CN204086135U - A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P - Google Patents

A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P Download PDF

Info

Publication number
CN204086135U
CN204086135U CN201420332842.2U CN201420332842U CN204086135U CN 204086135 U CN204086135 U CN 204086135U CN 201420332842 U CN201420332842 U CN 201420332842U CN 204086135 U CN204086135 U CN 204086135U
Authority
CN
China
Prior art keywords
volatile organic
fiber
interference
hollow
organic matter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201420332842.2U
Other languages
Chinese (zh)
Inventor
宁向平
袁剑英
李玥
梁子馨
赵春柳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Jiliang University
Original Assignee
China Jiliang University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Jiliang University filed Critical China Jiliang University
Priority to CN201420332842.2U priority Critical patent/CN204086135U/en
Application granted granted Critical
Publication of CN204086135U publication Critical patent/CN204086135U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The utility model is bright discloses a kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P, one section of hollow-core fiber is connected at single-mode fiber end, the end of hollow-core fiber is closed with certain polymeric material, between polymeric material and single-mode fiber end face, form F-P interference cavity, form volatile organic matter sensing head thus; Light beam enters the F-P interference cavity in the middle of hollow-core fiber by single-mode fiber, and when fibre-optical probe contact volatile organic matter, the thickness of polymeric material will change, thus change the length of interference cavity; The frequency spectrum of interference light is subject to the modulation of interference cavity length, by spectrometer, interference light is analyzed to the measurement that just can realize volatile organic matter.The utility model comprises wideband light source, three-dB coupler, sensor fibre, sensing probe and spectrometer.This sensor construction is simple, and compact, signal to noise ratio (S/N ratio) is high, can realize monitoring the real-time continuous of escaping gas in the system such as production run, disaster monitoring.

Description

一种基于光纤端面F-P干涉的挥发性有机物光纤传感器A Fiber Optic Sensor for Volatile Organic Compounds Based on F-P Interference of Fiber End Face

技术领域 technical field

本实用新型属于光纤传感领域,具体涉及一种基于光纤端面F-P干涉的挥发性有机物光纤传感器。该传感器结构简单,体积小巧,信噪比高,可在生产过程、灾害监测等系统中实现对挥发性有机物的实时连续监测。  The utility model belongs to the field of optical fiber sensing, in particular to a volatile organic compound optical fiber sensor based on the F-P interference of the optical fiber end face. The sensor has simple structure, small size and high signal-to-noise ratio, and can realize real-time continuous monitoring of volatile organic compounds in production process, disaster monitoring and other systems. the

背景技术 Background technique

挥发性有机物(volatile organic compounds,VOCs)是最常见的一类空气污染物,通常是指沸点在50~250℃,在常温常压下可以形成蒸汽的有机物,主要包括苯系物、有机氯化物、氟利昂系列、有机酮类、醇类、胺、醚以及脂类等。VOCs具有毒性、刺激性以及致癌性,会严重破坏环境和人体健康。因此发展灵敏、快速、准确测定空气中VOCs含量的方法是非常必要的。  Volatile organic compounds (volatile organic compounds, VOCs) are the most common type of air pollutants, usually referring to organic compounds with a boiling point of 50-250 °C that can form steam at normal temperature and pressure, mainly including benzene series, organic chlorides , Freon series, organic ketones, alcohols, amines, ethers and lipids, etc. VOCs are toxic, irritating and carcinogenic, and will seriously damage the environment and human health. Therefore, it is necessary to develop a method for sensitive, rapid and accurate determination of VOCs content in air. the

在现有的检测方法中,由于光纤的独特优点,例如体积小,损耗低,适于远程检测等,基于光纤的挥发性有机物检测越来越受到人们的重视。基于光纤的挥发性有机物检测方法种类很多,最常见的是基于光谱分析的方法,对待测气体的特征吸收谱线进行检测分析得到待测气体浓度。这种检测方法灵敏度高,响应快,但是常需要特殊的光源来匹配不同种类待测气体的吸收谱范围,因此成本高,限制了其应用范围。基于光纤光栅的挥发性有机物检测也有所报道,待测气体作用于光纤光栅外部,通过影响光纤光栅的纤芯、包层有效折射率引起谐振波长的漂移。但是光栅的刻写会对光纤造成损害,难以长期使用。  Among the existing detection methods, due to the unique advantages of optical fiber, such as small size, low loss, suitable for remote detection, etc., the detection of volatile organic compounds based on optical fiber has attracted more and more attention. There are many kinds of volatile organic compound detection methods based on optical fiber, and the most common method is based on spectral analysis, which detects and analyzes the characteristic absorption lines of the gas to be measured to obtain the concentration of the gas to be measured. This detection method has high sensitivity and fast response, but often requires a special light source to match the absorption spectrum range of different types of gases to be measured, so the high cost limits its application range. The detection of volatile organic compounds based on fiber Bragg grating has also been reported. The gas to be measured acts on the outside of the fiber Bragg grating and causes the shift of the resonance wavelength by affecting the effective refractive index of the fiber core and cladding of the fiber Bragg grating. However, the writing of the grating will cause damage to the optical fiber, making it difficult to use for a long time. the

针对上述问题,我们提出了一种基于光纤端面F-P干涉的挥发性有机物光纤传感器。这种传感器结构紧凑,可长期重复测量,便于微量监测,灵敏度高,同时具有光纤抗温度干扰的特性,可以很好的实现不同种类挥发性有机物的检测。  Aiming at the above problems, we propose a fiber optic sensor for volatile organic compounds based on F-P interference at the fiber end face. This kind of sensor has a compact structure, can be repeated for a long time, is convenient for trace monitoring, has high sensitivity, and has the characteristics of optical fiber anti-temperature interference, which can well realize the detection of different types of volatile organic compounds. the

实用新型内容 Utility model content

本实用新型的目的是提供了一种更为灵活简单、精确度高、可靠性好的基于光纤端面F-P干涉的气体压强光纤传感器。  The purpose of the utility model is to provide a gas pressure optical fiber sensor based on the F-P interference of the optical fiber end face which is more flexible, simple, high in accuracy and good in reliability. the

本实用新型的技术解决方案如下:  The technical solution of the utility model is as follows:

一种基于光纤端面F-P干涉的挥发性有机物光纤传感器,包括宽带光源(1)、3dB耦合器(2)、传输光纤(3)、传感探头(4)和光谱仪(5);上述的3dB耦合器包含四个端口,宽带光源(1)与光谱仪(5)输入分别与3dB耦合器一侧的两个端口相连,传输光纤(3)的一端与3dB耦合器的另一侧一个端口相连,传输光纤(3)的另一端与传感探头(4)相连;  A fiber optic sensor for volatile organic compounds based on F-P interference at the end face of an optical fiber, comprising a broadband light source (1), a 3dB coupler (2), a transmission fiber (3), a sensing probe (4) and a spectrometer (5); the above-mentioned 3dB coupling The filter contains four ports, the broadband light source (1) and the input of the spectrometer (5) are respectively connected to two ports on one side of the 3dB coupler, one end of the transmission fiber (3) is connected to a port on the other side of the 3dB coupler, and the transmission The other end of the optical fiber (3) is connected with the sensing probe (4);

上述传感探头(4),其特征是由一段空芯光纤与单模光纤相熔接构成F-P干涉腔,空芯光纤长度在1-3cm之间,空芯光纤的外端面由聚合物材料封闭;所述的聚合物材料具有吸收挥发物后体积膨胀的效果。  The above-mentioned sensing probe (4) is characterized in that a section of hollow-core optical fiber and a single-mode optical fiber are fused to form an F-P interference cavity, the length of the hollow-core optical fiber is between 1-3cm, and the outer end surface of the hollow-core optical fiber is closed by a polymer material; Said polymer material has the effect of volume expansion after absorbing volatile matter. the

本实用新型的有益效果在于:  The beneficial effects of the utility model are:

一种基于光纤端面F-P干涉的挥发性有机物光纤传感器,在单模传感光纤光缆一端连接一个光纤挥发性有机物传感探头,另一端经由3dB耦合器分别与宽带光源和光谱仪相连。  A volatile organic compound optical fiber sensor based on F-P interference at the end face of the optical fiber. One end of the single-mode sensing optical fiber cable is connected to an optical fiber volatile organic compound sensing probe, and the other end is connected to a broadband light source and a spectrometer through a 3dB coupler. the

宽带光源发出光束后,通过3dB耦合器耦合进入传感光纤,光束通过传感光纤进入传感探头。光束由单模光纤进入空芯光纤当中的F-P干涉腔,干涉腔的两个反射面由聚合物材料和单模光纤端面构成。在干涉腔中形成的干涉光经由单模光纤传回,通过3dB耦合器耦合入光谱仪。  After the broadband light source emits a beam, it is coupled into the sensing fiber through a 3dB coupler, and the beam enters the sensing probe through the sensing fiber. The light beam enters the F-P interference cavity in the hollow core fiber from the single-mode fiber, and the two reflection surfaces of the interference cavity are composed of polymer material and the end face of the single-mode fiber. The interference light formed in the interference cavity is transmitted back through the single-mode fiber, and coupled into the spectrometer through the 3dB coupler. the

当挥发性有机物与所述聚合物材料接触时,聚合物材料将发生膨胀,由此改变了F-P干涉腔的腔长。由于干涉光的频谱受到干涉腔长度的调制,通过光谱仪对干涉光进行分析便能实现对挥发性有机物的测量。  When volatile organic compounds come into contact with the polymer material, the polymer material will expand, thereby changing the cavity length of the F-P interference cavity. Since the spectrum of the interference light is modulated by the length of the interference cavity, the measurement of volatile organic compounds can be realized by analyzing the interference light with a spectrometer. the

通过光谱仪对干涉光波进行分析,即可得到挥发性有机物含量的变化。该发明灵活简单、精确度高、可靠性好,适用于多种需要进行挥发性有机物的实时监控和测量的场合。  By analyzing the interference light wave with a spectrometer, the change of the content of volatile organic compounds can be obtained. The invention is flexible and simple, has high precision and good reliability, and is suitable for various occasions requiring real-time monitoring and measurement of volatile organic compounds. the

附图说明 Description of drawings

图1是一种基于光纤端面F-P干涉的挥发性有机物光纤传感器的结构示意图。  Fig. 1 is a schematic structural diagram of a VOC optical fiber sensor based on F-P interference at the end face of the optical fiber. the

图2是一种基于光纤端面F-P干涉的挥发性有机物光纤传感器传感探头的结构示意图。  Fig. 2 is a schematic structural diagram of a sensing probe of a VOC optical fiber sensor based on F-P interference at the end face of the optical fiber. the

图中:单模光纤1 空芯光纤2 聚合物材料3  In the figure: single mode fiber 1 hollow core fiber 2 polymer material 3

具体实施方式 Detailed ways

以下结合附图与具体实施方式对本发明作进一步描述:  The present invention will be further described below in conjunction with accompanying drawing and specific embodiment:

如图1示,一种基于光纤端面F-P干涉的挥发性有机物光纤传感器,包括宽带光源(1)、3dB耦合器(2)、传输光纤(3)、传感探头(4)和光谱仪(5);上述的3dB耦合器包含四个端口,宽带光源(1)与光谱仪(5)输入分别与3dB耦合器一侧的两个端口相连,传输光纤(3)的一端与3dB耦合器的另一侧一个端口相连,传输光纤(3)的另一端与传感探头(4)相连。  As shown in Figure 1, a fiber optic sensor for volatile organic compounds based on F-P interference at the fiber end face, including a broadband light source (1), a 3dB coupler (2), a transmission fiber (3), a sensing probe (4) and a spectrometer (5) ; Above-mentioned 3dB coupler comprises four ports, broadband light source (1) and spectrometer (5) input are respectively connected with two ports on one side of 3dB coupler, and one end of transmission fiber (3) is connected with the other side of 3dB coupler One port is connected, and the other end of the transmission fiber (3) is connected with the sensing probe (4). the

如图2所示,上述传感探头(4),其特征是由一段空芯光纤与单模光纤相熔接构成F-P干涉腔,空芯光纤长度在1-3cm之间,空芯光纤的外端面由聚合物材料封闭;所述的聚合物材料具有吸收挥发物后体积膨胀的效果。  As shown in Figure 2, the above-mentioned sensing probe (4) is characterized in that a section of hollow-core optical fiber and a single-mode optical fiber are fused together to form an F-P interference cavity, the length of the hollow-core optical fiber is between 1-3cm, and the outer end surface of the hollow-core optical fiber Closed by a polymer material; said polymer material has the effect of volume expansion after absorbing volatile matter. the

本实用新型基于以下原理:  The utility model is based on the following principles:

宽带光源发出能量为I0的光束,3dB耦合器耦合进入传感光纤,再由传感光纤传导入有空心光纤构成的F-P干涉腔中。干涉光束经由单模光纤通过3dB耦合器进入光谱仪。光谱仪接受到的干涉光可表示为:  The broadband light source emits a light beam with energy I 0 , which is coupled into the sensing fiber by a 3dB coupler, and then transmitted into the FP interference cavity composed of a hollow fiber by the sensing fiber. The interfering beam enters the spectrometer via a single-mode fiber through a 3dB coupler. The interference light received by the spectrometer can be expressed as:

其中为相位角,λ为光波波长,neff为有效折射率,ΔL为干涉腔的长度变化量。利用相位解调可以实现对腔的长度L的求解。在中心波长处对进行泰勒展开:  in is the phase angle, λ is the wavelength of light, n eff is the effective refractive index, and ΔL is the length variation of the interference cavity. The length L of the cavity can be solved by phase demodulation. at the center wavelength for Perform Taylor expansion:

有  when have

ΔλΔλ == λλ 00 22 nno effeff ·· ΔLΔL -- -- -- (( 33 ))

由此得到干涉腔的长度变化ΔL与干涉波长变化Δλ的关系。  Thus, the relationship between the length change ΔL of the interference cavity and the interference wavelength change Δλ is obtained. the

通过光谱仪测量干涉波长的变化Δλ就可以得到由于挥发性有机物含量变化而引起的空芯光纤内部F-P干涉腔的长度变化ΔL。  By measuring the change Δλ of the interference wavelength with a spectrometer, the length change ΔL of the F-P interference cavity inside the hollow-core fiber caused by the change of the content of volatile organic compounds can be obtained. the

本实施方式的工作方式为:  The way this implementation works is:

宽带光源发的光入射到3dB耦合器中,光通过耦合器,经过传输光纤到达传感探头;由于吸收了外界的挥发性有机物,传感探头末端的聚合物材料发生膨胀,使传感探头内F-P腔长发生改变;F-P腔内的干涉光波长受到腔长的调制;干涉光波由传输光纤经由3dB耦合器进入到光谱仪中;由光谱仪可以观察到有挥发性有机物引起的干涉波长漂移;由此该传感器可以实现对挥发性有机物的传感。  The light emitted by the broadband light source is incident into the 3dB coupler, and the light passes through the coupler and reaches the sensing probe through the transmission fiber; due to the absorption of volatile organic compounds from the outside, the polymer material at the end of the sensing probe expands, causing the sensor probe to The F-P cavity length changes; the interference light wavelength in the F-P cavity is modulated by the cavity length; the interference light wave enters the spectrometer from the transmission fiber through the 3dB coupler; the interference wavelength shift caused by volatile organic compounds can be observed by the spectrometer; thus The sensor can realize the sensing of volatile organic compounds. the

该装置能实现挥发性有机物传感的关进技术为:  The shut-in technology that can realize the sensing of volatile organic compounds in this device is:

1.传感探头的端面镀有一种聚合物材料,这种聚合物材料与挥发性有机物接触时,聚合物材料将发生膨胀,其在空芯光纤内的长度将增加。随挥发性有机物浓度的增加,聚合物体积也将不断增加。  1. The end face of the sensing probe is coated with a polymer material. When the polymer material contacts with volatile organic compounds, the polymer material will expand and its length in the hollow-core optical fiber will increase. As the concentration of volatile organic compounds increases, the volume of the polymer will also increase continuously. the

2.在空芯光纤内,有聚合物材料和单模光纤端面构成F-P干涉腔。随着聚合物材料长度的变化,空芯光纤内的F-P干涉腔的长度将发生改变。由于干涉光的频谱受到干涉腔长度的调制,通过光谱仪对干涉光进行分析便能实现对挥发性有机物的测量。  2. In the hollow-core fiber, there are polymer materials and single-mode fiber end faces to form an F-P interference cavity. As the length of the polymer material changes, the length of the F-P interference cavity in the hollow-core fiber will change. Since the spectrum of the interference light is modulated by the length of the interference cavity, the measurement of volatile organic compounds can be realized by analyzing the interference light with a spectrometer. the

Claims (1)

1., based on the volatile organic matter Fibre Optical Sensor that fiber end face F-P interferes, comprise wideband light source (1), three-dB coupler (2), Transmission Fibers (3), sensing probe (4) and spectrometer (5); Above-mentioned three-dB coupler comprises four ports, wideband light source (1) and spectrometer (5) input and are connected with two ports of three-dB coupler side respectively, the port in one end of Transmission Fibers (3) and the opposite side of three-dB coupler is connected, and the other end of Transmission Fibers (3) is connected with sensing probe (4);
Above-mentioned sensing probe (4), it is characterized in that forming F-P interference cavity by one section of hollow-core fiber and the welding of single-mode fiber phase, hollow-core fiber length is between 1-3cm, and the outer face of hollow-core fiber is closed by polymeric material; Described polymeric material has the effect absorbing volumetric expansion after volatile matter.
CN201420332842.2U 2014-06-16 2014-06-16 A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P Expired - Fee Related CN204086135U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201420332842.2U CN204086135U (en) 2014-06-16 2014-06-16 A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201420332842.2U CN204086135U (en) 2014-06-16 2014-06-16 A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P

Publications (1)

Publication Number Publication Date
CN204086135U true CN204086135U (en) 2015-01-07

Family

ID=52178836

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201420332842.2U Expired - Fee Related CN204086135U (en) 2014-06-16 2014-06-16 A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P

Country Status (1)

Country Link
CN (1) CN204086135U (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105510277A (en) * 2015-12-01 2016-04-20 北京无线电计量测试研究所 Optical fiber methane sensor
CN113281579A (en) * 2021-04-28 2021-08-20 西安理工大学 Chip packaging electrostatic measurement sensor based on F-P interference principle
CN113701915A (en) * 2021-09-03 2021-11-26 西安石油大学 Preparation method of polymer-filled optical fiber temperature sensor embedded with air bubbles

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105510277A (en) * 2015-12-01 2016-04-20 北京无线电计量测试研究所 Optical fiber methane sensor
CN113281579A (en) * 2021-04-28 2021-08-20 西安理工大学 Chip packaging electrostatic measurement sensor based on F-P interference principle
CN113701915A (en) * 2021-09-03 2021-11-26 西安石油大学 Preparation method of polymer-filled optical fiber temperature sensor embedded with air bubbles
CN113701915B (en) * 2021-09-03 2023-06-23 西安石油大学 Preparation method of a polymer-filled optical fiber temperature sensor with embedded air bubbles

Similar Documents

Publication Publication Date Title
CN205941356U (en) Optical fiber sensor of simultaneous measurement volatile organic compounds concentration and temperature
CN107515054B (en) Optical fiber temperature and refractive index measurement sensing device based on Michelson interferometer
CN102419313B (en) Michelson interferometer based optical-fiber refraction index sensor and measuring method thereof
CN101929955B (en) Optical fiber Bragg grating refractive index sensor
CN104330101A (en) Optical fiber sensor capable of measuring temperatures and micrometric displacement simultaneously
CN106323915B (en) A device for detecting hydrogen sulfide gas based on optical fiber M-Z interferometer
CN206321374U (en) A kind of fabry perot interferometer baroceptor based on optical fiber ring laser
CN204718708U (en) A kind of sensor simultaneously measured with strain based on temperature that is spherical and thin-core fibers
CN104316106A (en) Optical fiber sensor based on Mach-Zehnder interference and fiber bragg grating
CN104807765B (en) The Gas in Oil of Transformer detection means of high sensitivity spectral absorption damped oscillation chamber
CN103852191B (en) The fibre optic temperature sensor that a kind of refractive index is insensitive
CN102279164A (en) Difference measurement method and device for low moisture content of fiber bragg grating with double wavelengths and double light paths
CN103528609A (en) Combined interference type multi-parameter optical fiber sensor
CN103278185A (en) Cavity ring-down fiber grating sensing demodulating device based on calibrated fiber grating
CN203587177U (en) Optical fiber liquid level sensor
CN105044033B (en) A kind of intensity demodulation type optical fiber gas sensing device and its method for sensing
CN109490235A (en) Spectrographic detection type gas sensor based on optical fiber Sagnac ring and optical fiber FP chamber cascade enhanced sensitivity
CN105783781A (en) Curvature sensor based on cladding mode interference with fiber Bragg grating
CN204086135U (en) A kind of volatile organic matter Fibre Optical Sensor of interfering based on fiber end face F-P
CN102226762B (en) Volatile organic compound sensor based on HC-PBF band gap movement
CN203657934U (en) Reflection-type temperature/refractive index two-parameter sensing device employing long-period FBG based on Sagnac ring
CN103196475B (en) Hybrid fiber bragg grating sensing system for simultaneously measuring temperature, humidity and gas concentration
CN106248602B (en) Hydrogen Sulfide Gas Sensing Device Based on Fiber F-P Interferometer
CN108318452A (en) A kind of cone of intensity modulation type four light fibre humidity transducer
CN204964381U (en) Gelatin concentration detection system based on different core fibre structure of single mode

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150107

Termination date: 20150616

EXPY Termination of patent right or utility model