferred structure schematic diagram that metal is subject to magnet.
In figure: 1. methanol-water storage vessel; 2. transferpump; 3. interchanger; 4. reformer; 41. reformer chamber; 42. electromagnetic heaters; 43. hydrogen purification apparatus; 44. insulation shells; 45. vaporization coil pipes; 5. gas diverter; 6. fuel cell; 7. alternating current-direct current power conversion device; 8. hydrogen storage bottle.
Embodiment
Below in conjunction with accompanying drawing, structural principle of the present utility model and principle of work are described in further detail.
As shown in Figure 1, a kind of methanol-water reformation hydrogen production machine, comprises methanol-water storage vessel 1, transferpump 2, interchanger 3 and reformer 4, wherein:
Methanol-water storage vessel 1, stores liquid first alcohol and water in it;
Transferpump 2, for being delivered to the reformer chamber 41 of reformer 4 by the first alcohol and water in methanol-water storage vessel 1;
Interchanger 3, is installed on the transport pipe between transferpump 2 and reformer 4, and the first alcohol and water of low temperature is in interchanger 3, and the high-temperature hydrogen exported with reformer 4 carries out heat exchange, and methyl alcohol and water temp raise, and hydrogen temperature reduces;
Reformer 4, be provided with reformer chamber 41, electromagnetic heater 42 and hydrogen purification apparatus 43, described electromagnetic heater 42 comprises solenoid and metal is subject to magnet, high frequency magnetic field can be produced after solenoid energising, metal is generated heat by magnet is subject to magnetic field induction, for reformer chamber 41 provides the heat energy of 350-570 DEG C of temperature, be preferably 350-409 DEG C; Catalyzer is provided with in described reformer chamber 41, methyl alcohol and water vapor are in reformer chamber 41, catalyzer is passed through under the pressure condition of 1-5MPa, under the effect of catalyzer, there is the transformationreation of methanol decomposition reaction and carbon monoxide, generate hydrogen and carbonic acid gas, this is the gas solid catalytic reaction system of component more than, many reactions, and reactional equation is: (1) CH
3oH → CO+2H
2, (2) H
2o+CO → CO
2+ H
2, (3) CH
3oH+H
2o → CO
2+ 3H
2, obtain the high-temperature gas mixture body based on carbonic acid gas and hydrogen; Described reformer chamber 41 is connected by connecting pipeline with hydrogen purification apparatus 43, and all or part of of connecting pipeline is arranged in reformer chamber 41, continues the high-temperature gas mixture body of heating from reformer chamber 41 output by the high temperature in reformer chamber 41; Connecting pipeline, as the buffering between reformer chamber 41 and hydrogen purification apparatus 43, makes the temperature of the high-temperature gas mixture body exported from reformer chamber 41 identical with the temperature of hydrogen purification apparatus 43 or close; Obtain hydrogen from the aerogenesis end of hydrogen purification apparatus 43, this hydrogen exports after interchanger 3, and carbon dioxide then can be discharged from reformer, or collects.
As shown in Figure 1, described methanol-water reformation hydrogen production machine also comprises gas diverter 5, fuel cell 6 and alternating current-direct current power conversion device 7, described gas diverter 5 is for shunting the hydrogen exported from interchanger 3, after gas diverter 5 is shunted, hydrogen partial enters fuel cell 6, certainly, the hydrogen partial entering fuel cell 6 only accounts for the sub-fraction (hydrogen of such as 20%) of the hydrogen that reformer exports, and most of hydrogen then collects or exports to other hydrogen and uses equipment (hydrogen of such as 80%); Described fuel cell 6 produces electric energy for the oxygen generation electrochemical reaction in hydrogen and air, the anode at fuel cell: 2H
2→ 4H
++ 4e
-, H
2split into two protons and two electronics, proton is through proton exchange membrane (PEM), and electronics, by positive plate, by external loading, and enters cathode bipolar plate, the negative electrode at fuel cell: O
2+ 4e
-+ 4H
+→ 2H
2o, proton, electronics and O
2recombine is to form H
2o; Produce electric energy through alternating current-direct current power conversion device 7 change after, for the electromagnetic heater 42 of described transferpump 2 and reformer 4 is powered.Further, described alternating current-direct current power conversion device 7 flows to the electricity of electromagnetic heater 42 is the high-frequency high-voltage of 20-40KHZ.Described methanol-water reformation hydrogen production machine is also provided with hydrogen storage bottle 8, and this hydrogen storage bottle 8 in reformer 4 start-up course, can be fuel cell 6 inputting hydrogen, fuel cell 6 is worked, and produces electric energy, for the electromagnetic heater 42 of transferpump 2 and reformer 4 is powered.
As shown in Figures 2 and 3, described reformer 4 comprises insulation shell 44, reformer chamber 41 and hydrogen purification apparatus 43 from outside to inside successively, the solenoid 421 of described electromagnetic heater 42 is arranged between insulation shell 44 and reformer chamber 41, described metal is arranged in reformer chamber 41 by magnet 422, and this metal can be that irony or stainless steel are subject to magnet by magnet.Further, described metal is provided with single or multiple lift by magnet 422, and metal is tubular structure (with reference to Fig. 4) or reticulated structure (with reference to Fig. 5) by magnet 422.The outside of described reformer chamber 41 and inner side are also provided with vaporization coil pipe 45, and first alcohol and water first passed through vaporization coil pipe 45 before entering reformer chamber 41, so that methyl alcohol and water vapor.
Described hydrogen purification apparatus 43 is the membrane separation unit at porous ceramic surface Vacuum Deposition palladium-silver alloy, and coatings is palladium-silver alloy, and the mass percent palladium of palladium-silver alloy accounts for 75%-78%, and silver accounts for 22%-25%; The difference of the inside and outside pressure of membrane separation unit is more than or equal to 1.1MPa.The manufacturing process of membrane separation unit can refer to the patent of invention 201210563913.5 that the applicant Shanghai Hejide Dynamic Hydrogen Machine Co., Ltd. applied on December 21st, 2012, membrane separation apparatus of methanol-water hydrogen producer and preparation method thereof.The utility model respectively organizes the mode that methanol-water reformation hydrogen production power generation module group adopts reformer reformation hydrogen production at the temperature of 300-570 DEG C and under catalyst action, its hydrogen manufacturing speed and efficiency high, methanol-water feedstock conversion efficiency and utilization ratio high, good stability; Because the temperature of hydrogen purification apparatus is identical with reformer chamber temperature or close, therefore, hydrogen purification efficiency can be significantly improved and reduce hydrogen purification difficulty, realizing fast film and be separated.
In technique scheme, the hydrogen production process of methanol-water reformation hydrogen production machine comprises the following steps:
A. control device controls the startup of methanol-water reformation hydrogen production machine, and the first alcohol and water in methanol-water storage vessel after interchanger, is delivered to the reformer chamber of reformer by transferpump, and in interchanger, methyl alcohol and water temp raise, and hydrogen temperature reduces;
B. control device controls the electromagnetic heater work of reformer, high frequency magnetic field is produced after the solenoid energising of electromagnetic heater, the metal of electromagnetic heater is generated heat by magnetic field induction by magnet, for reformer chamber provides 350-570 DEG C of temperature, in reformer chamber, under catalyst action, there is the reformation hydrogen production reaction of first alcohol and water, obtain the high-temperature gas mixture body based on carbonic acid gas and hydrogen in the first alcohol and water of vaporization;
C. the hydrogen purification apparatus that high-temperature gas mixture body enters reformer through connecting pipeline is separated, and obtains high-temperature hydrogen from the aerogenesis end of hydrogen purification apparatus, and this high-temperature hydrogen exports after interchanger cooling.
The hydrogen exported in described step C is after gas diverter, hydrogen partial enters fuel cell, in fuel cell, oxygen generation electrochemical reaction in hydrogen and air produces electric energy, the electric energy produced is after alternating current-direct current power conversion device, for powering for the electromagnetic heater of described transferpump and reformer, wherein, alternating current-direct current power conversion device flows to the electricity of electromagnetic heater is the high-frequency high-voltage of 20-40KHZ.
The above is only the utility model better embodiment, every above embodiment is done according to the technical solution of the utility model any trickle amendment, equivalent variations and modification, all belong in the scope of technical solutions of the utility model.
Claims (8)
1. a methanol-water reformation hydrogen production machine, is characterized in that: comprise methanol-water storage vessel, transferpump, interchanger and reformer, wherein:
Methanol-water storage vessel, stores liquid first alcohol and water in it;
Transferpump, for being delivered to the reformer chamber of reformer by the first alcohol and water in methanol-water storage vessel;
Interchanger, is installed on the transport pipe between transferpump and reformer, and the first alcohol and water of low temperature is in interchanger, and the high-temperature hydrogen exported with reformer carries out heat exchange, and methyl alcohol and water temp raise, and hydrogen temperature reduces;
Reformer, is provided with reformer chamber, electromagnetic heater and hydrogen purification apparatus, and described electromagnetic heater comprises solenoid and metal is subject to magnet, can produce high frequency magnetic field, metal is generated heat by magnet is subject to magnetic field induction, for reformer chamber provides heat energy after solenoid energising; Described reformer chamber is provided with catalyzer, and first alcohol and water reacts at the reformation hydrogen production of reformer chamber generation first alcohol and water, obtains the high-temperature gas mixture body based on carbonic acid gas and hydrogen; Described reformer chamber is connected by connecting pipeline with hydrogen purification apparatus, and all or part of of connecting pipeline is arranged at reformer chamber, and the high temperature by reformer chamber continues the high-temperature gas mixture body that heating exports from reformer chamber; Described connecting pipeline, as the buffering between reformer chamber and hydrogen purification apparatus, makes the temperature of the high-temperature gas mixture body exported from reformer chamber identical with the temperature of hydrogen purification apparatus or close; Obtain hydrogen from the aerogenesis end of hydrogen purification apparatus, this hydrogen exports after interchanger.
2. methanol-water reformation hydrogen production machine according to claim 1, it is characterized in that: described methanol-water reformation hydrogen production machine also comprises gas diverter, fuel cell and alternating current-direct current power conversion device, described gas diverter is for shunting the hydrogen exported from interchanger, after gas diverter shunting, hydrogen partial enters fuel cell; The oxygen generation electrochemical reaction that described fuel cell is used in hydrogen and air produces electric energy; Produce electric energy through alternating current-direct current power conversion device conversion after, for the electromagnetic heater of described transferpump and reformer is powered.
3. methanol-water reformation hydrogen production machine according to claim 2, is characterized in that: the electricity that described alternating current-direct current power conversion device flows to electromagnetic heater is the high-frequency high-voltage of 20-40KHZ.
4. methanol-water reformation hydrogen production machine according to claim 1, it is characterized in that: described methanol-water reformation hydrogen production machine is also provided with hydrogen storage bottle, this hydrogen storage bottle can in reformer start-up course, for fuel cell inputting hydrogen, make operation of fuel cells, produce electric energy, for the electromagnetic heater of transferpump and reformer is powered.
5. methanol-water reformation hydrogen production machine according to claim 1, it is characterized in that: described reformer comprises insulation shell, reformer chamber and hydrogen purification apparatus from outside to inside successively, the solenoid of described electromagnetic heater is arranged between insulation shell and reformer chamber, and described metal is arranged at reformer chamber by magnet.
6. methanol-water reformation hydrogen production machine according to claim 5, is characterized in that: described metal is provided with single or multiple lift by magnet, and metal is tubular structure or reticulated structure by magnet.
7. methanol-water reformation hydrogen production machine according to claim 5, is characterized in that: the outside of described reformer chamber and inner side are also provided with vaporization coil pipe, first alcohol and water before entering reformer chamber first by described vaporization coil pipe so that methyl alcohol and water vapor.
8. methanol-water reformation hydrogen production machine according to claim 1, is characterized in that: described hydrogen purification apparatus is the membrane separation unit at porous ceramic surface Vacuum Deposition palladium-silver alloy, and coatings is palladium-silver alloy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520449838.9U CN204778810U (en) | 2015-06-29 | 2015-06-29 | Methanol -water reformation hydrogen manufacturing machine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520449838.9U CN204778810U (en) | 2015-06-29 | 2015-06-29 | Methanol -water reformation hydrogen manufacturing machine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204778810U true CN204778810U (en) | 2015-11-18 |
Family
ID=54518902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520449838.9U Active CN204778810U (en) | 2015-06-29 | 2015-06-29 | Methanol -water reformation hydrogen manufacturing machine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN204778810U (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104986731A (en) * | 2015-06-29 | 2015-10-21 | 广东合即得能源科技有限公司 | Methanol-water reforming hydrogen making machine and hydrogen making method thereof |
| CN105329109A (en) * | 2015-11-25 | 2016-02-17 | 广东合即得能源科技有限公司 | Fuel battery car with auxiliary solar energy electricity generation |
| CN105449247A (en) * | 2015-11-25 | 2016-03-30 | 广东合即得能源科技有限公司 | Solar-assisted power generating charge station |
| WO2017080207A1 (en) * | 2015-11-09 | 2017-05-18 | 广东合即得能源科技有限公司 | Device for producing hydrogen using methanol steam reformation, and hydrogen production method thereof |
| CN114057161A (en) * | 2021-12-07 | 2022-02-18 | 湖南大学 | Electromagnetic induction heating methanol water reforming hydrogen production device and hydrogen production method thereof |
-
2015
- 2015-06-29 CN CN201520449838.9U patent/CN204778810U/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104986731A (en) * | 2015-06-29 | 2015-10-21 | 广东合即得能源科技有限公司 | Methanol-water reforming hydrogen making machine and hydrogen making method thereof |
| WO2017000780A1 (en) * | 2015-06-29 | 2017-01-05 | 广东合即得能源科技有限公司 | Methanol-water reforming hydrogen preparation machine and hydrogen preparation method thereof |
| WO2017080207A1 (en) * | 2015-11-09 | 2017-05-18 | 广东合即得能源科技有限公司 | Device for producing hydrogen using methanol steam reformation, and hydrogen production method thereof |
| CN105329109A (en) * | 2015-11-25 | 2016-02-17 | 广东合即得能源科技有限公司 | Fuel battery car with auxiliary solar energy electricity generation |
| CN105449247A (en) * | 2015-11-25 | 2016-03-30 | 广东合即得能源科技有限公司 | Solar-assisted power generating charge station |
| CN114057161A (en) * | 2021-12-07 | 2022-02-18 | 湖南大学 | Electromagnetic induction heating methanol water reforming hydrogen production device and hydrogen production method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104986731A (en) | Methanol-water reforming hydrogen making machine and hydrogen making method thereof | |
| CN105084311B (en) | The methanol-water hydrogen production system employing reforming technology and its application and hydrogen production process of a kind of zero carbon emission | |
| CN104362355A (en) | Methanol water hydrogen-making machine and hydrogen-making method thereof | |
| CN205222680U (en) | Methanol -water reformation hydrogen production system that zero carbon discharged and fuel cell car thereof | |
| CN104577168B (en) | Methanol water hydrogen production power generation system and hydrogen production power generation method | |
| CN204778810U (en) | Methanol -water reformation hydrogen manufacturing machine | |
| CN104362359A (en) | Electric generator based on methanol water hydrogen-making system and electricity generation method thereof | |
| CN105293432A (en) | Methanol water reforming hydrogen production machine and hydrogen production method thereof | |
| CN106242946B (en) | A kind of equipment and technique of solar hydrogen making synthesizing methanol | |
| CN105024628A (en) | Energy complementation self power supply system and power supply method | |
| CN109921060A (en) | A kind of system and method for storage and preparing synthetic gas based on solid oxide cell | |
| CN211854136U (en) | Water electrolysis hydrogen production waste heat utilization system | |
| CN104577163B (en) | A kind of hydrogen gas generating system and its electricity-generating method | |
| CN204289609U (en) | A kind of hydrogen gas generating system | |
| CN101003905A (en) | Membrane reactor of fuel cell, and method for using the reactor to prepare hydrogen dioxide | |
| CN101540410B (en) | Natural gas hydrogen production and proton-exchange film fuel cell integrated generation method and device thereof | |
| CN206219468U (en) | A kind of equipment of solar hydrogen making synthesizing methanol | |
| CN204189882U (en) | A kind of generator based on Methanol water hydrogen production system | |
| CN205489554U (en) | Millet power supply system is filled out in peak clipping based on methanol -water reformation hydrogen manufacturing power generation system | |
| CN205222681U (en) | Methanol -water reformation hydrogen manufacturing machine | |
| CN105811443A (en) | Peak shaving and load shifting power supply system and method based on methanol water reforming hydrogen generation power generation system | |
| CN204281300U (en) | A kind of methanol-water hydrogen making machine | |
| CN204289611U (en) | A kind of methanol-water preparing hydrogen, generating power system | |
| CN204794809U (en) | Energy complementation is from power supply system | |
| CN201402833Y (en) | Battery integration generating device based on natural-gas-prepared hydrogen and proton exchange membrane fuel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20210918 Granted publication date: 20151118 |