A kind of dielectric barrier discharge ozone generating-device
Technical field
The utility model relates to ozone generating-device, relates in particular to a kind of dielectric barrier discharge ozone generating-device.
Background technology
For ozonizer, anion generator, in plasma treatment and other discharge process core component working process, can produce a large amount of heats, this heat output must be lost with guarantee equipment and works at a lower temperature, dielectric barrier discharge ozone generating-device core component is between electrode, to have one deck dielectric substance, dielectric substance is between interior electrode and outer electrode, between dielectric substance and an electrode, be provided with gap as fluid channel, in the time mating suitable driving power between interior electrode and outer electrode, controlled discharge obtains needed different discharge effect, thereby obtain and output ozone gas mixture or plasma gas mixture with later use.Discharge process is accompanied by obvious exothermic effect, if can not fine design heat-dissipating structure and technique, to make electrode and dielectric substance temperature improve constantly or remain on very high-temperature, and make discharging fluid can not be converted into efficiently and stably desired substance, serious dielectric substance and the electrode of even puncturing.
Optimal situation is under lower temperature range and relative temperature constant state, to work by guarantee equipment.Prior art adopts according to distinct device structure is general that simple single electrode is air-cooled or two electrodes is air-cooled, or the air-cooled interior electrode water-cooling pattern of outer electrode, and such type of cooling exists a lot of problems, and does not reach technical requirements.When for ozonizer, air-cooledly electrode and medium can not be controlled at temperature to desirable low-temperature condition in a long time, ozone productive rate is very low at all, and concentration is also very low, thereby cause whole set equipment only can be used in lower concentration space disinfection industry the short period of time, and unit power consumption is very large.Reasonable scheme is to adopt outer electrode list water-cooled, more better scheme adopts the air-cooled electrode water-cooled of an electrode, water coolant adopts disposable in line or recycle system secondary heat radiation, but still there are two problems in water-cooled, because adopt tap water and make system gradually fouling make cooling system lost efficacy, need to use pure water or other safer heat-conducting fluid and increase cost of investment, in any case, all heat up and heat delivery arrived outside by heat-conducting fluid contact heating electrode, between heating electrode and fluid, always maintain a higher thermograde, fluid is by general secondary heat radiation behind the electrode thermal output outside vaporizer wind method of cooling that adopts, therefore heat-conducting fluid temperature also can keep a higher gradient relative to outside temperature, the existence of secondary thermograde makes electrode temperature far above outside temperature, electrode can only keep comparatively high temps working order, its working effect is unsatisfactory, unless the freezing heat exchange mode of the cooling employing of secondary, and such method is from investment, the angle of taking up an area and move is difficult to accept, particularly middle-size and small-size equipment, too complicated system penetration and promotion in practice in addition.Nonetheless, if want keeping system working temperature a desirable low temperature range job, automatically control extremely difficult realization, these all become the bottleneck of correlation technique progress.
Common dielectric barrier discharge ozone generating-device is as tubular discharge device, and outer tubular electrode is easy to by fin-shaped scatterer, its heat loss be arrived extraneous, and interior electrode can not simply solve by similar approach.As shown in Figure 1, conventional method is by internal electrode structure water stream channel, utilizes normal temperature flowing water to take away heat, and this structure is wasted a large amount of water coolants, is difficult to the four seasons effective at northern area, is particularly difficult to automatically keep cooling of electrode temperature range.As shown in Figure 2, carry out secondary heat radiation to interior electrode peripheral hardware circulating cooling system, this system complex and taking up space, often cause dispelling the heat bad because adopt cooling water evaporation to supplement deficiency, or lost efficacy down to blocking because water quality fouling is serious, or because the system component faults such as water circulating pump cause inefficacy, even if adopting, system radiating medium still can not thoroughly address these problems such as special cooling fluid or cooling oil.Another method as shown in Figure 3, to be designed to enclosed construction with interior electrode contact refrigerant, by interchanger and secondary degree of depth cooling system exchange heat radiation, this structure is more complicated, cost is higher, takes up an area greatlyr, and working cost is higher, trouble spot is more, is only applicable to be suitable for without other Large-Scale Equipment of selection scheme.
With the exception of this, existing structure cannot by load device with mate power standard, thereby be also not suitable for any assembly standardised prod to enhance productivity and to obtain accurate production capacity equipment, as shown in Figure 4, thereby different power supplys makes between each electric discharge device altogether by sharing a set of interior electrode heat-removal system, the difficulty that has increased insulation difficulty and electromagnetic shielding, makes complete machine in fragile state.
Summary of the invention
Technical problem to be solved in the utility model is: provide a kind of good heat dissipation, the dielectric barrier discharge ozone generating-device of reliable operation.
Technical solution of the present utility model is:
A kind of dielectric barrier discharge ozone generating-device, comprise interior electrode and outer electrode, outer electrode is provided with the 1st heat abstractor outward, outer electrode inner chamber is provided with dielectric, the inner chamber of dielectric is provided with interior electrode, between the inwall of dielectric and the outer wall of interior electrode, be provided with fluid channel, one end, fluid channel is provided with feeder connection, the other end of fluid channel is provided with channel outlet, interior electrode is the tubular body arranged inside of sealing, the inner chamber of tubular body arranged inside is vacuum and heat conductive medium is housed, the inwall of described tubular body arranged inside is provided with sintered wicks layer, or the inwall of tubular body arranged inside adopts capillary inwall, tubular body arranged inside stretches out the inner chamber of dielectric and is provided with the 2nd heat abstractor.
Above-mentioned the 1st heat abstractor is fin-shaped scatterer, and above-mentioned the 2nd heat abstractor is heat-pipe radiator, or radiator element, or cold water circulation device.
Above-mentioned capillary inwall is mesh-like inwall, or channel form inwall, or spirrillum inwall.
The pressure of above-mentioned vacuum state is 1000~10000 handkerchiefs.
A kind of dielectric barrier discharge ozone generation combination unit, formed by 2 groups or 2 groups of the above dielectric barrier discharge ozone generating-devices, All Media barrier discharge ozone generating-device is all provided with independently driving power or adopts same driving power, the gapped entrance of institute is in parallel to be communicated with, in parallel connection of the gapped outlet of institute.
Technique effect of the present utility model is: in the utility model, electrode is the tubular body arranged inside of sealing, the inner chamber of tubular body arranged inside is vacuum state and heat conductive medium is housed, the inwall of described tubular body arranged inside is provided with sintered wicks layer, or the inwall of tubular body arranged inside employing capillary inwall, tubular body arranged inside stretches out the inner chamber of dielectric and is provided with the 2nd heat abstractor.In the time that electrode generates heat to heat conductive medium transformation temperature, heat conductive medium moment steam raising, because decalescence is huge, moment is reduced electrode temperature, the rear heat conductive medium of gasification is full of tubular body arranged inside inner chamber and rises to rapidly the top of the 2nd heat abstractor, by the 2nd heat abstractor, heat conductive medium temperature is reduced, in the time that temperature is down to heat conductive medium liquefaction transformation temperature, emit heat of gasification and again become liquid, be back to bottom by tubular body arranged inside inwall, go round and begin again, thereby the electrode temperature that makes to generate heat remains on heat conductive medium transformation temperature region, ozone generating-device maintains stable working order, it is high yield, high density, constant production rate, permanent concentration.Hence one can see that, and the utility model radiating efficiency is high, and volume is little, simple in structure, and reliable operation is easy to promote the use of, ozone constant production rate and permanent concentration.
Brief description of the drawings
1, Fig. 1 is existing the 1st kind of ozone generating-device radiator structure schematic diagram.
2, Fig. 2 is existing the 2nd kind of ozone generating-device radiator structure schematic diagram.
3, Fig. 3 is existing the 3rd kind of ozone generating-device radiator structure schematic diagram.
4, Fig. 4 is existing the 4th kind of ozone generating-device radiator structure schematic diagram.
5, Fig. 5 is the utility model ozone generating-device structural representation.
6, Fig. 6 is the utility model embodiment 1 structural representation.
7, Fig. 7 is the utility model embodiment 2 structural representations.
8, Fig. 8 is electrode tubular body arranged inside silk screen inwall schematic diagram in the utility model.
9, Fig. 9 is electrode tubular body arranged inside trench wall schematic diagram in the utility model.
10, Figure 10 is electrode tubular body arranged inside inwall sintered wicks layer schematic diagram in the utility model.
11, Figure 11 is electrode tubular body arranged inside spiral inwall schematic diagram in the utility model.
12, Figure 12 is the utility model embodiment 3 structural representations.
In figure: 1, tubular body arranged inside, 2, outer electrode, the 3, the 1st heat abstractor, 4, radiator element, 5, fluid channel, 6, heat conductive medium, 7, dielectric, 8, heat-pipe radiator, 9, feeder connection, 10, channel outlet, 11, water pump, 12, driving power, 13, operating panel.
Embodiment
Describe in detail below in conjunction with drawings and embodiments.
Embodiment 1
Embodiment 1 is as Fig. 5, Fig. 6, Fig. 8, Fig. 9, shown in Figure 10 and Figure 11, a kind of dielectric barrier discharge ozone generating-device, comprise interior electrode and outer electrode 2, outer the 1st heat abstractor 3 that is provided with of outer electrode 2, outer electrode 2 inner chambers are provided with dielectric 7, the inner chamber of dielectric 7 is provided with interior electrode, between the inwall of dielectric 7 and the outer wall of interior electrode, be provided with fluid channel 5, 5 one end, fluid channel are provided with feeder connection 9, the other end of fluid channel 5 is provided with channel outlet 10, interior electrode is the tubular body arranged inside 1 of sealing, the inner chamber of tubular body arranged inside 1 is vacuum and heat conductive medium 6 is housed, the inwall of described tubular body arranged inside 1 is provided with sintered wicks layer, or the inwall of tubular body arranged inside 1 adopts capillary inwall, tubular body arranged inside 1 stretches out the inner chamber of dielectric 7 and is provided with the 2nd heat abstractor.
Described the 1st heat abstractor 3 is fin-shaped scatterer, and described the 2nd heat abstractor is radiator element 4, or cold water circulation device.Described capillary inwall is mesh-like inwall, or channel form inwall, or spirrillum inwall.The pressure of described vacuum state is 1000~10000 handkerchiefs.Dielectric 7 can adopt the blocking layer of the higher dielectric coefficient such as pottery, enamel, silica glass, high pbo glass, dielectric substance can be independent existence, also can be integrally formed with interior electrode, any utmost point of outer electrode, interior electrode, outer electrode can adopt inorganic materials, the organic conductive material etc. of the copper of stainless steel, titanium or titanium alloy, nickel or nickelalloy, gold or the precious metal such as silver-colored, the anti-oxidation processing of precompose or copper alloy, interpolation rare metal.Tube wall capillary structure, be that capillary inwall is conducive to liquid phase heat conductive medium evenly to lock and inhale parent and invest heating electrode cavity inner surface and be beneficial to heat radiation evenly, the more important thing is when gasification heat conductive medium and can deliver to rapidly tubular body arranged inside inwall and be uniformly distributed by capillary structure after the liquefaction of phase transformation is again dispelled the heat on top, carry out next loop cycle.
Molded metal fins heat radiation is continued to use in the heat radiation of the utility model outer electrode, interior electrode is by the refinement of tubular body arranged inside inner wall hair or install capillary structure body additional, be processed into the structure of suitable employing heat pipe phase transformation evaporative heat loss, be filled with electric discharge device heating power and require the normal low temperature medium adapting at tubular body arranged inside inner chamber, and heat radiation after being directly connected without thermal resistance to space heat elimination or with finished product vaporization heat tube radiator by outward extending interior electrode cavity.Wherein evaporating heat conductive medium can be water-based inorganic or organic normal temperature, or low temperature phase change material, or many substance mixture, can be also inorganic or organic normal temperature or low temperature phase change material or many substance mixture of oil base, the nontoxic also non-explosive of these materials, the complex transformation point of these heat conductive mediums is optional from 0 DEG C to 100 DEG C not etc., typical in 25 DEG C, 30 DEG C, 35 DEG C, 40 DEG C, 45 DEG C; Heat conductive medium is filled with in interior electrode tubular body arranged inside cavity by equalizer valve on request in right amount in interior electrode one end, fills the force value that keeps vacuum in front and filling process in interior electrode tubular body arranged inside cavity, and typical pressure value is at 1000 to 10000 handkerchiefs.The mechanism of this evaporative heat loss is: when electrode temperature gasifies transformation temperature higher than heat conductive medium, medium suppresses electrode temperature by heating up from the heat absorption of heating electrode and jumps, in the time that electrode generates heat to heat conductive medium transformation temperature, heat conductive medium moment steam raising, because decalescence is huge, moment is reduced electrode temperature, the rear medium of gasification is full of cavity and rises to rapidly the top of secondary thermal component, by fin slices radiator and blower fan, heat conductive medium temperature is reduced, in the time that temperature is down to heat conductive medium liquefaction transformation temperature, emit heat of gasification and again become liquid, inner tubal wall by tubular body arranged inside inner chamber is back to bottom, go round and begin again, thereby the electrode temperature that makes to generate heat can remain on heat conductive medium transformation temperature region substantially, thereby make electric discharge device obtain stable working order.
Embodiment 2
As shown in Figure 7, except described the 2nd heat abstractor is heat-pipe radiator 8, heat-pipe radiator 8 adopts two heat pipe evaporation heat sinks to embodiment 2.Other structure is with embodiment 1.Heat-pipe radiator takes full advantage of the Rapid Thermal hereditary property of heat-conduction principle and refrigeration filling, sees through heat pipe the heat of thermal objects is delivered to rapidly outside thermal source and carries out cooling.
Embodiment 3
Embodiment 3 dielectric barrier discharge ozone generation combination units are made up of the dielectric barrier discharge ozone generating-device of more than 2 groups or 2 groups embodiment 1 or embodiment 2, All Media barrier discharge ozone generating-device has independently driving power or adopts same driving power, gapped in parallel connection of entrance 9 of institute, gapped in parallel connection of outlet 10 of institute.
Embodiment 3 can by load device with mate power standard, thereby suitable any assembly standardised prod is to enhance productivity and to obtain accurate production capacity equipment, every group of dielectric barrier discharge ozone generating-device power supply independent or or adopt same driving power, the difficulty that has reduced insulation difficulty and electromagnetic shielding, makes complete machine in reliable state.
Below mainly describe the utility model principle as an example of tubular type discharge-blocking device example, other the heat radiation of the internal electrode such as the multi-plate discharge-blocking device of multi-electrode is also suitable for the utility model.
The utility model unaccomplished matter does not enumerate at this, and the utility model is similar or thus extend structure all within protection domain of the present utility model.
The unspecified content of the utility model is prior art, and those skilled in the art can obtain inspiration from the present embodiment and prior art, is out of shape and obtains other embodiment.Therefore, protection domain of the present utility model should be determined according to the protection domain of claim.