CN2045736U - Carbon dioxide generator - Google Patents

Carbon dioxide generator Download PDF

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Publication number
CN2045736U
CN2045736U CN89202640U CN89202640U CN2045736U CN 2045736 U CN2045736 U CN 2045736U CN 89202640 U CN89202640 U CN 89202640U CN 89202640 U CN89202640 U CN 89202640U CN 2045736 U CN2045736 U CN 2045736U
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CN
China
Prior art keywords
carbonic acid
acid gas
flue
calcining
preheating
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Withdrawn
Application number
CN89202640U
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Chinese (zh)
Inventor
于洪喜
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Individual
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Individual
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Priority to CN89202640U priority Critical patent/CN2045736U/en
Publication of CN2045736U publication Critical patent/CN2045736U/en
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Abstract

The utility model relates to a shaft furnace type carbon dioxide generator which takes limestone as raw material and takes coal as fuel, characterized in that the center of the generator is provided with a furnace liner made of heat resistant steel, and the furnace liner is internally provided with ores and is heated from outside, thus making a heating source and the heated ores be separated. The generator can obtain a great number of high-purity carbon dioxides and a great number of high-purity limes and magnesia. The utility model is suitable for producing the carbon dioxide in big industries.

Description

Carbon dioxide generator
What the present invention relates to is a kind ofly to do raw material with Wingdale, and coal is made the shaft furnace formula carbonic acid gas producer of fuel.
At present, the production method of the carbon dioxide in the kiln gas that the extraction mechanize shaft furnace production lime that the production of carbonic acid gas is both at home and abroad adopted produces, the carbon dioxide content in the kiln gas is at 35-42%, and content is lower.Because shaft furnace up-down structure basically identical, the coal charge multifuel combustion ventilates up and down, thereby impurity and harmful substance contents are very high in the carbon dioxide gas that produces.The mechanize shaft furnace is given the very bad control of wind in operation, give wind many in the kiln gas carbonic acid gas ratio reduce, temperature is too high, causes the big or dross of purification amount.In kiln gas, extract carbonic acid gas, need huge equipment for purifying, a large amount of alkali, various medicaments, hot gas etc., cost is quite high.The carbon dioxide gas purity of Ti Quing is not high in this way, and quality is difficult to guarantee.A kind of high-pureness carbon dioxide producer---electrothermic type carbon-dioxide generator.Be to do flue by silicon carbide, nichrome wire is equipped with in the flue outside, energising heats up, when being warmed up to 350-400 ℃, ore shuts fire door, after opening purging valve and bleeding off the not high carbon dioxide of purity, shut purging valve, producer begins works better, the carbon dioxide gas of producing with this stove adsorbs purification through cleaner, and purity can reach 99.5-99.9%.But, can not do raw material with Wingdale because this producer maximum operating temperature can only reach 950 ℃, thereby can only use the higher low-temperature decomposition raw material of cost.Current consumption is big, and output is little, under the relatively nervous situation of China's electric power, is unsuitable for big industrial production, and economic benefit is also undesirable.
Purpose of the present invention is exactly to design a kind of novel carbonic acid gas producer, this stove had both absorbed the mechanize shaft furnace and had done raw material with Wingdale, coal is done the big industrial characteristics of fuel, having absorbed the electrothermic type carbon-dioxide generator again heats outside flue, the ore of heating source and heating separately, can obtain the characteristics of high-pureness carbon dioxide, traditional firing mode is come a thoroughly change.
Carbonic acid gas producer of the present invention be by be positioned at body of heater top and bottom into and out of batch can, the preheating section on top, the calcining section at middle part, the vexed grey chamber and the cooling room of bottom, the combustion chamber of body of heater outside and the monitoring CO 2Concentration, the electrical control system of control furnace temperature is formed.
The preheating section that is positioned at upper of furnace body has a preheating flue that is positioned at waste heat burner hearth center of being made by 3Cr13Ni7Si2 high temperature steel, the preheating flue can worked below 700 ℃, for heat conductivility that improves the preheating flue and the erosion resistance that improves steel plate, scribble the high-temperature infrared wire material in the both sides of preheating flue, the effect of preheating flue is the Wingdale ore that is used in the waste heat heating input stove of calcining section.Because entering the waste heat of preheating section, the calcining section can reach 600 ℃-800 ℃, only do not absorb by the ore that enters the preheating flue, thereby be equipped with the jet flow water cooler in the outside of waste heat burner hearth, this jet flow water cooler is a cylinder that is equipped with numerous aperture on barrel, be divided into three sections outsides that are trapped among the waste heat burner hearth, when freezing air when the blast inlet of preheating section bottom enters water cooler, utilize the high flow rate of freezing air that heat is taken away, the warm air that heats is by to enter the combustion chamber combustion-supporting with the anastomosing hot-blast outlet in combustion chamber.The skin of jet flow water cooler is to accompany perlitic thermal insulation layer in the middle of the two-layered steel plates.
Be positioned at calcining Duan Youyi the calcining flue of being made by 1Cr25Ni20Si2 high temperature steel at body of heater middle part, the calcining flue places the center of high-temperature burner hearth, and is connected with the preheating flue.In order to improve radiation capacity and the corrosion resistance and the tear resistance of calcining flue, both side surface at the calcining flue scribbles the high-temperature infrared wire material, when the ore that is heated to 700 ℃ in the preheating flue enters the calcining flue, high heat by high-temperature burner hearth is Wingdale reheat to 800 ℃-1100 ℃, and at this moment ore begins to resolve into CaCO 3And CO 2Temperature in the high-temperature burner hearth is mounted on the thermopair and the outer electric heating control table of body of heater of this section and controls, the air door umformer of electrothermal meter and gas blower links together and controls the size of air output, makes the temperature in the high-temperature burner hearth be controlled at the optimum temps that ore decomposes all the time.The thermal insulation layer of forming with lagging material that is built into by refractory brick at the skin of high-temperature burner hearth.
Bottom in the calcining section, the top of cooling room is a vexed grey chamber, 800 ℃ material under the calcining section keeps temperature to continue to decompose at this, when material is reduced to indissoluble temperature, enter water cooler, water cooler is made up of many cooling tubes, and being inserted in needs in the middle of the refrigerative lime, by the high pressure cold wind that enters in the pipe heat is taken away, heated freezing air enters combustion chamber hot blast passage and carries out secondary to mend wind combustion-supporting by being contained in outlet this chamber and that communicate with combustion chamber hot blast passage.
The combustion chamber is positioned at the body of heater outside, on the workplatform of calcining section lower end, communicated with a calcining section high-temperature burner hearth by hot-air channel, the combustion chamber is provided with from the heating duct of preheating section with from the secondary secondary air channel of cooling section, coal is sent into calcining section burner hearth after the combustion chamber is combustion-supporting by hot blast.Build by laying bricks or stones with ordinary red brick this outside, combustion chamber, and liner is built into refractory brick, is provided with two thermopairs in the combustion chamber, and the temperature and the hot-air channel mouth temperature of monitoring combustion chamber are with the temperature of control calcining section high-temperature burner hearth.
Be provided with a charging stock tank at the top of body of heater, a feeding gate is arranged at the top of jar, a bell is arranged at the bottom, when material loading in stove, the bell of closing the batch can bottom earlier guarantees the absolute sealing of flue, after material is filled it up with, feeding gate is closed, the air of outside can not be sneaked into, open bell, ore flows in the flue.
Be positioned at the discharge tank of furnace bottom, also be provided with two doors, the discharge door of the feeding gate on batch can top and batch can bottom at the two ends up and down of jar.When wanting discharging, close discharge door earlier, open feeding gate, allow the lime stream batch can that overfills, close feeding gate then, open discharge door.
CO 2Enter next process by the air outlet that is placed on cooling room.
This carbonic acid gas producer is provided with an electric control system, comprises an electric control platform, an electric heating control table and a CO 2Monitor.Can measure controlled temperature, coal consumption, ore amount, kiln gas free air delivery, drop temperature, carbonic acid gas free air delivery at any time, to air quantity etc.
Carbonic acid gas producer of the present invention, carbon dioxide content adds purification up to 95-99% with anti-method of purification in the furnace gas, carbon dioxide purity can reach 99.5-99.99%, the easily control of heating can make to form the big area high temperature section in the burner hearth and do not make the raw material burning, dross.Its main products Wingdale and magnesium oxide purity height, output height, full scale production are realized control automatically.
Diagram describes the present invention with reference to the accompanying drawings below.
Figure: carbonic acid gas producer sectional view, wherein:
1. furnace shell steel plate charging stock tank 2.(preheating section)
3. perlite 4. jet flows three terraced water coolers
5. waste heat burner hearth 6. preheating flues
7. inlet of cold air 8. is calcined flues
9. high-temperature burner hearth 10. refractory brick
11. lagging material 12.(calcines section) the furnace shell steel plate
13. hot-air channel 14. hot air inlets
15. vexed grey chambers 16., combustion chamber
17. cooling cold wind import 18. cooling tubes
19.CO 2Export 20. electric control platforms
21. discharge tank 22. cooling hot-blast outlets
23. hot air outlet 24. secondaries are mended wind inlet
25.(furnace wall cooling room)
Preheating flue (6) upper end is communicated with charging stock tank (1), the lower end is communicated with calcining flue (8), in whole body of heater, be formed centrally a raw material flow process thorax, in the outside of preheating flue is the waste heat burner hearth (5) that a steel plate surrounds, the steel plate outside at the waste heat burner hearth is to be equipped with many eyelets above three, and be divided into the jet flow three terraced water coolers (4) that three stepwise cylinders are formed, upper and lower ends at jet flow three terraced water coolers, be welded with inlet of cold air (7) and hot air outlet (23) on the furnace shell steel plate (2), the hot air inlet (14) of hot air outlet and combustion chamber (15) joins.
Outside at calcining flue (8) is the high-temperature burner hearth (9) that a refractory brick (10) is built into, and high-temperature burner hearth communicates with the waste heat burner hearth, has a hot-air channel (13) to communicate with the combustion chamber on the furnace wall, lower end of high-temperature burner hearth.Vexed grey chamber (16) joins with the calcining section, communicates with the calcining flue.Many horizontal, vertical cooling tubes (18) are housed in the lower end of vexed grey chamber, and cooling cold wind import (17) and cooling hot-blast outlet (22), carbonic acid gas outlet (19) are welded on respectively on the cooling room furnace wall (25).The cooling hot-blast outlet communicates with secondary wind-supplying mouth (24) on the hot-air channel.
The thermal insulation layer of preheating section is to accompany perlite (3) by two-layered steel plates to constitute.The thermal insulation layer of calcining section is to be made of furnace shell steel plate (12) the folder lagging material (11) of refractory brick with the calcining section.Thermopair on electric control platform (20) and the stove and the position that needs to monitor are connected.

Claims (12)

1, a kind ofly does raw material with Wingdale, coal is made the shaft furnace formula carbonic acid gas producer of fuel, it is characterized in that it be by be positioned at body of heater top and bottom into and out of batch can, the preheating section on top, the calcining section at middle part, the vexed grey chamber and the cooling room of bottom, the combustion chamber of body of heater outside is formed;
2, carbonic acid gas producer according to claim 1 is characterized in that preheating section is by the preheating flue that places the waste heat burner hearth, places the outer water cooler of waste heat burner hearth, is welded on the cold wind import on the outside steel plate of thermal insulation layer, and hot-blast outlet is formed;
3, according to claim 1, the preheating section of 2 described carbonic acid gas producers, what it is characterized in that water cooler uses is jet flow three terraced water coolers;
4, according to claim 1, the preheating section of 2 described carbonic acid gas producers, what it is characterized in that the preheating flue uses is 3Cr13Ni7Si2 high temperature steel;
5, according to claim 1, the preheating flue of 2,4 described carbonic acid gas producer preheating sections is characterized in that the steel plate both sides of preheating flue scribble the high-temperature infrared wire material;
6, carbonic acid gas producer according to claim 1, it is characterized in that the section of calcining is the high-temperature burner hearth that is communicated with the combustion chamber by hot-air channel, put with high-temperature burner hearth in, and with the calcining flue that the preheating flue joins, form by the thermal insulation layer that refractory brick and lagging material constitute;
7, according to claim 1, the calcining section of 6 described carbonic acid gas producers is characterized in that calcining that flue uses is 1Cr25Ni20Si2 high temperature steel;
8, according to claim 1, the calcining flue of 6,7 described carbonic acid gas producer calcining sections is characterized in that scribbling the high-temperature infrared wire material in calcining flue steel plate both sides.
9, carbonic acid gas producer according to claim 1 is characterized in that cooling room is by placing indoor water cooler, be contained in the cooling cold wind import on the furnace wall, cooling hot-blast outlet and CO 2Outlet pipe is formed.
10, according to claim 1, the cooling room of 9 described carbonic acid gas producers is characterized in that water cooler is by the molecular wind pipe type water cooler of plurality of tubes.
11, carbonic acid gas producer according to claim 1 is characterized in that the top of charging stock tank is provided with feeding gate, and the bottom is provided with bell.
12, carbonic acid gas producer according to claim 1 is characterized in that the top of discharge tank is provided with feeding gate, and the bottom is provided with discharge door.
CN89202640U 1989-03-15 1989-03-15 Carbon dioxide generator Withdrawn CN2045736U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN89202640U CN2045736U (en) 1989-03-15 1989-03-15 Carbon dioxide generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN89202640U CN2045736U (en) 1989-03-15 1989-03-15 Carbon dioxide generator

Publications (1)

Publication Number Publication Date
CN2045736U true CN2045736U (en) 1989-10-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN89202640U Withdrawn CN2045736U (en) 1989-03-15 1989-03-15 Carbon dioxide generator

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CN (1) CN2045736U (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102531416A (en) * 2011-12-26 2012-07-04 建德市天石碳酸钙有限责任公司 Energy-saving lime kiln
CN104261700A (en) * 2014-10-20 2015-01-07 李正福 Device and method for manufacturing dry ice by utilizing radiant heat to produce active lime
CN105571314A (en) * 2015-12-17 2016-05-11 李华梅 Microwave carbon process magnesium smelting furnace
CN106675655A (en) * 2016-12-06 2017-05-17 西安交通大学 Device and method for biomass chemical chain gasification hydrogen production based on calcium-based carbon supporting body

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102531416A (en) * 2011-12-26 2012-07-04 建德市天石碳酸钙有限责任公司 Energy-saving lime kiln
CN102531416B (en) * 2011-12-26 2013-07-10 建德市天石碳酸钙有限责任公司 Energy-saving lime kiln
CN104261700A (en) * 2014-10-20 2015-01-07 李正福 Device and method for manufacturing dry ice by utilizing radiant heat to produce active lime
CN105571314A (en) * 2015-12-17 2016-05-11 李华梅 Microwave carbon process magnesium smelting furnace
CN105571314B (en) * 2015-12-17 2017-11-17 李华梅 Microwave carbon method magnesium refining furnace
CN106675655A (en) * 2016-12-06 2017-05-17 西安交通大学 Device and method for biomass chemical chain gasification hydrogen production based on calcium-based carbon supporting body
CN106675655B (en) * 2016-12-06 2019-06-11 西安交通大学 A kind of biomass chemical chain gasification device for producing hydrogen and method based on calcium base carbon carrier

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GR01 Patent grant
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
RN01 Renewal of patent term
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
RN01 Renewal of patent term
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee