CN204710081U - A kind of chemical emission cyclic processing device - Google Patents

A kind of chemical emission cyclic processing device Download PDF

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Publication number
CN204710081U
CN204710081U CN201520301966.9U CN201520301966U CN204710081U CN 204710081 U CN204710081 U CN 204710081U CN 201520301966 U CN201520301966 U CN 201520301966U CN 204710081 U CN204710081 U CN 204710081U
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China
Prior art keywords
reactor
tail gas
discharging pipe
processing device
circulating line
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Expired - Fee Related
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CN201520301966.9U
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Chinese (zh)
Inventor
张静娴
吴大珍
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Ningbo University
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Ningbo University
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Abstract

The utility model discloses a kind of chemical emission cyclic processing device, comprise reactor, reactor comprises upper kettle and lower kettle, the inside of reactor is provided with ring baffle, ring baffle is provided with screen pack, the bottom of reactor inside is provided with heating element heater, the upside of heating element heater is provided with heat-conducting plate, the inside of reactor is also provided with pressure sensor and temperature sensor, the left side of reactor is provided with controller, on the right side of reactor, lower end is also connected with exhaust outlet, exhaust outlet is connected with adsorbent bed, adsorbent bed is connected with sterilizing chamber, the lower end of sterilizing chamber is provided with tail gas discharging pipe, tail gas discharging pipe is provided with Tail gas measuring device, tail gas discharging pipe below Tail gas measuring device is connected with circulating line, the other end of circulating line is connected with reactor, circulating line is provided with by-pass valve control, tail gas discharging pipe below circulating line is also provided with by-pass valve control.The utility model structure is simple, easy to use, and treatment effect is good, is convenient to cleaning, long service life.

Description

A kind of chemical emission cyclic processing device
Technical field
The utility model relates to technical field of chemical, specifically a kind of chemical emission cyclic processing device.
Background technology
The various organic compound from waste gas such as hydrocarbon, alcohol, aldehyde, ketone, ether, ester, amine carboxylic acid, aromatic hydrocarbon, phenols in the waste gas that the industries such as petrochemical industry are discharged, harmful, the common symptoms caused is fatigue and weak, dizziness headache, n and V, nervous asthma, blood change etc.The material such as aldehyde, amine also foul smelling.Organic exhaust gas can also cause photochemical fog, causes secondary pollution.The purifying treatment method of current organic exhaust gas mainly contains absorption method: utilize the surface force of adsorbent organic exhaust gas adsorption at adsorbent surface, to purify the waste gas of discharging in production process.The molecular weight of waste gas is larger, and boiling point is higher, and concentration is higher, and temperature is lower, then the adsorption capacity of adsorbent is larger, and adsorption cycle is longer.Absorption method is applicable to the purification of low-concentration organic exhaust gas, also can be used for high-concentration organic waste gas and reclaims.Conventional adsorbent has active carbon, silica gel, ion exchange resin etc.But cost is higher, application is less at present.Burning facture-organic exhaust gas, under the effect of temperature 200 ~ 400 DEG C with catalyst, is oxidized to carbon dioxide and water, releases the combustion heat simultaneously.Production by Catalytic Combustion Process is mainly used in the purification of organic exhaust gas of high temperature, high concentration, continuous blow-down, and under temperature is 600 ~ 800 DEG C and the holdup time is the condition of 0.3 ~ 0.5 second, organic gas can burn completely, becomes carbon dioxide and water.Direct combustion method is applicable to the organic waste-gas purification of high temperature, high concentration, and heat-recoverable.It is more that direct combustion method consumes the energy, should adopt heavy oil, natural gas makes pre-heat energy.During preheating, burning indoor temperature should be homogeneous, makes whole waste gas all be heated to predetermined temperature, otherwise can produce cacodorous intermediate product.If any the boiler of air volumematching, waste gas can be burnt in the boiler as air inducing.Absorption process: the method absorbing high-concentration organic waste gas with absorbing liquid.Absorbing liquid can simultaneous oxidation, neutralization part foul gas.Usual absorption process, as the pretreatment of organic exhaust gas, as dedusting, oil mist removing, except water soluble ingredient etc., and then to purify with additive method further.
But general petrochemical enterprise, due to its exhaust gas constituents complexity, is difficult to it to purify completely by a kind of method, causes in the tail gas of discharge and also contain gas harmful in a large number, have a strong impact on the healthy of nearby residents.
Utility model content
The purpose of this utility model is the chemical emission cyclic processing device providing a kind of structure simple, easy to use, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the utility model provides following technical scheme:
A kind of chemical emission cyclic processing device, comprise reactor, described reactor comprises upper kettle and lower kettle, described upper kettle is connected by nut with lower kettle, the upper end of reactor is provided with air inlet and charging aperture, the lower end, left side of reactor is provided with slag-drip opening, the inside of reactor is provided with ring baffle, described ring baffle is provided with screen pack, the bottom of reactor inside is provided with heating element heater, the upside of described heating element heater is provided with heat-conducting plate, the inside of reactor is also provided with pressure sensor and temperature sensor, the left side of reactor is provided with controller, on the right side of reactor, lower end is also connected with exhaust outlet, described exhaust outlet is connected with adsorbent bed, described adsorbent bed is connected with sterilizing chamber, the inside of described sterilizing chamber is provided with ultraviolet generater and ozone generator, the lower end of sterilizing chamber is provided with tail gas discharging pipe, described tail gas discharging pipe is provided with Tail gas measuring device, tail gas discharging pipe below described Tail gas measuring device is connected with circulating line, the other end of described circulating line is connected with reactor, circulating line is provided with by-pass valve control, tail gas discharging pipe below circulating line is also provided with by-pass valve control.
As further program of the utility model: be provided with Gask-O-Seal between described upper kettle and lower kettle.
As further program of the utility model: described temperature sensor is all connected with controller with pressure sensor.
As further program of the utility model: described adsorbent bed adopts active carbon fixed adsorption bed.
As further program of the utility model: the horizontal level of described screen pack is higher than the horizontal level of exhaust outlet.
As the utility model further scheme: the position of described slag-drip opening is higher than the position of screen pack.
Compared with prior art, the beneficial effects of the utility model are: first burnt by the organic exhaust gas of high concentration, burning can adopt pressure combustion or add catalyst combustion, make most organic exhaust gas can be oxidized to carbon dioxide and water, release the combustion heat simultaneously, the organic compound content existed in waste gas after burning process reduces greatly, then adsorption treatment is carried out, compare and directly carry out adsorption treatment, cost reduces greatly, also have a small amount of remaining organic compound to adopt ultraviolet beam to irradiate after adsorption treatment and carry out cracking, adopt ozone simultaneously, ozone is polymerized with in free state polluter atom, generate new, harmless or low harmful substances, as CO2, H2O etc., simultaneously, Pre-Ozonation on Organic Matter has extremely strong oxidation, the elimination effect got instant result is had to foul gas and other excitant peculiar smell, finally reach the object of thoroughly purification.Reactor is divided into upper kettle and lower kettle, reactor can be dismantled, convenient cleaning, ensure the treatment effect of exhaust-gas treatment next time, be provided with screen pack, can prevent a large amount of solid particle from entering in adsorbent bed along with gas or being retained in exhaust outlet the life-span of the equipment that affects, add the service life of equipment, and screen pack is for removably connecting, facilitate cleaning and the replacing of screen pack.Be provided with heating element heater and temperature sensor, adopt this mode of heating, homogeneous heating, and coordinate with temperature controller, make the temperature stabilization heated, be provided with Tail gas measuring device, when Tail gas measuring device detects that tail gas is qualified, by-pass valve control on tail gas discharging pipe is opened, and tail gas is discharged, when Tail gas measuring device detects that tail gas is defective, by-pass valve control on circulating line is opened, make circulation of tail gas return reactor, again purify, can ensure that gas purification is thorough.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the utility model embodiment, be clearly and completely described the technical scheme in the utility model embodiment, obviously, described embodiment is only the utility model part embodiment, instead of whole embodiments.Based on the embodiment in the utility model, those of ordinary skill in the art are not making the every other embodiment obtained under creative work prerequisite, all belong to the scope of the utility model protection.
Refer to Fig. 1, in the utility model embodiment, a kind of chemical emission cyclic processing device, comprise reactor 1, described reactor 1 comprises upper kettle 2 and lower kettle 3, described upper kettle 2 is connected by nut with lower kettle 3, Gask-O-Seal is provided with between upper kettle 2 and lower kettle 3, convenient cleaning, ensure the treatment effect of exhaust-gas treatment next time, the upper end of reactor 1 is provided with air inlet 5 and charging aperture 4, the lower end, left side of reactor 1 is provided with slag-drip opening 8, the inside of reactor 1 is provided with ring baffle 6, described ring baffle 6 is provided with screen pack 7, the position of slag-drip opening 8 is higher than the position of screen pack 7, can prevent a large amount of solid particle from entering into adsorbent bed 15 li along with gas or being retained in the life-span affecting equipment in exhaust outlet 11, add the service life of equipment, and screen pack 7 is for removably connecting, facilitate cleaning and the replacing of screen pack 7.
The bottom of reactor 1 inside is provided with heating element heater 9, the upside of described heating element heater 9 is provided with heat-conducting plate 10, the inside of reactor 1 is also provided with pressure sensor 12 and temperature sensor 13, the left side of reactor 1 is provided with controller 14, temperature sensor 13 is all connected with controller 14 with pressure sensor 12, adopts this mode of heating, homogeneous heating, and coordinate with temperature controller, make the temperature stabilization heated.On the right side of reactor 1, lower end is also connected with exhaust outlet 11, the horizontal level of screen pack 7 is higher than the horizontal level of exhaust outlet 11, described exhaust outlet 11 is connected with adsorbent bed 15, described adsorbent bed 15 adopts active carbon fixed adsorption bed, adsorbent bed 15 is connected with sterilizing chamber 16, the inside of described sterilizing chamber 16 is provided with ultraviolet generater 17 and ozone generator 18, the lower end of sterilizing chamber 16 is provided with tail gas discharging pipe 19, described tail gas discharging pipe 19 is provided with Tail gas measuring device 20, tail gas discharging pipe 19 below described Tail gas measuring device 20 is connected with circulating line 22, the other end of described circulating line 22 is connected with reactor 1, circulating line 22 is provided with by-pass valve control 21, tail gas discharging pipe 19 below circulating line 22 is also provided with by-pass valve control 21, when Tail gas measuring device 20 detects that tail gas is qualified, by-pass valve control 21 on tail gas discharging pipe 19 is opened, tail gas is discharged, when Tail gas measuring device 20 detects that tail gas is defective, by-pass valve control 21 on circulating line 22 is opened, circulation of tail gas is made to return reactor 1, again purify, can ensure that gas purification is thorough.
The organic exhaust gas of high concentration first burns by the utility model, burning can adopt pressure combustion or add catalyst combustion, make most organic exhaust gas can be oxidized to carbon dioxide and water, release the combustion heat simultaneously, the organic compound content existed in waste gas after burning process reduces greatly, then adsorption treatment is carried out, compare and directly carry out adsorption treatment, cost reduces greatly, also have a small amount of remaining organic compound to adopt ultraviolet beam to irradiate after adsorption treatment and carry out cracking, adopt ozone simultaneously, ozone is polymerized with in free state polluter atom, generate new, harmless or low harmful substances, as CO2, H2O etc., simultaneously, Pre-Ozonation on Organic Matter has extremely strong oxidation, the elimination effect got instant result is had to foul gas and other excitant peculiar smell, finally reach the object of thoroughly purification.

Claims (6)

1. a chemical emission cyclic processing device, comprise reactor (1), it is characterized in that, described reactor (1) comprises upper kettle (2) and lower kettle (3), described upper kettle (2) is connected by nut with lower kettle (3), the upper end of reactor (1) is provided with air inlet (5) and charging aperture (4), the lower end, left side of reactor (1) is provided with slag-drip opening (8), the inside of reactor (1) is provided with ring baffle (6), described ring baffle (6) is provided with screen pack (7), the bottom of reactor (1) inside is provided with heating element heater (9), the upside of described heating element heater (9) is provided with heat-conducting plate (10), the inside of reactor (1) is also provided with pressure sensor (12) and temperature sensor (13), the left side of reactor (1) is provided with controller (14), lower end, reactor (1) right side is also connected with exhaust outlet (11), described exhaust outlet (11) is connected with adsorbent bed (15), described adsorbent bed (15) is connected with sterilizing chamber (16), the inside of described sterilizing chamber (16) is provided with ultraviolet generater (17) and ozone generator (18), the lower end of sterilizing chamber (16) is provided with tail gas discharging pipe (19), described tail gas discharging pipe (19) is provided with Tail gas measuring device (20), the tail gas discharging pipe (19) of described Tail gas measuring device (20) below is connected with circulating line (22), the other end of described circulating line (22) is connected with reactor (1), circulating line (22) is provided with by-pass valve control (21), the tail gas discharging pipe (19) of circulating line (22) below is also provided with by-pass valve control (21).
2. a kind of chemical emission cyclic processing device according to claim 1, is characterized in that, is provided with Gask-O-Seal between described upper kettle (2) and lower kettle (3).
3. a kind of chemical emission cyclic processing device according to claim 1, is characterized in that, described temperature sensor (13) is all connected with controller (14) with pressure sensor (12).
4. a kind of chemical emission cyclic processing device according to claim 1, is characterized in that, described adsorbent bed (15) adopts active carbon fixed adsorption bed.
5. a kind of chemical emission cyclic processing device according to claim 1, is characterized in that, the horizontal level of described screen pack (7) is higher than the horizontal level of exhaust outlet (11).
6. a kind of chemical emission cyclic processing device according to claim 1, is characterized in that, the position of described slag-drip opening (8) is higher than the position of screen pack (7).
CN201520301966.9U 2015-05-11 2015-05-11 A kind of chemical emission cyclic processing device Expired - Fee Related CN204710081U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107362683A (en) * 2017-08-21 2017-11-21 昆明鹏翼达气体产品有限公司 A kind of ultra-pure gases purification devices and purification process
CN108686250A (en) * 2018-07-01 2018-10-23 周元忠 A kind of plasma generator
CN109647619A (en) * 2018-12-29 2019-04-19 西南石油大学 A kind of dirty air purifying apparatus by capacitance principle

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107362683A (en) * 2017-08-21 2017-11-21 昆明鹏翼达气体产品有限公司 A kind of ultra-pure gases purification devices and purification process
CN108686250A (en) * 2018-07-01 2018-10-23 周元忠 A kind of plasma generator
CN109647619A (en) * 2018-12-29 2019-04-19 西南石油大学 A kind of dirty air purifying apparatus by capacitance principle

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151021

Termination date: 20180511

CF01 Termination of patent right due to non-payment of annual fee