CN204274019U - A kind of intelligent temperature control high-efficient thermal insulation cup - Google Patents

A kind of intelligent temperature control high-efficient thermal insulation cup Download PDF

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CN204274019U
CN204274019U CN201420787247.8U CN201420787247U CN204274019U CN 204274019 U CN204274019 U CN 204274019U CN 201420787247 U CN201420787247 U CN 201420787247U CN 204274019 U CN204274019 U CN 204274019U
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cup
heat
phase
tube wall
thermos cup
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金兆国
彭磊
邹军锋
詹万初
张天翔
赵英民
马荣萍
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Haiying Aerospace Materials Research Institute (Suzhou) Co., Ltd
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Aerospace Research Institute of Materials and Processing Technology
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Abstract

The utility model provides a kind of intelligent temperature control high-efficient thermal insulation cup, and described thermos cup has cup, it is characterized in that, described cup from inside to outside comprises inner tube wall, heat conduction phase change layer, aerogel heat-proof layer and outer tube wall successively.Described thermos cup, owing to have employed high heat conduction phase-change material and aerogel material, therefore has significant fast cooling to temperature required and can keep the feature of this temperature the long period.Intelligent temperature control high-efficient thermal insulation cup tool of the present utility model has been widely used, and daily hollow insulation cup, vacuum cup can be replaced for daily drinking-water, also can be used as tee-steeping cup, children drink cream jug etc.

Description

A kind of intelligent temperature control high-efficient thermal insulation cup
Technical field
The utility model relates to a kind of thermos cup, especially a kind of intelligent temperature control high-efficient thermal insulation cup.
Background technology
At present, the common thermos cup on market is generally vacuum or the hollow insulation cup of the sandwich-type be made up of stainless steel, glass or pottery.Because its heat-insulating property is fine, the boiling water poured in its glass is caused to be in the condition of high temperature for a long time and cannot to drink in time,, reduce fast within a short period of time again after hot water in cup is down to consumption temperature (about 50 DEG C) meanwhile, be unfavorable for drinking for a long time.In addition, for use of making tea (as green tea about 80 DEG C) and children's milk-powder brewing (40 to 50 DEG C), drink the thermos cup of milk with (about 40 DEG C), cause useful composition in tealeaves and milk powder to go bad because water temperature is too high, losing nutritive value, also cannot drink rapidly simultaneously.
Therefore, a kind of high-efficient thermal insulation cup that can keep again this temperature can be down to temperature required rapidly by boiling water while is for a long time needed in daily life.
Can absorb or release heat when phase-change material (PCMs) refers to that material undergoes phase transition and this material self-temperature is constant or change little a kind of intellectual material.Due to the function such as adaptive environment temperature adjusting of its uniqueness, be thus widely used in the fields such as Solar use, industrial exhaust heat Waste Heat Recovery, building energy conservation, constant temperature dress ornament, cold-storage and thermal storage air-conditioning and electrical part constant temperature equal energy source, material, Aero-Space, weaving, electric power, medical instrument, building.
Aerogel material, the gel rubber material of to be a kind of decentralized medium be gas, mutually build up by colloidal particle a kind of nanoporous solid material with network structure formed, this material has the distinguishing features such as porosity is high, specific area is large, density is little, thermal conductivity low (in current known solid material, thermal conductivity is minimum), in calorifics, acoustics, optics, microelectronics, particle detection etc., all have very wide application potential.Fibre-reinforced aerogel composite is extremely valued a kind of novel light high efficiency heat insulation material in recent years, in successful Application spacecraft thermal protection system.But, at present also not by aerogel material and phase-change material connected applications in manufacture fast-cooling thermal insulating cup, because it is generally acknowledged that phase-change material can enter into the microcosmic of aeroge when being phase-changed into liquid or gaseous fluid material, thus cause the deterioration of thermal insulation performance of aerogel material, thus the cold heat-insulating property of the speed of fast-cooling thermal insulating cup is caused to keep for a long time.In addition, relative to other provision for thermal insulations, the application of aerogel material in fast-cooling thermal insulating cup has obvious advantage.Such as, relative to other materials, aerogel material has significantly superior heat-proof quality; Relative to vacuum heat-preserving measure, aerogel material uses easily, on the contrary, vacuum heat-preserving measure needs to provide hermetic vacuum chamber, such vacuum chamber is on the one hand along with use may easily leak air inlet body, on the other hand, the temperature of hundreds of degrees Celsius is needed when welding production vacuum chamber, such temperature easily causes the irreversible breaking (volatilization of such as phase-change material) to phase-change material, thus causes the decline of the fast cold-peace heat storage performance of phase-change material even to lose.
Chinese patent CN92100602.0 and CN93201178.0 reports a kind of quick cooling insulation container, by in container, the phase-change material composition in outer wall and intermediate layer, this cool-bag is widely used various phase-change material, but it is low to there is thermal conductivity in inorganic salts phase-change material wherein, the problem of cyclical stability difference, there is the phenomenon of corrosion inwall in fatty acid phase-change material wherein, there is the low problem of thermal conductivity in paraffin class phase-change material, in addition, this thermos cup does not adopt good Insulation, do not have good heat insulation effect, therefore, this cool-bag practical application effect is limited, CN201110184586.8 reports a kind of layering thermos cup, be made up of routine paraffin wax phase-change material and common heat-insulation layer, but its paraffin thermal conductivity used is lower, heat-insulation layer heat insulation effect is general simultaneously, so there is water in the cup temperature drop temperature efficiency slow (8min is cooled to 70 DEG C, 20min is cooled to consumption temperature 50 DEG C) in this layering thermos cup, water temperature can not regulate and control and the heat insulation effect obviously practical problems such as limited, CN201420208307.6 reports a kind of thermos cup being added with nested type phase-change thermal storage layer, have employed the cylinder phase-change thermal storage layer of the closed interlayer sidewall having double-deck barrel to be formed be made up of stainless steel, preparation technology is extremely complicated for this closed interlayer formula reservoir structure, and there is the reservoir problem on deformation that in interlayer, phase-change material causes because of the alternate repetition of Swelling and contraction in long-term melting and process of setting, and then impact and inner tube wall fit tightly, thus the problem causing the cooling-down effect that formed because hot water in cup greatly reduces to reservoir heat transfer efficiency limited.In addition, this reservoir adopts inorganic hydrated salt class material sodium acetate trihydrate as phase-change material, and it exists thermal conductivity lower (about 0.5W/mK), can not regulate and control and the bad problem of stable circulation; CN201320414844.1 reports a kind of fast cooling thermos cup, be made up of heat-conducting layer (thermos cup inwall), alloy type phase change materials, thermal insulation layer, owing to have employed the higher phase change materials of thermal conductivity, water in the cup temperature drop temperature is effectively improved, but there is cyclical stability difference in this bismuth, gallium, indium, ashbury metal class phase-change material, and there is stronger corrosion inwall effect and certain toxicity, not easily high volume applications.In addition, the heat insulation mode that this thermos cup adopts vacuum glass, plastics or thermal insulation ceramics etc. traditional, wherein, vacuum glass complex manufacturing technology and there is larger potential safety hazard, the thermal conductivity of plastics (0.2W/mK to 0.5W/mK) and pottery (0.5W/mK to 5W/mK) is higher, heat-proof quality is poor, unsuitable long-time heat preservation.The phase-change thermos cup of CN203953160U, CN200320116231.6 and other open report, exist equally above-mentioned similar due to the function such as phase-change material and insulating layer material limited and do not reach good practical function.
The similar fast-cooling thermal insulating cup based on phase-change material heat accumulation (container) Problems existing described by above-mentioned publication mainly contains: the phase-change material thermal conductivity that (1) adopts is low; (2) latent heat of phase change of phase-change material is limited; (3) cyclical stability of phase-change material is poor; (4) coefficient of thermal expansion of phase-change material is large; (5) phase-change material has certain toxicity; (6) phase-change material is expensive; (7) fast-cooling thermal insulating cup insulation does not adopt the effect of heat insulation of heat-insulation and heat-preservation measure or employing limited; (8) long-term heat preservation performance is not good; (9) manufacture difficulty is large.
Utility model content
In order to solve one or more the problems referred to above, the utility model provides a kind of intelligent temperature control high-efficient thermal insulation cup.
The purpose of this utility model is achieved through the following technical solutions:
1. an intelligent temperature control high-efficient thermal insulation cup, described thermos cup has cup, it is characterized in that, described cup from inside to outside comprises inner tube wall, heat conduction phase change layer, aerogel heat-proof layer and outer tube wall successively.
2. the thermos cup as described in technical scheme 1, is characterized in that, described cup also comprises the intermediate cylinder parietal layer between described heat conduction phase change layer and aerogel heat-proof layer.
3. the thermos cup as described in technical scheme 1 or 2, is characterized in that, described thermos cup also comprises bowl cover.
4. the thermos cup according to any one of technical scheme 1 to 3, is characterized in that, described thermos cup also comprises the opening that is communicated with the outer space of described inner tube wall and the seal for closing described opening.
5. the thermos cup according to any one of technical scheme 1 to 4, is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 1 ~ 10mm.
6. the thermos cup as described in technical scheme 5, is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 1 ~ 5mm.
7. the thermos cup as described in technical scheme 6, is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 2 ~ 5mm.
8. the thermos cup according to any one of technical scheme 1 to 7, it is characterized in that, the material of the inner tube wall in described cup, outer tube wall and/or middle barrel is selected from the group be made up of stainless steel, aluminium alloy, titanium alloy, magnesium alloy, copper, plastics, pottery, glass.
9. the thermos cup as described in technical scheme 8, is characterized in that, the material of the inner tube wall in described cup, outer tube wall and/or middle barrel is selected from the group be made up of stainless steel, aluminium alloy, pottery.
10. the thermos cup as described in technical scheme 1 or 2, is characterized in that, the thermal conductivity of the material of described inner tube wall is higher than the thermal conductivity of the material of described outer tube wall.
Compared with other published various hollow insulation cup, vacuum cup and the fast-cooling thermal insulating cup (or cool-bag) containing simple phase-change material, the utility model has the following advantages:
(1) thermos cup of the present utility model has significant fast cooling to temperature required and can keep the feature of this temperature the long period, therefore, has good practical value.
(2) the phase-change material phase transition temperature adjustable (30 to 85 DEG C), latent heat of phase change high (160 to 270kJ/kg), the good cycling stability that adopt of the utility model, the more important thing is that thermal conductivity is high and adjustable (0.2 to 20W/mK), insulation when can really to realize under the fast cooling of thermos cup and certain specified temp long.
(3) the utility model adopts fiber composite aerogel material as thermal insulation layer, and thermal conductivity low (0.01 to 0.03W/mK), heat-proof quality are excellent, high insulating effect.
(4) structure is simple, easily manufactures and uses.
Intelligent temperature control high-efficient thermal insulation cup tool of the present utility model has been widely used, and daily hollow insulation cup, vacuum cup can be replaced for daily drinking-water, also can be used as tee-steeping cup, children drink cream jug etc.
Accompanying drawing explanation
Fig. 1 shows the structural representation according to an intelligent temperature control high-efficient thermal insulation cup preferred embodiment of the present utility model.Wherein, Reference numeral is expressed as follows: 1. outer tube wall; 2. fiber aerogel heat-proof layer; 3. middle barrel; 4. heat conduction phase change layer; 5. inner tube wall; 6. bowl cover.
Detailed description of the invention
The utility model provides a kind of intelligent temperature control high-efficient thermal insulation cup, and described thermos cup has cup, it is characterized in that, described cup from inside to outside comprises inner tube wall, heat conduction phase change layer, aerogel heat-proof layer and outer tube wall successively.
For phase-change material, its phase transformation mode mainly contains solid-solid phase-change, solid-liquid phase change, liquid-vapour phase change, solid-vapour phase change etc., wherein solid-solid phase-change is owing to producing without liquid or steam state material and being convenient for people to practical engineering application in phase transition process, but due to its transition temperature range be not suitable for drinking water glass with and easy generation plastic crystal phenomenon and thermos cup described in the utility model cannot be applied to; Liquid-vapour phase is become, the phase-change material of the form such as solid-vapour phase change, and cause larger internal expansion pressure due to the generation of steam state material, also cannot be applied to thermos cup described in the utility model.So, only have the most applicable thermos cup described in the utility model of the phase transformation of solid-liquid form.For the phase-change material of solid-liquid form, kind is a lot, metal species phase transformation wherein has stronger corrosivity and certain toxicity, and inorganic hydrated salt exists the problems such as crystallization, excessively cold, non-synergistic effect and causes its stable circulation poor, is also not suitable for repeatedly recycling.For avoiding the problems referred to above, the utility model have employed higher aliphatic hydrocarbon, the phase-change material such as alkane type paraffin and polyethylene glycol of good cycling stability.
Some preferred embodiment in, described phase-change material be selected from by carbon number be 18 to 50 higher aliphatic hydrocarbon (such as 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 32, 34, 36, 38, 40, 42, 44, 46, 47, the higher aliphatic hydrocarbon of 48 or 50 carbon atoms), fusing point is that (such as fusing point is 30 for the alkane type paraffin of 30 DEG C to 85 DEG C, 40, 50, 60, 70, the alkane type paraffin of 80 or 85 DEG C), molecular weight be 800 to 20000 polyethylene glycol (such as molecular weight is 800, 900, 1000, 2000, 4000, 8000, the polyethylene glycol of 10000 or 20000) group that forms, it is further preferred that described phase-change material be selected from by by carbon number be 18 to 50 higher aliphatic hydrocarbon and fusing point be the group that the alkane type paraffin of 30 DEG C to 85 DEG C forms, further preferably, described phase-change material to be fusing point the be alkane type paraffin of 30 DEG C to 85 DEG C.
Existing phase-change material (comprise have that such as fusing point is controlled, the paraffin of low price, the advantage such as the nontoxic) problem that ubiquity thermal conductivity is low, makes to use it to there is the problem that thermos cup content cannot be made to cool rapidly as during phase-change material in fast-cooling thermal insulating cup.
In the utility model, use the phase-change material (being sometimes referred to as heat conduction phase-change material or high heat conduction phase-change material herein) with high heat conductance.Some preferred embodiment in, the thermal conductivity of described heat conduction phase change layer is 0.2 to 20W/mK, such as, be 0.2,0.4,0.8,1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 or 20W/mK.In order to improve the thermal conductivity of phase-change material, to make thermos cup that content wherein can be made to cool rapidly, the utility model some preferred embodiment in by utilizing the filler (being sometimes referred to as " high heat filling " or " heat filling " herein) with high heat conductance to mix with phase-change material (phase-change material as escribed above) or compound and obtain having the high heat conduction phase-change material of above-mentioned thermal conductivity.In this case, above-mentioned heat conduction phase change layer comprises phase-change material and heat filling.
Some preferred embodiment in, described heat filling is be selected from the group be made up of aluminium powder, copper powder, graphite powder, nano aluminum nitride, heat conduction carbon fiber, Graphene, expanded graphite.It is further preferred that described heat filling is selected from the group be made up of heat conduction carbon fiber, Graphene, expanded graphite; Further preferably, described heat filling is selected from the group be made up of Graphene and expanded graphite, because such material has laminated structure, each laminated structure mutually overlaps and is present in material, therefore there is the material of ratio as existed with spherical particle there is more superior thermal conductivity, this may be because contact area is less between each particle of spherical particle material, sometimes even occurs situation about not contacting with each other between adjacent particle at material internal.
Heat filling is except improving except thermal conductivity, heat filling can also be adopted to change the transition of phase-change material, solid-liquid phase change material such as can be made to become solid-solid phase change material, thus the fluid-phase decreasing phase-change material is to the adverse effect of aerogel material heat-barrier material (by the being hereafter further described in more detail) performance for heat-insulation and heat-preservation or the needs that avoid arranging middle barrel between thermal insulation layer and phase-change material layers.
Such as, in the utility model when high heat filling reaches certain proportion, if expanded graphite mass percentage is more than 10%, Graphene mass percentage more than 5%, copper powder and aluminium powder mass percentage more than 40%, when graphite powder and high heat conducting fiber mass percentage more than 30%, the porosity higher due to it and specific area, pro forma " Gu Gu-" phase transformation can be converted into the high heat conduction phase change layer formed after phase-change material compound, therefore, liquid state phase change material can be avoided in conventional solid-liquid phase change process the destruction of aerogel material nano-pore structure, improve it and recycle stability.
So, some preferred embodiment in, the mass percentage content of the described phase-change material in described heat conduction phase change layer is 50% to 100%, such as, be 50,60,70,80,85,90,95%; Be more preferably 70% to 95%; More preferably 80% to 90%.In addition, the mass percentage content of the described heat filling in described heat conduction phase change layer is 5% to 30%, such as, be 5,10,15,20,25 or 30%; Be more preferably 10% to 20%.The mass percentage of described phase-change material and described heat filling can the needs of thermal conductivity and phase transformation phase be selected.
The heat put aside after phase transformation of absorbing heat to prevent phase-change material can not scatter and disappear too fast and have influence on the heat-insulating property of thermos cup, and the utility model is also provided with aerogel heat-proof layer outside heat conduction phase change layer.Some preferred embodiment in, described aerogel heat-proof layer adopts fiber composite aerogel heat-insulating material, it is the fiber composite aerogel heat-insulating material that heat-proof quality is best so far that aerogel material such as ties up composite aerogel heat-barrier material, its heat-proof quality is far away higher than the cotton felt, plastics, foam, pottery etc. of routine, therefore, there is good heat insulation effect.Due to heat filling can be adopted to change the phase transformation phase of phase-change material, therefore when phase-change material becomes solid-solid phase change material after adopting heat filling to fill, can without the need to arranging any barrier layer (such as intermediate cylinder parietal layer) hereinafter described between heat conduction phase change layer and aerogel heat-proof layer.Thus, the utility model adopts the fiber composite aerogel material of heat conduction phase change layer material and heat-proof quality excellence, realizes the combination of efficient heat transfer and effectively insulating, and then obtains a kind of fast cooling truly and the high-efficient thermal insulation cup of temperature control.Alternatively, also can barrier layer be set and be combined solid-liquid phase change material and described aerogel heat-proof layer.
When using fiber composite aerogel heat-insulating material, described fiber composite aerogel heat-insulating material is made up of fiber and aerogel material compound.Some preferred embodiment in, the thermal conductivity of described aerogel heat-proof layer is 0.01 to 0.03W/mK, such as, be 0.01,0.02 or 0.03W/mK.
In addition, preferred described fiber is be selected from the group be made up of glass fibre, quartz fibre, high silica fiber, alumina silicate fibre, mullite fiber, basalt fibre, carbon fiber, aramid fiber, polyester fiber, nylon fiber, polypropylene fiber; It is further preferred that described fiber is selected from the group be made up of glass fibre, quartz fibre, high silica fiber, alumina silicate fibre, basalt fibre; Further preferably, described fiber is selected from the group be made up of glass fibre and high silica fiber.In addition preferably, described aerogel material is selected from the group be made up of aerosil, alumina aerogels, zirconia aerogels, carbon aerogels, phenolic aldehyde aeroge, cellulose aerogels; It is further preferred that described aerogel material is selected from the group be made up of aerosil, alumina aerogels, zirconia aerogels, further preferably, described aerogel material is aerosil.
In addition, the melt phase change temperature of the utility model to described phase-change material has no particular limits, and prerequisite is the intended applications that described melt phase change temperature will meet thermos cup.Generally, described melt phase change temperature can be 30 to 85 DEG C, such as 30,40,50,60,70,80 or 85 DEG C.Such as, for drinking-water thermos cup or feeding bottle, consumption temperature is advisable at 30 to 40 DEG C, and therefore can choose melt phase change temperature is 30 DEG C to 40 DEG C.Same, as choosing the phase-change material that melt phase change temperature is 50 DEG C to 85 DEG C during dish-up container.The container that ladles out soup can choose the phase-change material that melt phase change temperature is such as 40 DEG C to 55 DEG C.
In the utility model, preferably select the phase-change material with high latent heat of phase change, to improve cooling and heat storage capacity, especially when the thermos cup of high power capacity.Some preferred embodiment in, the latent heat of phase change of described phase-change material is 160 to 270kJ/kg, such as, be 160,170,180,190,200,210,220,230,240,250,260 or 270kJ/kg.
When heat filling content is lower, heat conduction phase-change material may still be solid-liquid phase change material, in this case, in order to prevent phase-change material undergo phase transition after adverse effect is caused to the microstructure of the aerogel material in aerogel heat-proof layer, intermediate cylinder parietal layer can be set between described heat conduction phase change layer and aerogel heat-proof layer.Certainly, even if described heat conduction phase-change material is solid-solid phase change material, this intermediate cylinder parietal layer also can be set.
In addition, thermos cup described in the utility model can also comprise bowl cover, and this bowl cover can be identical with the 26S Proteasome Structure and Function of common vacuum cup cover.Connection between bowl cover with cup can be and is such as threaded.
In an alternative embodiment, described thermos cup can also comprise the opening that is communicated with the outer space of described inner tube wall and the seal for closing described opening.Can increase, reduce or to change phase-change material wherein as required.
The thickness of the thickness to heat conduction phase change layer of the present utility model and aerogel heat-proof layer is not particularly limited, as required the thickness of the thickness of heat conduction phase change layer and/or aerogel heat-proof layer can be arranged to 1 to 10mm, such as 1,2,3,4,5,6,7,8,9 or 10mm; Preferably 1 to 5mm, more preferably 2 to 3mm.
Some preferred embodiment in, the inner tube wall in the cup of described thermos cup, outer tube wall and middle barrel material are selected from the group be made up of stainless steel, aluminium alloy, titanium alloy, magnesium alloy, copper, plastics, pottery, glass; Be preferably stainless steel, aluminium alloy, pottery, more excellent in selecting stainless steel.Cup wall thickness does not have particular/special requirement, identical with existing thermos cup.
Referring now to Fig. 1, thermos cup described in the utility model is described.
Fig. 1 shows the structural representation of the intelligent temperature control high-efficient thermal insulation cup according to a preferred embodiment of the present utility model, and this thermos cup comprises outer tube wall 1, aerogel heat-proof layer 2, middle barrel 3, heat conduction phase change layer 4, inner tube wall 5, and optional bowl cover 6.Heat conduction phase change layer 4 is close to inner tube wall 5, realizes the quick transmission of the hot phase change layer of hot water heat guide in cup.Aerogel heat-proof layer 2 is arranged between heat conduction phase change layer 4 and outer tube wall 1, prevents heat that heat conduction phase change layer 4 absorbs to external diffusion, realizes heat insulation function.In addition, barrel 3 in the middle of one deck can be set as required between heat conduction phase change layer 4 and aerogel heat-proof layer 2, object be to prevent when phase-change material is fluid-phase (such as liquid phase) (such as when in heat conduction phase change layer 4, heat filling content is low due to phase-change material melting after ooze out liquid time) adverse effect that aerogel heat-proof layer 2 is caused.In addition, described thermos cup also comprises bowl cover 6 alternatively.
Some preferred embodiment in, can be upwards recessed at the bottom of the cup of described thermos cup, thus at the bottom of cup, there is air when holding cup, to improve heat insulation effect further.
Some preferred embodiment in, described inner tube wall has the heat conductivility higher than described outer tube wall, thus is conducive to provide the fast cold-peace insulation effect of cup.
Some preferred embodiment in, described thermos cup arranges the opening that may be used for changing, increase or reduce phase-change material, seal the seal of described opening, can be reduced by described opening as required thus, increase, change phase-change material, and utilize seal to close described opening in the process used.
The utility model provides a kind of intelligent and high-efficiency thermos cup, an advantage of described thermos cup is to adopt high heat conduction phase-change material as reservoir, the melt phase change process of phase-change material is utilized to absorb the principle of a large amount of latent heat of phase change, achieving water in the cup temperature can be down to temperature required fast, meets drinker's within a short period of time and drinkable demand.Meanwhile, along with the prolongation of time, when after water temperature drop, reservoir solidifies phase transition process and before release, the large calorimetric of absorption, in water in the cup, avoids water temperature significantly to decline, and plays and maintains the effect of water temperature within the scope of consumption temperature.Therefore, this thermos cup has the function of intelligent temperature control.In addition, this thermos cup adopts current thermal conductivity is minimum, effect of heat insulation is best aerogel material as thermal insulation layer, realize the effect of thermos cup long-time heat preservation further, overcome heat-proof quality deficiency or the vacuum heat-insulation manufacturing process complexity of other heat-barrier materials existence and forming the destruction to phase-change material in vacuum chamber process.
Another advantage of thermos cup of the present utility model is by by obtaining the adjustable heat conduction phase change layer of thermal conductivity after phase-change material and heat filling compound, with satisfied different occasion to the demand of different rate of temperature fall.The phase transition temperature of the phase-change material adopted has alternative, meets the demand of different occasion to different consumption temperature.The phase-change material adopted has higher latent heat of phase change, meets the demand that reservoir heat storage capacity is large, thus can reduce the ratio of thermos cup volume and weight shared by reservoir; The phase-change material adopted has good cyclical stability, meet thermos cup daily in the demand that repeatedly uses.In addition, the cubical expansivity of the compound phase change layer formed after phase-change material and heat filling compound is low, avoids because the repetitive process of the expansion-contraction in the phase-change material course of work is on the impact of the distortion that thermos cup causes.
It is pointed out that in this article in addition, " be selected from by ... group " any one referring to and be selected from described group unless otherwise stated, term, or any combination two or more arbitrarily in described group.In addition unless otherwise stated, described in present patent application file and raw material all can directly purchase from the market.
Embodiment
Hereafter by with the form of embodiment, the utility model is described in further detail.But these embodiments are just illustrated with regard to preferred embodiment of the present utility model, and protection domain of the present utility model should not be construed as and is only limitted to these embodiments.
Embodiment 1:
Manufacture a kind of intelligent temperature control high-efficient thermal insulation cup, wherein adopt stainless steel as outer tube wall and inner tube wall, be close to 2mm heat conduction phase change layer outside inner tube wall, be close to 2mm glass fibre composite silicon dioxide aerogel heat-proof layer outside heat conduction phase change layer, aerogel heat-proof layer is outward outer tube wall.Wherein heat conduction phase change layer is composited by mass percentage 90% and 10% by the paraffin of fusing point 60 DEG C and expanded graphite, and thermal conductivity is 10W/mK, and the phase transition temperature of fusing point 60 DEG C of paraffin is 60 DEG C, and latent heat of phase change is 210kJ/kg.
In this intelligent temperature control high-efficient thermal insulation cup, pour the hot water of more than 95 DEG C into, after 1min, in cup, hot water is down to about 80 DEG C, and after 3min, in cup, hot water is down to about 60 DEG C, reaches the temperature of tentatively drinking.Under the state that bowl cover covers tightly, in cup, hot water maintains 60 to 55 DEG C and reaches 1h, and then in cup, temperature slowly declines.Thermos cup described in this embodiment can be used for the thermos cup of daily drinking-water.
Embodiment 2:
Manufacture a kind of intelligent temperature control high-efficient thermal insulation cup, wherein adopt stainless steel as outer tube wall and inner tube wall, be close to 2mm heat conduction phase change layer outside inner tube wall, be close to 3mm glass fibre composite silicon dioxide aerogel heat-proof layer outside heat conduction phase change layer, fiber composite aerogel heat-proof layer is outward outer tube wall.Wherein heat conduction phase change layer is composited by mass percentage 95% and 5% by the paraffin of fusing point 80 DEG C and Graphene, and its thermal conductivity is 5W/mK, and wherein the phase transition temperature of fusing point 80 DEG C of paraffin is 80 DEG C, and latent heat of phase change is 250kJ/kg.
In this intelligent temperature control high-efficient thermal insulation cup, pour the hot water of more than 95 DEG C into, after 1min, in cup, hot water is down to about 80 DEG C, reaches the temperature of make tea (green tea).Under the state that bowl cover covers tightly, in cup, hot water maintains 80 ~ 70 DEG C and reaches 1h, and then in cup, temperature slowly declines.Intelligent temperature control high-efficient thermal insulation cup described in this embodiment can be used for the daily thermos cup of water of drinking tea of making tea.
Embodiment 3:
Manufacture a kind of intelligent temperature control high-efficient thermal insulation cup, wherein adopt glass as outer tube wall and inner tube wall, outside inner tube wall, be close to 2mm heat conduction phase change layer.Wherein heat conduction phase change layer is composited by mass percentage 80% and 20% by the paraffin of fusing point 40 DEG C and expanded graphite, and its thermal conductivity is 20W/mK, and wherein the phase transition temperature of fusing point 40 DEG C of paraffin is 40 DEG C, and latent heat of phase change is 220kJ/kg.
In this intelligent temperature control high-efficient thermal insulation cup, pour the hot water of about 70 DEG C into, after 2min, in cup, hot water is down to about 40 DEG C, reaches the temperature brewing milk powder.Under the state that bowl cover covers tightly, in cup, hot water maintains 40 ~ 35 DEG C and reaches 0.5h, and then in cup, temperature slowly declines.Intelligent temperature control high-efficient thermal insulation cup described in this embodiment can be used for the thermos cup that daily children brew milk powder drink milk.
Embodiment 4 to 16
Except content listed by following table 1, embodiment 4 to 16 adopts the mode identical with embodiment 1 to implement.
In order to verify the cyclical stability of thermos cup, 100 experimental tests (initial water temperature is 95 DEG C) are carried out to the thermos cup that embodiment 17 to 22 obtains.Result shows, the hot water rate of temperature fall in the thermos cup of embodiment 17 to embodiment 20 and temperature retention time, without significant change, show that it has good cyclical stability.For embodiment 17 and 18, supposition is that form phase transformation does not cause adverse effect to aerogel heat-insulating material because the heat filling effect in heat conduction phase change layer high in embodiment 17 to embodiment 18 forms " Gu Gu-"; For embodiment 19 to embodiment 20, supposition avoids the destruction that the liquid state phase change material after phase transformation causes aerogel heat-proof layer.The thermos cup of embodiment 21 and 22 is when second time uses, and temperature retention time foreshortens to 0.5h by 1.5h; When using for the 5th time, it is without obvious insulating process, supposition is because heat filling is less, the pore space structure of liquid to aerogel material produced during the phase transformation of heat conduction phase change layer produces obvious destruction, its heat-proof quality is caused greatly to decline, the temperature retention time showing as thermos cup shortens greatly, reduces Practical Performance.
Embodiment described herein is only to preferred embodiment example of the present utility model explanation.The utility model person of ordinary skill in the field can carry out various amendment according to content disclosed in the utility model to described embodiment, but the technical scheme not departing from essence of the present utility model revised thus and obtain still drops within appended claims limited range.

Claims (10)

1. an intelligent temperature control high-efficient thermal insulation cup, described thermos cup has cup, it is characterized in that, described cup from inside to outside comprises inner tube wall, heat conduction phase change layer, aerogel heat-proof layer and outer tube wall successively.
2. thermos cup as claimed in claim 1, it is characterized in that, described cup also comprises the intermediate cylinder parietal layer between described heat conduction phase change layer and aerogel heat-proof layer.
3. thermos cup as claimed in claim 1 or 2, it is characterized in that, described thermos cup also comprises bowl cover.
4. thermos cup as claimed in claim 1 or 2, is characterized in that, described thermos cup also comprises the opening that is communicated with the outer space of described inner tube wall and the seal for closed described opening.
5. thermos cup as claimed in claim 1 or 2, it is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 1 ~ 10mm.
6. thermos cup as claimed in claim 1 or 2, it is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 1 ~ 5mm.
7. thermos cup as claimed in claim 1 or 2, it is characterized in that, the thickness of described heat conduction phase change layer and/or the thickness of described aerogel heat-proof layer are 2 ~ 5mm.
8. thermos cup as claimed in claim 1 or 2, it is characterized in that, the material of the inner tube wall in described cup, outer tube wall and/or middle barrel is selected from the group be made up of stainless steel, aluminium alloy, titanium alloy, magnesium alloy, copper, plastics, pottery, glass.
9. thermos cup as claimed in claim 1 or 2, is characterized in that, the material of the inner tube wall in described cup, outer tube wall and/or middle barrel is selected from the group be made up of stainless steel, aluminium alloy, pottery.
10. thermos cup as claimed in claim 1 or 2, is characterized in that, the thermal conductivity of the material of described inner tube wall is higher than the thermal conductivity of the material of described outer tube wall.
CN201420787247.8U 2014-12-15 2014-12-15 A kind of intelligent temperature control high-efficient thermal insulation cup Active CN204274019U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104398095A (en) * 2014-12-15 2015-03-11 航天特种材料及工艺技术研究所 Intelligent temperature control efficient heat preservation cup
CN106852623A (en) * 2016-12-01 2017-06-16 深圳中凝科技有限公司 For the preparation method of thermos cup inner thermal insulating layer
CN108344318A (en) * 2018-05-14 2018-07-31 深圳市帝洋科技有限公司 Temperature control regenerative apparatus and temperature control heat storage container

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104398095A (en) * 2014-12-15 2015-03-11 航天特种材料及工艺技术研究所 Intelligent temperature control efficient heat preservation cup
CN106852623A (en) * 2016-12-01 2017-06-16 深圳中凝科技有限公司 For the preparation method of thermos cup inner thermal insulating layer
CN108344318A (en) * 2018-05-14 2018-07-31 深圳市帝洋科技有限公司 Temperature control regenerative apparatus and temperature control heat storage container

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Patentee before: AEROSPACE RESEARCH INSTITUTE OF SPECIAL MATERIAL AND PROCESS TECHNOLOGY