CN204116340U - For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation - Google Patents

For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation Download PDF

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Publication number
CN204116340U
CN204116340U CN201420619071.5U CN201420619071U CN204116340U CN 204116340 U CN204116340 U CN 204116340U CN 201420619071 U CN201420619071 U CN 201420619071U CN 204116340 U CN204116340 U CN 204116340U
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China
Prior art keywords
high pressure
pressure vessel
transformer oil
reaction vessel
infrared heater
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Expired - Fee Related
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CN201420619071.5U
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Chinese (zh)
Inventor
于会民
马书杰
张绮
张培恒
王会娟
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China Petroleum and Natural Gas Co Ltd
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China Petroleum and Natural Gas Co Ltd
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Abstract

The utility model discloses a kind of device for oxidation stability of transformer oil rapid evaluation and reaction vessel, this device comprises: high-pressure oxidation reaction vessel, control device and aerating device; This high-pressure oxidation reaction vessel and this aerating device are all connected with this control device, and this high-pressure oxidation reaction vessel is connected with this aerating device; This high-pressure oxidation reaction vessel comprises further: high pressure vessel, for measuring the temperature sensor of this high pressure vessel internal temperature, infrared heater and cooling fan; This infrared heater is arranged on the outside of this high pressure vessel; This cooling fan is arranged on the below of this high pressure vessel; This temperature sensor, this infrared heater and this cooling fan are all electrically connected with this control device.The utility model can control oxidation stability of transformer oil evaluation residing for temperature in the scope of national standard demand so that realize the rapid evaluation of oxidation stability of transformer oil.

Description

For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation
Technical field
The technical field that the Oxidation Stability that the utility model relates to liquid insulating material is evaluated, particularly relates to a kind of device for oxidation stability of transformer oil rapid evaluation and high-pressure oxidation reaction vessel.
Background technology
In recent years, China's power industry has entered the developing period of bulk power grid, extra-high voltage grid, has in succession built up 1000kV ultra-high voltage AC transmission engineering and ± 800kV extra-high voltage direct-current transmission engineering.Solve a series of basic world-class difficult problem such as the control of ultra-high voltage AC transmission system electro-magnetic transient, insulation configuration, electromagnetic environment, device fabrication under the rigor condition such as high voltage, heavy current, heavy pollution and define complete technical system.Correlation technique is applied in multiple successive projects, and has popularizing application prospect widely, and economic and social profit is remarkable especially, achieves the innovation and breakthrough with milestone significance.
Transformer is extremely important power transmission and transforming equipment in power transmission engineering, and the overall development of its industry development and power industry is closely related.In operation, transformer oil, except the long period effect will bearing high voltage, lightning impulse and switching overvoltage, also will stand the impact of the factor such as high temperature, metal material catalytic oxidation, can cause its decreasing insulating.
Therefore as the transformer oil of predominating insulation in transformer except should possessing good electric property, also should possess good oxidation stability.The antioxygenic property of transformer oil is the very important index of transformer oil, is the important foundation that transformer oil service rating divides, and is also the Main Basis that transformer manufacturer selects transformer oil.
Specifically, transformer oil is one of stock used in power transmission system, in the oil-filled electric equipments such as transformer, reactor, mutual inductor, switch, mainly play insulation and cooling heat dissipation effect.Because electrical equipment is in the defeated change process of electric power, transformer oil can be subject to the impact of the factors such as oxygen, temperature, electric field, metal, insulating material and be oxidized, the chemical reaction such as cracking, generate the oxide such as a large amount of superoxide and alcohol, aldehyde, ketone, acid, generate the insolubless such as greasy filth through condensation reaction again, cause oil quality deterioration, reduce serviceable life.
At present, two classes are mainly contained for the instrument of oxidation stability of transformer oil evaluation both at home and abroad:
One class meets NB SH/T 0811, ASTM D2440 method and IEC61125 method oxidation stability of transformer oil analyzer.
Principle is: at the temperature (100 DEG C, 110 DEG C or 120 DEG C) of regulation, under the catalytic action of copper, within 164 hours or the 500 hours test period of regulation, pass into oxygen or air carries out oxidation test, measure the acid number and precipitation or dielectric dissipation factor that are oxidized rear oil, judged the oxidation stability of transformer oil by the acid number of oxygenated oil and the size of precipitation and dielectric dissipation factor.
The maximum defect of above method is that the test period is comparatively large, is generally all greater than 160 hours.
Another kind of is rotary oxygen bomb instrument, meets ASTMD2112 (SH/T0193) method, is a kind of accelerated test procedures of oxidation stability of transformer oil.
Principle is: tested oil sample, distilled water and copper coil are put into a glass sample holder, then it is put into oxygen bomb, oxygen pressure initial in oxygen bomb is 620kPa, puts into the oil bath of 140 DEG C, subsequently, with the speed axial-rotation of 100 revs/min.When pressure drop is to during lower than top pressure 172kPa, terminate test, the reaction time of record oil and oxygen.
It is that test temperature is too high that these class methods exist major defect, the maximum operating temperature (hot(test)-spot temperature) of transformer oil is about 120 DEG C, both differences 20 DEG C, the evaluation result that the Oxidation Stability evaluating transformer oil under too high test temperature can lead to errors.Because conventional transformer oil antioxidant DBPC uses below 120 DEG C, during more than 120 DEG C, can there is thermal decomposition in antioxidant DBPC, thus cause the reduction of its anti-oxidation efficacy.
Country transformer oil new standard GB2536-11 formally implements, the oxidation stability of regulation transformer oil carries out 500 h run to evaluate below 120 DEG C, the increase of oxidation stability of transformer oil test period reduces the efficiency of transformer oil development and evaluation, proposes higher requirement to oxidation stability of transformer oil evaluation device security performance.
And existing testing equipment cannot realize the oxidation stability evaluation of transformer oil under short period and lower temperature, become the focal point of industry.
For the deficiency of existing oxidation stability of transformer oil rapid method for assessment, a kind of device for oxidation stability of transformer oil rapid evaluation need be developed.Test temperature is at 120 DEG C and following, and (within 500 minutes) can complete within the very short test period, do with the equipment of employing NB SH/T 0811 method and within 500 hours, compared with oxidation results, there is good consistance, for the Oxidation Stability of rapid evaluation transformer oil provides technical support.
Summary of the invention
The utility model solve technical matters be, control transformer oil oxidation stability evaluation residing for temperature in the scope of national standard demand so that realize the rapid evaluation of oxidation stability of transformer oil.
In order to solve the problem, the utility model discloses a kind of device for oxidation stability of transformer oil rapid evaluation, comprising: high-pressure oxidation reaction vessel, control device and aerating device;
This high-pressure oxidation reaction vessel and this aerating device are all connected with this control device, and this high-pressure oxidation reaction vessel is connected with this aerating device;
This high-pressure oxidation reaction vessel comprises further:
High pressure vessel, for measuring the temperature sensor of this high pressure vessel internal temperature, infrared heater and cooling fan;
This infrared heater is arranged on the outside of this high pressure vessel;
This cooling fan is arranged on the below of this high pressure vessel;
This temperature sensor, this infrared heater and this cooling fan are all electrically connected with this control device.
Also be placed with glass cylinder in this high pressure vessel, above this glass cylinder, be also disposed with gasket seal and spring shim.
Sealing pad is tetrafluoroethene gasket seal, and this spring shim is fluororubber spring shim.
This high pressure vessel comprises high pressure vessel cup and high pressure vessel lid further, and the lower edge of this high pressure vessel lid is socketed with O-ring seal.
The top edge of this high pressure vessel lid is provided with fixing seal ring.
The invention also discloses a kind of high-pressure oxidation reaction vessel for oxidation stability of transformer oil rapid evaluation, comprising:
High pressure vessel, for measuring the temperature sensor of this high pressure vessel internal temperature, infrared heater and cooling fan;
This high pressure vessel is placed in this infrared heater;
This cooling fan is arranged on the below of this infrared heater;
This infrared heater and this cooling fan are all electrically connected with this control device.
Also be placed with glass cylinder in this high pressure vessel, above this glass cylinder, be also disposed with gasket seal and spring shim.
Sealing pad is tetrafluoroethene gasket seal, and this spring shim is fluororubber spring shim.
This high pressure vessel comprises high pressure vessel cup and high pressure vessel lid further, and the lower edge of this high pressure vessel lid is socketed with O-ring seal.
The top edge of this high pressure vessel lid is provided with fixing seal ring.
The utility model can control oxidation stability of transformer oil evaluation residing for temperature in the scope of national standard demand so that realize the rapid evaluation of oxidation stability of transformer oil.
Accompanying drawing explanation
Figure 1 shows that the structural representation of the device for oxidation stability of transformer oil rapid evaluation of the present utility model.
Figure 2 shows that the structure detailed maps of the device for oxidation stability of transformer oil rapid evaluation of the present utility model.
Figure 3 shows that the structural representation of high-pressure oxidation reaction vessel 101 of the present utility model.
Figure 4 shows that the detailed structure view of high-pressure oxidation reaction vessel 101 of the present utility model.
Figure 5 shows that the sectional structure chart of glass cylinder of the present utility model.
Wherein, Reference numeral:
For the device 100 of oxidation stability of transformer oil rapid evaluation
High-pressure oxidation reaction vessel 101
Aerating device 102
Control device 103
Self-filler 1021
Gas cylinder 1022
High-pressure pressure sensor 5
Input and output gas valve 6
Safety pressure release valve 7
Fixing seal ring 8
High pressure vessel lid 9
O-ring seal 10
Spring shim 11
Gasket seal 12
Glass cylinder 13
Copper coil 14
Magnetic stir bar 15
High pressure vessel cup 16
Metal bath 17
Infrared heater 18
Magnetic stirrer 19
Temperature sensor 20
Cooling fan 21
Housing 22
Embodiment
Describe in detail of the present utility model for the device of oxidation stability of transformer oil rapid evaluation and the specific implementation of reaction vessel below in conjunction with drawings and Examples.
The utility model, in order to solve the technical matters of temperature in the scope of national standard demand residing for the evaluation of control transformer oil oxidation stability, first needs erection one for the device 100 of oxidation stability of transformer oil rapid evaluation.Be illustrated in figure 1 the structural representation of the device for oxidation stability of transformer oil rapid evaluation of the present utility model.
Device 100 for oxidation stability of transformer oil rapid evaluation comprises high-pressure oxidation reaction vessel 101, aerating device 102 and control device 103.
This high-pressure oxidation reaction vessel 101 and this aerating device 102 are all connected with this control device 103, and this high-pressure oxidation reaction vessel 101 is also connected with this aerating device 102.
Control device 103 can be a station server, there is arithmetic capability, also according to the design parameter of transformer oil oxidizing process, control command can be sent to this high-pressure oxidation reaction vessel 101 and aerating device 102, and then change the experimental situation in this high-pressure oxidation reaction vessel 101.
Be illustrated in figure 2 the structure detailed maps of the device for oxidation stability of transformer oil rapid evaluation of the present utility model.
As figure shows, aerating device 102 comprises self-filler 1021 and gas cylinder 1022 further.In an embodiment optimized, this gas cylinder 1022 is a welding bottle.
One end of self-filler 1021 is connected with the input and output gas valve (label 6 in Fig. 4) of this high-pressure oxidation reaction vessel 101, and one end is connected with welding bottle 1022, and one end is connected with control device 103.
Self-filler 1021 obtains the control command of inflation from control device 103, and then is conveyed in high-pressure oxidation reaction vessel 101 by this input and output gas valve by the gas in gas cylinder 1022.
Be illustrated in figure 3 the structural representation of high-pressure oxidation reaction vessel 101 of the present utility model.Be illustrated in figure 4 the detailed structure view of high-pressure oxidation reaction vessel 101 of the present utility model.
High-pressure oxidation reaction vessel 101 comprises high pressure vessel, for measuring the temperature sensor 20 of this high pressure vessel internal temperature, infrared heater 18 and cooling fan 21.This infrared heater 18 is arranged on the outside of this high pressure vessel, and this cooling fan 21 is arranged on the below of this high pressure vessel, and this temperature sensor 20, this infrared heater 18 and this cooling fan 21 are all electrically connected with this control device 103.
Specifically, high pressure vessel comprises high pressure vessel cup 16, high pressure vessel lid 9, high-pressure pressure sensor 5, input and output gas valve 6, safety pressure release valve 7, fixing seal ring 8, O-ring seal 10, spring shim 11, gasket seal 12, glass cylinder 13, copper coil 14, magnetic stir bar 15, metal bath 17, magnetic stirrer 19 further.
This high pressure vessel lid 9 covers on the top of this high pressure vessel cup 16.
This magnetic stir bar 15 is placed in this glass cylinder 13, and also can place test oil sample and copper coil 14 in this glass cylinder 13, this magnetic stir bar 15 is for stirring this test oil sample.Be illustrated in figure 5 the sectional structure chart of glass cylinder 13, what this glass cylinder 13 was vertical is placed in this high pressure vessel cup 16.
High-pressure pressure sensor 5 is arranged on this high pressure vessel lid 9 by a gas circuit, this gas circuit penetrates this high pressure vessel lid 9, make pressure transducer 4 by this gas circuit, the force value of this high pressure vessel inside can be detected, and detected value can be sent to control device 103.
Input and output gas valve 6 is also formed in this gas circuit, and high-pressure pressure sensor 5 and this input and output gas valve 6 share same gas circuit.This input and output gas valve 6 is connected with this self-filler 1021, and input and output gas valve 6 carries gas to increase the force value in high pressure vessel by this gas circuit in high pressure vessel, or release gas is to reduce the force value in high pressure vessel.
This gas circuit is also provided with a safety pressure release valve 7, for keeping the force value in this high pressure vessel in a default zone of reasonableness.
When the force value in this high pressure vessel progressively rises and closes on preset maximum value, this safety pressure release valve 7 discharges gas in this high pressure vessel to outside this high pressure vessel, to avoid the further increase of force value, exceeds default zone of reasonableness.
Gasket seal 12 and spring shim 11 is also disposed with above the rim of a cup of this glass cylinder 13.The top of spring shim 11 is provided with this high pressure vessel lid 9.
Sealing pad 12 seals for the cup for this glass cylinder, and this spring shim 11 is for being pressed on glass cylinder 13 by the sealing pad 12 of below, in case tested oil sample spills when inflating.
In an embodiment optimized, sealing pad 12 is O fluoro-rubber sealing spacer.This spring shim 11 is fluororubber spring shim.
Also be inserted in O-ring seal 10 in high pressure vessel lid 9 lower edge, sealing circle 10, in the assembling process of high pressure vessel lid 9 and high pressure vessel cup 16, carries out the sealing of interface, avoids Leakage Gas.
In an optimal enforcement example, sealing circle 10 is O viton seal ring.
In the top edge of this high pressure vessel lid 9, be also provided with fixing seal ring 8, screw this fixing seal ring 8 and can be used for closely fixing this high pressure vessel lid 9 on this high pressure vessel cup 16.
This high pressure vessel cup 16 is arranged in metal bath 17.This magnetic stirrer 19 is arranged on the below of metal bath 17, and it drives magnetic stir bar 15 to rotate.
This infrared heater 18 is arranged on the outside of this high pressure vessel cup 16.In an optimal enforcement example, this infrared heater 18 envelopes all or part of lateral surface of this high pressure vessel cup 16.This infrared heater 18, for heating this high pressure vessel cup 16, makes the internal temperature of this high pressure vessel cup 16 promote.This infrared heater 18 is connected with this control device 103, receives the control command of this infrared heater 18.
This temperature sensor 20 is arranged in this metal bath 17, and for measuring tempeature, this temperature is equal to the temperature value in this high pressure vessel cup 16.The temperature value obtained measured by this temperature sensor 20, by wired or wireless mode, is sent to control device 103.
Cooling fan 21 is arranged on the below of this high pressure vessel cup 16, and its wind produced upwards can be advanced along the lateral surface of infrared heater 18, to be reached for the object of this high pressure vessel cup 16 cooling.Cooling fan 21 is connected with control device 103, the control command of receiving control device 103.
As known in Fig. 4, high-pressure oxidation reaction vessel 101 also comprises a housing 22, for forming air channel between the inwall of this housing 22 and the outer wall of this infrared heater 18 so that the wind that produces of cooling fan 21 upwards advance reduce temperature.
This working method being used for the device 100 of oxidation stability of transformer oil rapid evaluation is:
Control device 103 is filled with the high pressure oxygen (such as 5-10MPa) of specified quantitative to high-pressure oxidation reaction vessel 101 by data line control aerating device 102, it is 120 DEG C by the Data Control infrared heater 18 of temperature sensor 20 and cooling fan 21 temperature realized in high-pressure oxidation reaction vessel 101 simultaneously, now, under copper existent condition, the oxidation rate of transformer oil can be accelerated.The stir speed (S.S.) that control device 103 controls magnetic stirrer 19 is 200 turns/min, and every 1 minute gathers 1 pressure data by high-pressure pressure sensor 5, gets the destination node of oxygen pressure decline the fastest time as oxidation reaction, and stops experiment.
Wherein, when the temperature that control device 103 is found in high-pressure oxidation reaction vessel 101 by temperature sensor 20 is on the low side, control this cooling fan 21 reduce rotating speed or quit work, and control this infrared heater 18 and increase the efficiency of heating surface, to promote the temperature in high-pressure oxidation reaction vessel 101.
When control device 103 finds the temperature drift in high-pressure oxidation reaction vessel 101 by temperature sensor 20, control this cooling fan 21 and increase rotating speed, and control this infrared heater 18 and reduce the efficiency of heating surface or quit work, to reduce the temperature in high-pressure oxidation reaction vessel 101.
Then by control device 103 and cooling fan 21, the cooperatively interacting of infrared heater 18, the temperature that can control in high-pressure oxidation reaction vessel remains in the scope of oxidation stability of transformer oil evaluation national standard.
The utility model has the advantages that temperature of reaction be set in 120 degree consistent with the temperature of reaction of NB SH/T 0811 oxidation stability of transformer oil assessment method, and by improve oxygen pressure carry out Reaction time shorten.For the judgement of terminal, when adopting oxygen pressure fall off rate the fastest, the corresponding time is test findings, substitute in ASTMD2112 rotary bomb oxidation test rapid evaluation insulating oil oxidation stability method and specify, when pressure drop is to during lower than top pressure 172kPa, the basis for estimation of Experiment on Function terminal.Because under 10MPa 172kPa fall can not significant reaction go out transformer oil oxidation reaction accelerate time point.
The utility model adopts infrared heater heating, and reaction rate is fast, and thermal inertia is little, does not have the pollution problem that the oil gas volatilization of oil bath and harmful gas produce, and operation is simpler, need not loaded down with trivial details ground clean container.Adopt equipment of the present utility model institute test result to do with the equipment of employing NB SH/T 0811 method and compared with oxidation results, there is good consistance in 500 hours.The earth shortens the test period, improves work efficiency.
And the temperature stabilization in high-pressure oxidation reaction vessel can be remained on 120 DEG C by the utility model.
In sum, be described in detail the technical solution of the utility model, the obvious deformation program of the protection domain that various done by those skilled in the art do not depart from required by the utility model also all belongs to open scope of the present utility model.

Claims (10)

1. for a device for oxidation stability of transformer oil rapid evaluation, it is characterized in that, comprising: high-pressure oxidation reaction vessel, control device and aerating device;
This high-pressure oxidation reaction vessel and this aerating device are all connected with this control device, and this high-pressure oxidation reaction vessel is connected with this aerating device;
This high-pressure oxidation reaction vessel comprises further:
High pressure vessel, for measuring the temperature sensor of this high pressure vessel internal temperature, infrared heater and cooling fan;
This infrared heater is arranged on the outside of this high pressure vessel;
This cooling fan is arranged on the below of this high pressure vessel;
This temperature sensor, this infrared heater and this cooling fan are all electrically connected with this control device.
2. device as claimed in claim 1, is characterized in that, be also placed with glass cylinder in this high pressure vessel, be also disposed with gasket seal and spring shim above this glass cylinder.
3. device as claimed in claim 2, it is characterized in that, sealing pad is tetrafluoroethene gasket seal, and this spring shim is fluororubber spring shim.
4. device as claimed in claim 1, it is characterized in that, this high pressure vessel comprises high pressure vessel cup and high pressure vessel lid further, and the lower edge of this high pressure vessel lid is socketed with O-ring seal.
5. device as claimed in claim 4, it is characterized in that, the top edge of this high pressure vessel lid is provided with fixing seal ring.
6., for a high-pressure oxidation reaction vessel for oxidation stability of transformer oil rapid evaluation, it is characterized in that, comprising:
High pressure vessel, for measuring the temperature sensor of this high pressure vessel internal temperature, infrared heater and cooling fan;
This high pressure vessel is placed in this infrared heater;
This cooling fan is arranged on the below of this infrared heater;
This infrared heater and this cooling fan are all electrically connected with this control device.
7. as the container that claim 6 is stated, it is characterized in that, in this high pressure vessel, be also placed with glass cylinder, above this glass cylinder, be also disposed with gasket seal and spring shim.
8. container as claimed in claim 7, it is characterized in that, sealing pad is tetrafluoroethene gasket seal, and this spring shim is fluororubber spring shim.
9. container as claimed in claim 6, it is characterized in that, this high pressure vessel comprises high pressure vessel cup and high pressure vessel lid further, and the lower edge of this high pressure vessel lid is socketed with O-ring seal.
10. container as claimed in claim 9, it is characterized in that, the top edge of this high pressure vessel lid is provided with fixing seal ring.
CN201420619071.5U 2014-10-23 2014-10-23 For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation Expired - Fee Related CN204116340U (en)

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CN201420619071.5U CN204116340U (en) 2014-10-23 2014-10-23 For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation

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Application Number Priority Date Filing Date Title
CN201420619071.5U CN204116340U (en) 2014-10-23 2014-10-23 For device and the reaction vessel of oxidation stability of transformer oil rapid evaluation

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105738413A (en) * 2014-12-10 2016-07-06 中国石油天然气股份有限公司 Device and method for rapid detection of oxidation stability of transformer oil
CN110940608A (en) * 2018-09-21 2020-03-31 中国石油天然气股份有限公司 Device and method for determining tendency of transformer oil to generate oil sludge and capability of transformer oil to dissolve oil sludge under thermal fault condition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105738413A (en) * 2014-12-10 2016-07-06 中国石油天然气股份有限公司 Device and method for rapid detection of oxidation stability of transformer oil
CN110940608A (en) * 2018-09-21 2020-03-31 中国石油天然气股份有限公司 Device and method for determining tendency of transformer oil to generate oil sludge and capability of transformer oil to dissolve oil sludge under thermal fault condition
CN110940608B (en) * 2018-09-21 2022-06-03 中国石油天然气股份有限公司 Device and method for determining tendency of transformer oil to generate oil sludge and capability of transformer oil to dissolve oil sludge under thermal fault condition

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