CN204058558U - The golden agitator of a kind of ultrasound-enhanced leaching - Google Patents
The golden agitator of a kind of ultrasound-enhanced leaching Download PDFInfo
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- CN204058558U CN204058558U CN201420429703.1U CN201420429703U CN204058558U CN 204058558 U CN204058558 U CN 204058558U CN 201420429703 U CN201420429703 U CN 201420429703U CN 204058558 U CN204058558 U CN 204058558U
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- transmission shaft
- cell body
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- agitator
- golden
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- 238000002386 leaching Methods 0.000 title claims abstract description 27
- 238000002604 ultrasonography Methods 0.000 title claims abstract description 21
- 230000005540 biological transmission Effects 0.000 claims abstract description 41
- 210000005056 cell body Anatomy 0.000 claims abstract description 18
- 238000009423 ventilation Methods 0.000 claims abstract description 9
- 238000012546 transfer Methods 0.000 abstract description 3
- 238000005272 metallurgy Methods 0.000 abstract description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 19
- 239000010931 gold Substances 0.000 description 19
- 229910052737 gold Inorganic materials 0.000 description 19
- 238000000034 method Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 238000000605 extraction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- MJLGNAGLHAQFHV-UHFFFAOYSA-N arsenopyrite Chemical compound [S-2].[Fe+3].[As-] MJLGNAGLHAQFHV-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000017179 Crocus angustifolius Nutrition 0.000 description 1
- 241000181637 Crocus angustifolius Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 229910052964 arsenopyrite Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- -1 permanganate Chemical compound 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The utility model relates to the golden agitator of a kind of ultrasound-enhanced leaching, belongs to technical field of wet metallurgy.The golden agitator of this ultrasound-enhanced leaching, comprise cell body, opening for feed, discharge port, whipped-up structure, ultrasound structure and ventilation device, described whipped-up structure comprises paddle wheel, transmission shaft and electric motor, ultrasound structure comprises ultrasonic transducer, wire, ultrasonic generator and turner, ventilation device comprises ventage and air outlet, described cell body departs from cell body center and arranges the transmission shaft passed from cell body top, transmission shaft bottom is provided with paddle wheel, transmission shaft upper end connects electric motor, transmission shaft is installed the ultrasonic transducer in hollow cylindrical, ultrasonic transducer is connected with ultrasonic generator by wire, wire is provided with turner and this turner is connected with transmission shaft top, transmission shaft is that hollow shape top end face is provided with ventage, transmission shaft bottom end face is provided with air outlet.This agitator improves rate of mass transfer.
Description
Technical field
The utility model relates to the golden agitator of a kind of ultrasound-enhanced leaching, belongs to technical field of wet metallurgy.
Background technology
Gold have also been obtained widespread use, as technical fields such as electronics, communication, aerospace, chemical industry, medical treatment due to its excellent performance in modern high technology industry.Along with the continuous increase of gold mine mining mineral resource amount, the reserves that higher-grade easily processes gold mine are day by day exhausted, and Refractory Au-ores will become the valuable source of gold industry from now on.How effectively and the exploitation Refractory Au-ores of persistence, be China's gold industry technical barrier in the urgent need to address.
Verified in gold geology reserves in China, about had about 1000t to belong to pyrite/arsenopyrite coated Refractory Au-ores, it is one of main Refractory Au-ores.The embedding cloth of gold in this kind of gold mine among pyrite and mispickel lattice, and wherein the sulphur of high-content and arsenic very harmful to Cyanide Leaching; Industrially must carry out pre-treatment to it, open the parcel to gold, remove the material that sulphur and arsenic etc. affect cyaniding simultaneously, can effective Leaching of Gold.At present, the industrial method for pre-oxidizing applied has: roasting method, high-pressure oxidation method, biological pre-oxidation method, oxidation method etc., but these methods all exist certain deficiency.Such as, roasting method easily causes burning, forms caking, hinders gold to leach further, and along with the raising of environmental requirement, waste gas pollution control and treatment cost improves, and its range of application is restricted; High-pressure oxidation method operates at high temperature under high pressure, and equipment material requires high, and investment cost is large, and undesirable to the material treatment effect higher containing organic carbon; The available bacterial classification of bacterial oxidation method is limited, and reaction time is long, ensure that bacteria live and breeding make reaction conditions comparatively harsh.Recent decades, along with the continuous research of scientific worker, successively there is Nitric acid catalyzing and oxidizing method, chlorination process and adopted the chemical substances such as superoxide, permanganate, potassium bichromate, perchlorate, hypochlorite, ozone to carry out the method for preoxidation in oxidation treatment process, but these methods, due to problems such as equipment, operation or costs, rest on the laboratory study stage substantially.
Although under the long-term endeavour of investigators, cyanide gold-leaching technology is own through obtaining significant progress.Along with peroxide reagent helps the appearance of leaching technology, the development of technology for gold extraction has been pushed to a climax.Under the effect of peroxide reagent that hydrogen peroxide is representative, the leaching rate of gold and even leaching yield are obtained for and significantly improve, and the leaching gold time significantly shortens.But, continue development on this basis and just seem more difficult.Soak golden speed to seem to reach certain limit, be difficult to substantial further raising.Therefore, technology for gold extraction development reach this climax stage while, enter again " bottleneck " stage.In this case, continue to improve the golden speed of leaching, need a kind of new breakthrough, and the fundamental way realizing new breakthrough be exactly seek new thinking from the intrinsic propesties of the golden process of leaching.Therefore, how intense cyaniding gold extraction technology, enhances productivity, thus reaches the reduction scale of capital construction, investment reduction, reduction production cost, has become key subjects of current gold scientific effort.
Summary of the invention
For above-mentioned prior art Problems existing and deficiency, the utility model provides a kind of ultrasound-enhanced leaching golden agitator.The golden agitator transmission shaft of this ultrasound-enhanced leaching and paddle wheel depart from cell body center, effectively prevent phenomenon of turning round and round, and be conducive to the Homogeneous phase mixing of solid-liquid-gas three-phase, improve rate of mass transfer, the utility model is achieved through the following technical solutions.
The golden agitator of a kind of ultrasound-enhanced leaching, comprise cell body 9, opening for feed 11, discharge port 12, whipped-up structure, ultrasound structure and ventilation device, described whipped-up structure comprises paddle wheel 1, transmission shaft 3 and electric motor 4, ultrasound structure comprises ultrasonic transducer 2, wire 6, ultrasonic generator 7 and turner 8, ventilation device comprises ventage 5 and air outlet 10, described cell body 9 departs from cell body center and arranges the transmission shaft 3 passed from cell body 9 top, transmission shaft 3 bottom is provided with paddle wheel 1, transmission shaft 3 upper end connects electric motor 4, transmission shaft 3 is installed the ultrasonic transducer 2 in hollow cylindrical, ultrasonic transducer 2 is connected with ultrasonic generator 7 by wire 6, wire 6 is provided with turner 8 and this turner 8 is connected with transmission shaft 3 top, transmission shaft 3 is provided with ventage 5 for hollow shape top end face, transmission shaft 3 is provided with air outlet 10 for hollow shape bottom end face.
End face side, described cell body 9 top is provided with opening for feed 11, and bottom cell body 9, side is provided with discharge port 12.
The using method of the golden agitator of this ultrasound-enhanced leaching: when connecting electric motor 4, electric motor 4 drives paddle wheel 1 rotation at a high speed along clockwise direction by transmission shaft 3.Ventilate to the ventage 5 on transmission shaft 3 top, gas is gone out by the air outlet 10 bottom transmission shaft 3 simultaneously, and the ore pulp in agitator can form airwater mist cooling admixture under the state stirred; Ore pulp in stirrer, under the air passed into and the strong stirring action of impeller 1, forms powerful eddy current rotary motion.Because transmission shaft 3 departs from cell body center, effectively prevent phenomenon of turning round and round, be conducive to airwater mist cooling mixing, make the increase of diffusion like this, accelerate the golden speed of leaching to a certain extent, meanwhile, the electric power that ultrasonic generator 7 produces is transferred to ultrasonic transducer 2 by wire 6, then electric energy conversion is that acoustic energy launches ultrasonic wave to the ore pulp in agitator 9 by ultrasonic transducer 2, and ultrasonic wave produces cavitation phenomenon in ore pulp.When cavitation bubble collapses, in space minimum in very short time and around cavitation bubble, produce the high temperature and about 5 × 10 of more than 5000K
7the high pressure of Pa, rate of temperature change is up to 10
9k/s, and the jet producing that strong shockwave and (or) speed per hour reach 400Km, the strong impact force formed under cavitation and acoustic pressure effect due to ore pulp and jet impulse goldc grains, therefore goldc grains surface is difficult to form passivation layer.Jet produces strong stirring action to ore pulp again, accelerates and facilitate the dissolving of goldc grains.To the continuous and effective leaching oxygen that ore pulp solution passes into air and both leaching process can be provided to need and also ensure that ultrasonic cavitation.In sum, due to paddle wheel 1 and pass into the violent stirring effect of air and hyperacoustic cavatition, largely solving the problem producing passivation layer when soaking gold, achieving the leaching velocity accelerating gold, improve the leaching yield of gold, shorten the object of extraction time.
The beneficial effects of the utility model are: transmission shaft and the paddle wheel of (1) this agitator depart from cell body center, effectively prevent phenomenon of turning round and round, and are conducive to the Homogeneous phase mixing of solid-liquid-gas three-phase, improve rate of mass transfer; (2) transmission shaft of this agitator is designed to hollow, and there is ventpipe on top, and there is escape pipe lower end, and ventilation effect directly occurs in transmission shaft, accelerates the gas stirring effect of ore pulp, has saved the device space simultaneously; (3) this agitator ultrasonic transducer is hollow cylindrical, can directly be enclosed within transmission shaft, can increase according to required ultrasonic power or reduce ultrasonic transducer quantity, ultrasonic transducer dismounting, easy for installation; (4) this agitator means structure is simple, stable.
Accompanying drawing explanation
Fig. 1 is the golden agitator structure schematic diagram of the ultrasound-enhanced leaching of the utility model.
In figure: 1-paddle wheel, 2-ultrasonic transducer, 3-transmission shaft, 4-electric motor, 5-ventage, 6-wire, 7-ultrasonic generator, 8-turner, 9-cell body, 10-air outlet, 11-opening for feed, 12-discharge port.
Embodiment
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Embodiment 1
As shown in Figure 1, the golden agitator of this ultrasound-enhanced leaching, comprise cell body 9, opening for feed 11, discharge port 12, whipped-up structure, ultrasound structure and ventilation device, described whipped-up structure comprises paddle wheel 1, transmission shaft 3 and electric motor 4, ultrasound structure comprises ultrasonic transducer 2, wire 6, ultrasonic generator 7 and turner 8, ventilation device comprises ventage 5 and air outlet 10, described cell body 9 departs from cell body center and arranges the transmission shaft 3 passed from cell body 9 top, transmission shaft 3 bottom is provided with paddle wheel 1, transmission shaft 3 upper end connects electric motor 4, transmission shaft 3 is installed the ultrasonic transducer 2 in hollow cylindrical, ultrasonic transducer 2 is connected with ultrasonic generator 7 by wire 6, wire 6 is provided with turner 8 and this turner 8 is connected with transmission shaft 3 top, transmission shaft 3 is provided with ventage 5 for hollow shape top end face, transmission shaft 3 bottom end face is provided with air outlet 10.
Wherein end face side, cell body 9 top is provided with opening for feed 11, and bottom cell body 9, side is provided with discharge port 12.
By reference to the accompanying drawings embodiment of the present utility model is explained in detail above, but the utility model is not limited to above-mentioned embodiment, in the ken that those of ordinary skill in the art possess, various change can also be made under the prerequisite not departing from the utility model aim.
Claims (2)
1. the golden agitator of ultrasound-enhanced leaching, it is characterized in that: comprise cell body (9), opening for feed (11), discharge port (12), whipped-up structure, ultrasound structure and ventilation device, described whipped-up structure comprises paddle wheel (1), transmission shaft (3) and electric motor (4), ultrasound structure comprises ultrasonic transducer (2), wire (6), ultrasonic generator (7) and turner (8), ventilation device comprises ventage (5) and air outlet (10), described cell body (9) departs from cell body center and arranges the transmission shaft (3) passed from cell body (9) top, transmission shaft (3) bottom is provided with paddle wheel (1), transmission shaft (3) upper end connects electric motor (4), the upper ultrasonic transducer (2) installed in hollow cylindrical of transmission shaft (3), ultrasonic transducer (2) is connected with ultrasonic generator (7) by wire (6), wire (6) is provided with turner (8) and this turner (8) is connected with transmission shaft (3) top, transmission shaft (3) is provided with ventage (5) for hollow shape top end face, transmission shaft (3) bottom end face is provided with air outlet (10).
2. the golden agitator of ultrasound-enhanced leaching according to claim 1, is characterized in that: end face side, described cell body (9) top is provided with opening for feed (11), and side, cell body (9) bottom is provided with discharge port (12).
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104805289A (en) * | 2015-03-26 | 2015-07-29 | 中国环境科学研究院 | Efficient and automatic device for recovering cadmium ions in high-cadmium solution and recovery method |
CN107201443A (en) * | 2017-06-23 | 2017-09-26 | 厦门环资矿业科技股份有限公司 | A kind of automatic leaching device |
CN112391526A (en) * | 2020-11-11 | 2021-02-23 | 郑州大学 | Mining multifunctional ultrasonic pretreatment device and use method thereof |
-
2014
- 2014-08-01 CN CN201420429703.1U patent/CN204058558U/en active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104805289A (en) * | 2015-03-26 | 2015-07-29 | 中国环境科学研究院 | Efficient and automatic device for recovering cadmium ions in high-cadmium solution and recovery method |
CN107201443A (en) * | 2017-06-23 | 2017-09-26 | 厦门环资矿业科技股份有限公司 | A kind of automatic leaching device |
CN107201443B (en) * | 2017-06-23 | 2019-05-10 | 厦门环资矿业科技股份有限公司 | A kind of automatic leaching device |
CN112391526A (en) * | 2020-11-11 | 2021-02-23 | 郑州大学 | Mining multifunctional ultrasonic pretreatment device and use method thereof |
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