CN203904775U - Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board - Google Patents
Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board Download PDFInfo
- Publication number
- CN203904775U CN203904775U CN201420313668.7U CN201420313668U CN203904775U CN 203904775 U CN203904775 U CN 203904775U CN 201420313668 U CN201420313668 U CN 201420313668U CN 203904775 U CN203904775 U CN 203904775U
- Authority
- CN
- China
- Prior art keywords
- antibacterial
- paper
- base paper
- layer
- mould inhibitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The utility model relates to novel antibacterial, mildewproof and moistureproof decorative paper for an artificial board. The decorative paper comprises base paper and a compound layer, wherein the compound layer sequentially comprises a first resin layer, a second resin layer and an antibacterial and mildewproof layer. The product provided by the utility model is good in moistureproof, antibacterial and mildewproof performances.
Description
Technical field
The utility model relates to wood-based plate facing paper technical field, is specifically related to a kind of antibacterial, mildew-resistant, moistureproof artificial board facing paper.
Background technology
In recent years, people bring up to unprecedented height to the attention of disease Control and prevention, and the public is more and more higher to the hygienic requirements of self inhabitation, work and living environment, and this has greatly promoted the fast development of antimicrobial technology and anti-biotic material.Antimicrobial technology and anti-biotic material have had epoch-making achievement in weaving and leather field, but in wood-based plate facing paper industry, are also in the exploratory stage.
There will be a few thousand sheets facing paper adhesion phenomena on the one hand in facing paper industry, the wood-based plate facing paper of producing is in the time of stacking, and under Action of Gravity Field, the bond paper of bottom is easily sticked together.Secondly, the production of facing paper, is generally one and soaks Lauxite, two soak melamine resin, no matter be Lauxite or melamine resin, before not solidifying completely, all contain a large amount of hydrophilic radicals, such as hydroxyl (OH) and amino (NH
2), hydrophilic radical easily absorbs airborne moisture, Lauxite and melamine resin are partly dissolved, thereby generation adhesion phenomenon, Action of Gravity Field in addition, the bonding of bottom must be tighter, and facing paper itself is very crisp, as easy as rolling off a log tearing while separating paper, thus cause scrapping, can not use.
On the other hand because facing facing paper goods are easily stained and grow a large amount of harmful microorganisms such as bacterium, fungi in using and depositing process, thereby become the important propagating source of disease.Therefore, how to develop antibacterial, mildew-resistant, moistureproof facing paper ornament materials is existing market main flow.
At present, to be mainly divided into inorganic be antibacterial, mould inhibitor and organic anti-bacterial, mould inhibitor to antibacterial, mould inhibitor.Inorganic series antibacterial agent is the antibacterial ability that utilizes the metals itself such as silver, copper, zinc to have, by the method such as physical absorption or ion-exchange, antiseptic is made on the surface that the metals such as silver, copper, zinc or its ion is fixed on to the porous material such as zeolite, silica gel, is then joined and in goods, just can obtain the material with antibiotic property.The metals such as mercury, cadmium, lead have the same anti-microbial property of silver, but its ion is harmful, and the metal ions such as copper, nickel, cobalt, with certain color, can affect the appearance colour of goods.Patent: CN2556247Y provides the preparation method of antibiotic impregnated bond paper, and the material of employing is nano-titanium oxide or nano zine oxide, and this material is with having certain antibiotic property, but its intensity is only 1/1000 of nano silver material.Therefore silver ion antimicrobial agent dominate in inorganic series antibacterial agent.
On market effect preferably antibacterial, mould inhibitor be respectively silver-series antibacterial agent and quaternary ammonium salt antiseptic.Wherein silver-series antibacterial agent is stripping property, and antibacterial range is wide, corrosion-resistant, uses safety, and can kill the bacterium having infected.But the light sensitive effect of silver-series antibacterial agent is very strong, easily oxidation stain, affects the outward appearance of material.And quaternary ammonium salt antiseptic is non-dissolution type antiseptic, there is anti-microbial property good, sterilization speed is fast, but can only suppress the harmful bacteria of material itself, is difficult to untouchable position to produce bactericidal action.
Utility model content
The purpose of this utility model is to overcome the defect of above-mentioned prior art, and a kind of antibacterial, mildew-resistant, moistureproof artificial board facing paper and preparation method thereof are provided.
For addressing the above problem, the technical scheme that the utility model adopts is as follows:
A kind of antibacterial and mouldproof, moistureproof artificial board facing paper, comprise base paper, and it also comprises the composite bed being compounded on base paper, and described composite bed is followed successively by the first resin bed, the second resin bed and antibacterial and mouldproof layer from the bottom up; Described the first resin bed is low urea formaldehyde resin layer; Described the second resin bed is melmac layer.
Wherein, described antibacterial and mouldproof layer is made up of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor.
This artificial board facing paper, wherein, low urea formaldehyde resin layer is mainly filled the space in printing paper fiber; Melamine resin layer is given water-fast, the resistant in surface, the performance such as heat-resisting, weather-proof; Organic and inorganic antibiotic layer, that organic and inorganic antiseptic plays is antibacterial, mildew-resistant, moistureproof performance; And organic and inorganic antibiotic layer forms fine and close protection structure; can avoid the hydrophilic radical in Lauxite layer or melamine resin layer to contact with airborne steam, thereby avoid moisture that Lauxite and melamine resin are partly dissolved to generation adhesion phenomenon.
In the utility model, further preferred scheme is that described base paper is made up of paper fiber, between described adjacent paper fiber, there is hole, the compound surface of described low urea formaldehyde resin layer and base paper be provided with and base paper on the projection that matches of space between paper fiber, described projection is filled in space.This structural design, makes base paper and composite bed realize good compound action, avoid compound insecure and produce easily separated phenomenon.
Compared with prior art, the utility model has the advantages that: artificial board facing paper, wherein, low urea formaldehyde resin layer is mainly filled the space in printing paper fiber; Melamine resin layer is given water-fast, the resistant in surface, the performance such as heat-resisting, weather-proof; Organic and inorganic antibiotic layer, that organic and inorganic antiseptic plays is antibacterial, mildew-resistant, moistureproof performance; And organic and inorganic antibiotic layer forms fine and close protection structure, can avoid the hydrophilic radical in Lauxite layer or melamine resin layer to contact with airborne steam, avoid moisture that thereby Lauxite and melamine resin are partly dissolved to generation adhesion phenomenon, there is moistureproof effect; Between described adjacent paper fiber, there is hole, the compound surface of described low urea formaldehyde resin layer and base paper be provided with and base paper on the projection that matches of space between paper fiber, described projection is filled in space, this structural design, make base paper and composite bed realize good compound action, avoid compound insecure and produce easily separated phenomenon.
Below in conjunction with the drawings and the specific embodiments, the utility model is described in further detail.
Brief description of the drawings
Fig. 1 is antibacterial, the mildew-resistant of the utility model embodiment 1, moistureproof artificial board facing paper structural representation.
Detailed description of the invention
Embodiment 1
In conjunction with Fig. 1.A kind of antibacterial, mildew-resistant, moistureproof artificial board facing paper, comprise base paper 1, and it also comprises the composite bed being compounded on base paper, and described composite bed is followed successively by the first resin bed 2, the second resin bed 3 and antibacterial and mouldproof layer 4 from the bottom up; Described the first resin bed is low urea formaldehyde resin layer; Described the second resin bed is melmac layer; Described antibacterial, mildew-resistant layer is made up of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor.
This is antibacterial, mildew-resistant, moistureproof artificial board facing paper make just like below method:
Get woodgrained paper (being base paper), weigh by weight following component: 100 parts of low urea formaldehyde resins; 0.1 part of bleeding agent; 0.2 part, low urea formaldehyde resin curing agent; 40 parts of melmacs; Melamine cured dose 0.1 part; 0.04 part of releasing agent; 0.1 part of dedusting agent; 0.04 part of defoamer; 0.5 part of organic anti-bacterial, mould inhibitor; 0.5 part, inorganic antibacterial, mildew-resistant powder; 12 parts of organic solvents; PVP2 part.
(1) prepare low urea formaldehyde resin and melmac;
The preparation method of the low urea formaldehyde resin in described step (1) is: get 0.1 part of 100 parts of low urea formaldehyde resins by weight, 0.2 part, low urea formaldehyde resin curing agent and bleeding agent and mix, then regulate that pH is 6.8, viscosity is for (25 DEG C, be coated with 4 glasss) 12 seconds, solid content are 40%, density is 1.1 (g/cm
3), water number is 2.0, to obtain final product;
The preparation method of the melmac in described step (1) is: get 0.04 part of 40 parts, melamine cured dose 0.1 part of melmac by weight, 0.04 part of releasing agent, 0.1 part of dedusting agent and defoamer mix then regulate that pH is 8.0, viscosity is for (25 DEG C, be coated with 4 glasss) 13 seconds, solid content are 49%, density is 1.20 (g/cm
3), water number is 1.8, to obtain final product.
(2) prepare organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor;
The preparation method of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor is in described step (2): get parts by weights meter 12 parts of inorganic antibacterial, 0.5 part of mould inhibitor, PVP2 part and ethanol are mixed, then ultrasonic dispersion 20min makes inorganic antibacterial, mould inhibitor dispersion suspension liquid; Then in inorganic antibacterial, mould inhibitor dispersion suspension liquid, add 0.5 part of organic anti-bacterial, mould inhibitor by weight, to obtain final product.
(3) get base paper, base paper be immersed in the low urea formaldehyde resin that step (1) makes, then by base paper through thering is the baking oven of 3 temperature sections; In described step (3), 3 sections of temperature of baking oven are respectively 145 DEG C, 150 DEG C and 148 DEG C, obtain low urea formaldehyde resin layer.
(4) utilize up-down rollers melamine resin to be coated on the low urea formaldehyde resin obtaining through step (3), obtain melamine resin layer;
(5) organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor are coated on the melamine resin layer obtaining through step (4), then utilize stainless steel chill roll extruding base paper, then base paper process is there is to the baking oven of 4 temperature sections, obtain antibacterial and mouldproof layer, obtain product.In described step (5), 4 sections of temperature of baking oven are respectively 140 DEG C, 156 DEG C, 158 DEG C and 140 DEG C.
Embodiment 2
A kind of antibacterial, mildew-resistant, moistureproof artificial board facing paper, comprise base paper, and it also comprises the composite bed being compounded on base paper, and described composite bed is followed successively by the first resin bed, the second resin bed and antibacterial and mouldproof layer from the bottom up; Described the first resin bed is low urea formaldehyde resin layer; Described the second resin bed is melmac layer; Described antibacterial and mouldproof layer is made up of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor.
This is antibacterial, mildew-resistant, moistureproof artificial board facing paper make just like below method:
Get woodgrained paper (being base paper), weigh by weight following component: 100 parts of low urea formaldehyde resins; 0.3 part of bleeding agent; 0.3 part, low urea formaldehyde resin curing agent; 60 parts of melmacs; Melamine cured dose 0.3 part; 0.05 part of releasing agent; 0.3 part of dedusting agent; 0.05 part of defoamer; 1 part of organic anti-bacterial, mould inhibitor; 1 part, inorganic antibacterial, mildew-resistant powder; 25 parts of organic solvents; PVP4 part.
(1) prepare low urea formaldehyde resin and melmac;
The preparation method of the low urea formaldehyde resin in described step (1) is: get 0.3 part of 100 parts of low urea formaldehyde resins by weight, 0.3 part, low urea formaldehyde resin curing agent and bleeding agent and mix, then regulate that pH is 7.5, viscosity is for (25 DEG C, be coated with 4 glasss) 14 seconds, solid content are 48%, density is 1.2 (g/cm
3), water number is 4.0, to obtain final product;
The preparation method of the melmac in described step (1) is: get 0.05 part of 60 parts, melamine cured dose 0.3 part of melmac by weight, 0.05 part of releasing agent, 0.3 part of dedusting agent and defoamer mix then regulate that pH is 9.0, viscosity is for (25 DEG C, be coated with 4 glasss) 15 seconds, solid content are 52%, density is 1.22 (g/cm
3), water number is 2.5, to obtain final product.
(2) prepare organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor;
The preparation method of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor is in described step (2): get parts by weights meter 25 parts of inorganic antibacterial, 1 part of mould inhibitor, PVP4 part and organic solvents are mixed, then ultrasonic dispersion 20min makes inorganic antibacterial, mould inhibitor dispersion suspension liquid; Then in inorganic antibacterial, mould inhibitor dispersion suspension liquid, add 1 part of organic anti-bacterial, mould inhibitor by weight, to obtain final product.
(3) get base paper, base paper be immersed in the low urea formaldehyde resin that step (1) makes, then by base paper through thering is the baking oven of 3 temperature sections, obtain low urea formaldehyde resin layer; In described step (3), 3 sections of temperature of baking oven are respectively 145 DEG C, 150 DEG C and 148 DEG C.
(4) utilize up-down rollers melamine resin to be coated on the low urea formaldehyde resin layer obtaining through step (3), obtain melamine resin layer;
(5) organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor are coated on the melamine resin layer obtaining through step (4), then utilize stainless steel chill roll extruding base paper, then base paper process is there is to the baking oven of 4 temperature sections, obtain antibacterial and mouldproof layer, obtain product.In described step (5), 4 sections of temperature of baking oven are respectively 140 DEG C, 156 DEG C, 158 DEG C and 140 DEG C.
Embodiment 3
A kind of antibacterial, mildew-resistant, moistureproof artificial board facing paper, comprise base paper, and it also comprises the composite bed being compounded on base paper, and described composite bed is followed successively by the first resin bed, the second resin bed and antibacterial and mouldproof layer from the bottom up; Described the first resin bed is low urea formaldehyde resin layer; Described the second resin bed is melmac layer; Described antibacterial and mouldproof layer is made up of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor.
This is antibacterial, mildew-resistant, moistureproof artificial board facing paper make just like below method:
Get woodgrained paper (being base paper), weigh by weight following component: 100 parts of low urea formaldehyde resins; 0.2 part of bleeding agent; 0.26 part, low urea formaldehyde resin curing agent; 50 parts of melmacs; Melamine cured dose 0.2 part; 0.048 part of releasing agent; 0.2 part of dedusting agent; 0.046 part of defoamer; 0.8 part of organic anti-bacterial, mould inhibitor; 0.6 part, inorganic antibacterial, mildew-resistant powder; 20 parts of organic solvents; PVP3 part.
(1) prepare low urea formaldehyde resin and melmac;
The preparation method of the low urea formaldehyde resin in described step (1) is: get 0.2 part of 100 parts of low urea formaldehyde resins by weight, 0.26 part, low urea formaldehyde resin curing agent and bleeding agent and mix, then regulate that pH is 7.1, viscosity is for (25 DEG C, be coated with 4 glasss) 13 seconds, solid content are 45%, density is 1.15 (g/cm
3), water number is 3.1, to obtain final product;
The preparation method of the melmac in described step (1) is: get 0.046 part of 50 parts, melamine cured dose 0.2 part of melmac by weight, 0.048 part of releasing agent, 0.2 part of dedusting agent and defoamer mix then regulate that pH is 8.5, viscosity is for (25 DEG C, be coated with 4 glasss) 14 seconds, solid content are 50%, density is 1.21 (g/cm
3), water number is 2.2, to obtain final product.
(2) prepare organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor;
The preparation method of organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor is in described step (2): get parts by weights meter 20 parts of inorganic antibacterial, 0.6 part of mould inhibitor, PVP3 part and organic solvents are mixed, then ultrasonic dispersion 20min makes inorganic antibacterial, mould inhibitor dispersion suspension liquid; Then in inorganic antibacterial, mildewproof powder preparation dispersion suspension liquid, add 0.8 part of organic anti-bacterial, mould inhibitor by weight, to obtain final product.
(3) get base paper, base paper be immersed in the low urea formaldehyde resin that step (1) makes, then by base paper through thering is the baking oven of 3 temperature sections, obtain low urea formaldehyde resin layer; In described step (3), 3 sections of temperature of baking oven are respectively 145 DEG C, 150 DEG C and 148 DEG C.
(4) utilize up-down rollers melamine resin to be coated on the low urea formaldehyde resin obtaining through step (3), obtain melamine resin layer;
(5) organic anti-bacterial, mould inhibitor and inorganic antibacterial, mould inhibitor are coated in through step (4) obtain melamine resin on, then utilize stainless steel chill roll extruding base paper, then base paper process is there is to the baking oven of 4 temperature sections, obtain antibacterial and mouldproof layer, obtain product.In described step (5), 4 sections of temperature of baking oven are respectively 140 DEG C, 156 DEG C, 158 DEG C and 140 DEG C.
Embodiment 4
Antibacterial, the mildew-resistant of getting that embodiment 1-3 makes, moistureproof artificial board facing paper, be cut into respectively the small pieces of 50 × 50mm, compiling is respectively first group, second group and the 3rd group, then the product anti-microbial property that utilizes JLSZ2801:2000 " the detection evaluation of antibacterial product anti-microbial property " to make embodiment 1-3 is evaluated, reference substance is common plastics, detection property mushroom is Gram-negative bacteria, specifically selects Escherichia coli, proteus; Gram-negative bacteria, specifically selects staphylococcus aureus, streptococcus, and testing result is in Table 1-4
Table 1: Chinese People's Anti-Japanese Military and Political College's enterobacteria performance test table
Table 2: resistance to deformation bacillus performance test chart
Table 3: streptococcus performance test table
Table 4: anti-Staphylococcus aureus performance test table
Can be found out by data in upper table, product of the present utility model is all greater than 99% to Escherichia coli, proteus, staphylococcus aureus and streptococcic anti-microbial property, has excellent anti-microbial property.
Embodiment 5
Get antibacterial that embodiment 1-3 makes, mildew-resistant, moistureproof artificial board facing paper, be cut into respectively the small pieces of 50 × 50mm, compiling is respectively first group, second group and the 3rd group, then utilize " the anti-microbial property test method of QB/T2591-2003 antibiotic plastic " to carry out fungicidal properties test, respectively by aspergillus niger, Aspergillus terreus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, the spore suspension of ball hair shell drops on testing sample and culture medium, 28 DEG C of temperature, under condition more than relative humidity 90%RH, cultivate 28d, then sample observational record data test at once and the results are shown in Table 5:
Table 5 fungicidal properties test chart
| ? | Mildew area | Ratio | Mildew-resistant grade |
| First group | Not long | 0 | 0 |
| Second group | Not long | 0 | 0 |
| The 3rd group | 20mm2 | 0.8％ | 1 |
Mildew-resistant grading index: not long, 0 grade; Mildew area is lower than 10%, 1 grade; Mildew area 10-30%, 2 grades; Mildew area 30-60%, 3 grades; Mildew area 60-100%, 4 grades.From upper table, data can be found out, product mildew-resistant grade of the present utility model reaches 0 grade or 1 grade, and fungicidal properties is superior.
In addition, the product of the embodiment 1-3 preparing, can not produce and be adhered phenomenon.
Above-mentioned embodiment is only preferred embodiment of the present utility model; the scope that can not limit with this utility model protection, the variation of any unsubstantiality that those skilled in the art does on basis of the present utility model and replacement all belong to the utility model scope required for protection.
Claims (2)
1. antibacterial, mildew-resistant, a moistureproof artificial board facing paper, comprise base paper, it is characterized in that: it also comprises the composite bed being compounded on base paper, and described composite bed is followed successively by the first resin bed, the second resin bed and antibacterial and mouldproof layer from the bottom up; Described the first resin bed is low urea formaldehyde resin layer; Described the second resin bed is melmac layer.
2. antibacterial, mildew-resistant according to claim 1, moistureproof artificial board facing paper, it is characterized in that: described base paper is made up of paper fiber, between described adjacent paper fiber, there is hole, the compound surface of described low urea formaldehyde resin layer and base paper be provided with and base paper on the projection that matches of space between paper fiber, described projection is filled in space.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420313668.7U CN203904775U (en) | 2014-06-12 | 2014-06-12 | Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420313668.7U CN203904775U (en) | 2014-06-12 | 2014-06-12 | Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203904775U true CN203904775U (en) | 2014-10-29 |
Family
ID=51779065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420313668.7U Active CN203904775U (en) | 2014-06-12 | 2014-06-12 | Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203904775U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111926622A (en) * | 2020-04-17 | 2020-11-13 | 浙江圣奥家具制造有限公司 | Antibacterial melamine decorative paper and preparation method thereof |
| CN117141094A (en) * | 2023-08-31 | 2023-12-01 | 永清霍尔茨门业有限公司 | Preparation process of super-soft fireproof plate |
-
2014
- 2014-06-12 CN CN201420313668.7U patent/CN203904775U/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111926622A (en) * | 2020-04-17 | 2020-11-13 | 浙江圣奥家具制造有限公司 | Antibacterial melamine decorative paper and preparation method thereof |
| CN117141094A (en) * | 2023-08-31 | 2023-12-01 | 永清霍尔茨门业有限公司 | Preparation process of super-soft fireproof plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104018402B (en) | A kind of antibacterial, mildew-resistant, moistureproof wood-based plate facing paper and preparation method thereof | |
| CN102584113B (en) | Preparation method of novel diatom mud environment-friendly interior wall coatings | |
| CN101733983B (en) | Inorganic nano-silver mildew-proof antibacterial healthy decorative veneer and manufacturing method thereof | |
| CN103468096B (en) | A kind of preparation method of environment-friendly type long-acting mildew-resisting paint | |
| CN105176216A (en) | Diatom ooze coating and preparation method thereof | |
| CN103725132B (en) | A kind of antibacterial self paint and preparation method thereof | |
| CN101348630A (en) | Mildewproof dew resisting coating and preparation thereof | |
| CN103469987A (en) | Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper | |
| CN103937351A (en) | Wallpaper base membrane and preparation method thereof | |
| EP3146842B1 (en) | Method for imparting an article or a hygiene product with antimicrobial activity and the article and the hygiene product imparted with the antimicrobial activity | |
| Huang et al. | Comparison of resistance improvement to fungal growth on green and conventional building materials by nano-metal impregnation | |
| US20190143267A1 (en) | Compositions and methods for removing air pollutants | |
| KR101052608B1 (en) | Aqueous paints for humidity controlling and deodorizing activity in the room | |
| CN203904775U (en) | Novel antibacterial, mildewproof and moistureproof decorative paper for artificial board | |
| CN104419279A (en) | Antibacterial hydrophilic coating | |
| CN103980833A (en) | Long-acting antibacterial wet adhesive for wallpaper and preparation method thereof | |
| JP2009013376A (en) | Water paint for interior finish | |
| CN106280998A (en) | A kind of high-efficient purification and the diatom ooze coating of oil rub resistance | |
| KR101094720B1 (en) | An ornament-plate forming the surface-layer on an ornament-sheet made of thermosetting resin having antibiosis of weather resistance | |
| KR101554027B1 (en) | Functional paint compositions | |
| CA2544740A1 (en) | Anti-bacterial additive | |
| CN204552512U (en) | A kind of wood-based plate door of heat discoloration | |
| CN103911913A (en) | Preparation method of heat-bonding deodorization mildew-resistant antibacterial silk wallpaper | |
| CN104017410A (en) | Antibacterial composite floor based on nano zinc particles | |
| CN104098949A (en) | Indoor decoration coating additive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 528100, Guangdong City, Sanshui District, Leping Town, central science and Technology Industrial Zone Planning B District 52 (F1), (F2), (F3), (F5), (F7) () Patentee after: Guangdong, Tianyuan state exchange new materials Limited by Share Ltd Address before: 528100 (F1), (F2), (), (F3), (F5), B District, Guangdong science and Technology Industrial Zone, Leping Town, Sanshui District, Chongqing City Patentee before: Foshan Tianyuan Huibang Decoration Materials Co., Ltd. |