CN203480852U - Lead shielding block on end face of nuclear fuel channel of heavy water nuclear reactor nuclear power station - Google Patents
Lead shielding block on end face of nuclear fuel channel of heavy water nuclear reactor nuclear power station Download PDFInfo
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- CN203480852U CN203480852U CN201320474356.XU CN201320474356U CN203480852U CN 203480852 U CN203480852 U CN 203480852U CN 201320474356 U CN201320474356 U CN 201320474356U CN 203480852 U CN203480852 U CN 203480852U
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Abstract
The utility model relates to a lead shielding block on the end face of a nuclear fuel channel of a heavy water nuclear reactor nuclear power station. The lead shielding block comprises a plurality of layers of overlapped lead foil which are provided with positioning holes used for enabling the lead shielding block to be arranged on the fuel channel in a sleeved mode. Silicon rubber layers are arranged on the outer side edges of the layers of overlapped lead foil and the inner walls of the positioning holes. When the lead shielding block is used, the fuel channel can not be damaged, and the lead shielding block is low in weight, easy to manufacture, quick and convenient to install, and higher in safety.
Description
Technical field
The utility model relates to a kind of nuclear radiation protection articles for use, relates to especially a kind of heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece.
Background technology
End face shielding occupies very important status in the radiation protection of nuclear power station especially heavy water reactor nuclear power station, and " end face " herein refers to heavy water reactor power station fuel channel end, the facade that is depth shape being comprised of the pipeline of formed objects.During the overhaul of heavy water team nuclear power station, a large amount of service works concentrates on fuel channel end face and neighboring area thereof, and the radiation dose level of fuel channel end face is very high, according to statistics, each large revision of the convention have 80% according to radiation, come from end region and end face relevant range outward, this cause end face maintenance personal and the suffered radiation dose of staff higher.What is more important, prolongation along with the unit operation time, the radiation level of end face relevant range still can further increase, this becomes the region that nuclear power station radiation protection work should be paid close attention to and study undoubtedly, also be key and the emphasis place that reduces end region maintenance personal and routine work personnel collective dose, the study hotspot of this scientific research field at present especially.
Plumbous have higher atomic number, relative low price because of it, can effectively shield gamma-rays and become the most conventional protective shielding metal, in nuclear radiation field and place, is widely applied.Just because of this, in the application of heavy water nuclear-power reactor fuel channel end face alpha ray shield, originally generally by rope, cold roll moulding stereotype was suspended on passage, to play shielded nucleus radiation, protection operating personnel's effect.
But adopt this stereotype shielding slab to have following many drawbacks:
1. for avoiding damaging fuel channel outside surface, need very careful operation, suspension difficulty is large, elapsed time is long, does not meet plant area's safe construction standard;
2. between stereotype piece, often exist and compared with large gap, cause ray to be revealed, thereby occur radiation risk, cannot realize the integrated whole alpha ray shield effect of whole end face;
3. harder because of stereotype appearance, the stereotype contingency that hangs on eminence meets accident and drops, and easily injures staff by a crashing object or equipment is caused to damage, has larger potential safety hazard;
4. stereotype in use easily causes surface stain and be difficult for decontamination, thereby causes learies larger, and can cause pollution to a certain degree to environment;
5. in use easily flexural deformation of stereotype, and be difficult to resile, cause extra stereotype consumption, and strengthened the operation easier in hoisting process.
For the drawback of above-mentioned lead, carried out a lot of research and practices both at home and abroad, and obtained some achievements.
For example, in nuclear industry end face shielding application abroad, researched and developed novel shielding material, this material is the coagulum obtaining by lead powder and the even mixed pressure of silicon rubber.Although this class coagulum can overcome many drawbacks of cold roll moulding stereotype preferably, but still has major defect:
(1) in its preparation process, relate to lead powder is mixed to mold pressing with silicon rubber under certain proportion, required complex process, lead powder process is seriously polluted;
(2) although finished product can keep the original flexibility of colloid, but cannot provide larger lead powder ratio, thereby make the lead equivalent of finished product low, for enough lead equivalents are provided, need to strengthen material usage, cause adopting the lead weight of the equal lead equivalent of shielding slab weight ratio that this material makes much larger.Can increase the weight of like this transportation and the load of jacking equipment, the more important thing is that can increase the weight of operating personnel hangs the working strength in process in shielding slab transportation and dress, the prolongation shield engineering set-up time, increase the risk that operating personnel are subject to radiation;
(3) this material manufacture craft very complicated, and guaranteeing that in equal lead equivalent situation, required silicon rubber is more, so manufacturing cost is higher, is unfavorable for application and the popularization of product.
Again for example, in nuclear industry end face shielding application at home, researched and developed novel lead shield piece.< < Chinese Nuclear Industry In The Past > > 11 phase < < reactor end face fuel channel bulk shielding technical research > > in 2011 have disclosed and have a kind ofly adopted flame retardant type silastic-layer and by the shielding slab structure of 10 layers of superimposed internal layer of lead foil.This shielding slab is because of outsourcing silastic-layer and interior superimposed lead foil, make shielding slab less deadweight keep large effectively lead equivalent, can also obtain certain flexibility simultaneously, even accidental fall or collision fuel channel, can not cause damage to fuel channel and uphole equipment, thereby there is higher security yet.But this shielding slab also comes with some shortcomings:
(1) shielding slab of these One's name is legions is fixed on fuel channel end region to need extra support/suspension bracket assist fixing, so enters in station except transporting shielding slab, also needs the transhipments such as fixed support to enter in station.Yet nuclear power station has strict restriction to entering the size, weight, kind etc. of material in station, and nuclear power station is between turn(a)round just between reactor building and other work implements and material transport compact district, therefore extra support or hanging holder set can increase undoubtedly the workload of end face shield engineering and cause transfer tool resource nervous, and can extend personnel's hold-up time, strengthen radiation risk.
(2) ageing resistance under hollow and high temperature low temperature still can not meet the demands, thus cause repeat performance and stability poor, change frequently, increased operating cost.
Therefore, for research and development a kind of can't harm fuel channel, deadweight light, be easy to preparation, rapid and convenient be installed, and the fuel channel shielding slab with greater security is to need one of urgent technical barrier solving for entering China's nuclear industry of time between overhauls(TBO).
Summary of the invention
The technical matters that the utility model solves be to provide a kind of can't harm fuel channel, deadweight light, be easy to preparation and installation and heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece safe and convenient to use.
For solving the problems of the technologies described above, the utility model proposes a kind of heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece, described lead shield piece comprises Multi-stacking compaction lead foil, on it, offer for described lead shield piece is set in to the pilot hole on fuel channel, the outer side edges of described Multi-stacking compaction lead foil and described pilot hole internal face are provided with silastic-layer.
In described lead shield piece of the present utility model, as a kind of embodiment, described lead shield piece can be rectangular, for example rectangle or square, and described pilot hole is preferably placed at the center of this rectangle.
In described lead shield piece of the present utility model, as a kind of embodiment, the outside surface of described Multi-stacking compaction lead foil is all wrapped up and is coated with silastic-layer by bonding and/or compression molding.
In which, the implication of " bonding and/or compression molding " refers to can be separately wraps up covering by bonding, or by compression molding, wrap up covering separately, or by bonding and combinations two kinds of modes of compression molding, wrap up covering, preferably the combination parcel by bonding and two kinds of modes of compression molding covers silastic-layer.
In which, all exposed surfaces of Multi-stacking compaction lead foil are all by covering that silastic-layer wraps up, comprise the upper surface of the superiors' lead foil, the periphery side of the lower surface of orlop lead foil, Multi-stacking compaction lead foil, be all covered with silastic-layer on the internal face of pilot hole.By parcel like this, cover, whole Multi-stacking compaction lead foil is intactly all wrapped up by silastic-layer, and becomes a silastic-layer integral body.
In described lead shield piece of the present utility model, as a kind of embodiment, the thickness of described silastic-layer is 2-15 mm, for example can be to indefiniteness 2 mm, 4 mm, 6 mm, 8 mm, 10 mm, 12 mm or 14 mm.
In described lead shield piece of the present utility model, as a kind of embodiment, silastic-layer thickness in described Multi-stacking compaction lead foil two opposite planar, is greater than the layer thickness of described Multi-stacking compaction aluminium foil outer side edges place silicon rubber, and the thickness that is greater than described pilot hole internal face place silastic-layer.
In which, described " Multi-stacking compaction lead foil two opposite planar " refer to the upper surface of the superiors' lead foil and the lower surface of orlop lead foil.
In described lead shield piece of the present utility model, as a kind of embodiment, atomization processing has been carried out on the surface of described Multi-stacking compaction lead foil two opposite planar.
In described lead shield piece of the present utility model, as a kind of embodiment, on described Multi-stacking compaction lead foil outside surface, be coated with silicon rubber-metal adhesive (can applying again after atomization is processed), described silastic-layer sticks on the outside surface of described Multi-stacking compaction lead foil by this silicon rubber-metal adhesive.Described " tackifier " also referred to as " bonding agent ", and both have and/or refer to identical implication.
In described lead shield piece of the present utility model, as a kind of embodiment, the weight of described lead shield piece is 2-15 kg, for example can be to indefiniteness 2 kg, 4 kg, 6 kg, 8 kg, 10 kg, 12 kg 14 kg.
In described lead shield piece of the present utility model, as a kind of embodiment, the hardness of described silastic-layer is 30-80 Shao Er hardness, for example can be to indefiniteness 30 Shao Er hardness, 40 Shao Er hardness, 50 Shao Er hardness, 60 Shao Er hardness, 70 Shao Er hardness or 80 Shao Er hardness.
In described lead shield piece of the present utility model, as a kind of embodiment, the number of plies that laminates of described Multi-stacking compaction lead foil is not particularly limited, can be according to practical operation demand (lead equivalent demand) and suitablely determine, for example can be 2-20 layer, this scope has comprised any concrete point value wherein, as 3 layers, 5 layers, 7 layers, 9 layers, 11 layers, 13 layers, 15 layers, 17 layers or 19 layers.
In described lead shield piece of the present utility model, as a kind of embodiment, the thickness of every layer of lead foil in described Multi-stacking compaction lead foil is 0.1-1.0 mm, this scope has comprised any concrete point value wherein, as 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm or 1 mm.
In described lead shield piece of the present utility model, as a kind of embodiment, described silastic-layer material is food-grade silicon rubber, or is flame-proof silicon rubber.This flame-proof silicon rubber can prepare by the following method: food-grade silicon rubber, silicon rubber flame-retardant agent are added in mixing roll and carry out banburying, make it the mixing silicon rubber evenly obtaining.Both consumptions are consumption as known in the art, as long as make gained silicon rubber have flame retardant effect and required hardness.
In which, described silicon rubber flame-retardant agent can be any one or the arbitrarily multiple combination in fire retardant known in this field, indefiniteness ground, for example can exemplify inorganic combustion inhibitor, as antimony oxide, aluminium hydroxide, magnesium hydroxide, containing boron fire retardant preservative as hydration zinc borate and barium metaborate, containing molybdenum fire retardant as molybdenum trioxide and nitric acid molybdenum; Organic fire-retardant, as tetrabromophthalic anhydride, deca-BDE, HBB, trioctyl phosphate, tricresyl phosphate, tributyl phosphate, two (hydroxy ethoxy) ether of tetrabromobisphenol A, tetrabromobisphenol A allyl ether etc.
In addition, the preparation method of above-mentioned heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece comprises the steps:
(1). the preparation of multiple-layer stacked lead foil;
(2). use silicon rubber wrapped multiple stack lead foil;
(3). compression molding, obtains described lead shield piece.
In described preparation method of the present utility model, as a kind of embodiment, described step (1) comprises the steps:
(1.1) plumbous purification
Raw material lead is heated to 330 ℃ of-350 ℃ of meltings, and is warming up to 370-390 ℃ with the programming rate of 3-5 ℃/min, during stir, and remove the impurity float on plumbous liquid top completely;
(1.2) stereotype pouring moulding
The plumbous liquid of step (1.1) is watered to mould, and naturally cooling, obtain the stereotype that thickness is 1-2 cm;
(1.3) stereotype is cold rolling
Use cold-rolling equipment, under normal temperature, the stereotype of step (1.2) is rolled, obtain the lead foil that thickness is 0.1-1 mm;
Wherein, rolling number of times is not particularly limited, as long as make gained lead foil evenly fine and close, does not wherein have bubble.
(1.4) lead foil stack
The lead foil of step (1.3) is cut into same size and in heartcut, go out the pilot hole of comparable size, then superpose, obtain multiple-layer stacked lead foil.Its number of plies can be carried out suitable selection as required, for example, can be 2-20 layer.
In described preparation method of the present utility model, as a kind of embodiment, described step (2) is specially: use all or part of wrapped multiple stack of silicon rubber lead foil.
In which, the implication of " all wrapped multiple stack lead foil " be all exposed surfaces of Multi-stacking compaction lead foil all by covering that silastic-layer wraps up, comprise the upper surface of the superiors' lead foil, the periphery side of the lower surface of orlop lead foil, Multi-stacking compaction lead foil, be all covered with silastic-layer on the internal face of pilot hole.By parcel like this, cover, whole Multi-stacking compaction lead foil is intactly all wrapped up by silastic-layer, and becomes a silastic-layer integral body.
In which, the implication of " part wrapped multiple stack lead foil " for example can refer to that the outer side edges of Multi-stacking compaction lead foil and described pilot hole internal face are provided with silastic-layer.
In which, optionally, can before parcel, atomization processing be carried out to strengthen the bonding degree on described silastic-layer and lead foil surface in the surface of described Multi-stacking compaction lead foil two opposite planar.
In which, more preferably, after atomization is processed, to coating silicon rubber-metal adhesive on the surface, parcel place of Multi-stacking compaction lead foil (concrete kind or enumerate following " product structure embodiment 2 " as seen), thereby silastic-layer is sticked on the parcel surface of described multiple-layer stacked lead foil by this silicon rubber-metal adhesive.
In described preparation method of the present utility model, as a kind of embodiment, described step (3) is specific as follows:
Multiple-layer stacked lead foil after the parcel of step (2) gained is carried out to compression molding, wherein, patrix temperature is 150-175 ℃, counterdie temperature is 160-190 ℃, pressure is 180 T (180 tons), clamp time is 10-30 minute, thereby has obtained the described lead shield piece that the utility model comprises Multi-stacking compaction lead foil and silastic-layer.
In the utility model, except as otherwise noted and/or regulation, " multiple-layer stacked lead foil " has the different implications that refers to from " Multi-stacking compaction lead foil ", the former refers to the multilayer lead foil that does not carry out compression molding processing obtaining after lead foil stack, and the latter refers to described " multiple-layer stacked lead foil " carried out to the lead foil of multilayer more closely obtaining after compression molding processing.
Said method of the present utility model and the utility model fuel channel end face lead shield piece making thus, tool has the following advantages:
1. after there is non-destructive distortion, still can resile, there is good hollow.
2. due to the using and wrapping up of outer silicon rubber, make contact position softness and the high resilience of described lead shield piece and end face pipeline, hard collision, wearing and tearing or damage can not occur.Meanwhile, due to silicon rubber existence, it is difficult for staining, more easy cleaning, and fire protection flame retarding.
3. compare with lead powder processing technology, more environmental protection of lead foil moulding process of the present utility model, easy operating, and can the number of plies of lead foil can be suitablely set according to the actual needs of different lead equivalents, there is applicability and dirigibility widely.
4. can obtain higher lead equivalent, owing to having adopted the processing such as improving of lead, cold rolling, compression molding, the physical aspect that makes lead foil is homogeneous more, quality is more even, thereby the single stereotype than same thickness has higher lead equivalent, radiation protection and shield effectiveness are better, thereby have further alleviated the weight of lead shield plate, and this has promoted again convenience and the controllability of operation conversely.
5. fire-retardant, the heat insulation and protective effect due to specific silicon rubber layer has more wide in range Applicable temperature, can in the temperature range of-60 ℃ to 250 ℃, use, thereby adapt to different severe rugged environments, has good environmental suitability and long-time stability.
Due to above-mentioned plurality of advantages, heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece of the present utility model and preparation method thereof, has broad application prospects and huge economic efficient latent at aspects such as commercial Application, nuclear radiation protections.
Accompanying drawing explanation
Fig. 1 is the vertical view of the lead shield piece of product structure embodiment 1.
Fig. 2 is the cut-away illustration of the lead shield piece of product structure embodiment 1.
Fig. 3 is the vertical view of the lead shield piece of product structure embodiment 2.
Fig. 4 is the cut-away illustration of the lead shield piece of product structure embodiment 2.
Embodiment
Below by specific embodiment, the utility model is elaborated.
product structure embodiment 1
As shown in Figure 1 and Figure 2, the heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece of the present embodiment comprises Multi-stacking compaction lead foil 10, on this Multi-stacking compaction lead foil 10, offer for lead shield piece being set in to the pilot hole 19 on fuel channel, and the outer side edges 13 of Multi-stacking compaction lead foil 10 and described pilot hole 19 internal faces 14 are provided with silastic-layer 21,22.Be the upper surface 11, lower surface 12 of Multi-stacking compaction lead foil 10 except a part of surface coverage with outer side edges 13 and pilot hole 19 internal face 14 junctions has silastic-layer, all the other most surfaces are by silastic-layer parcel and cover.The silastic-layer of the present embodiment adopts the mode of part parcel to wrap up the significant points that covers Multi-stacking compaction lead foil 10, prevents Multi-stacking compaction lead foil 10 damage fuel channel and other equipment.Silastic-layer can be by mold pressing or adhesive attachment on Multi-stacking compaction lead foil 10.
Lead foil has good pliability, adopts the Multi-stacking compaction lead foil 10 of the lead foil stack formation of thin softness can effectively weaken finished product interior metal acting force to outer wrapping silicon rubber when falling, and reduces damage.And the lead foil of multilayer build-up is still easier to recover prototype after deforming.
The benefit that pilot hole 19 is set is: in use, the pilot hole 19 of Multi-stacking compaction lead foil 10 is set in fuel channel (not shown), without outside auxiliary ceiling suspension or support, can be fixed on fuel channel lead shield piece is sheathed.As long as the interval layout in conjunction with fuel channel, design the size with the corresponding lead shield piece of quantity of fuel channel, just can so that each fuel channel after sheathed lead shield piece, and its around the clearance space between adjacent fuel channel by the shutoff of corresponding adjacent lead shield piece institute, thereby make whole fuel channel end face by complete shielding.
In addition, the benefit that silastic-layer is set on pilot hole 19 internal faces 14 of Multi-stacking compaction lead foil 10 is: when lead shield piece is set on the outer tube wall of fuel channel, the silastic-layer 21 on Multi-stacking compaction lead foil 10 pilot hole 19 internal faces 14 contacts the outer tube wall extruding with fuel channel.Because silicon rubber is softer and have certain elasticity, therefore can prevent that lead shield piece from causing scratch to damage to fuel channel appearance.
Although although lead shield piece of the present utility model is designed to be set on fuel channel outer tube wall, fail to stop the region, port of fuel channel end, but in fact owing to being generally built-in with fuel rod screening cover in fuel channel, and port is also provided with capping, through actual measurement, the radiation dose in fuel channel terminal part region is very little, in safety standard tolerance interval, therefore with lead shield piece of the present utility model, shield fuel channel end face, meet safety standard requirements.That is to say, use the utility model lead shield piece to build end face shield engineering, not only easy to be quick, can reduce transhipment and entering nuclear power station materials inside, but also end face shield effectiveness can also meet the requirement of the parties concerned.
Suppose that fuel channel is for rule distribution in length and breadth, fuel channel spacing distance in horizontal direction is a, and the spacing distance of the fuel channel on vertical direction is b, and lead shield piece can be designed to regular rectangle, making the wherein length of a relative side is a, and the length of another relative side is b.When mounted, the side that lead shield block length is a is parallel to horizontal direction, and the side that length is b is parallel to vertical direction.
The lead shield piece of the present embodiment is rectangular, and described pilot hole 19 is positioned at the center of this rectangle.For preventing from overlapping the lead shield piece installing, rotate, cause interference and hinder to the suit of the lead shield piece of adjacent fuel channel, can further the pilot hole of Multi-stacking compaction lead foil 10 19 be arranged on to middle position, the center of gravity of lead shield piece is positioned on the axis of pilot hole 19, the stability while being sleeved on fuel channel to strengthen lead shield piece.
The lead shield piece weight of the present embodiment is 2-15kg, and the thickness of silastic-layer is 2-15mm, and the hardness of silastic-layer is 30-70 Shao Er hardness.According to practical experience, add up, if lead shield piece is greater than 15kg jin, operating personnel install about 10-15 and will feel exhausted and need to have a rest, and drag installation progress and the speed of slow end face shield engineering, and nuclear power station working environment radiation level is higher, there is to strict demand the shield engineering set-up time.Guaranteeing, under the prerequisite of enough lead equivalents, should lower the weight of single lead shield piece, so the thickness of silastic-layer to be not more thick better as far as possible.If the hardness of silastic-layer is too small, one comes the hollow of lead shield piece poor, and two pierce through silastic-layer for fear of inner Multi-stacking compaction lead foil 10, so just need to increase the thickness of silastic-layer, increase the weight of the weight of lead shield piece.If silastic-layer hardness is excessive, the hollow of lead shield piece, by poor, cannot restore to the original state after bending certain angle.Therefore, silastic-layer need to be obtained the balance of thickness and hardness.
The silastic-layer material of the present embodiment can adopt food-grade silicon rubber, or the silicon rubber making for following method.
product structure embodiment 2
As shown in Figure 3, Figure 4, the difference of the present embodiment and embodiment 1 is, the silastic-layer employing of the present embodiment " parcel entirely " mode, and the outside surface of Multi-stacking compaction lead foil 30 is all wrapped up and is covered all silastic-layers 40 by compression molding and/or bonding mode.Be the exposed surface of Multi-stacking compaction lead foil all by covering that silastic-layer wraps up, comprise the upper surface 31 of the superiors' lead foil, the lower surface 32 of orlop lead foil, is all covered with silastic-layer 40 on the periphery side 33 of Multi-stacking compaction lead foil, the internal face 34 of pilot hole 39.For Multi-stacking compaction lead foil provides comprehensive protection, when strengthening shielding slab intensity, can also strengthen globality and the hollow of lead shield piece.Preparation/the method for making of the present embodiment can be with reference to following embodiment.
In addition, silastic-layer thickness in two opposite planar of Multi-stacking compaction lead foil (being the upper surface 31 of the superiors' lead foil and the lower surface 32 of orlop lead foil), be greater than the layer thickness of described Multi-stacking compaction aluminium foil outer side edges 33 place's silicon rubber, and be greater than the thickness of described pilot hole 39 internal face 34 place's silastic-layers.The thickness of the layer thickness of Multi-stacking compaction aluminium foil outer side edges 33 place's silicon rubber and pilot hole 39 internal face 34 place's silastic-layers does not damage fuel channel and other equipment as long as meet, but Multi-stacking compaction lead foil two opposite planar because area will be much larger than the area of its periphery side and pilot hole internal face, its thickness is larger on the impact of the globality of lead shield piece and hollow.In order to guarantee the hollow of lead shield piece, need to thicken the silastic-layer thickness in Multi-stacking compaction lead foil two opposite planar, cause the silastic-layer thickness meeting in Multi-stacking compaction lead foil two opposite planar relatively large.
Further, process through atomization on the surface of Multi-stacking compaction lead foil two opposite planar, to strengthen the bonding degree on described silastic-layer and lead foil surface.
Further, after atomization is processed, the outside surface of Multi-stacking compaction lead foil can also apply for example sprayed silicon rubber-metal tackifier, to strengthen the adhesion between silastic-layer and Multi-stacking compaction lead foil.At the outside surface of Multi-stacking compaction lead foil, apply (can by hand or equipment evenly spray) tackifier, except strengthening silastic-layer adhering to lead foil surface, can also play isolation silastic-layer and lead foil and prevent both generation noxious materials that reacts, and weaken cohesive strength between the two.Described silicon rubber-metal adhesive can be heat vulcanizate stick as nylon heat vulcanizate stick, polyurethane heat vulcanizate stick etc., as specifically exemplifying of indefiniteness, can enumerate Primer 607 tackifier, CILBOND 80C tackifier, Chemlok 252X tackifier, Chemlok 220 tackifier, chemosill 225 tackifier, cilbond 24 tackifier, cilbond 89 tackifier, cilbond 33 tackifier, cilbond 36 tackifier etc., preferably Primer 607 tackifier.
preparation example 1: the preparation of multiple-layer stacked lead foil
(1.1) plumbous purification
Raw material lead is heated to 330 ℃, then with the programming rate of 3 ℃/min, is warming up to 370 ℃, make its melting, during continue to stir, and use scraper plate to remove the impurity that floats on plumbous liquid top, until without floating thing.
(1.2) stereotype pouring moulding
The plumbous liquid of step (1.1) is watered to mould, and naturally cooling, obtain the stereotype that thickness is 1 cm.
(1.3) stereotype is cold rolling
Use cold-rolling equipment, under normal temperature, the stereotype of step (1.2) is carried out to repeat-rolling, until even compact and wherein existing without bubble obtains the lead foil that thickness is 0.1 mm;
(1.4) lead foil stack
The lead foil of step (1.3) is cut into same size and in heartcut, go out the pilot hole of comparable size, then superpose, obtain multiple-layer stacked lead foil, obtain respectively total number of plies and be the stack lead foil of 5 layers, 10 layers, 15 layers and 20 layers.
preparation example 2: the preparation of multiple-layer stacked lead foil
(1.1) plumbous purification
Raw material lead is heated to 340 ℃ of gels, then with the programming rate of 4 ℃/min, is warming up to 380 ℃, make its melting, during continue to stir, and use scraper plate to remove the impurity that floats on plumbous liquid top, until without floating thing.
(1.2) stereotype pouring moulding
The plumbous liquid of step (1.1) is watered to mould, and naturally cooling, obtain the stereotype that thickness is 1.5 cm.
(1.3) stereotype is cold rolling
Use cold-rolling equipment, under normal temperature, the stereotype of step (1.2) is carried out to repeat-rolling, until even compact and wherein existing without bubble obtains the lead foil that thickness is 0.5 mm;
(1.4) lead foil stack
The lead foil of step (1.3) is cut into same size and in heartcut, go out the pilot hole of comparable size, then superpose, obtain multiple-layer stacked lead foil, obtain respectively total number of plies and be the stack lead foil of 5 layers, 10 layers, 15 layers and 20 layers.
preparation example 3: the preparation of multiple-layer stacked lead foil
(1.1) plumbous purification
Raw material lead is heated to 350 ℃ of gels, then with the programming rate of 5 ℃/min, is warming up to 390 ℃, make its melting, during continue to stir, and use scraper plate to remove the impurity that floats on plumbous liquid top, until without floating thing.
(1.2) stereotype pouring moulding
The plumbous liquid of step (1.1) is watered to mould, and naturally cooling, obtain the stereotype that thickness is 2 cm.
(1.3) stereotype is cold rolling
Use cold-rolling equipment, under normal temperature, the stereotype of step (1.2) is carried out to repeat-rolling, until even compact and wherein existing without bubble obtains the lead foil that thickness is 1 mm;
(1.4) lead foil stack
The lead foil of step (1.3) is cut into same size and in heartcut, go out the pilot hole of comparable size, then superpose, obtain multiple-layer stacked lead foil, obtain respectively total number of plies and be the stack lead foil of 5 layers, 10 layers, 15 layers and 20 layers.
preparation example 4: as the preparation of outer field silicon rubber
Silicon rubber, hydration zinc borate are added in mixing roll and carry out banburying, make it mixing even, thereby obtain the silicon rubber as silastic-layer, called after silicon rubber-1.
Except hydration zinc borate wherein being replaced with respectively antimony oxide, aluminium hydroxide, barium metaborate, nitric acid molybdenum, tetrabromophthalic anhydride, deca-BDE, HBB, trioctyl phosphate, tricresyl phosphate, two (hydroxy ethoxy) ether of tetrabromobisphenol A, tetrabromobisphenol A allyl ether, with identical preparation method, obtained doing respectively the silicon rubber of silastic-layer, respectively called after silicon rubber-2, silicon rubber-3, silicon rubber-4, silicon rubber-5, silicon rubber-6, silicon rubber-7, silicon rubber-8, silicon rubber-9, silicon rubber-10, silicon rubber-11 and silicon rubber-12.
Wherein the hardness of silicon rubber-1, silicon rubber-5 and silicon rubber-9 is 30 Shao Er hardness; The hardness of silicon rubber-2, silicon rubber-6 and silicon rubber-10 is 45 Shao Er hardness; Silicon rubber-3, silicon rubber-7 and silicon rubber-11 hardness are 60 Shao Er hardness; Silicon rubber-4, silicon rubber-8 and silicon rubber-12 hardness are 75 Shao Er hardness.
embodiment 1: the preparation of lead shield piece
Total number of plies that preparation example 1 is obtained is 5 layers, 10 layers, the stack lead foil of 15 layers and 20 layers, and to upper surface, lower surface carries out atomization processing, then to all outer surfaces, spraying is selected from a kind of silicon rubber-metal adhesive listed in " product structure embodiment 2 ", finally use respectively silicon rubber-1, silicon rubber-2, silicon rubber-3, complete parcel is carried out in silicon rubber-4, and (wrap up 5 stacked silicon rubber for lead foil-1 that add, 10 stacked silicon rubber for lead foil-2 parcels that add, 15 stacked silicon rubber for lead foil-3 parcel and 20 stacked silicon rubber for lead foil-4 parcels that add of adding), then carry out respectively compression molding processing, wherein patrix temperature is 150 ℃, counterdie temperature is 160 ℃, pressure is 180 T, clamp time is 10 minutes, silastic-layer thickness is 4 mm, thereby obtain four kinds of not lead shield pieces of the layer lead foil number of plies.
embodiment 2: the preparation of lead shield piece
Total number of plies that preparation example 2 is obtained is 5 layers, 10 layers, the stack lead foil of 15 layers and 20 layers, and to upper surface, lower surface carries out atomization processing, then to all outer surfaces, spraying is selected from a kind of silicon rubber-metal adhesive listed in " product structure embodiment 2 ", finally use respectively silicon rubber-5, silicon rubber-6, silicon rubber-7, complete parcel is carried out in silicon rubber-8, and (wrap up 5 stacked silicon rubber for lead foil-5 that add, 10 stacked silicon rubber for lead foil-6 parcels that add, 15 stacked silicon rubber for lead foil-7 parcel and 20 stacked silicon rubber for lead foil-8 parcels that add of adding), then carry out respectively compression molding processing, wherein patrix temperature is 165 ℃, counterdie temperature is 175 ℃, pressure is 180 T, clamp time is 20 minutes, silastic-layer thickness is 8 mm, thereby obtain four kinds of not lead shield pieces of the layer lead foil number of plies.
embodiment 3: the preparation of lead shield piece
Total number of plies that preparation example 3 is obtained is 5 layers, 10 layers, the stack lead foil of 15 layers and 20 layers, and to upper surface, lower surface carries out atomization processing, then to all outer surfaces, spraying is selected from a kind of silicon rubber-metal adhesive listed in " product structure embodiment 2 ", finally use respectively silicon rubber-9, silicon rubber-10, silicon rubber-11, complete parcel is carried out in silicon rubber-12, and (wrap up 5 stacked silicon rubber for lead foil-9 that add, 10 stacked silicon rubber for lead foil-10 parcels that add, 15 stacked silicon rubber for lead foil-11 parcel and 20 stacked silicon rubber for lead foil-12 parcels that add of adding), then carry out respectively compression molding processing, wherein patrix temperature is 175 ℃, counterdie temperature is 190 ℃, pressure is 180 T, clamp time is 30 minutes, silastic-layer thickness is 12 mm, thereby obtain four kinds of not lead shield pieces of the layer lead foil number of plies.
performance test
hollow
Use rebound resilience tester as known in the art to measure the hollow performance of gained lead shield piece in embodiment 1-6, the results are shown in following table:
As seen from the above table, all lead shield pieces in embodiment 1-3 all have good hollow, even if under the flexural deformation up to 30 °, still can resile completely, have demonstrated good hollow performance.
weatherability and resistance to aging
<1>. all lead shield pieces in embodiment 1-3 are carried out to low temperature and the performance test of high temperature hollow at following temperature, thereby whether Applicable temperature scope and the outer silicon rubber of investigating them is aging, wherein, the hollow degree of measuring respectively flexibility and be 10 °, 20 ° and 30 ° at each temperature, the results are shown in following table:
As can be seen here, even if in the high temperature and low temperature range of-60 ℃ to 250 ℃, all lead shield pieces of the present utility model still have good hollow, have demonstrated good weather resistance.
<2>. at each temperature of above-mentioned <1>, maintain after 60 hours, measure the degree of aging of outer silicon rubber, performance when initial compares, and investigates the rate of change of each performance index, the results are shown in following table:
As seen from the above table, maintain after 60 hours in the high temperature of-60 ℃ to 250 ℃ and low temperature range, the fluctuation of the Ageing Index of the outer silicon rubber that the utility model is all is very little, has shown excellent ageing resistance.Therefore, lead shield piece described in the utility model can be stablized use over a long time, has good stability.
The purposes that should be appreciated that these embodiment is only for the utility model is described but not be intended to limit protection domain of the present utility model.In addition; also should understand; after having read technology contents of the present utility model, those skilled in the art can make various changes, modification and/or modification to the utility model, within these all equivalent form of values fall within the protection domain that the application's appended claims limits equally.
Claims (8)
1. a heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece, described lead shield piece comprises Multi-stacking compaction lead foil, on it, offer for described lead shield piece is set in to the pilot hole on fuel channel, the outer side edges of described Multi-stacking compaction lead foil and described pilot hole internal face are provided with silastic-layer.
2. heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as claimed in claim 1, is characterized in that: described lead shield piece is rectangular, and described pilot hole is positioned at the center of rectangle.
3. heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as claimed in claim 1, is characterized in that: the outside surface of described Multi-stacking compaction lead foil is all wrapped up and is coated with silastic-layer by compression molding and/or bonding mode.
4. heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as claimed in claim 3, it is characterized in that: the silastic-layer thickness in described Multi-stacking compaction lead foil two opposite planar, be greater than the layer thickness of described Multi-stacking compaction aluminium foil outer side edges place silicon rubber, and the thickness that is greater than described pilot hole internal face place silastic-layer.
5. heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as claimed in claim 3, is characterized in that: process through atomization on the surface of described Multi-stacking compaction lead foil two opposite planar.
6. heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as claimed in claim 5, is characterized in that: on the outside surface of described Multi-stacking compaction lead foil, be coated with silicon rubber-metal adhesive.
7. the heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as described in claim 1-6 any one, it is characterized in that: the weight of described lead shield piece is 2-15kg, the thickness of described silastic-layer is 2-15mm, and the hardness of described silastic-layer is 30-80 Shao Er hardness.
8. the heavy water nuclear reactor Nuclear Power Station fuel channel end face lead shield piece as described in claim 1-6 any one, is characterized in that: described silastic-layer material is food-grade silicon rubber or flame-proof silicon rubber.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320474356.XU CN203480852U (en) | 2013-08-05 | 2013-08-05 | Lead shielding block on end face of nuclear fuel channel of heavy water nuclear reactor nuclear power station |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201320474356.XU CN203480852U (en) | 2013-08-05 | 2013-08-05 | Lead shielding block on end face of nuclear fuel channel of heavy water nuclear reactor nuclear power station |
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| CN203480852U true CN203480852U (en) | 2014-03-12 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103943162A (en) * | 2013-08-05 | 2014-07-23 | 深圳艾顿辐射防护安全设备有限公司 | Lead shielding block on end face of nuclear fuel channel in heavy water reactor nuclear power station and preparation method thereof |
| CN109994236A (en) * | 2017-12-29 | 2019-07-09 | 中国核动力研究设计院 | A kind of integrated form shielding material composite construction |
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2013
- 2013-08-05 CN CN201320474356.XU patent/CN203480852U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103943162A (en) * | 2013-08-05 | 2014-07-23 | 深圳艾顿辐射防护安全设备有限公司 | Lead shielding block on end face of nuclear fuel channel in heavy water reactor nuclear power station and preparation method thereof |
| CN103943162B (en) * | 2013-08-05 | 2017-02-22 | 深圳艾顿辐射防护安全设备有限公司 | Lead shielding block on end face of nuclear fuel channel in heavy water reactor nuclear power station and preparation method thereof |
| CN109994236A (en) * | 2017-12-29 | 2019-07-09 | 中国核动力研究设计院 | A kind of integrated form shielding material composite construction |
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