CN207845410U - A kind of zinc borate production wastewater treatment equipment - Google Patents

A kind of zinc borate production wastewater treatment equipment Download PDF

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Publication number
CN207845410U
CN207845410U CN201820030463.6U CN201820030463U CN207845410U CN 207845410 U CN207845410 U CN 207845410U CN 201820030463 U CN201820030463 U CN 201820030463U CN 207845410 U CN207845410 U CN 207845410U
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China
Prior art keywords
outlet
holding vessel
water
connection
solids
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Expired - Fee Related
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CN201820030463.6U
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Chinese (zh)
Inventor
张帅
杨亮亮
牛俊卜
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Shandong Special Paul Environmental Protection And Energy Saving Technology Co Ltd
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Shandong Special Paul Environmental Protection And Energy Saving Technology Co Ltd
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Abstract

The utility model discloses a kind of zinc borate production wastewater treatment equipment, including MVR vapo(u)rization systems, concentrator, centrifuge A, solids holding vessel A, cooler crystallizer, solids holding vessel B, scraper type centrifuge, the water inlet connection waste water water source of MVR vapo(u)rization systems, the water outlet of MVR vapo(u)rization systems connects concentrator, the solids outlet connection centrifuge A of concentrator, supernatant outlet is by connecting scraper type centrifuge after cooler crystallizer, the solids outlet connection solids holding vessel A of centrifuge A, liquid outlet connects the water inlet of MVR vapo(u)rization systems, the solids outlet connection solids holding vessel B of scraper type centrifuge, liquid outlet connects the water inlet of MVR vapo(u)rization systems.This equipment can make that zinc borate produces the sodium sulphate in waste water and boric acid crystallizes precipitations respectively, two kinds of byproducts of recycling, and waste water evaporation process can be carried out continuously, and improve waste water treatment efficiency.

Description

A kind of zinc borate production wastewater treatment equipment
Technical field
The utility model is related to sewage treatment equipment technical fields more particularly to a kind of zinc borate production wastewater treatment to set It is standby.
Background technology
For zinc borate as a kind of novel halogen-free flame retardants, flame retarding efficiency is high, moderate, environmentally friendly, therefore Application prospect is extremely wide, and at home and abroad yield is very big.Currently, zinc borate production technology is mainly borax-zinc sulfate method.This Process will produce a large amount of Na+、Zn2+、SO2- 4、B2O2- 4Type inorganic wastewater (NaSO4Content 18% or so), if without place The directly outer row of reason, will seriously pollute environment, the highly difficult of wastewater treatment constrains production efficiency.
Processing to high-salt wastewater, method the most cost-effective is evaporative crystallization.But to Na+、Zn2+、SO2- 4、 B2O2- 4During type inorganic wastewater is evaporated, it is precipitated with the crystallization of sodium sulphate, mother liquor can be enriched with B in system2O2- 4.When B2O2- 4When being enriched to a certain concentration, a large amount of boric acid fine grain can be generated in vapo(u)rization system, easily block process pipe, and very Difficulty is separated by solid-liquid separation.Gu after evaporating a period of time, it is necessary to which stop brush tank, and evaporation process is made to be difficult to continue progress.Processing is difficult Degree is high, inefficiency.
Invention content
The utility model in view of the deficiencies of the prior art, develops a kind of zinc borate production wastewater treatment equipment, at the waste water Reason equipment can efficiently be handled zinc borate production waste water.
The utility model solve technical problem technical solution be:On the one hand, the embodiments of the present invention provide one Kind zinc borate production wastewater treatment equipment, including MVR vapo(u)rization systems, concentrator, centrifuge A, solids holding vessel A, cooling knot Brilliant device, solids holding vessel B, scraper type centrifuge, the water inlet connection waste water water source of MVR vapo(u)rization systems, MVR vapo(u)rization systems Water outlet connects concentrator, and the solids outlet of concentrator connects centrifuge A, supernatant outlet by being connected after cooler crystallizer Scraper type centrifuge, the solids outlet connection solids holding vessel A of centrifuge A, liquid outlet connection MVR vapo(u)rization systems into The mouth of a river, the water inlet of the solids outlet connection solids holding vessel B, liquid outlet connection MVR vapo(u)rization systems of scraper type centrifuge Mouthful.
As an optimization, the MVR vapo(u)rization systems include that raw water tank, feed pump, temporary storage tank, heat exchanger, separator, steam add Hot equipment, drainer, scratch pool, discharging pump, the water inlet connection waste water water source of raw water tank, the water outlet of raw water tank pass through charging The temporary storage tank of connection is pumped, the water outlet of temporary storage tank connects concentrator by discharging pump, and separator is arranged in the top of temporary storage tank, point Bottom from device is connected to temporary storage tank;The bottom of temporary storage tank is connected to heat exchanger, and cycle is provided between temporary storage tank and heat exchanger It pumps, heating pipeline is provided in heat exchanger, heat the gas outlet of the entrance connection steam-heating apparatus of pipeline, heat going out for pipeline Mouth connects drainer entrance, and steam (vapor) outlet is provided at the top of heat exchanger, and steam (vapor) outlet connects separator, set at the top of separator It is equipped with indirect steam outlet, the air inlet of indirect steam outlet connection steam-heating apparatus;The water outlet connection of drainer is temporary Pond is provided with condensation gas outlet at the top of drainer.Waste water enters heat exchanger after passing sequentially through raw water tank, feed pump, temporary storage tank, Heated pipeline is thermally formed steam, and steam partially changes into liquid after entering separator, part keeps steam condition, liquid into Enter temporary storage tank, steam enters heating tube road after steam-heating apparatus heats and heats stoste.
As an optimization, the MVR vapo(u)rization systems further include preheater, and cold water channel, hot water channel are provided in preheater, Cold water channel is arranged between feed pump and temporary storage tank, and hot water channel is arranged between the water outlet and scratch pool of drainer.
As an optimization, the cross-sectional area of the separator is more than the cross-sectional area of heat exchanger.
As an optimization, the MVR vapo(u)rization systems also condensing gas holding vessel, condensation gas outlet connection condensing gas holding vessel into Gas port, condensing gas holding vessel connect vacuum pump, exhaust passage, the row of condensing gas holding vessel are provided at the top of condensing gas holding vessel The mouth of a river connects scratch pool.
As an optimization, the steam-heating apparatus is compressor.
As an optimization, the compressor is Roots Compressor, single machine high-speed centrifugal compressor, single machine low-speed centrifugal formula Any one in fan-compressor.
As an optimization, the cooler crystallizer is to recycle pipe portion with the DTB type vacuum evaporation crystallizers for forcing outer circulation It is arranged with tubular heat exchanger.
The effect provided in utility model content is only the effect of embodiment, rather than whole effects that utility model is all Fruit, above-mentioned technical proposal has the following advantages that or advantageous effect:
1. equipment can make, zinc borate produces the sodium sulphate in waste water and boric acid crystallizes precipitation respectively, recycles two kinds of by-products Product, and waste water evaporation process can be carried out continuously, and improve waste water treatment efficiency.
2. by using MVR vapo(u)rization systems, the potential of steam is taken full advantage of, discarded steam is utilized, except booting fortune Row is outer, and entire evaporation process is without being passed through steam.
3. by the way that preheater is arranged, thermal energy is taken full advantage of, waste water treatment efficiency is improved.By the cross that separator is arranged Area of section is more than the cross-sectional area of heat exchanger, and the space in separator is more than the space in heat exchanger, and steam enters separation Pressure, temperature all decline after device, improve separating effect.
4. by the way that condensing gas holding vessel, vacuum pump is arranged, condensing gas be recovered under reduced pressure after moisture and is discharged again, is reduced Pollution to air.
5. providing heat source by compressor, compared with conventional evaporator, temperature difference smaller can reach mild evaporation, pole Big improves product quality.
Description of the drawings
Fig. 1 is a kind of schematic diagram of embodiment of the utility model.
Specific implementation mode
In order to clearly illustrate the technical characterstic of this programme, below by specific implementation mode, and its attached drawing is combined, to this Utility model is described in detail.Following disclosure provides many different embodiments or example is used for realizing the utility model Different structure.In order to simplify the disclosure of the utility model, hereinafter the component of specific examples and setting are described.This Outside, the utility model can in different examples repeat reference numerals and/or letter.This repetition is in order to simplified and clear Purpose itself does not indicate the relationship between discussed various embodiments and/or setting.It should be noted that illustrated in the accompanying drawings Component be not drawn necessarily to scale.The utility model be omitted the description to known assemblies and treatment technology and process to avoid It is unnecessarily limiting the utility model.
Fig. 1 is a kind of embodiment of the utility model, as shown, a kind of zinc borate production wastewater treatment equipment, including MVR vapo(u)rization systems, concentrator 10, centrifuge A11, solids holding vessel A12, cooler crystallizer 9, solids holding vessel B122, Scraper type centrifuge 112, the water inlet connection waste water water source of MVR vapo(u)rization systems, the water outlet of MVR vapo(u)rization systems connect concentrator 10, the solids of concentrator 10 outlet connection centrifuge A11, supernatant outlet by connected after cooler crystallizer 9 scraper type from Scheming 112, the solids outlet connection solids holding vessel A12 of centrifuge A11, liquid outlet connection MVR vapo(u)rization systems into The mouth of a river, solids outlet connection solids holding vessel B122, the liquid outlet of scraper type centrifuge 112 connect MVR vapo(u)rization systems Water inlet.This equipment can make that zinc borate produces the sodium sulphate in waste water and boric acid crystallizes precipitations respectively, two kinds of byproducts of recycling, And waste water evaporation process can be carried out continuously, and improve waste water treatment efficiency.Operation principle:Zinc borate production waste water is directly beaten Enter MVR vapo(u)rization systems to be evaporated, 96 DEG C of evaporating temperature, system vacuum 35kPa.In evaporation process, with sulfate crystal It is precipitated, B in mother liquor2O2- 4It is progressively enriched with.Evaporation capacity is controlled in sodium sulphate and boric acid saturated line hereinafter, sodium sulphate is made to tie as far as possible Crystalline substance, and boric acid is not precipitated, and controls B in liquid phase2O2- 4Concentration is below 25%.It is control with solid content in evaporator in actual production Processed, solid content controls below 15%.Material concentration discharges after reaching design value in device to be evaporated, and slurry squeezes into concentrator 10.Slurry 2 hours residence times or more in concentrator 10, bottom solid are mainly sodium sulphate, B2O2- 4It is primarily present in supernatant In liquid.10 bottom material of concentrator is sent from scheming A11 and is separated by solid-liquid separation, and obtains solid phase sodium sulphate product, and liquid returns to MVR evaporations system System;10 supernatant of concentrator send cooler crystallizer 9, controls 40 DEG C of temperature, and boric acid crystallization in cooler crystallizer 9 is made to be precipitated.Knot After the completion of crystalline substance, scraper type centrifuge 112 is sent to be separated by solid-liquid separation, obtain solid phase boric acid product, centrifuge mother liquor sends MVR evaporators back to Further it is concentrated by evaporation.The processing equipment realizes the separation of sodium sulphate and boric acid, when efficiently solving sulfate crystal because B2O2- 4Enrichment generates fine grain, and caused by serious plugging phenomenon, so that production is carried out continuously.Meanwhile obtaining two high-purities Product, recycled sodium sulphate and boric acid.The utility model grasps sulfuric acid by laboratory test and practical production experience Sodium and boric acid mixed solution crystallization rule, obtain evaporation control point, sodium sulphate are made to be precipitated as much as possible in evaporation process, and Boric acid is not precipitated, and effectively prevent vapo(u)rization system due to generating fine grain the phenomenon that plugging.Boric acid solution crystallization rule is grasped, in routine In waste water evaporation technology, be added boric acid crystallization processes, using two sections of crystallisation modes of sodium sulphate-boric acid, respectively be made sodium sulphate and Boric acid byproduct obtains larger economic benefit, while realizing solid waste zero-emission.
The MVR vapo(u)rization systems include raw water tank 1, feed pump 2, temporary storage tank 7, heat exchanger 4, separator 5, steam heating set Standby 13, drainer 14, scratch pool 18, discharging pump 6, the water inlet connection waste water water source of raw water tank 1, the water outlet of raw water tank 1 are logical The temporary storage tank 7 of the connection of feed pump 2 is crossed, the water outlet of temporary storage tank 7 connects concentrator 10 by discharging pump 6, and separator 5 is arranged temporary The top of tank 7 is deposited, the bottom of separator 5 is connected to temporary storage tank 7;The bottom of temporary storage tank 7 is connected to heat exchanger 4, temporary storage tank 7 with change It is provided with circulating pump 19 between hot device 4, heating pipeline 4-1 is provided in heat exchanger 4, the entrance of heating pipeline 4-1 connects steam The outlet of the gas outlet of heating equipment 13, heating pipeline 4-1 connects 14 entrance of drainer, and the top of heat exchanger 4 is provided with steam 4-2 is exported, the top of steam (vapor) outlet 4-2 connections separator 5, separator 5 is provided with indirect steam outlet 5-1, and indirect steam goes out The air inlet of mouth 5-1 connections steam-heating apparatus 13;The water outlet of drainer 14 connects scratch pool 18, and the top of drainer 14 is set It is equipped with condensation gas outlet 14-1.Waste water enters heat exchanger 4, heated pipe after passing sequentially through raw water tank 1, feed pump 2, temporary storage tank 7 Road 4-1's is thermally formed steam, and steam partially changes into liquid after entering separator 5, and part keeps steam condition, liquid to enter temporary Tank 7 is deposited, steam enters heating tube road 4-1 after the heating of steam-heating apparatus 13 and heats stoste.By using MVR vapo(u)rization systems, Discarded steam is utilized in the potential for taking full advantage of steam, and in addition to being switched on and running, entire evaporation process is without being passed through steam.
The MVR vapo(u)rization systems further include preheater 3, and cold water channel 3-1, hot water channel 3-2 are provided in preheater 3, Cold water channel 3-1 is arranged between feed pump 2 and temporary storage tank 7, hot water channel 3-2 be arranged water outlet in drainer 14 with it is temporary Between pond 18.By the way that preheater 3 is arranged, thermal energy is taken full advantage of, waste water treatment efficiency is improved.
The cross-sectional area of the separator 5 is more than the cross-sectional area of heat exchanger 4.By the way that the transversal of separator 5 is arranged Face area is more than the cross-sectional area of heat exchanger 4, and the space in separator 5 is more than the space in heat exchanger 4, and steam enters separation Pressure, temperature all decline after device 5, improve separating effect.
The MVR vapo(u)rization systems also condensing gas holding vessel 15, condensation gas outlet 14-1 connection condensing gases holding vessel 15 into Gas port, condensing gas holding vessel 15 connect vacuum pump 16, and the top of condensing gas holding vessel 15 is provided with exhaust passage 17, condensing gas storage Deposit the discharge outlet connection scratch pool 18 of tank 15.By the way that condensing gas holding vessel 15, vacuum pump 16 is arranged, condensing gas is depressurized back It is discharged again after receiving moisture, reduces the pollution to air.
The steam-heating apparatus 13 is compressor.Heat source, compared with conventional evaporator, temperature difference are provided by compressor Smaller can reach mild evaporation, greatly improve product quality.
The compressor is Roots Compressor, single machine high-speed centrifugal compressor, the compression of single machine low-speed centrifugal formula wind turbine Any one in machine.
The cooler crystallizer 9 is with the DTB type vacuum evaporation crystallizers for forcing outer circulation, and cycle tube portion is equipped with row Pipe heat exchanger.Heat exchanger cools down recycle stock, and control material temperature makes boric acid sufficient crystallising at 40 DEG C or so.
Although above-mentioned be described the specific implementation mode of utility model in conjunction with attached drawing, not to the utility model The limitation of protection domain, based on the technical solution of the present invention, those skilled in the art need not pay creativeness The various modifications or changes that working can make are still within the scope of the present invention.

Claims (8)

1. a kind of zinc borate production wastewater treatment equipment, it is characterized in that:Including MVR vapo(u)rization systems, concentrator (10), centrifuge A (11), solids holding vessel A (12), cooler crystallizer (9), solids holding vessel B (122), scraper type centrifuge (112), MVR The water inlet connection waste water water source of vapo(u)rization system, the water outlet connection concentrator (10) of MVR vapo(u)rization systems, concentrator (10) are consolidated Body object outlet connection centrifuge A (11), supernatant outlet connect scraper type centrifuge (112) afterwards by cooler crystallizer (9), from The solids outlet connection solids holding vessel A (12) of scheming A (11), the water inlet of liquid outlet connection MVR vapo(u)rization systems, are scraped Blade centrifuge (112) solids outlet connection solids holding vessel B (122), liquid outlet connection MVR vapo(u)rization systems into The mouth of a river.
2. a kind of zinc borate production wastewater treatment equipment according to claim 1, characterized in that the MVR vapo(u)rization systems Including raw water tank (1), feed pump (2), temporary storage tank (7), heat exchanger (4), separator (5), steam-heating apparatus (13), drainer (14), scratch pool (18), discharging pump (6), the water inlet connection waste water water source of raw water tank (1), the water outlet of raw water tank (1) pass through The water outlet of the temporary storage tank (7) of feed pump (2) connection, temporary storage tank (7) connects concentrator (10), separator by discharging pump (6) (5) it is arranged in the top of temporary storage tank (7), the bottom of separator (5) is connected to temporary storage tank (7);The bottom of temporary storage tank (7) and heat exchange Device (4) is connected to, and circulating pump (19) is provided between temporary storage tank (7) and heat exchanger (4), heating pipeline is provided in heat exchanger (4) (4-1), the gas outlet of the entrance connection steam-heating apparatus (13) of heating pipeline (4-1), the outlet connection of heating pipeline (4-1) Drainer (14) entrance is provided with steam (vapor) outlet (4-2) at the top of heat exchanger (4), and steam (vapor) outlet (4-2) connects separator (5), Indirect steam outlet (5-1) is provided at the top of separator (5), indirect steam exports (5-1) connection steam-heating apparatus (13) Air inlet;The water outlet of drainer (14) connects scratch pool (18), and condensation gas outlet is provided at the top of drainer (14) (14-1)。
3. a kind of zinc borate production wastewater treatment equipment according to claim 2, characterized in that the MVR vapo(u)rization systems Further include preheater (3), is provided with cold water channel (3-1), hot water channel (3-2) in preheater (3), cold water channel (3-1) is set It sets between feed pump (2) and temporary storage tank (7), water outlet and scratch pool in drainer (14) is arranged in hot water channel (3-2) (18) between.
4. a kind of zinc borate production wastewater treatment equipment according to claim 2, characterized in that the separator (5) Cross-sectional area is more than the cross-sectional area of heat exchanger (4).
5. a kind of zinc borate production wastewater treatment equipment according to claim 2, characterized in that the MVR vapo(u)rization systems Also condensing gas holding vessel (15), the air inlet of condensation gas outlet (14-1) connection condensing gas holding vessel (15), condensing gas holding vessel (15) vacuum pump (16) is connected, exhaust passage (17), condensing gas holding vessel (15) are provided at the top of condensing gas holding vessel (15) Discharge outlet connection scratch pool (18).
6. a kind of zinc borate production wastewater treatment equipment according to claim 2, characterized in that the steam-heating apparatus (13) it is compressor.
7. a kind of zinc borate production wastewater treatment equipment according to claim 6, characterized in that the compressor is Roots Any one in formula compressor, single machine high-speed centrifugal compressor, single machine low-speed centrifugal formula fan-compressor.
8. a kind of zinc borate production wastewater treatment equipment according to claim 1, characterized in that the cooler crystallizer (9) it is with the DTB type vacuum evaporation crystallizers for forcing outer circulation, cycle tube portion is equipped with tubular heat exchanger.
CN201820030463.6U 2018-01-08 2018-01-08 A kind of zinc borate production wastewater treatment equipment Expired - Fee Related CN207845410U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114230083A (en) * 2021-12-30 2022-03-25 天津市生态环境科学研究院(天津市环境规划院、天津市低碳发展研究中心) Method for online recycling of copper plating waste liquid in surface treatment of metal product
CN115159738A (en) * 2022-08-19 2022-10-11 山东五维阻燃科技股份有限公司 Method for separating and purifying zinc borate production wastewater by using phase diagram

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114230083A (en) * 2021-12-30 2022-03-25 天津市生态环境科学研究院(天津市环境规划院、天津市低碳发展研究中心) Method for online recycling of copper plating waste liquid in surface treatment of metal product
CN115159738A (en) * 2022-08-19 2022-10-11 山东五维阻燃科技股份有限公司 Method for separating and purifying zinc borate production wastewater by using phase diagram

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Granted publication date: 20180911

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