CN204198870U - A kind of device for ionic liquid electrodeposition - Google Patents
A kind of device for ionic liquid electrodeposition Download PDFInfo
- Publication number
- CN204198870U CN204198870U CN201420650622.4U CN201420650622U CN204198870U CN 204198870 U CN204198870 U CN 204198870U CN 201420650622 U CN201420650622 U CN 201420650622U CN 204198870 U CN204198870 U CN 204198870U
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- Prior art keywords
- ionic liquid
- rubber plug
- negative electrode
- anode
- electrolyzer
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- 239000002608 ionic liquid Substances 0.000 title claims abstract description 45
- 238000004070 electrodeposition Methods 0.000 title claims abstract description 19
- 229920002545 silicone oil Polymers 0.000 claims abstract description 19
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 8
- 238000000151 deposition Methods 0.000 abstract description 4
- 230000008021 deposition Effects 0.000 abstract description 4
- 239000003792 electrolyte Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model relates to a kind of device for ionic liquid electrodeposition, belongs to technical field of metallurgical equipment.This silicone oil groove in the device of ionic liquid electrodeposition is placed in well heater, electrolyzer is placed in silicone oil groove inside, electrolyzer top is provided with rubber plug, electrolyte bath places ionic liquid, upper part of the electrolytic cell is provided with negative electrode and anode, negative electrode and anode bottom are immersed in ionic liquid, negative electrode is connected with power supply with anode, rubber plug crown center position arranges whipped-up structure, side, rubber plug top is inserted thermometer simultaneous temperature meter bottom and is immersed in ionic liquid, rare gas element tank inserts rubber plug top near anode side by inlet pipe, tail is inhaled device and is inserted rubber plug top near negative electrode side by vapor pipe.This electric deposition device equipment is simple, practical, can meet the requirement that ionic liquid is strict in electrodeposition process, and this device can make ionic liquid be in inert environments all the time in electrodeposition process, and completely isolated with moisture.
Description
Technical field
The utility model relates to a kind of device for ionic liquid electrodeposition, belongs to technical field of metallurgical equipment.
Background technology
Ionic liquid a kind of to be made up of anions and canons, at the organic salt that room temperature or near room temperature are in a liquid state, has that electrochemical window is wide, good conductivity, liquid state range are wide, without the excellent properties such as vapour pressure, good stability, is a kind of green solvent.In galvanic deposit or electrolysis, ionic liquid has merged the advantage of high-temperature molten salt and the aqueous solution: have wider electrochemical window and good electroconductibility, at room temperature can obtain in high-temperature molten salt could the metal that goes out of galvanic deposit and alloy, but the severe corrosive not having high-temperature molten salt such; Simultaneously, in ionic liquid, go back electrodepositable or obtain most of metal that can obtain in aqueous, and without side reaction, the metal quality thus obtained is better, current efficiency is higher, particularly to aluminium, magnesium, titanium etc. be difficult in aqueous the metal that obtains of galvanic deposit and alloy all the more so.The above-mentioned characteristic of ionic liquid and good specific conductivity thereof make it the brand-new liquid becoming galvanic deposit research, are more and more applied in electrodeposit metals.
But because the electric deposition device existed in prior art can not meet conditional request strict in ionic liquid electrodeposition process: as ionic liquid must carry out galvanic deposit in an inert atmosphere, can not moisture be there is in ionic liquid heat-processed otherwise ionic liquid easily absorbs moisture, affect the purity of ionic liquid so that affect the most metals quality that galvanic deposit obtains.
Summary of the invention
For prior art Problems existing and deficiency, the utility model provides a kind of device for ionic liquid electrodeposition.This electric deposition device equipment is simple, practical, the requirement that ionic liquid is strict in electrodeposition process can be met, this device can make ionic liquid be in all the time in inert environments in electrodeposition process, and it is completely isolated with moisture, therefore the most metals quality that obtains of final galvanic deposit is better, and the utility model is achieved through the following technical solutions.
A kind of device for ionic liquid electrodeposition, comprise power supply 1, whipped-up structure 2, thermometer 4, vapor pipe 7, tail inhales device 8, inlet pipe 9, rubber plug 10, electrolytic cell assembly, heating unit and rare gas element tank 14, described electrolytic cell assembly comprises electrolyzer 12, negative electrode 3 and anode 11, heating unit comprises silicone oil groove and well heater 6 that silicone oil 5 is housed, silicone oil groove is placed on well heater 6, electrolyzer 12 is placed in silicone oil groove inside, electrolyzer 12 top is provided with rubber plug 10, ionic liquid 13 is placed in electrolyzer 12 inside, electrolyzer 12 top is provided with negative electrode 3 and anode 11, negative electrode 3 and anode 11 bottom are immersed in ionic liquid 13, negative electrode 3 is connected with power supply 1 with anode 11, rubber plug 10 crown center position arranges whipped-up structure 2, side, rubber plug 10 top is inserted thermometer 4 simultaneous temperature meter 4 bottom and is immersed in ionic liquid 13, rare gas element tank 14 inserts rubber plug 10 top near anode 11 side by inlet pipe 9, tail is inhaled device 8 and is inserted rubber plug 10 top near negative electrode 3 side by vapor pipe 7.
Described whipped-up structure 2 is agitator 2-1 or stirrer 2-2.
Tail is inhaled device 8 and is inhaled the concrete absorbing material placed in device 8 according to practical situation determination tail.
This is used for the device of ionic liquid electrodeposition: first by device according to foregoing description, the vibrational power flow of Fig. 1 or Fig. 2 connects, then rare gas element tank 14 is opened, and open well heater 6 simultaneously, when well heater 6 according to thermometer 4 show ionic liquid 5 arrive temperature required time, power-on switch, whipped-up structure 2 switch carries out electrolytic deposition process, what well heater 6 kept needed for ionic liquid 5 in the process is temperature-resistant, after electrolytic deposition process terminates, turn off power switch, close rare gas element tank 14, take out the metal namely obtaining galvanic deposit after negative electrode 3 is cleaned, finally close well heater 6.
The beneficial effects of the utility model are: this electric deposition device equipment is simple, practical, the requirement that ionic liquid is strict in electrodeposition process can be met, this device can make ionic liquid be in all the time in inert environments in electrodeposition process, and completely cut off with moisture completely, therefore finally the most metals quality that obtains of galvanic deposit is better.
Accompanying drawing explanation
Fig. 1 is the utility model structural representation A;
Fig. 2 is the utility model structural representation B.
In figure: 1-power supply, 2-whipped-up structure, 2-1-agitator, 2-2 stirrer, 3-negative electrode, 4-thermometer, 5-silicone oil, 6-well heater, 7-vapor pipe, 8-tail inhales device, 9-inlet pipe, 10-rubber plug, 11-anode, 12-electrolyzer, 13-ionic liquid, 14-rare gas element tank.
Embodiment
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Embodiment 1
As shown in Figure 1, this is used for the device of ionic liquid electrodeposition, comprise power supply 1, whipped-up structure 2, thermometer 4, vapor pipe 7, tail inhales device 8, inlet pipe 9, rubber plug 10, electrolytic cell assembly, heating unit and rare gas element tank 14, described electrolytic cell assembly comprises electrolyzer 12, negative electrode 3 and anode 11, heating unit comprises silicone oil groove and well heater 6 that silicone oil 5 is housed, silicone oil groove is placed on well heater 6, electrolyzer 12 is placed in silicone oil groove inside, electrolyzer 12 top is provided with rubber plug 10, ionic liquid 13 is placed in electrolyzer 12 inside, electrolyzer 12 top is provided with negative electrode 3 and anode 11, negative electrode 3 and anode 11 bottom are immersed in ionic liquid 13, negative electrode 3 is connected with power supply 1 with anode 11, rubber plug 10 crown center position arranges whipped-up structure 2, side, rubber plug 10 top is inserted thermometer 4 simultaneous temperature meter 4 bottom and is immersed in ionic liquid 13, rare gas element tank 14 inserts rubber plug 10 top near anode 11 side by inlet pipe 9, tail is inhaled device 8 and is inserted rubber plug 10 top near negative electrode 3 side by vapor pipe 7, wherein whipped-up structure 2 is agitator 2-1.
Embodiment 2
As shown in Figure 2, this is used for the device of ionic liquid electrodeposition, comprise power supply 1, whipped-up structure 2, thermometer 4, vapor pipe 7, tail inhales device 8, inlet pipe 9, rubber plug 10, electrolytic cell assembly, heating unit and rare gas element tank 14, described electrolytic cell assembly comprises electrolyzer 12, negative electrode 3 and anode 11, heating unit comprises silicone oil groove and well heater 6 that silicone oil 5 is housed, silicone oil groove is placed on well heater 6, electrolyzer 12 is placed in silicone oil groove inside, electrolyzer 12 top is provided with rubber plug 10, ionic liquid 13 is placed in electrolyzer 12 inside, electrolyzer 12 top is provided with negative electrode 3 and anode 11, negative electrode 3 and anode 11 bottom are immersed in ionic liquid 13, negative electrode 3 is connected with power supply 1 with anode 11, rubber plug 10 crown center position arranges whipped-up structure 2, side, rubber plug 10 top is inserted thermometer 4 simultaneous temperature meter 4 bottom and is immersed in ionic liquid 13, rare gas element tank 14 inserts rubber plug 10 top near anode 11 side by inlet pipe 9, tail is inhaled device 8 and is inserted rubber plug 10 top near negative electrode 3 side by vapor pipe 7, wherein whipped-up structure 2 is stirrer 2-2.
By reference to the accompanying drawings embodiment of the present utility model is explained in detail above, but the utility model is not limited to above-mentioned embodiment, in the ken that those of ordinary skill in the art possess, various change can also be made under the prerequisite not departing from the utility model aim.
Claims (2)
1. the device for ionic liquid electrodeposition, it is characterized in that: comprise power supply (1), whipped-up structure (2), thermometer (4), vapor pipe (7), tail inhales device (8), inlet pipe (9), rubber plug (10), electrolytic cell assembly, heating unit and rare gas element tank (14), described electrolytic cell assembly comprises electrolyzer (12), negative electrode (3) and anode (11), heating unit comprises silicone oil groove and well heater (6) that silicone oil (5) is housed, silicone oil groove is placed on well heater (6), electrolyzer (12) is placed in silicone oil groove inside, electrolyzer (12) top is provided with rubber plug (10), ionic liquid (13) is placed in electrolyzer (12) inside, electrolyzer (12) top is provided with negative electrode (3) and anode (11), negative electrode (3) and anode (11) bottom are immersed in ionic liquid (13), negative electrode (3) is connected with power supply (1) with anode (11), rubber plug (10) crown center position arranges whipped-up structure (2), rubber plug (10) side, top is inserted thermometer (4) simultaneous temperature meter (4) bottom and is immersed in ionic liquid (13), rare gas element tank (14) inserts rubber plug (10) top near anode (11) side by inlet pipe (9), tail is inhaled device (8) and is inserted rubber plug (10) top near negative electrode (3) side by vapor pipe (7).
2. the device for ionic liquid electrodeposition according to claim 1, is characterized in that: described whipped-up structure (2) is agitator (2-1) or stirrer (2-2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420650622.4U CN204198870U (en) | 2014-11-04 | 2014-11-04 | A kind of device for ionic liquid electrodeposition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420650622.4U CN204198870U (en) | 2014-11-04 | 2014-11-04 | A kind of device for ionic liquid electrodeposition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204198870U true CN204198870U (en) | 2015-03-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420650622.4U Expired - Fee Related CN204198870U (en) | 2014-11-04 | 2014-11-04 | A kind of device for ionic liquid electrodeposition |
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| Country | Link |
|---|---|
| CN (1) | CN204198870U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105954613A (en) * | 2016-04-29 | 2016-09-21 | 中国船舶重工集团公司第七二五研究所 | Titanium electrode acceleration life testing device |
| CN108754605A (en) * | 2018-06-22 | 2018-11-06 | 东北大学 | The device and method of electro-deposition oriented growth metal single crystal in aqueous electrolyte |
-
2014
- 2014-11-04 CN CN201420650622.4U patent/CN204198870U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105954613A (en) * | 2016-04-29 | 2016-09-21 | 中国船舶重工集团公司第七二五研究所 | Titanium electrode acceleration life testing device |
| CN108754605A (en) * | 2018-06-22 | 2018-11-06 | 东北大学 | The device and method of electro-deposition oriented growth metal single crystal in aqueous electrolyte |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150311 Termination date: 20161104 |