CN203360192U - 一种难降解工业废水处理装置 - Google Patents
一种难降解工业废水处理装置 Download PDFInfo
- Publication number
- CN203360192U CN203360192U CN 201320412377 CN201320412377U CN203360192U CN 203360192 U CN203360192 U CN 203360192U CN 201320412377 CN201320412377 CN 201320412377 CN 201320412377 U CN201320412377 U CN 201320412377U CN 203360192 U CN203360192 U CN 203360192U
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- Prior art keywords
- pond
- treatment unit
- ultrafiltration
- effluent treatment
- industrial effluent
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- 239000010842 industrial wastewater Substances 0.000 title abstract description 4
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 31
- 239000012528 membrane Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound 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- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound 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NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound 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OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000002306 biochemical method Methods 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000001112 coagulant Effects 0.000 abstract description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N Nitrobenzene Chemical compound 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[O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 2
- 230000003311 flocculating Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound 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Abstract
本实用新型公开了一种难降解工业废水处理装置，其特征在于：包括通过管道依次相连的混凝池、絮凝沉淀池、中间水池、三维电解反应槽、超滤水池和超滤透过水池。本实用新型所述的难降解工业废水处理装置具有的:硝基苯、苯胺、苯酚类化工、造纸废水等难以采用常规生化法来处理，采用三维电解法，具有处理比表面积大、处理时间短、产水好、效率高的优点；采用三维电解法结合膜处理技术，可以将难降解工业废水处理成可以回用的水，处理能力强。
Description
一种难降解工业废水处理装置
技术领域
[0001] 本实用新型涉及废水处理领域，特别涉及一种难降解工业废水处理装置。
背景技术
[0002] 现代工业，特别是制药业、纺织业、焦化厂、炼油厂等企业的发展，使含有难降解有机污染物的工业废水日益增多。含有硝基苯、苯胺、苯酚类化工废水、造纸、医药、农药、皮革、印染等工业废水中的有机污染物由于其结构稳定、可生化性差、毒性强等特点，导致常规的物理、化学、生物方法难以满足净化处理在技术和经济上的要求。
[0003] 膜分离是以选择性透过膜为分离介质，当膜两侧存在推动力时，原料的组分可透过选择膜而对混合物进行分离、提纯、浓缩的一种分离过程。用于水处理的膜种类很多，但按照膜的功能可分为微滤(MF)、超滤(UF)、纳滤(NF)、反渗透(RO)、电渗析技术(ED)等。但是膜技术设备用于工业废水处理时对进水要求高，对废水的C0D、SS、浊度等均有限制，进水水质越好，其处理能力也相应越强。
发明内容
[0004] 本实用新型的目的在于提供一种能够有效处理难降解废水的难降解工业废水处
理装置。
[0005] 为达到上述目的，本实用新型所提出的技术方案为:一种难降解工业废水处理装置，其特征在于:包括通过管道依次相连的混凝池、絮凝沉淀池、中间水池、三维电解反应槽、超滤水池和超滤透过水池。
[0006] 进一步，所述的超滤透过水池还通过管道与保安过滤器，高压泵、反渗透系统、回用水池相连。
[0007] 进一步，所的三维电解反应槽的阳极采用钛钌合金，阴极采用钢板或石墨板，极板间距10-30mm ;在极板间隙填充颗粒作为第三极。
[0008] 进一步，所述的颗粒优选为选择陶粒、石墨粒子或活性炭颗粒。
[0009] 进一步，所述的三维电解反应槽的底部安装曝气装置。
[0010] 进一步，所述的超滤水池中的超滤装置为浸没式超滤装置或非浸没式的管柱式超滤装置，所述的浸没式超滤装置中的陶瓷膜优选为中空纤维膜组件。
[0011] 采用上述技术方案，本实用新型所述的难降解工业废水处理装置具有的:
[0012] I)硝基苯、苯胺、苯酚类化工、造纸废水等难以采用常规生化法来处理，采用三维电解法，具有处理比表面积大、处理时间短、产水好、效率高的优点；
[0013] 2)采用三维电解法结合膜处理技术，可以将难降解工业废水处理成可以回用的水，处理能力强。
附图说明
[0014] 图1为本实用新型所述的难降解工业废水处理装置示意图。具体实施方式
[0015] 下面结合附图和具体实施方式，对本实用新型做进一步说明。
[0016] 如图1所示，一种难降解工业废水处理装置，包括通过管道依次相连的混凝池11、絮凝沉淀池12、中间水池13、三维电解反应槽14、超滤水池16和超滤透过水池17，超滤透过水池17还通过管道与保安过滤器18，高压泵19、反渗透系统20、回用水池21相连；所述的三维电解反应槽14的阳极采用钛钌合金，阴极采用钢板或石墨板，极板间距10-30mm ;在极板间隙填充颗粒作为第三极，颗粒优选为选择陶粒、石墨粒子或活性炭颗粒，三维电解反应槽14的底部安装曝气装置15，所述的超滤水池16中的超滤装置为浸没式超滤装置或非浸没式的管柱式超滤装置，所述的浸没式超滤装置中的陶瓷膜优选为中空纤维膜组件。
[0017] 具体使用时，难降解工业废水先进入混凝池、絮凝池，将废水中较大的悬浮颗粒物除去，然后进入中间水池，经沉淀后，上清液进入三维电解反应槽。经电解处理后，再进入超滤系统、超滤产水进入超滤透过水池，经保安过滤器过滤后，进入反渗透系统处理，处理后的产水进入回用水池，收集待用。具体的，混凝、絮凝沉淀池:采用的药剂选择先加聚合氯化铝在混凝池进行混凝反应，搅拌后废水进入絮凝池，投加聚丙烯酰胺，形成大颗粒后进行沉淀；三维电解反应槽:阳极采用钛钌合金，阴极采用钢板或石墨板，极板间距10-30mm，外力口直流电；在极板间隙填充颗粒作为第三极，选择陶粒、石墨粒子或活性炭颗粒；同时在反应器的底部安装曝气装置，通过曝气鼓入空气或者氧气，一方面促进反应的进行，另一方面减少电极板的板结几率，提高使用效率。
[0018] 在上述实施例中，仅对本实用新型进行了示范性描述，但是本领域技术人员在阅读本专利申请后可以在不脱离本实用新型的精神和范围的情况下对本实用新型进行各种修改。
Claims (6)
1.一种难降解工业废水处理装置，其特征在于:包括通过管道依次相连的混凝池、絮凝沉淀池、中间水池、三维电解反应槽、超滤水池和超滤透过水池；所的三维电解反应槽的阳极采用钛钌合金，阴极采用钢板或石墨板，极板间距10-30mm ;在极板间隙填充颗粒作为第二极。
2.根据权利要求1所述的难降解工业废水处理装置，其特征在于:所述的超滤透过水池还通过管道与保安过滤器，高压泵、反渗透系统、回用水池相连。
3.根据权利要求1所述的难降解工业废水处理装置，其特征在于:所述的颗粒为陶粒、石墨粒子或活性炭颗粒。
4.根据权利要求1所述的难降解工业废水处理装置，其特征在于:所述的三维电解反应槽的底部安装曝气装置。
5.根据权利要求1所述的难降解工业废水处理装置，其特征在于:所述的超滤水池中的超滤装置为浸没式超滤装置或非浸没式的管柱式超滤装置。
6.根据权利要求5所述的难降解工业废水处理装置，其特征在于:所述的浸没式超滤装置中的陶瓷膜为中空纤维膜组件。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105271615A (zh) * | 2015-10-29 | 2016-01-27 | 长江大学 | 电化学复合式膜生物反应器 |
| CN105321589A (zh) * | 2014-07-23 | 2016-02-10 | 上海一鸣过滤技术有限公司 | 一种采用全膜法处理放射性废水的方法 |
| CN108640230A (zh) * | 2018-04-03 | 2018-10-12 | 上海大学 | 生物炭/电解联合处理硝基苯废水的方法 |
| CN108726742A (zh) * | 2018-07-06 | 2018-11-02 | 常熟浦发第二热电能源有限公司 | 一种生活垃圾渗沥液用净化工艺 |
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2013
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105321589A (zh) * | 2014-07-23 | 2016-02-10 | 上海一鸣过滤技术有限公司 | 一种采用全膜法处理放射性废水的方法 |
| CN105271615A (zh) * | 2015-10-29 | 2016-01-27 | 长江大学 | 电化学复合式膜生物反应器 |
| CN108640230A (zh) * | 2018-04-03 | 2018-10-12 | 上海大学 | 生物炭/电解联合处理硝基苯废水的方法 |
| CN108726742A (zh) * | 2018-07-06 | 2018-11-02 | 常熟浦发第二热电能源有限公司 | 一种生活垃圾渗沥液用净化工艺 |
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Effective date of registration: 20140505 Address after: Software Park Siming District of Xiamen city in Fujian province 361000 two sunrise Road No. 26 107 Patentee after: Xiamen Weinatong Membrane Technology Co., Ltd. Address before: 366300 No. 37 Xinmin Street, South Gate, Changting County, Fujian, Longyan Patentee before: Tong Jialiang |
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Granted publication date: 20131225 Termination date: 20140711 |