CN203370333U - Continuous type liquid separation device - Google Patents
Continuous type liquid separation device Download PDFInfo
- Publication number
- CN203370333U CN203370333U CN201320406605.1U CN201320406605U CN203370333U CN 203370333 U CN203370333 U CN 203370333U CN 201320406605 U CN201320406605 U CN 201320406605U CN 203370333 U CN203370333 U CN 203370333U
- Authority
- CN
- China
- Prior art keywords
- mixed material
- casing
- gravity liquid
- low
- liquid outlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 74
- 238000000926 separation method Methods 0.000 title abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 45
- 230000005484 gravity Effects 0.000 claims description 26
- 238000009413 insulation Methods 0.000 claims description 26
- -1 polypropylene Polymers 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 210000003298 dental enamel Anatomy 0.000 claims description 3
- 229920002313 fluoropolymer Polymers 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000007770 graphite material Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 abstract description 17
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QPVRKFOKCKORDP-UHFFFAOYSA-N 1,3-dimethylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC(C)(O)CC=C1 QPVRKFOKCKORDP-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
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- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The utility model relates to a continuous type liquid separation device. According to the continuous type liquid separation device, a separation device main body is composed of a box body and a jacket which covers the box body and is used for preserving heat, wherein the side wall of the box body is provided with a mixed material inlet and a low-specific-gravity liquid outlet; the vertical height of the low-specific-gravity liquid outlet is greater than that of the mixed material inlet; a mixed material outlet is formed in the bottom of the box body. With the adoption of the device provided by the utility model, the separation of a product and a catalyst can be realized automatically, continuously and efficiently in a process of synthesizing PCMX (Parachlorometaxylenol) by oxychlorination and the mass percentage of the catalyst in the separated product is less than 0.05%.
Description
Technical field
The utility model relates to separator, is specifically related to a kind of continous way liquid separating appts.
Background technology
PCMX(4-chloro-3, the 5-xylenol) be a kind of antimildew and antibacterial agent of wide spectrum, most Gram-positive/negative bacterium, fungi and mould are killed to effect, be widely used in family expenses and daily disinfection, as anti-dandruff shampoo, hand cleanser, germicidal soap and personal hygiene care product, also can be used as anticorrisive agent and mould inhibitor for industrial circles such as glue, coating, paint, weaving, leather and papermaking.
Under the cupric catalyst exists, adopt in the technique of the synthetic PCMX of hydrochloric acid oxidation chlorination MX, reaction needs catalyst is separated with product after finishing.In prior art, general insulation stratification method or the crystallisation by cooling method of adopting carried out separating of catalyst and product, and these methods exist following problem: occupation area of equipment is large; Required labour intensity is large; Can only intermittently operated, efficiency is low.
The utility model content
(1) technical problem that will solve
For problems of the prior art, the purpose of this utility model is to provide a kind of continous way liquid separating appts, can be used for oxychlorination and synthesizes continuous products of separated and catalyst in the technical process of PCMX.
(2) technical scheme
For achieving the above object, the utility model provides a kind of continous way liquid separating appts, in the technical process of the synthetic PCMX of oxychlorination, because catalyst is soluble in water, product P CMX is insoluble to water, and aqueous phase catalyst (1.2～1.3) proportion is larger than product (1.1～1.15), can utilize described liquid separating appts to realize that in this technical process, the high-efficiency and continuous of product and catalyst is separated.
The liquid separating appts main body that the utility model provides is casing 1 and is wrapped in the outer chuck 2 for insulation of casing 1, wherein, described casing 1 sidewall is provided with mixed material entrance 3 and low-gravity liquid outlet 4, the vertical height of described low-gravity liquid outlet 4 is higher than described mixed material entrance 3, and described casing 1 bottom is provided with high specific gravity liquid outlet 5.
Wherein, described chuck 2 is respectively equipped with one or more thermal insulation medium entrances 6 and thermal insulation medium outlet 7.
Wherein, described thermal insulation medium entrance 6 is arranged at the top of described chuck 2.
Wherein, described thermal insulation medium outlet 7 is arranged near described low-gravity liquid outlet 4 and/or described high specific gravity liquid outlet 5.
Wherein, described mixed material entrance 3 and low-gravity liquid outlet 4 are relatively arranged on the sidewall of described casing 1.
Wherein, described high specific gravity liquid outlet 5 pipelines 8 that also are connected with for exporting high specific gravity liquid, the vertical height h of described pipeline meets following formula:
（h-h
2）/h
1=ρ
1/ρ
2
Wherein, h
1for low-gravity liquid height in the interior mixed material of casing 1, h
2for hyperbaric solution height in the interior mixed material of casing 1; ρ
1for the density of low-gravity liquid in mixed material, ρ
2density for high specific gravity liquid in mixed material.
Wherein, the inwall material of described casing 1 is glass fiber reinforced polypropylene tubing, enamel, fluoroplastics or graphite material.
In liquid separating appts, the heat insulation function of chuck 2 can guarantee that the temperature in casing is greater than the fusing point (90 ℃) that product P CMX in the reaction system of PCMX is synthesized in oxychlorination, prevents that product is set in casing as mentioned above.More than the arranging of described device box 1 volume guarantees that the time of staying of mixed material in casing 1 reach 15min.Concrete technological means is: make the flow velocity of casing 1 volume and mixed material entrance 3 be certain proportion.For example: when casing 1 volume is 25L, charging rate is controlled at 1.66L/min when following, more than can guaranteeing that the time of staying of mixed material in casing 1 reach 15min.
(3) beneficial effect
Compared with prior art, the utility model has the advantage of: utilize this device, can in the technique of the synthetic PCMX of oxychlorination, realize automatically, continuously, efficiently separating of product and catalyst.The utility model is used through pilot experiment, and in separating obtained product, the catalyst quality mark, lower than 0.05%, proves that it can reach the purpose of efficient products of separated and catalyst.
The accompanying drawing explanation
Fig. 1 is the structural representation of the continous way liquid separating appts that provides of the utility model.
In figure: 1, casing; 2, chuck; 3, mixed material entrance; 4, low-gravity liquid outlet; 5, high specific gravity liquid outlet; 6, thermal insulation medium entrance; 7, thermal insulation medium outlet; 8, pipeline.
Fig. 2 is the schematic diagram of pipeline 8 and material vertical height in the separator that provides of the utility model.
In figure: h
1mean low-gravity liquid height in the interior mixed material of casing; h
2mean hyperbaric solution height in the interior mixed material of casing; H means high specific gravity liquid outlet height.
The specific embodiment
Following embodiment is used for the utility model is described, but is not used for limiting scope of the present utility model.
As shown in Figure 1, described liquid separating appts main body is casing 1 and is wrapped in the outer chuck 2 for insulation of casing 1, wherein, described casing 1 sidewall is provided with mixed material entrance 3 and low-gravity liquid outlet 4, the vertical height of described low-gravity liquid outlet 4 is higher than described mixed material entrance 3, and described casing 1 bottom is provided with high specific gravity liquid outlet 5.
Wherein, described chuck 2 is respectively equipped with one or more thermal insulation medium entrances 6 and thermal insulation medium outlet 7.
Wherein, described thermal insulation medium entrance 6 is arranged at the top of described chuck 2.
Wherein, described thermal insulation medium outlet 7 is arranged near described low-gravity liquid outlet 4 and/or described high specific gravity liquid outlet 5.
Wherein, described mixed material entrance 3 and low-gravity liquid outlet 4 are relatively arranged on the sidewall of described casing 1.
Wherein, as shown in Figure 2, described high specific gravity liquid outlet 5 pipelines 8 that also are connected with for exporting high specific gravity liquid, the vertical height h of described pipeline according to low-gravity liquid and high specific gravity liquid (for example, in the technical process of the synthetic PCMX of oxychlorination, be low-gravity product and high specific gravity aqueous phase catalyst) density, and the interfacial level of required control calculated, meet following formula:
（h-h
2）/h
1=ρ
1/ρ
2
Wherein, h
1for low-gravity liquid height in mixed material in casing, h
2for hyperbaric solution height in mixed material in casing; ρ
1for the density of low-gravity liquid in mixed material, ρ
2for the density of high specific gravity liquid in mixed material, can be according to pressure formula ρ
1* h
1* g+ ρ
2* h
2* g=ρ
2* h*g draws above-mentioned formula.Low-gravity liquid outlet 4 can pass through h with the difference in height of high specific gravity liquid outlet 5
1+ h
2-h obtains.
Wherein, the inwall material of described casing 1 is glass fiber reinforced polypropylene tubing, enamel, fluoroplastics or graphite material.
Described device for the continuous separate of liquid from as during for the synthetic PCMX reaction system of oxychlorination, mixed material entrance 3 connects the material outlet of the synthetic PCMX reaction system of oxychlorination, makes material to be separated enter into casing 1; Low-gravity liquid outlet 4 is communicated with the product equipment for after-treatment; The outlet 5 of high specific gravity liquid is communicated with the catalyst equipment for after-treatment by pipeline 8; Thermal insulation medium entrance 6 is the entrance that thermal insulation medium (for example steam) enters chuck; Thermal insulation medium outlet 7 is left the outlet of chuck for thermal insulation medium, and use steam is during as thermal insulation medium, and exit is provided with drain valve, but the water that exhaust steam condenses after cooling.After described device connects, at first pass into high specific gravity liquid in casing 1, liquid level reaches mixed material entrance 3, mixed material can directly not discharged by high specific gravity liquid outlet 5 when guaranteeing that this device has just been brought into use, and guarantee in separation process the purity from high specific gravity liquid outlet 5 liquid of discharging; Pass into thermal insulation medium again in chuck 2, open the chuck heat insulation function, after reaching 70～90 ℃ of preset temperatures, by mixed material entrance 3, in casing, pass into mixed material, device is come into operation.In use procedure, product overflows from low-gravity liquid outlet 4, and catalyst is discharged and flowed into pipeline 8 from high specific gravity liquid outlet 5.The flow velocity of low-gravity liquid outlet 4 and high specific gravity liquid outlet 5 is determined by the flow velocity of mixed material entrance 3, in actual production, more than guaranteeing that the time of staying of mixed material in casing 1 reach 15min, flow velocity to mixed material entrance 3 is controlled, for example: the casing 1 that is 25L for volume, the flow control of mixed material entrance 3 is below 1.66L/min.
Adopt described device to carry out after separating, use the copper ion detection method to carry out titration to separating obtained product, testing result shows that the mass fraction of residual catalyst wherein is lower than 0.05%, as can be seen here, adopt separator of the present utility model to separate in the product obtained, the content of catalyst impurities obviously reduces, good separating effect.
Although, above used general explanation, the specific embodiment and test, the utility model has been done to detailed description, on the utility model basis, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements on the basis of not departing from the utility model spirit, all belong to the claimed scope of the utility model.
Claims (7)
1. a continous way liquid separating appts, is characterized in that, described separator main body is casing (1) and is wrapped in the outer chuck (2) for insulation of casing (1); Wherein, described casing (1) sidewall is provided with mixed material entrance (3) and low-gravity liquid outlet (4), the vertical height of described low-gravity liquid outlet (4) is higher than described mixed material entrance (3), and described casing (1) bottom is provided with high specific gravity liquid outlet (5).
2. liquid separating appts according to claim 1, is characterized in that, described chuck (2) is respectively equipped with one or more thermal insulation medium entrances (6) and thermal insulation medium outlet (7).
3. liquid separating appts according to claim 2, is characterized in that, described thermal insulation medium entrance (6) is arranged at the top of described chuck (2).
4. liquid separating appts according to claim 2, is characterized in that, described thermal insulation medium outlet (7) is arranged near described low-gravity liquid outlet (4) and/or described high specific gravity liquid outlet (5).
5. liquid separating appts according to claim 1, is characterized in that, described mixed material entrance (3) and low-gravity liquid outlet (4) are relatively arranged on the sidewall of described casing (1).
6. liquid separating appts according to claim 1, is characterized in that, described high specific gravity liquid outlet (5) also is connected with the pipeline (8) for exporting high specific gravity liquid, and the vertical height h of described pipeline (8) meets following formula:
（h-h
2）/h
1=ρ
1/ρ
2
Wherein, h
1for low-gravity liquid height in the interior mixed material of casing (1), h
2for hyperbaric solution height in the interior mixed material of casing (1); ρ
1for the density of low-gravity liquid in mixed material, ρ
2density for high specific gravity liquid in mixed material.
7. according to the described liquid separating appts of claim 1-6 any one, it is characterized in that, the inwall material of described casing (1) is glass fiber reinforced polypropylene tubing, enamel, fluoroplastics or graphite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320406605.1U CN203370333U (en) | 2013-07-09 | 2013-07-09 | Continuous type liquid separation device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320406605.1U CN203370333U (en) | 2013-07-09 | 2013-07-09 | Continuous type liquid separation device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203370333U true CN203370333U (en) | 2014-01-01 |
Family
ID=49832891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201320406605.1U Expired - Lifetime CN203370333U (en) | 2013-07-09 | 2013-07-09 | Continuous type liquid separation device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203370333U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107271247A (en) * | 2016-04-08 | 2017-10-20 | 中国石油化工股份有限公司 | A kind of separation method of Macerals of Hydrocarbon Source Rocks |
| CN110270137A (en) * | 2019-07-01 | 2019-09-24 | 新疆神邦环境工程有限公司 | Oily-water seperating equipment and system and water-oil separating control method |
-
2013
- 2013-07-09 CN CN201320406605.1U patent/CN203370333U/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107271247A (en) * | 2016-04-08 | 2017-10-20 | 中国石油化工股份有限公司 | A kind of separation method of Macerals of Hydrocarbon Source Rocks |
| CN107271247B (en) * | 2016-04-08 | 2019-11-08 | 中国石油化工股份有限公司 | A kind of separation method of Macerals of Hydrocarbon Source Rocks |
| CN110270137A (en) * | 2019-07-01 | 2019-09-24 | 新疆神邦环境工程有限公司 | Oily-water seperating equipment and system and water-oil separating control method |
| CN110270137B (en) * | 2019-07-01 | 2022-08-02 | 新疆神邦环境工程有限公司 | Oil-water separation device and system and oil-water separation control method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of utility model: A kind of continous way liquid separating appts Effective date of registration: 20150824 Granted publication date: 20140101 Pledgee: Bank of Beijing Limited by Share Ltd. Changsha branch Pledgor: HUNAN LIJIE BIOCHEMICAL Co.,Ltd. Registration number: 2015430000020 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 410000 1 South, Ningxiang Economic Development Zone, Hunan, Changsha Patentee after: HUNAN LIJIE BIOLOGICAL GROUP CO.,LTD. Address before: 410000 1 South, Ningxiang Economic Development Zone, Hunan, Changsha Patentee before: HUNAN LIJIE BIOCHEMICAL Co.,Ltd. Address after: 410000 1 South, Ningxiang Economic Development Zone, Hunan, Changsha Patentee after: HUNAN LIJIE BIOCHEMICAL Co.,Ltd. Address before: 410000 1 South, Ningxiang Economic Development Zone, Hunan, Changsha Patentee before: HUNAN LIJIE BIOCHEMICAL Co.,Ltd. |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20160805 Granted publication date: 20140101 Pledgee: Bank of Beijing Limited by Share Ltd. Changsha branch Pledgor: HUNAN LIJIE BIOCHEMICAL Co.,Ltd. Registration number: 2015430000020 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of utility model: A kind of continous way liquid separating appts Effective date of registration: 20160902 Granted publication date: 20140101 Pledgee: Bank of Beijing Limited by Share Ltd. Changsha branch Pledgor: HUNAN LIJIE BIOLOGICAL GROUP CO.,LTD. Registration number: 2016430000032 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20171117 Granted publication date: 20140101 Pledgee: Bank of Beijing Limited by Share Ltd. Changsha branch Pledgor: HUNAN LIJIE BIOLOGICAL GROUP CO.,LTD. Registration number: 2016430000032 |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181022 Address after: 415000 Hai de Lu, Qixing nun village, de Shan town, Changde economic and Technological Development Zone, Changde, Hunan Patentee after: Hunan crown bio chemical technology Co.,Ltd. Address before: 410000 1 South, Ningxiang Economic Development Zone, Hunan, Changsha Patentee before: HUNAN LIJIE BIOLOGICAL GROUP CO.,LTD. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of utility model: Continuous type liquid separation device Effective date of registration: 20181203 Granted publication date: 20140101 Pledgee: Zhejiang Yangfan Holding Co.,Ltd. Pledgor: Hunan crown bio chemical technology Co.,Ltd. Registration number: 2018430000117 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200401 Granted publication date: 20140101 Pledgee: Zhejiang Yangfan Holding Co.,Ltd. Pledgor: Hunan crown bio chemical technology Co.,Ltd. Registration number: 2018430000117 |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20140101 |