CN104362359A - Electric generator based on methanol water hydrogen-making system and electricity generation method thereof - Google Patents
Electric generator based on methanol water hydrogen-making system and electricity generation method thereof Download PDFInfo
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- CN104362359A CN104362359A CN201410622203.4A CN201410622203A CN104362359A CN 104362359 A CN104362359 A CN 104362359A CN 201410622203 A CN201410622203 A CN 201410622203A CN 104362359 A CN104362359 A CN 104362359A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
The invention discloses an electric generator based on a methanol water hydrogen-making system and an electricity generation method thereof. The electric generator comprises a methanol water storage container, a delivery pump, a heat exchanger, a reformer, a separation device and a fuel cell, wherein the delivery pump is used for delivering methanol and water to a reforming chamber of the reformer; the heat exchanger is used for carrying out heat exchange on the low-temperature methanol and water and a high-temperature mixed gas output from the reforming chamber; the reformer is provided with the reforming chamber and an electric heater, and the electric heater provides heat energy for the reforming chamber; and the high-temperature mixed gas which takes carbon dioxide and hydrogen as main parts is prepared in the reforming chamber, passes through the heat exchanger and then enters the separation device to be separated to obtain the hydrogen, and the hydrogen is delivered to the fuel cell and subjected to electrochemical reaction in the fuel cell to generate electric energy, a part of the electric energy provides electricity for the delivery pump and the electric heater, and the rest of the electric energy is output. According to the electric generator, the reformer has no need of being provided with a combustion chamber, an air inlet fan, an air inlet channel and a smoke window, the heating temperature inside the reformer is easily controlled and stable, and the reformer is simple in structure, stable in operation and low in overhaul difficulty.
Description
Technical field
The present invention relates to generating equipment technical field, particularly a kind of generator based on Methanol water hydrogen production system and electricity-generating method thereof.
Background technology
Hydrogen is one of the optimal energy of a kind of 21 century, and when the coal of identical weight of burning, gasoline and hydrogen, the energy that hydrogen produces is maximum, and the product of its burning is water, does not have lime-ash and waste gas, does not pollute the environment; And the mainly CO that coal and oil combustion generate
2and SO
2, greenhouse effect and acid rain can be produced respectively.Coal and reserves are limited, and hydrogen is mainly stored in water, and after burning, unique product is also water, can produce hydrogen continuously, be finished never.The distribution of hydrogen is very extensive, and water is exactly large " warehouse " of hydrogen, wherein contains the hydrogen of 11%.There is the hydrogen of 1.5% earth Rio; All contain hydrogen in oil, coal, natural gas, animal and plant body etc.The main body of hydrogen exists with the form of compound water, and earth surface about 70% is covered for water, and very greatly, therefore can say, hydrogen is the energy of " inexhaustible, nexhaustible " to moisture storage capacity.If can with suitable method preparing hydrogen, so hydrogen also will be the energy that a kind of price is quite cheap.
At present, the annual production of hydrogen is about 3,600 ten thousand tons in the world, and hydrogen production process mainly contains two kinds: one, most hydrogen produce from oil, coal and natural gas, and this method needs to consume fossil fuel natively very in short supply; Two, about have the hydrogen of 4% to be produce by the method for brine electrolysis, it is large that this method consumes electric energy, do not calculate very much.Along with the progress of technology, adopt the technology of first alcohol and water reformation hydrogen production to be gradually developed, it can reduce the energy consumption in Chemical Manufacture and reduce costs, and is expected to alternative electric energy and consumes king-sized electrolysis hydrogen producing process.Advanced methanol steam reforming technology is utilized to produce H
2with CO
2mist, then through palladium membrane separator be separated, H can be obtained respectively
2and CO
2.
With reference to Chinese invention application 201310576349.5(applicant: Shanghai Hejide Dynamic Hydrogen Machine Co., Ltd.), which disclose the system and method that a kind of hydrogen utilizing immediate system to obtain carries out generating electricity, it is hydrogen manufacturing subsystem and power generation sub-system that the core of the system of this generating sends out part.Wherein, hydrogen manufacturing subsystem comprises: the reformer chamber of methyl alcohol and steam reformer, at 350-409 DEG C of temperature 1-5M Pa pressure condition under pass through catalyst, under the effect of catalyst, there is the transformationreation of methanol decomposition reaction and carbon monoxide, generate hydrogen and carbon dioxide, this is the gas solid catalytic reaction system of component more than, many reactions.Reactional equation is as follows: (1) CH
3oH → CO+2H
2; (2) H
2o+CO → CO
2+ H
2; (3) CH
3oH+H
2o → CO
2+ 3H
2, the H that reforming reaction generates
2and CO
2, then the palladium membrane separator through separation chamber is by H
2and CO
2be separated, obtain high-purity hydrogen.In reformer, be also provided with vaporizer and combustion chamber, vaporizer is gasificated into steam before being used for that methyl alcohol and water are entered reformer, and combustion chamber is used for passing through H
2combustion heat release, for reformer chamber provides the reforming reaction temperature of 350-409 DEG C, and provides heat for vaporizer.
But, also there is following disappearance in the system that the above-mentioned hydrogen utilizing immediate system to obtain carries out generating electricity: one, needs to arrange combustion chamber due to reformer, therefore, reformer also needs to arrange the air inlet fan for oxygen in fan-in air and air intake passage, and for discharging the smokestack of the rear waste gas produced of burning, high-temp waste gas is discharged from smokestack, not only wastes heat energy, and easily affects hydrogen generating system each several part equipment operation; Two, in combustion chamber, combustion of hydrogen temperature often soars to more than 1000 DEG C in the short time, easily burns out reformer, and, the mode of combustion of hydrogen heat release is difficult to control, the temperature stability difference (temperature of combustion chamber requires between 405-570 DEG C usually) of combustion chamber; Three, reformer arranges the parts such as the chamber such as vaporizer, combustion chamber, air inlet fan, air intake passage and smokestack, increases structural complexity and the maintenance difficulty of reformer.
Summary of the invention
The technical problem to be solved in the present invention is for above-mentioned deficiency of the prior art, a kind of generator based on Methanol water hydrogen production system is provided, the reformer of this generator is without the need to arranging combustion chamber, air inlet fan, air intake passage and smokestack, heating-up temperature in reformer easily controls, stable, reformer structure is comparatively simple, working stability, and maintenance difficulty is less; The present invention also will provide a kind of electricity-generating method of this generator for this reason.
For solving above-mentioned first technical problem, technical scheme of the present invention is: a kind of generator based on Methanol water hydrogen production system, comprises methanol-water reservoir vessel, delivery pump, heat exchanger, reformer, separator and fuel cell, wherein:
Methanol-water reservoir vessel, stores liquid first alcohol and water in it;
Delivery pump, for being delivered to the reformer chamber of reformer by the first alcohol and water in methanol-water reservoir vessel;
Heat exchanger, is installed on the conveyance conduit between delivery pump and reformer, and the first alcohol and water of low temperature is in heat exchanger, and the high-temperature gas mixture body exported with reformer chamber carries out heat exchange, and methyl alcohol and coolant-temperature gage raise, vaporization;
Reformer, be provided with reformer chamber and electric heater, electric heater provides heat energy for reformer chamber, and reformer chamber is provided with catalyst, and first alcohol and water reacts at the reformation hydrogen production of reformer chamber generation first alcohol and water, obtain the high-temperature gas mixture body based on carbon dioxide and hydrogen, this high-temperature gas mixture body, after heat exchanger, enters separator, and this high-temperature gas mixture body is in heat exchanger, carry out heat exchange with the first alcohol and water of low temperature, mist temperature reduces;
Separator, for separating of based on the mist of carbon dioxide and hydrogen, mist, after separator, isolates hydrogen, is delivered to fuel cell;
Fuel cell, in fuel cell, there is electrochemical reaction in the oxygen in hydrogen and air, produce electric energy, a part of electric energy is that the electric heater of delivery pump and reformer is powered, and remaining electric energy exports.
As to further elaboration of the present invention:
Also be provided with compensation vapourizing unit between described heat exchanger and reformer, this compensation vapourizing unit is provided with electric heater, and described first alcohol and water can be vaporized further after compensating vapourizing unit; The electric energy that described fuel cell produces is also for the electric heater compensating vapourizing unit is powered.
The electric heater of described reformer comprises resistance heater and metal casting heat carrier, and this metal casting heat carrier is coated on outside reformer chamber.
Described separator is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%-78%, and silver accounts for 22%-25%.
Described reformer is provided with start battery device, and this start battery device can heavily managed in device start-up course, for the electric heater of delivery pump and reformer is powered; Described reformer or be provided with combustion-type starting drive, this combustion-type starting drive can heavily managed in device start-up course, is reformer chamber heating by combustion methanol.
Described methanol-water hydrogen making machine is also provided with hydrogen storage bottle, and this hydrogen storage bottle can heavily managed in device start-up course, is fuel cell inputting hydrogen, makes operation of fuel cells, produces electric energy, for the electric heater of delivery pump and reformer is powered.
For solving above-mentioned second technical problem, technical scheme of the present invention is: the above-mentioned electrical power generators method based on Methanol water hydrogen production system, comprises the following steps:
A. control device controls the reformer chamber that the first alcohol and water in methanol-water reservoir vessel is delivered to reformer by delivery pump;
B. the first alcohol and water of low temperature is in heat exchanger, and the high-temperature gas mixture body exported with reformer chamber carries out heat exchange, and methyl alcohol and coolant-temperature gage raise, vaporization;
The first alcohol and water of c. vaporizing enters reformer chamber, at 350-409 DEG C of temperature and catalyst action, the reformation hydrogen production reaction of first alcohol and water occurs, obtains the high-temperature gas mixture body based on carbon dioxide and hydrogen;
D. this high-temperature gas mixture body is after heat exchanger, enters separator, and this high-temperature gas mixture body, in heat exchanger, carries out heat exchange with the first alcohol and water of low temperature, and mist temperature reduces;
E. mist is after separator is separated, and isolates hydrogen, is delivered to fuel cell;
In fuel cell, there is electrochemical reaction in the oxygen f. in hydrogen and air, produce electric energy, a part of electric energy is that the electric heater of delivery pump and reformer is powered, and remaining electric energy exports.
Also comprise vaporization compensation process between described step b and step c, first alcohol and water is after heat exchanger, and the first alcohol and water of not vaporizing completely is vaporized further in vaporization compensation arrangement.
The invention has the beneficial effects as follows: one, due to reformer of the present invention be provided with into reformer chamber heating electric heater, therefore reformer is without the need to arranging combustion chamber, air inlet fan, air intake passage and smokestack, be a reformer closed on the whole, high-temp waste gas can not be discharged, avoid thermal waste, avoid because high-temp waste gas affects hydrogen generating system each several part equipment operation, avoid because of the destruction problem of burning to reformer; Two, the electric energy of electric heater of the present invention and delivery pump is provided by fuel cell, and the hydrogen required for fuel cell comes from the hydrogen that the present invention obtains, and thus makes adaptability of the present invention extremely strong, not by the restriction of regional condition; Three, the heating-up temperature of electric heater easily controls, and the present invention can stably make reformer chamber keep the reforming reaction temperature of 350-409 DEG C; Four, reformer is without the need to arranging the parts such as the chamber such as vaporizer, combustion chamber, air inlet fan, air intake passage and smokestack, greatly reduces structural complexity and the maintenance difficulty of reformer.
Accompanying drawing explanation
Fig. 1 is overall structure block diagram of the present invention.
Fig. 2 is the overall structure block diagram of one embodiment of the present invention.
In figure: 1. methanol-water reservoir vessel; 2. delivery pump; 3. heat exchanger; 4. reformer; 41. reformer chamber; 42. electric heaters; 5. separator; 6. fuel cell; 7. compensate vapourizing unit; 71. electric heaters; 8. gas diverter; 9. hydrogen storage bottle.
Embodiment
Below in conjunction with accompanying drawing, structural principle of the present invention and operation principle are described in further detail.
As shown in Figure 1, a kind of generator based on Methanol water hydrogen production system, comprises methanol-water reservoir vessel 1, delivery pump 2, heat exchanger 3, reformer 4, separator 5 and fuel cell 6, wherein:
Methanol-water reservoir vessel 1, stores liquid first alcohol and water in it;
Delivery pump 2, for being delivered to the reformer chamber 41 of reformer 4 by the first alcohol and water in methanol-water reservoir vessel 1;
Heat exchanger 3, is installed on the conveyance conduit between delivery pump 2 and reformer 4, and the first alcohol and water of low temperature is in heat exchanger 3, and the high-temperature gas mixture body exported with reformer chamber 4 carries out heat exchange, and methyl alcohol and coolant-temperature gage raise, vaporization;
Reformer 4, be provided with reformer chamber 41 and electric heater 42, electric heater 42 provides the heat energy of 350-409 DEG C of temperature for reformer chamber 41, is provided with catalyst in reformer chamber 41, and methyl alcohol and steam are in reformer chamber 41, catalyst is passed through under the pressure condition of 1-5M Pa, under the effect of catalyst, there is the transformationreation of methanol decomposition reaction and carbon monoxide, generate hydrogen and carbon dioxide, this is the gas solid catalytic reaction system of component more than, many reactions, and reactional equation is: (1) CH
3oH → CO+2H
2, (2) H
2o+CO → CO
2+ H
2, (3) CH
3oH+H
2o → CO
2+ 3H
2, obtain the high-temperature gas mixture body based on carbon dioxide and hydrogen, this high-temperature gas mixture body, after heat exchanger 3, enters separator 5, and this high-temperature gas mixture body, in heat exchanger 3, carries out heat exchange with the first alcohol and water of low temperature, and mist temperature reduces;
Separator 5, for separating of based on the mist of carbon dioxide and hydrogen, mist, after separator 5, isolates hydrogen, is delivered to fuel cell 6; Described separator 5 is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%-78%, and silver accounts for 22%-25%; The difference of the inside and outside pressure of membrane separation device is more than or equal to 1.1MPa;
Fuel cell 6, in fuel cell 6, there is electrochemical reaction, the anode at fuel cell: 2H in the oxygen in hydrogen and air
2→ 4H
++ 4e
-, H
2split into two protons and two electronics, proton is through proton exchange membrane (PEM), and electronics, by positive plate, by external loading, and enters cathode bipolar plate; Negative electrode at fuel cell: O
2+ 4e
-+ 4H
+→ 2H
2o, proton, electronics and O
2recombine to form H
2o; A part for the electric energy that fuel cell produces, for the electric heater 42 of delivery pump 2 and reformer 4 is powered, this part electric energy is the sub-fraction of total electric energy, such as 10%, remaining most of electric energy exports.
As shown in Figure 2, as to present invention further optimization mode, also be provided with between described heat exchanger 3 and reformer 4 and compensate vapourizing unit 7, this compensation vapourizing unit 7 is provided with electric heater 71, and described first alcohol and water can be vaporized further after compensating the compensation vaporization pipeline in vapourizing unit 7; The electric energy that described fuel cell 6 produces is also for the electric heater 71 compensating vapourizing unit 7 is powered.
In technique scheme, the electric heater 42 of described reformer 4 comprises resistance heater and metal casting heat carrier, and this metal casting heat carrier is coated on outside reformer chamber 41.
In technique scheme, methanol-water hydrogen making machine needs the starting drive arranging reformer, this starting drive has three kinds of schemes: one, reformer 4 arrange start battery device, and this start battery device can heavily managed in device start-up course, for the electric heater of delivery pump and reformer is powered; Two, reformer 4 or be provided with combustion-type starting drive, this combustion-type starting drive can heavily managed in device start-up course, is reformer chamber heating by combustion methanol; Three, methanol-water hydrogen making machine is also provided with hydrogen storage bottle 9, and this hydrogen storage bottle 9 can heavily managed in device 4 start-up course, is fuel cell 6 inputting hydrogen, fuel cell 6 is worked, and produces electric energy, for the electric heater 42 of delivery pump 2 and reformer 4 is powered.
The hydrogen production process of above-mentioned methanol-water hydrogen making machine, comprises the following steps:
A. control device controls the reformer chamber that the first alcohol and water in methanol-water reservoir vessel is delivered to reformer by delivery pump;
B. the first alcohol and water (such as 10-20 DEG C) of low temperature is in heat exchanger, and the high-temperature gas mixture body (such as 350-409 DEG C) exported with reformer chamber carries out heat exchange, and methyl alcohol and coolant-temperature gage raise (such as 150-300 DEG C), vaporization;
The first alcohol and water of c. vaporizing enters reformer chamber, at 350-409 DEG C of temperature and catalyst action, the reformation hydrogen production reaction of first alcohol and water occurs, obtains the high-temperature gas mixture body based on carbon dioxide and hydrogen;
D. this high-temperature gas mixture body is after heat exchanger, enters separator, and this high-temperature gas mixture body, in heat exchanger, carries out heat exchange with the first alcohol and water of low temperature, and mist temperature reduces (being such as reduced to 35-40 DEG C);
E. mist is after separator is separated, and isolates hydrogen, and is delivered to fuel cell;
In fuel cell, there is electrochemical reaction in the oxygen f. in hydrogen and air, produces electric energy, and the electric energy sub-fraction of generation is that the electric heater of delivery pump and reformer is powered, and remaining most of electric energy exports.
Also comprise vaporization compensation process between described step b and step c, first alcohol and water is after heat exchanger, and the first alcohol and water of not vaporizing completely is vaporized further in vaporization compensation arrangement.
The above is only better embodiment of the present invention, every above execution mode is done according to technical scheme of the present invention any trickle amendment, equivalent variations and modification, all belong in the scope of technical solution of the present invention.
Claims (9)
1. based on a generator for Methanol water hydrogen production system, it is characterized in that: comprise methanol-water reservoir vessel, delivery pump, heat exchanger, reformer, separator and fuel cell, wherein:
Methanol-water reservoir vessel, stores liquid first alcohol and water in it;
Delivery pump, for being delivered to the reformer chamber of reformer by the first alcohol and water in methanol-water reservoir vessel;
Heat exchanger, is installed on the conveyance conduit between delivery pump and reformer, and the first alcohol and water of low temperature is in heat exchanger, and the high-temperature gas mixture body exported with reformer chamber carries out heat exchange, and methyl alcohol and coolant-temperature gage raise, vaporization;
Reformer, be provided with reformer chamber and electric heater, electric heater provides heat energy for reformer chamber, and reformer chamber is provided with catalyst, and first alcohol and water reacts at the reformation hydrogen production of reformer chamber generation first alcohol and water, obtain the high-temperature gas mixture body based on carbon dioxide and hydrogen, this high-temperature gas mixture body, after heat exchanger, enters separator, and this high-temperature gas mixture body is in heat exchanger, carry out heat exchange with the first alcohol and water of low temperature, mist temperature reduces;
Separator, for separating of based on the mist of carbon dioxide and hydrogen, mist, after separator, isolates hydrogen, is delivered to fuel cell;
Fuel cell, in fuel cell, there is electrochemical reaction in the oxygen in hydrogen and air, produce electric energy, a part of electric energy is that the electric heater of delivery pump and reformer is powered, and remaining electric energy exports.
2. the generator based on Methanol water hydrogen production system according to claim 1, it is characterized in that: between described heat exchanger and reformer, be also provided with compensation vapourizing unit, this compensation vapourizing unit is provided with electric heater, and described first alcohol and water can be vaporized further after compensating vapourizing unit; The electric energy that described fuel cell produces is also for the electric heater compensating vapourizing unit is powered.
3. the generator based on Methanol water hydrogen production system according to claim 1, is characterized in that: the electric heater of described reformer comprises resistance heater and metal casting heat carrier, and this metal casting heat carrier is coated on outside reformer chamber.
4. the generator based on Methanol water hydrogen production system according to claim 1, it is characterized in that: described separator is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%-78%, and silver accounts for 22%-25%.
5. the generator based on Methanol water hydrogen production system according to claim 1, is characterized in that: described reformer is provided with start battery device, and this start battery device can heavily managed in device start-up course, for the electric heater of delivery pump and reformer is powered.
6. the generator based on Methanol water hydrogen production system according to claim 1, is characterized in that: described reformer is provided with combustion-type starting drive, and this combustion-type starting drive can heavily managed in device start-up course, is reformer chamber heating by combustion methanol.
7. the generator based on Methanol water hydrogen production system according to claim 1, it is characterized in that: described methanol-water hydrogen making machine is also provided with hydrogen storage bottle, this hydrogen storage bottle can heavily managed in device start-up course, for fuel cell inputting hydrogen, make operation of fuel cells, produce electric energy, for the electric heater of delivery pump and reformer is powered.
8. claim 1-7 any one is based on the electrical power generators method of Methanol water hydrogen production system, it is characterized in that, comprises the following steps:
A. control device controls the reformer chamber that the first alcohol and water in methanol-water reservoir vessel is delivered to reformer by delivery pump;
B. the first alcohol and water of low temperature is in heat exchanger, and the high-temperature gas mixture body exported with reformer chamber carries out heat exchange, and methyl alcohol and coolant-temperature gage raise, vaporization;
The first alcohol and water of c. vaporizing enters reformer chamber, at 350-409 DEG C of temperature and catalyst action, the reformation hydrogen production reaction of first alcohol and water occurs, obtains the high-temperature gas mixture body based on carbon dioxide and hydrogen;
D. this high-temperature gas mixture body is after heat exchanger, enters separator, and this high-temperature gas mixture body, in heat exchanger, carries out heat exchange with the first alcohol and water of low temperature, and mist temperature reduces;
E. mist is after separator is separated, and isolates hydrogen, is delivered to fuel cell;
In fuel cell, there is electrochemical reaction in the oxygen f. in hydrogen and air, produce electric energy, a part of electric energy is that the electric heater of delivery pump and reformer is powered, and remaining electric energy exports.
9. the electrical power generators method based on Methanol water hydrogen production system according to claim 8, it is characterized in that, also comprise vaporization compensation process between described step b and step c, first alcohol and water is after heat exchanger, and the first alcohol and water of not vaporizing completely is vaporized further in vaporization compensation arrangement.
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| WO2016070590A1 (en) * | 2014-11-07 | 2016-05-12 | 广东合即得能源科技有限公司 | Hydrogen production machine utilizing methanol and water and hydrogen production method thereof |
| WO2017020656A1 (en) * | 2015-08-06 | 2017-02-09 | 广东合即得能源科技有限公司 | Methanol water reforming-based hydrogen production electric generator |
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| CN110862067A (en) * | 2019-10-28 | 2020-03-06 | 中科院大连化学物理研究所张家港产业技术研究院有限公司 | Low-pressure hydrogen production system of methanol-water hydrogenation station and working method thereof |
| CN112856219A (en) * | 2019-11-12 | 2021-05-28 | 现代自动车株式会社 | Reforming system connected to raw gas vaporization system |
| CN114876633A (en) * | 2022-04-28 | 2022-08-09 | 上海威佳天意新能源科技有限公司 | Methanol fuel double-circuit power generation device and heat exchange system thereof |
| CN115020768A (en) * | 2022-06-20 | 2022-09-06 | 中科氢焱零碳人居科技(苏州)有限公司 | Methanol hydrogen production fuel cell combined heat and power supply system |
| WO2022193545A1 (en) * | 2021-03-15 | 2022-09-22 | 华能国际电力股份有限公司 | Fuel cell system directly utilizing methanol reformed gas and operating method of fuel cell system |
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| CN110862067A (en) * | 2019-10-28 | 2020-03-06 | 中科院大连化学物理研究所张家港产业技术研究院有限公司 | Low-pressure hydrogen production system of methanol-water hydrogenation station and working method thereof |
| CN110862067B (en) * | 2019-10-28 | 2023-08-18 | 中科院大连化学物理研究所张家港产业技术研究院有限公司 | Low-pressure hydrogen production system of methanol water hydrogenation station and working method thereof |
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