CN204674125U - Transmission increasing disappears shadow AZO electro-conductive glass and contactor control device - Google Patents
Transmission increasing disappears shadow AZO electro-conductive glass and contactor control device Download PDFInfo
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- CN204674125U CN204674125U CN201520307659.1U CN201520307659U CN204674125U CN 204674125 U CN204674125 U CN 204674125U CN 201520307659 U CN201520307659 U CN 201520307659U CN 204674125 U CN204674125 U CN 204674125U
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Abstract
The utility model is applicable to electro-conductive glass technical field, provide a kind of transmission increasing to disappear shadow AZO electro-conductive glass and contactor control device, the transmission increasing shadow AZO electro-conductive glass that disappears comprises glass substrate, is stackedly arranged at the antireflection layer on glass substrate one surface and the stacked shadow layer that disappears being arranged at another surface of glass substrate, and the surface of the shadow layer that disappears is provided with AZO rete; Disappear shadow layer surface when being provided with AZO rete and when not being provided with AZO rete to the difference of visible light reflectance lower than 2%, transmission increasing disappears the overall transmitance of shadow AZO electro-conductive glass higher than 87%.The utility model is provided with in the both sides of glass substrate disappear shadow layer and antireflection layer respectively, effectively eliminates the etching line of AZO rete, improves light transmittance, can obtain the high grade picture of high brightness, clear exquisiteness; Further, will disappear shadow layer and antireflection layer set up glass substrate both sides separately, technique can be made to simplify and adjustability improves, and reduce complexity and the uncertainty of plated film, improving product yield.
Description
Technical field
The utility model belongs to electro-conductive glass technical field, and particularly a kind of transmission increasing disappears shadow AZO electro-conductive glass and contactor control device.
Background technology
AZO glass, i.e. the ZnO transparent conductive glass of adulterated al are the one of TCO glass, and the same with the TCO glass such as ito glass also have feature that is transparent and conduction, can be used for producing touch screen device.Traditional AZO electro-conductive glass, when having same conductivity with ITO, transmitance is poor, and conductive layer etching line is obvious, causes display effect not good enough.
Utility model content
The purpose of this utility model is to provide a kind of transmission increasing to disappear shadow AZO electro-conductive glass, is intended to improve transmitance and desalination etching line, improves display effect.
The utility model realizes like this, a kind of transmission increasing disappears shadow AZO electro-conductive glass, comprise glass substrate, be stackedly arranged at the antireflection layer on described glass substrate one surface and the stacked shadow layer that disappears being arranged at described another surface of glass substrate, described in the disappear surface of shadow layer be provided with AZO rete; When the described shadow layer surface that disappear is provided with AZO rete and when not being provided with AZO rete to the difference of visible light reflectance lower than 2%, described transmission increasing disappears the overall transmitance of shadow AZO electro-conductive glass higher than 87%.
As optimal technical scheme of the present utility model:
The described shadow layer that disappears comprises the first niobium pentaoxide rete or the first titanium oxide film layer and the first silica coating that are cascading from described glass substrate, the refractive index that described first niobium pentaoxide rete corresponds to 550nm is 2.20 ~ 2.40, thickness is 5 ~ 50nm, the refractive index that described first silica coating corresponds to 550nm is 1.40 ~ 1.50, and thickness is 30 ~ 100nm.
Described antireflection layer comprises the second silica coating and the second niobium pentaoxide rete or the second titanium oxide film layer that set gradually from described glass substrate, the refractive index that described second silica coating corresponds to 550nm is 1.40 ~ 1.50, thickness is 5 ~ 50nm, the refractive index that described second niobium pentaoxide rete corresponds to 550nm is 2.20 ~ 2.40, and thickness is 40 ~ 100nm.
The thickness of described AZO rete is 50 ~ 300nm, and the refractive index of corresponding 550nm is 1.80 ~ 1.95, and resistivity is 5 × 10
-4Ω/cm.
Another object of the present utility model is to provide a kind of contactor control device, at least comprises a substrate, and the transmission increasing described in described substrate adopts disappears shadow AZO electro-conductive glass, and the disappear AZO etched film of shadow AZO electro-conductive glass of described transmission increasing becomes touch control electrode.
The AZO electro-conductive glass that the utility model provides is provided with in the both sides of glass substrate disappear shadow layer and antireflection layer respectively, effectively eliminates the etching line of AZO rete, and improves light transmittance, can obtain the high grade picture of high brightness, clear exquisiteness; And, due to shadow layer and each freedom of the antireflection layer at least two membranes formation of disappearing, if the two is plated in the same side, then cross assembly of thin films complex manufacturing, the change of every one deck all affects comparatively large on whole film system, the present embodiment shadow layer that will disappear sets up glass substrate both sides separately with antireflection layer, can make technique simplification and adjustability raising, reduce complexity and the uncertainty of plated film, improving product yield.
Accompanying drawing explanation
Fig. 1 is that transmission increasing that the utility model embodiment provides disappears the structural representation of shadow AZO electro-conductive glass;
Fig. 2 is that transmission increasing that the utility model embodiment provides disappears the transmittance curve figure of shadow AZO electro-conductive glass when arranging antireflection layer and do not arrange antireflection layer;
Fig. 3 is that transmission increasing that the utility model embodiment provides disappears the method flow diagram of shadow AZO electro-conductive glass.
Detailed description of the invention
In order to make the purpose of this utility model, technical scheme and advantage clearly understand, below in conjunction with drawings and Examples, the utility model is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the utility model, and be not used in restriction the utility model.
Below in conjunction with specific embodiment, specific implementation of the present utility model is described in detail:
Please refer to Fig. 1, the utility model embodiment provides a kind of transmission increasing to disappear shadow AZO electro-conductive glass, it comprises glass substrate 01, is stackedly arranged at the antireflection layer 02 on glass substrate 01 1 surface (tin face) and the stacked shadow layer 03 that disappears being arranged at another surface of glass substrate 01 (air surface), this surface disappearing shadow layer 03 is provided with AZO rete 04, this AZO rete 04 is generally used for etched electrodes, as the touch control electrode in touch control display apparatus or display driver electrode.This shadow layer 03 that disappears can desalinate the etching line caused after AZO rete 04 is etched into electrode, when be not provided with disappear shadow layer 03 time, the electrode that AZO rete 04 etches and the substrate surface covered without electrode larger to visible light reflectance difference, cause electrode etch line obvious, in the present embodiment, disappear shadow layer 03 as refractive index matching layers, be arranged between AZO rete 04 and glass substrate 01, destructive interference is there is thus eliminates etching line in visible ray on AZO material surface and the surface that do not covered by AZO material, the independent shadow layer 03 that disappears to visible light reflectance with when being provided with AZO rete 04 to the difference of visible light reflectance lower than 2%.This shadow layer that disappears effectively can be desalinated and even ignored etching line, makes display frame without the interference of etching line, promotes quality.On another surface of glass substrate 01, be provided with antireflection layer 02, significantly can improve the transmitance of visible ray, and then improve the brightness of display, the overall transmitance of whole AZO electro-conductive glass can be made higher than 87% by antireflection layer 02.As shown in Figure 2, top curve is the transmittance curve being provided with antireflection layer, and lower curve is the transmittance curve not arranging antireflection layer.
The AZO electro-conductive glass that the present embodiment provides is provided with in the both sides of glass substrate 01 disappear shadow layer 03 and antireflection layer 02 respectively, effectively eliminates the etching line of AZO rete 04, and improves light transmittance, can obtain the high grade picture of high brightness, clear exquisiteness; And, due to shadow layer 03 and each freedom of the antireflection layer 02 at least two membranes formation of disappearing, if the two is plated in the same side, then cross assembly of thin films complex manufacturing, the change of every one deck all affects comparatively large on whole film system, the present embodiment shadow layer 03 that will disappear sets up glass substrate 01 both sides separately with antireflection layer 02, technique can be made to simplify and adjustability raising, reduce complexity and the uncertainty of plated film, improving product yield.
In the present embodiment, the shadow layer 03 that disappears comprises the first niobium pentaoxide rete 031 (or first titanium oxide film layer) and the first silica coating 032 be cascading from glass substrate 01, the refractive index that first niobium pentaoxide rete 031 corresponds to 550nm is 2.20 ~ 2.40, thickness is 5 ~ 50nm, the refractive index that first silica coating 032 corresponds to 550nm is 1.40 ~ 1.50, and thickness is 30 ~ 100nm.The thickness of AZO rete 04 is 50 ~ 300nm, and the refractive index of corresponding 550nm is 1.80 ~ 1.95, and resistivity is 5 × 10
-4Ω/cm.Above-mentioned material is arranged according to above-mentioned parameter coupling, the shadow effect that preferably disappears can be obtained.
In addition, this glass substrate 01 can adopt thickness to be the soda-lime-silica glass of 0.5 ~ 2.0mm (such as 0.5mm, 0.7mm, 1.1mm etc.), Pyrex or aluminosilicate glass.
In the present embodiment, antireflection layer 02 comprises the second silica coating 021 and the second niobium pentaoxide rete 022 (or second titanium oxide film layer) set gradually from glass substrate 01, the refractive index that second silica coating 021 corresponds to 550nm is 1.40 ~ 1.50, thickness is 5 ~ 50nm, the refractive index that second niobium pentaoxide rete 022 corresponds to 550nm is 2.20 ~ 2.40, and thickness is 40 ~ 100nm.Arranged according to above-mentioned parameter coupling by above-mentioned material, the transmitance of visible ray can be brought up to more than 87%.
The above-mentioned transmission increasing shadow AZO electro-conductive glass that disappears is made by following method, concrete reference diagram 3, and step is as follows:
In step S101, choose original sheet glass and carry out plated film pre-treatment, obtaining glass substrate;
In the present embodiment, by the original sheet glass of desired thickness through cutting into required size, then obtain the glass substrate 01 needed for plated film through pretreatment process such as edging, grinding, cleanings.
In step s 102, adopt on a surface of glass substrate 01 Mid frequency alternative magnetron sputtering technique to be coated with the first niobium pentaoxide rete 031 or the first titanium oxide film layer and the first silica coating 032 successively, obtain the shadow layer 03 that disappears;
In step s 103, AZO rete 04 is coated with on shadow layer 03 surface that disappears;
In step S104, Mid frequency alternative magnetron sputtering technique is adopted to be coated with the second silica coating 021 and the second niobium pentaoxide rete 022 or the second titanium oxide film layer successively on another surface of glass substrate 01, obtain antireflection layer 02, and then obtain transmission increasing and to disappear shadow AZO electro-conductive glass.
Particularly, be placed on transmission dolly by ready glass substrate 01, setting transmission dolly walking speed, enters vacuum coating equipment, is heated to about 50 ~ 150 DEG C steps into niobium pentaoxide target position through the bringing-up section of cavity, preferred Ar tolerance at 200sccm, preferred O
2tolerance is at 100sccm, and preferred sputtering pressure is 3 × 10
-3target used is twin target, adopt Mid frequency alternative magnetron sputtering on glass substrate 01, be coated with the first niobium pentaoxide rete 031, the refractive index that first niobium pentaoxide rete 031 corresponds to 550nm is 2.20 ~ 2.40, thickness is 5 ~ 50nm, after being coated with the first niobium pentaoxide rete, enter silicon target target position, preferred Ar tolerance is at 200sccm, O
2tolerance controls to adopt PID to control, and control voltage is at 420V, and preferred sputtering pressure is 3 × 10
-3, target used is twin target, adopts Mid frequency alternative magnetron sputtering method to be coated with the first silica coating 032 on the first niobium pentaoxide rete 031.The refractive index that first silica coating 032 corresponds to 550nm is 1.40 ~ 1.50, and thickness is 30 ~ 100nm.Glass substrate 01 continues through bringing-up section, reaches about 350 DEG C enter AZO target position in temperature, and AZO target is more than 2% doping, and preferred Ar tolerance is at 300sccm, and preferred sputtering pressure is 5 × 10
-3, be HTHP sputtering technology, adopt magnetically controlled DC sputtering to be coated with AZO rete 04 on the first silica coating 032.The thickness of AZO rete 04 is 50 ~ 300nm, and the refractive index of corresponding 550nm is 1.80 ~ 1.95, and resistivity is 5 × 10
-4Ω/cm.Thus complete being coated with of disappear shadow layer 03 and AZO rete 04.
Further, make to plate the disappear glass of shadow layer 03 and AZO rete 04 and enter niobium target target position and silicon target target position successively, be coated with anti-reflection film in glass air face.First enter niobium pentaoxide target position, preferred Ar tolerance at 200sccm, preferred O
2tolerance is at 100sccm, and preferred sputtering pressure is 3 × 10
-3, target used is twin target, adopts Mid frequency alternative magnetron sputtering in the air surface of glass substrate 01, be coated with the second niobium pentaoxide rete 022.After being coated with the second niobium pentaoxide rete 022, enter silicon target target position, preferred Ar tolerance is at 200sccm, O
2tolerance controls to adopt PID to control, and control voltage is at 420V, and preferred sputtering pressure is 3 × 10
-3, target used is twin target, adopts Mid frequency alternative magnetron sputtering to be coated with the second silica coating 021 on the second niobium pentaoxide rete 022.Obtain anti-reflection film.Thus complete transmission increasing and to disappear the making of shadow AZO electro-conductive glass.
The transmission increasing made by the said method shadow AZO electro-conductive glass that disappears is had simultaneously and disappears shadow and increase the effect of light transmittance, makes the performance of this product, outward appearance reaches requirement in field of electronic display application.And antireflection layer 02 and the shadow layer 03 that disappears are divided into the both sides of glass substrate 01, technique are simplified and adjustability raising, reduce complexity and the uncertainty of plated film, improving product yield.The method is simple to operate, with low cost, is very suitable for suitability for industrialized production.
In other embodiments, the shadow layer 03 that disappears can thickness be 1.0mm electron level soda-lime-silica glass be substrate, uses magnetron sputtering coater, and adopt Mid frequency alternative magnetron sputtering to be coated with refractive index matching layers (IM layer), Ar tolerance is at 180sccm, O
2tolerance, at 60sccm, ensures that sputtering pressure is 2.5 × 10
-3, niobium target used is twin target, and adopt Mid frequency alternative magnetron sputtering on glass substrate 01, be coated with the first niobium pentaoxide rete 031, the thickness that this technique plates out is probably at 12nm.On the first niobium pentaoxide rete 031, be coated with first silica coating 032 of 38nm subsequently, preferred Ar tolerance is at 150 ~ 200sccm, O
2tolerance controls to adopt PID to control, and control voltage is at 420V, and preferred sputtering pressure is 2.5 × 10
-3, target used is twin target, adopts Mid frequency alternative magnetron sputtering method.The glass substrate 01 of the refractive index matching layers (IM layer) plated continues through bringing-up section, and reach about 350 DEG C in temperature and enter AZO target position, AZO target is 2% doping, and preferred Ar tolerance is at 250sccm, and preferred sputtering pressure is 6.5 × 10
-3, adopt magnetically controlled DC sputtering to be coated with 120nmAZO rete 04 on the first silica coating 032.
The transmission increasing that the utility model provides disappears the device that shadow AZO electro-conductive glass is applicable to containing touch-screen, the utility model provides a kind of contactor control device further, it at least comprises a substrate, namely this substrate can adopt above-mentioned transmission increasing to disappear shadow AZO electro-conductive glass, and AZO rete 04 is wherein etched into touch control electrode.Adopt the clear exquisiteness of the picture of the contactor control device of this AZO electro-conductive glass, without the interference of etching line, and brightness is high, improves Consumer's Experience further, is applicable to extensively adopting.
The foregoing is only preferred embodiment of the present utility model; not in order to limit the utility model; all do within spirit of the present utility model and principle any amendment, equivalent to replace and improvement etc., all should be included within protection domain of the present utility model.
Claims (5)
1. transmission increasing disappears a shadow AZO electro-conductive glass, it is characterized in that, comprises glass substrate, is stackedly arranged at the antireflection layer on described glass substrate one surface and the stacked shadow layer that disappears being arranged at described another surface of glass substrate, described in the disappear surface of shadow layer be provided with AZO rete; When the described shadow layer surface that disappear is provided with AZO rete and when not being provided with AZO rete to the difference of visible light reflectance lower than 2%, described transmission increasing disappears the overall transmitance of shadow AZO electro-conductive glass higher than 87%.
2. transmission increasing as claimed in claim 1 disappears shadow AZO electro-conductive glass, it is characterized in that, the described shadow layer that disappears comprises the first niobium pentaoxide rete or the first titanium oxide film layer and the first silica coating that are cascading from described glass substrate, the refractive index that described first niobium pentaoxide rete corresponds to 550nm is 2.20 ~ 2.40, thickness is 5 ~ 50nm, the refractive index that described first silica coating corresponds to 550nm is 1.40 ~ 1.50, and thickness is 30 ~ 100nm.
3. transmission increasing as claimed in claim 1 disappears shadow AZO electro-conductive glass, it is characterized in that, described antireflection layer comprises the second silica coating and the second niobium pentaoxide rete or the second titanium oxide film layer that set gradually from described glass substrate, the refractive index that described second silica coating corresponds to 550nm is 1.40 ~ 1.50, thickness is 5 ~ 50nm, the refractive index that described second niobium pentaoxide rete corresponds to 550nm is 2.20 ~ 2.40, and thickness is 40 ~ 100nm.
4. transmission increasing as claimed in claim 1 disappears shadow AZO electro-conductive glass, and it is characterized in that, the thickness of described AZO rete is 50 ~ 300nm, and the refractive index of corresponding 550nm is 1.80 ~ 1.95, and resistivity is 5 × 10
-4Ω/cm.
5. a contactor control device, is characterized in that, at least comprises a substrate, and described substrate adopts the transmission increasing described in any one of Claims 1 to 4 to disappear shadow AZO electro-conductive glass, and the disappear AZO etched film of shadow AZO electro-conductive glass of described transmission increasing becomes touch control electrode.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105084773A (en) * | 2015-05-13 | 2015-11-25 | 信义光伏产业(安徽)控股有限公司 | Anti-reflection vanishing AZO conductive glass, and manufacture method and touch control apparatus thereof |
CN105353930A (en) * | 2015-11-17 | 2016-02-24 | 信义光伏产业(安徽)控股有限公司 | OGS capacitive touch screen, preparation method thereof and touch display device |
CN106587655A (en) * | 2017-01-23 | 2017-04-26 | 蚌埠玻璃工业设计研究院 | Shadow-eliminating and reflection-reducing conductive glass |
CN107162438A (en) * | 2017-06-19 | 2017-09-15 | 合肥市惠科精密模具有限公司 | A kind of method of TFT LCD glass substrate double-sided coatings |
-
2015
- 2015-05-13 CN CN201520307659.1U patent/CN204674125U/en active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105084773A (en) * | 2015-05-13 | 2015-11-25 | 信义光伏产业(安徽)控股有限公司 | Anti-reflection vanishing AZO conductive glass, and manufacture method and touch control apparatus thereof |
CN105353930A (en) * | 2015-11-17 | 2016-02-24 | 信义光伏产业(安徽)控股有限公司 | OGS capacitive touch screen, preparation method thereof and touch display device |
CN106587655A (en) * | 2017-01-23 | 2017-04-26 | 蚌埠玻璃工业设计研究院 | Shadow-eliminating and reflection-reducing conductive glass |
CN107162438A (en) * | 2017-06-19 | 2017-09-15 | 合肥市惠科精密模具有限公司 | A kind of method of TFT LCD glass substrate double-sided coatings |
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