CN204509427U - By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed - Google Patents
By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed Download PDFInfo
- Publication number
- CN204509427U CN204509427U CN201520140023.2U CN201520140023U CN204509427U CN 204509427 U CN204509427 U CN 204509427U CN 201520140023 U CN201520140023 U CN 201520140023U CN 204509427 U CN204509427 U CN 204509427U
- Authority
- CN
- China
- Prior art keywords
- cooling tank
- crystallizer
- vibration
- crystallization
- inner core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
The utility model discloses a kind of device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution, comprise cooling tank and crystallizer, cooling tank is the long tubular construction of jacketed type of inner core and urceolus composition and longitudinally arranges, inner core cross section is regular polygon; Rotating shaft from inner core longitudinally through, fiber brush bundle implanted by bristle in rotating shaft drum; Cooling tank inner core is in communication with the outside through airduct and vacuum fan and forms air-cooled circuit; Cooling tank chuck and return water pipe, water cooling tower, water circulating pump and water inlet pipe form Water-cooling circulating circuit; Cooling tank chuck connects the water hammer vibrator of crankshaft-link rod and piston composition; Be provided with solution inlet pipe to be crystallized above cooling tank, below is connected crystallizer through wedged bottom groove, chute with underflow pipe; Crystallizer is cone bottom structure, and the cone end connects filter vibration through mortar pump and sieves.The utility model design is unique, ingenious, practical, provides the device of calcium ions and magnesium ions in a kind of removal manganese sulfate solution of perfect in shape and function, has a extensive future.
Description
Technical field
The utility model relates to a kind of device removed by calcium ions and magnesium ions crystallisation by cooling after vibration in manganese sulfate solution.
Background technology
Xiangxi Autonomous Prefecture is the main producing region of manganese, and one of " manganese triangle " that Ye Shishi China is famous, has the good reputation of " east manganese is all ", but the manganese resource of this area mostly and calcium, magnesium ion symbiosis.
The process for processing of manganese be all generally manganese ore is beaten after powder with sulfuric acid chemical combination, then press filtration, electrolysis, due to the existence of calcium ions and magnesium ions a large amount of in manganese sulfate solution, not only wastes power, affect the purity of manganese product, also easily cause electrolyzer to block, impact is produced, therefore, calcium magnesium vitriol in manganese sulfate solution is removed, there is important actual application value and industrialization meaning.
Solubleness is lower at low temperatures for calcium magnesium vitriol, its solubleness is comparatively responsive to temperature, thus can be removed after the calcium magnesium sulphate crystal in manganese sulfate solution by the mode of cooling, but lack the complexes removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution in prior art, the breakthrough of complexes needs to overcome that cooling tank inwall effective heat exchange area is little, efficiency is low, be difficult to be separated after cooling tank inwall crystallization attachment and remove, crystallizer such as easily to block at many technical bottlenecks.
Utility model content
The technical problems to be solved in the utility model overcomes the deficiencies in the prior art exactly, a kind of perfect in shape and function is provided, the cooling tank coefficient of heat transfer is high, speed of cooling is fast, be convenient to be separated after cooling tank inwall crystallization attachment, even if be also easy to the complexes removed by calcium ions and magnesium ions crystallisation by cooling after vibration in manganese sulfate solution solved after crystallizer blocking.
For overcoming the deficiencies in the prior art, the utility model takes following technical scheme:
By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed, comprise cooling tank and crystallizer, it is characterized in that: cooling tank is the long tubular construction of jacketed type of inner core and urceolus composition and longitudinally arranges, inner core cross section is regular polygon; Rotating shaft from inner core longitudinally through, fiber brush bundle implanted by bristle in rotating shaft drum; Cooling tank inner core is in communication with the outside through airduct and vacuum fan and forms air-cooled circuit; Cooling tank chuck and return water pipe, water cooling tower, water circulating pump and water inlet pipe form Water-cooling circulating circuit; Cooling tank chuck connects the water hammer vibrator of crankshaft-link rod and piston composition; Be provided with solution inlet pipe to be crystallized above cooling tank, below is connected crystallizer through wedged bottom groove, chute with underflow pipe; Crystallizer is cone bottom structure, and the cone end connects filter vibration through mortar pump and sieves.
Described cooling tank inner core be provided with adjustable with fiber brush bundle distance except crystalline style.
Described crystallizer is provided with vibrator.
Described crystallizer top connects overflow groove.
Described crystallization tank body is communicated with at the bottom of crystallizer with anti-blocking pump through pipeline.
The liquid exit of described filter vibration sieve connects crystallizer, and solid outlet connects crystal groove.
Described rotating shaft is fixed by upper and lower bearing support, is driven and rotates, be provided with anti-bucket above step by belt pulley.
Device is made up of two portions, heat exchange cooling and Crystallization Separation, and heat-exchanger rig is formed primarily of the fiber brush bundle of reasonable Arrangement in inner core, urceolus, rotating shaft and rotating shaft, and the chuck that inner core and urceolus are formed is hydrologic cycle cooling system.
During device running, solution to be crystallized is introduced by inlet pipe, start air-cooled circuit and and Water-cooling circulating circuit, solution to be crystallized flows out from top to bottom, air is pumped by blower fan through inner core from lower to upper, solution is rotarily driven by fiber brush bundle and forms reverse-flow direct contact heat transfer with airflow and water evaporates fast cooling, simultaneously from the cold water of water cooling tower also by partition and solution high efficient heat exchanging, dual function makes solution temperature to be crystallized decline fast.
Temperature declines and makes part calcium ions and magnesium ions crystallization on cooling tank inwall and fiber brush bundle, when fiber brush bundle is by the attachment of comparatively polycrystal, can operate except crystalline style completes cleaning operation close to or far away from fiber brush Shu Peihe axis of rotation; When cooling tank inwall has more crystallization, the water hammer vibrator of crankshaft-link rod and piston composition can be started, make dilation in tank body elastic range by high-low pressure Aquapulse, the crystallization of cooling tank inwall be peeled off and comes off.
Cooled solution enters bottom crystallizer by chute, underflow pipe, liquid by bottom enter rising flooding process due to condensate depression very high, calcium magnesium vitriol wherein can crystallization sedimentation rapidly, mortar pump is started when needing, extract magma to filtration vibratory screening apparatus, calcium ions and magnesium ions vibration after crystallization exports at crystal groove, and the solution after filtration flows back to crystallizer and carries out recrystallization process.
When crystallizer bottom deposit crystal too much causes blocking, anti-blocking pump can be opened and stir loose mouth of pipe place crystal, restart mortar pump and complete crystal conveying separation; When the crystallization of crystallizer tank skin is more, the vibrator that can start many reasonable set layout makes crystal peel off output.
Solution after crystallizer intercrystalline goes scratch pool to store by overflow groove, carries out next step electrolytic manganese operation.
Compared with prior art, the beneficial effects of the utility model are also:
Overcome the cooling tank coefficient of heat transfer low, the defect that speed of cooling is slow, air-flow cooling is all efficient countercurrent flow in conjunction with partition water cooling, also the ingenious fiber brush bundle that make use of rotates the stirring of solution and gets rid of to barrel process, fiber brush bundle attaching liq and air-flow heat exchange, and solution and barrel has very large effective heat exchange area and the heat exchange efficiency of solution inside is also very high, thus heat exchange flow is very big.
Operation except crystalline style can close to away from fiber brush bundle, coordinate axis of rotation can the convenient crystal cleaning operation completed on fiber brush bundle.
Water hammer vibrator uses high-low pressure Aquapulse to make dilation in tank body elastic range that inwall crystallization is peeled off to come off, simple, ingenious, to equipment without any damage, and the regular polygon structure of inner core that crystal is come off is efficient especially, thoroughly.
Pump recoil is used to dredge the crystal blocking of crystallizer, simple and reliable, ingenious.
The utility model design is unique, ingenious, practical, provides the device of calcium ions and magnesium ions in a kind of removal manganese sulfate solution of perfect in shape and function, has a extensive future.
Accompanying drawing explanation
Fig. 1 is two dimensional structure schematic diagram of the present utility model.
Fig. 2 is the structure for amplifying schematic diagram of water hammer vibrator.
Fig. 3 is the A-A cross section structure schematic diagram of cooling tank.
In figure, each label represents:
1, fiber brush bundle; 2, solution inlet pipe to be crystallized; 3, except crystalline style; 4, airduct; 5, vacuum fan; 7, return water pipe; 8, crankshaft-link rod; 9, piston; 10, valve; 11, water cooling tower; 12, water circulating pump; 13, valve; 14 water inlet pipes; 15, inner core; 16, rotating shaft; 16-1, bristle drum; 16-2, anti-bucket; 16-3, bearing support; 16-4, belt pulley; 17, chute; 17-1, wedged bottom groove; 18, urceolus; 19, overflow groove; 20, underflow pipe; 21, crystallizer; 23, filter vibration sieve; 24, vibrator; 25, crystal groove; 26, mortar pump; 28, anti-blocking pump.
Embodiment
Now by reference to the accompanying drawings, the utility model is illustrated further.
As shown in Figure 1, Figure 2 and Figure 3 by the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed, comprise cooling tank and crystallizer 21, cooling tank is the long tubular construction of jacketed type of inner core 15 and urceolus 18 composition and longitudinally arranges, inner core cross section is regular polygon; Rotating shaft 16 from inner core 15 longitudinally through, bristle in rotating shaft drum 16-1 implants fiber brush bundle 1; Cooling tank inner core 15 is in communication with the outside through airduct 4 and vacuum fan 5 and forms air-cooled circuit; Cooling tank chuck and return water pipe 7, water cooling tower 11, water circulating pump 12 and water inlet pipe 14 form Water-cooling circulating circuit; Cooling tank chuck connects the water hammer vibrator of crankshaft-link rod 8 and piston 9 composition; Be provided with solution inlet pipe 2 to be crystallized above cooling tank, below is connected crystallizer 21 through wedged bottom groove 17-1, chute 17 with underflow pipe 20; Crystallizer 21 is cone bottom structure, and the cone end connects filter vibration through mortar pump 26 and sieves 23.
Described cooling tank inner core be provided with adjustable with fiber brush bundle distance except crystalline style 3.
Described crystallizer is provided with vibrator 24.
Described crystallizer top connects overflow groove 19.
Described crystallization tank body is communicated with at the bottom of crystallizer with anti-blocking pump 28 through pipeline.
The liquid exit of described filter vibration sieve 23 connects crystallizer 21, and solid outlet connects crystal groove 25.
Described rotating shaft 16 is fixed by upper and lower bearing support 16-3, is driven and rotates, be provided with anti-bucket 16-2 above step by belt pulley 16-4.
Device is made up of two portions, heat exchange cooling and Crystallization Separation, and heat-exchanger rig is formed primarily of the fiber brush bundle 1 of reasonable Arrangement in inner core 15, urceolus 18, rotating shaft 16 and rotating shaft, and the chuck that inner core 15 and urceolus 18 are formed is hydrologic cycle cooling system.
During device running, solution to be crystallized is introduced by inlet pipe 2, start air-cooled circuit and and Water-cooling circulating circuit, solution to be crystallized flows out from top to bottom, air is pumped by blower fan 5 through inner core from lower to upper, solution is rotarily driven by fiber brush bundle 1 and forms reverse-flow direct contact heat transfer with airflow and water evaporates fast cooling, simultaneously from the cold water of water cooling tower 11 also by partition and solution high efficient heat exchanging, dual function makes solution temperature to be crystallized decline fast.
Temperature declines and makes part calcium ions and magnesium ions crystallization on cooling tank inwall and fiber brush bundle, when fiber brush bundle 1 is by the attachment of comparatively polycrystal, can operate except crystalline style 3 coordinates rotating shaft 16 to rotate cleaning operation close to or far away from fiber brush bundle 1; When cooling tank inwall has more crystallization, the water hammer vibrator of crankshaft-link rod 8 and piston 9 composition can be started, make dilation in tank body elastic range by high-low pressure Aquapulse, the crystallization of cooling tank inwall be peeled off and comes off.
Cooled solution enters bottom crystallizer 21 by chute 17, underflow pipe 20, liquid by bottom enter rising flooding process due to condensate depression very high, calcium magnesium vitriol wherein can crystallization sedimentation rapidly, mortar pump 26 is started when needing, extract magma to filtration vibratory screening apparatus 23, calcium ions and magnesium ions vibration after crystallization exports at crystal groove 25, and the solution after filtration flows back to crystallizer 21 and carries out recrystallization process.
When crystallizer 21 bottom deposit crystal too much causes blocking, anti-blocking pump 28 can be opened and stir loose mouth of pipe place crystal, restart mortar pump 26 and complete crystal conveying separation; When the crystallization of crystallizer 21 tank skin is more, the vibrator 24 that can start many reasonable set layout makes crystal peel off output.
Solution after crystallizer intercrystalline goes scratch pool to store by overflow groove 19, carries out next step electrolytic manganese operation.
Above-mentioned just preferred embodiment of the present utility model, not does any pro forma restriction to the utility model.Any those of ordinary skill in the art, when not departing from technical solutions of the utility model scope, the technology contents of above-mentioned announcement all can be utilized to make many possible variations and modification to technical solutions of the utility model, or be revised as the Equivalent embodiments of equivalent variations.Therefore, every content not departing from technical solutions of the utility model, according to the utility model technical spirit to any simple modification made for any of the above embodiments, equivalent variations and modification, all should drop in the scope of technical solutions of the utility model protection.
Claims (7)
1. by the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed, comprise cooling tank and crystallizer, it is characterized in that: cooling tank is the long tubular construction of jacketed type of inner core and urceolus composition and longitudinally arranges, inner core cross section is regular polygon; Rotating shaft from inner core longitudinally through, fiber brush bundle implanted by bristle in rotating shaft drum; Cooling tank inner core is in communication with the outside through airduct and vacuum fan and forms air-cooled recycle circuit; Cooling tank chuck and return water pipe, water cooling tower, water circulating pump and water inlet pipe form Water-cooling circulating circuit; Cooling tank chuck connects the water hammer vibrator of crankshaft-link rod and piston composition; Be provided with solution inlet pipe to be crystallized above cooling tank, below is connected crystallizer through wedged bottom groove, chute with underflow pipe; Crystallizer is cone bottom structure, and the cone end connects filter vibration through mortar pump and sieves.
2. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: described cooling tank inner core be provided with adjustable with fiber brush bundle distance except crystalline style.
3. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: described crystallizer is provided with vibrator.
4. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: described crystallizer top connects overflow groove.
5. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: described crystallization tank body is communicated with at the bottom of crystallizer with anti-blocking pump through pipeline.
6. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: the liquid exit of described filter vibration sieve connects crystallizer, and solid outlet connects crystal groove.
7. the device removed by calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution according to claim 1, is characterized in that: described rotating shaft is fixed by upper and lower bearing support, is driven and rotates, be provided with anti-bucket above step by belt pulley.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520140023.2U CN204509427U (en) | 2015-03-12 | 2015-03-12 | By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520140023.2U CN204509427U (en) | 2015-03-12 | 2015-03-12 | By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204509427U true CN204509427U (en) | 2015-07-29 |
Family
ID=53707421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520140023.2U Expired - Fee Related CN204509427U (en) | 2015-03-12 | 2015-03-12 | By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN204509427U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114146484A (en) * | 2021-11-30 | 2022-03-08 | 聊城鲁西多元醇新材料科技有限公司 | Drying treatment production line and method for circulating water slime |
-
2015
- 2015-03-12 CN CN201520140023.2U patent/CN204509427U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114146484A (en) * | 2021-11-30 | 2022-03-08 | 聊城鲁西多元醇新材料科技有限公司 | Drying treatment production line and method for circulating water slime |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100375714C (en) | Process for preparing anhydrous mirabilite by freezing method | |
| CN206444230U (en) | A kind of big flow forced circulation good antiscale property freezing and crystallizing device | |
| CN104587700A (en) | Thickener | |
| CN204057987U (en) | Saltcake continuous seepage freezing and crystallizing device | |
| CN204509427U (en) | By the device that calcium ions and magnesium ions crystallization after vibration in manganese sulfate solution is removed | |
| US20160221833A1 (en) | Method and System for Preparing High Purity Lithium Carbonate | |
| CN103482660A (en) | Method and system for preparing high-purity lithium carbonate | |
| CN106048262A (en) | Purifying method and purifying apparatus for gallium | |
| CN104674004B (en) | Device for vibratory removal of calcium and magnesium ions in manganese sulfate solution after crystallization | |
| CN109850958A (en) | A kind of discarded printed nickel net recovery and treatment method | |
| CN204455242U (en) | By the device of centrifugation after calcium ions and magnesium ions crystallization in manganese sulfate solution | |
| CN203668013U (en) | Potassium nitrate purification equipment | |
| CN104674003B (en) | A kind of by the device of centrifugation after calcium ions and magnesium ions crystallization in electrolytic manganese solution | |
| CN109971200A (en) | A kind of recycling preparation method of disperse orange dye | |
| CN104674005B (en) | By the device of centrifugation after calcium ions and magnesium ions crystallization in manganese sulfate solution | |
| CN104630472B (en) | A kind of device that calcium ions and magnesium ions crystallization after vibration in electrolytic manganese solution is removed | |
| CN207845410U (en) | A kind of zinc borate production wastewater treatment equipment | |
| CN105174230A (en) | Technology for preparing refined sulfuric acid from smelting waste gas by means of direct absorption method | |
| CN206438094U (en) | One Plant Extracts material concentrator | |
| CN201971934U (en) | Acid bath cooling crystallization device with plate type heat exchanger | |
| CN104692418B (en) | By the device of recovery centrifugal after brine concentration crystallization | |
| CN210009654U (en) | Ammonium sulfate cooling crystallization device | |
| CN209307144U (en) | A kind of circular water treating system | |
| CN202297195U (en) | Refrigeration denitration device for brine rich in nitro | |
| CN208525884U (en) | A kind of magnesium sulfate continuous crystallisation device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150729 Termination date: 20160312 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |