CN203191558U - Self-power positioning shoe - Google Patents
Self-power positioning shoe Download PDFInfo
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- CN203191558U CN203191558U CN 201320142430 CN201320142430U CN203191558U CN 203191558 U CN203191558 U CN 203191558U CN 201320142430 CN201320142430 CN 201320142430 CN 201320142430 U CN201320142430 U CN 201320142430U CN 203191558 U CN203191558 U CN 203191558U
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Abstract
The utility model discloses a self-power positioning shoe to solve the problem in the prior art that positioning shoes cannot be used normally once the power supply dies and cannot realize remote control positioning by relatives and other contact person. The self-power positioning shoe comprises a shoe body, and the shoe body further comprises a power supply module, a central processing module, a GPS positioning module and a wireless communication module. The power supply module is connected with the central processing module and supplies power for the central processing module; and the power supply module further comprises a nanometer friction generator and an energy storage apparatus; the nanometer friction generator is used for converting the mechanical energy into electric energy; and the energy storage apparatus is used for storing electric energy. The central processing module is respectively connected with the GPS positioning module and the wireless communication module, and used for controlling the GPS positioning module to carry out positioning and providing the positioning information generated by the GPS positioning module to the wireless communication module; and the wireless communication module sends the positioning information to a predetermined receiving end.
Description
Technical field
The utility model relates to a kind of footwear, and particularly a kind of self-powered is located footwear.
Background technology
Along with development of science and technology, the location footwear have been come into people's life step by step as a kind of high-tech product.Existing location footwear generally all adopt battery or external charging formula power supply to power, but out of doors the explorer fall behind or run into accident, old man or children lost or face a danger, act as a planted agent that the police faces a danger, in many situations such as VIP or booming income crowd are kidnaped, in case the power supply of location footwear exhausts, the user can't in time give location footwear charging, thereby influenced the use of location footwear, the life security of having brought inconvenience and may jeopardizing the user to the user.
In addition, existing location footwear can only position the transmission of information by the mode that the user initiatively triggers, and can't realize the function by the transmission of contact person's Long-distance Control locating information such as kith and kin.This shows, extraneous then can't relate to the user of these location footwear when the user can't initiatively position because of fortuitous event, can't succour.
The utility model content
The utility model provides a kind of self-powered location footwear, in case just exhaust and can't normally use in order to solve location of the prior art footwear power supply, and can not be by the problem of contact person's Long-distance Control such as kith and kin location.
A kind of self-powered location footwear, comprise the footwear body, further comprise in the described footwear body: power module, central processing module, GPS locating module and wireless communication module, wherein, described power module links to each other with described central processing module, and described power module further comprises nano friction generator and energy storage device; Described central processing module links to each other with described GPS locating module and controls described GPS locating module and positions; Described central processing module further links to each other with described wireless communication module and locating information that described GPS locating module is produced offers described wireless communication module.
Alternatively, these self-powered location footwear further comprise: trigger the alarm switch that described central processing module control GPS locating module positions, it is arranged on the described footwear body, and links to each other with described central processing module.
Alternatively, described alarm switch comprises one or more in the following type: snap switch, pushbutton switch, vibration switch and audio-switch.
Alternatively, described wireless communication module further receives the positioning control signal from external unit, described positioning control signal is sent to central processing module, and described central processing module is controlled described GPS locating module and is positioned when receiving described positioning control signal.
Alternatively, described wireless communication module comprises one or more in GSM transceiver, Wi-Fi transceiver, WCDMA transceiver, the GPRS transceiver.
Alternatively, described nano friction generator comprises: first electrode that is cascading, the first high molecular polymer insulation course, and second electrode; Wherein, described first electrode is arranged on first side surface of the described first high molecular polymer insulation course; And second side surface of the described first high molecular polymer insulation course is towards the described second electrode setting, and described first electrode and second electrode are respectively first output terminal and second output terminal of described nano friction generator.
Alternatively, the described first high molecular polymer insulation course is provided with micro-nano structure towards the face of second electrode.
Alternatively, described nano friction generator further comprises: be arranged on the second high molecular polymer insulation course between described second electrode and the described first high molecular polymer insulation course, then described second electrode is arranged on first side surface of the described second high molecular polymer insulation course; And second side surface of second side surface of the described second high molecular polymer insulation course and the described first high molecular polymer insulation course is oppositely arranged.
Alternatively, at least one face in two faces being oppositely arranged of the described first high molecular polymer insulation course and the second high molecular polymer insulation course is provided with micro-nano structure.
Alternatively, described nano friction generator further comprises: be arranged on the thin layer between two parties between the described first high molecular polymer insulation course and the described second high molecular polymer insulation course, wherein, at least one face in two faces that described thin layer between two parties and the first high molecular polymer insulation course are oppositely arranged is provided with micro-nano structure, and/or at least one face in two faces being oppositely arranged of described thin layer between two parties and the second high molecular polymer insulation course is provided with micro-nano structure.
Alternatively, described nano friction generator comprises: first electrode that is cascading, the first high molecular polymer insulation course, electrode layer between two parties, the second high molecular polymer insulation course and second electrode; Wherein, described first electrode is arranged on first side surface of the described first high molecular polymer insulation course; Described second electrode is arranged on first side surface of the described second high molecular polymer insulation course, described electrode layer between two parties is arranged between second side surface of second side surface of the described first high molecular polymer insulation course and the described second high molecular polymer insulation course, and on the face of the described relatively electrode layer between two parties of the described first high molecular polymer insulation course and/or the face of the described relatively electrode layer between two parties of the described second high molecular polymer insulation course be provided with micro-nano structure, described first electrode and the series connection of second electrode are that first output terminal of described nano friction generator, described electrode layer between two parties are second output terminal of described nano friction generator.
Alternatively, described energy storage device comprises: the electric signal that links to each other with the output electrode of nano friction generator, described nano friction generator is exported carries out the rectification circuit module that rectification is handled; Link to each other with described rectification circuit module, the unidirectional Rectified alternating current of described rectification circuit module output is carried out that filtering is handled and the filtering circuit module that obtains dc signal; The energy-storage travelling wave tube that links to each other with described filtering circuit module, the dc signal of described filtering circuit module output is stored.
Alternatively, described energy-storage travelling wave tube is ultracapacitor, and then described energy storage device also comprises: charge control module and switch/transformation module; Described charge control module is connected with the filtering circuit module, receives the dc signal of described filtering circuit module output; Described charge control module is connected with described ultracapacitor, receives the charging voltage of described ultracapacitor feedback; Described charge control module is connected with described switch/transformation module, and described charge control module is exported described control signal according to described dc signal and the controlled signal of described charging voltage to described switch/transformation module; Described switch/transformation module is connected with described filtering circuit module, the dc signal of the circuit module that accepts filter output; Described switch/transformation module is connected with described ultracapacitor, and described switch/transformation module is carried out the switch switching according to the control signal that receives and the dc signal that described filtering circuit module is exported is carried out exporting to described ultracapacitor after transformation is handled.
Alternatively, described energy storage device also comprises: the generator control module; Described generator control module is connected with described ultracapacitor, receives the charging voltage of described ultracapacitor feedback; Described generator control module is connected with described nano friction generator, the signal that described generator control module stops to generate electricity to described nano friction generator output according to described charging voltage.
Among the utility model embodiment, power for the location footwear by the nano friction generator, to realize positioning function.Because the nano friction generator can be converted to electric energy with mechanical energy, thereby realize self-energizing, need not battery or external power supply, thereby the problem that can not in time power when having avoided power supply to exhaust.And because wireless communication module wherein can initiatively receive the positioning control signal that kith and kin send, thereby when the user can't initiatively position because of fortuitous event, the external world also can relate to the user of these location footwear, thereby succours.
Description of drawings
Fig. 1 shows the structural representation of the location footwear that the utility model embodiment provides;
Fig. 2 a shows a kind of structural representation of the energy storage device of the location footwear that the utility model embodiment provides;
Fig. 2 b shows another structural representation of the energy storage device of the location footwear that the utility model embodiment provides;
Fig. 3 a and Fig. 3 b show perspective view and the cross-sectional view of first kind of structure of nano friction generator respectively;
Fig. 4 a and Fig. 4 b show perspective view and the cross-sectional view of second kind of structure of nano friction generator respectively;
Fig. 5 a and Fig. 5 b show perspective view and the cross-sectional view of the third structure of nano friction generator respectively;
Fig. 6 a and Fig. 6 b show perspective view and the cross-sectional view of the 4th kind of structure of nano friction generator respectively.
Embodiment
For fully understanding purpose, feature and the effect of the utility model, by following concrete embodiment, the utility model is elaborated, but the utility model is not restricted to this.
The utility model provides a kind of self-powered location footwear, just exhausts and can't normally use in case can solve location of the prior art footwear power supply, and can not be by the problem of contact person's Long-distance Control such as kith and kin location.
Fig. 1 shows the self-powered location footwear that the utility model embodiment provides, and comprises the footwear body, further comprises in the footwear body: power module 1, central processing module 2, GPS locating module 3 and wireless communication module 4.
Wherein, power module 1 links to each other with central processing module 2, is used to central processing module 2 power supplies.Wherein, power module 1 further comprises nano friction generator 11 and energy storage device 12.Nano friction generator 11 is used for mechanical energy is converted to electric energy, realizing self-energizing, will give detailed introduction in the back separately about the concrete structure of nano friction generator.Energy storage device 12 is used for the electric energy that nano friction generator 11 produces is stored.Alternatively, energy storage device 12 may further include: rectification circuit, link to each other with the nano friction generator, be used for the AC energy of nano friction generator output is carried out rectification, thereby will size and Orientation all time dependent alternating current change direction into and do not change the time dependent single-phase Rectified alternating current of size in time; Filtering circuit links to each other with rectification circuit, and remaining AC compounent in the direct current signal of the single-phase pulsation of rectification circuit output is carried out filtering; Transforming circuit links to each other with filtering circuit, the direct current signal of the single-phase pulsation of filtering circuit output is carried out transformation handle, and obtains being fit to the electric signal that charges to energy-storage travelling wave tube; Energy-storage travelling wave tube links to each other with transforming circuit, and the electric energy of transforming circuit output is stored.Here, energy-storage travelling wave tube can select for use energy-storage travelling wave tubes such as lithium battery, Ni-MH battery, super capacitor to realize flexibly.When the user did not use positioning function, the user jammed on the electric energy that the nano friction generator produces and can be stored in this energy storage device, and continued accumulation, to guarantee that sufficient electric energy supply is arranged when using positioning function.
Be example with the ultracapacitor with the energy-storage travelling wave tube in the energy storage device below, introduce two kinds of possible structures of above-mentioned energy storage device 12 in detail.
The self-powered that Fig. 2 a provides for the utility model is located a kind of circuit theory synoptic diagram of energy storage device in the footwear.The inner structure that Fig. 2 a shows energy storage device with and with the annexation of nano friction generator 11.Shown in Fig. 2 a, energy storage device comprises: rectification circuit module 51, filtering circuit module 52 and ultracapacitor 54.Wherein, rectification circuit module 51 links to each other with the output terminal of nano friction generator 11, and the electric signal that nano friction generator 11 is exported carries out the rectification processing.Particularly, two input end 51A of rectification circuit module 51 and 51B are connected two output terminals of nano friction generator respectively, receive the electric signal of nano friction generator 11 outputs.For comprising a plurality of nano friction generator Structure, two output terminals of a plurality of nano friction generators are connected in parallel, and are connected with 51B with two input end 51A of rectification circuit module 51 then.
Two output terminal 51C of rectification circuit module 51 are connected with filtering circuit module 52 with 51D, and the unidirectional Rectified alternating current that the electric signal that rectification circuit module 51 is exported nano friction generator 11 carries out obtaining after rectification is handled is exported to filtering circuit module 52.Filtering circuit module 52 is connected with ultracapacitor 54, and filtering circuit module 52 is carried out filtering with the unidirectional Rectified alternating current of rectification circuit module 51 output and handled and obtain dc signal and export to ultracapacitor 54.
Shown in Fig. 2 a, filtering circuit module 52 has two ends.Particularly, the first end 52A of filtering circuit module 52 is connected with the output terminal 51D of rectification circuit module 51, and the second end 52B of filtering circuit module 52 is connected with the output terminal 51C of rectification circuit module 51.The first end 52A of filtering circuit module 52 is connected with the first end 54A of ultracapacitor, and the second end 52B of filtering circuit module 52 is connected with the second end 54B of ultracapacitor.In actual applications, the general ground connection of the second end 52B of filtering circuit module 52.
For the circuit shown in Fig. 2 a, when external force acts on the nano friction generator, can make nano friction generator generation mechanical deformation, thereby produce the pulse electrical signal that exchanges.The pulse electrical signal of this interchange at first inputs to the rectification circuit module, by the rectification circuit module it is carried out rectification, obtains the direct current of unidirectional pulsation.The direct current of this unidirectional pulsation inputs to the filtering circuit module again and carries out filtering, and the interference noise in the direct current of unidirectional pulsation is carried out filtering, obtains dc signal.At last, this dc signal directly inputs to ultracapacitor and charges.Here can also can charge simultaneously for the ultracapacitor of a plurality of parallel connections for a ultracapacitor charging.
The advantage of foregoing circuit is: (1) produces the size of electric energy and the size of ultracapacitor electric capacity and charging voltage according to the nano friction generator, by regulating the correlation parameter of filtering circuit module, make it possible to the electric energy that utilizes the nano friction generator to produce to greatest extent, improve energy conversion efficiency; (2) according to the difference of applied environment, the voltage amplitude scope that the nano friction generator produces is bigger, can it be adjusted into adaptation to the voltage of ultracapacitor charging by regulating the correlation parameter of filtering circuit module, overcome the uncertainty that the nano friction generator produces voltage swing.
Further, energy storage device can also adopt a kind of more preferred construction.The self-powered that Fig. 2 b provides for the utility model is located the another kind of circuit theory synoptic diagram of energy storage device in the footwear.The inner structure that Fig. 2 b shows preferred energy storage device with and with the annexation of nano friction generator.Shown in Fig. 2 b, energy storage device also comprises charge control module 63 and switch/transformation module 64 except comprising rectification circuit module 61, filtering circuit module 62 and ultracapacitor 65.Wherein the function of rectification circuit module 61 and filtering circuit module 62 repeats no more referring to above.
Charge control module 63 is connected with filtering circuit module 62, the d. c. voltage signal U1 of circuit module 62 outputs that accept filter; Charge control module 63 is connected with ultracapacitor 65, receives the charging voltage U of ultracapacitor 65 feedbacks; Charge control module 63 also is connected with switch/transformation module 64, and charge control module 63 is according to d. c. voltage signal U1 and the controlled signal of charging voltage U, to switch/transformation module 64 output control signals.Switch/transformation module 64 is connected with filtering circuit module 62, the d. c. voltage signal U1 of circuit module 62 outputs that accept filter; Switch/transformation module 64 also is connected with ultracapacitor 65, switch/transformation module 64 is carried out the switch switching and the d. c. voltage signal of filtering circuit module 62 outputs is regulated processing according to the control signal that receives, and is adjusted to adapt to the voltage U 2 of giving ultracapacitor 65 chargings.
For the circuit shown in Fig. 2 b, different with Fig. 2 a is, handle the d. c. voltage signal U1 that obtains through filtering and input to charge control module 63, charge control module 63 can decide and when ultracapacitor 65 be charged according to the size of this d. c. voltage signal U1; And ultracapacitor 65 charge conditions are paid close attention to, come gauge tap/transformation module 64 according to the situation of ultracapacitor 65 chargings.The output voltage of wave circuit module 62 is output voltages that progressively increase after filtration, and this output voltage is up to increasing to pressure limiting voltage, and this pressure limiting voltage is a circuit protection voltage, prevents that circuit from damaging because of overtension.
Because whole charging circuit module does not have external power supply, it also is to come from nano friction generator electricity that charge control module 63 gauge tap/transformation module 64 is given the working power of ultracapacitor 65 chargings, therefore specially in charge control module 63 trigger voltage is set, after filtering circuit module 62 output voltages reached this trigger voltage, charge control module 63 just driving switch/transformation module 64 started charging.
Another effect of charge control module 63 is according to the size of the d. c. voltage signal U1 that obtains through filtering and the size of ultracapacitor 65 charging voltage U, U1 regulates to d. c. voltage signal, be adjusted to the voltage U 2 that adapts to ultracapacitor 65 chargings, and selectivity driving switch/transformation module 64 gives ultracapacitor 65 chargings.
According to C=Q/U as can be known, the capacity C of ultracapacitor is a fixed value, and in the process to the ultracapacitor charging, quantity of electric charge Q is in continuous increase, and the voltage U of ultracapacitor is also in continuous rising thereupon.Charge to ultracapacitor for more effective, charge control module 63 is according to the numerical information of the d. c. voltage signal U1 of the charging voltage U of ultracapacitor 65 feedback and 62 outputs of filtering circuit module, come the circuit in by-pass cock/transformation module 64, realization obtains the real time charging voltage U 2 of ultracapacitor 65 to the conversion of voltage U 1 to U2.A corresponding charging matching relationship is arranged, to guarantee the highest energy conversion efficiency between U2 and the U.For instance, suppose that the voltage that is full of of ultracapacitor 65 is U0, charge control module 63 compares charging voltage U and the U0 of ultracapacitor 65 feedbacks, if U, shows ultracapacitor 65 also underfills less than U0, needs to continue charging; If U equals U0, show that ultracapacitor 65 has been full of.Simultaneously, charge control module 63 also compares d. c. voltage signal U1 and the U0 of 62 outputs of filtering circuit module, if U1 is greater than U0, then charge control module 63 output control signal gauge tap/64 couples of U1 of transformation module carry out the step-down processing, obtain the real time charging voltage U 2 of ultracapacitor 65; If U1 is less than U0, then charge control module 63 output control signal gauge tap/64 couples of U1 of transformation module processing of boosting obtains the real time charging voltage U 2 of ultracapacitor 65.
Here can be a ultracapacitor charging, also can as Fig. 2 b, show three ultracapacitors for a plurality of ultracapacitor chargings, these three ultracapacitors are connected in parallel.When being the charging of a plurality of ultracapacitors, can be full of one by one, also can be full of simultaneously.Be full of in the following manner one by one and realize: the charging voltage U that charge control module 63 is fed back the current ultracapacitor that is charging is full of voltage U 0 and compares with it, if U has reached U0, charge control module 63 output control signal gauge tap/transformation modules 64 switch to next ultracapacitor with switch, continue as next ultracapacitor and charge so.
Further, in order to protect the nano friction generator, energy storage device can also comprise generator control module 66.This generator control module 66 is connected with ultracapacitor 65, receives the charging voltage U of ultracapacitor 65 feedbacks; Generator control module 66 also is connected with the nano friction generator, exports the signal that stops to generate electricity to the nano friction generator.When ultracapacitor 65 is full of, can obtain one and be full of voltage, this is full of voltage and feeds back to generator control module 66, and then generator control module 66 can close the nano friction generator, thereby stops generating.
The advantage of the circuit shown in Fig. 2 b is: (1) is owing to the external force size that acts on the nano friction generator is uncertain, the alternating current size that makes the nano friction generator produce is also uncertain, this circuit can convert uncertain magnitude of voltage to the magnitude of voltage that is fit to the ultracapacitor charging, adaptability is strong, has expanded the application of self-charging ultracapacitor; (2) owing to designed charge control module especially in the circuit, regulate its charging voltage according to the real-time voltage of ultracapacitor, make real-time voltage and the charging voltage of ultracapacitor keep a dynamic matching relationship, reach the electric energy that the nano friction generator is sent and filled to greatest extent and given ultracapacitor, realized maximum energy storage effect; (3) according to being full of of ultracapacitor, whether the work of generator control module control nano friction generator, and then prolong the serviceable life of nano friction generator; (4) when charging for a plurality of ultracapacitors, when one of them is full of, can automatically switches to next ultracapacitor and charge.
After having introduced the implementation of power module, continuation is with reference to Fig. 1, central processing module 2 links to each other with wireless communication module 4 with GPS locating module 3 respectively, being used for control GPS locating module 3 positions, and the locating information that GPS locating module 3 is produced offers wireless communication module 4, by wireless communication module 4 above-mentioned locating information sent to predetermined receiving end.
Particularly, when central processing module 2 positions at control GPS locating module 3, mainly by initiatively triggering and passive triggering dual mode are controlled.
In the mode that initiatively triggers, need an alarm switch 5 be set at the footwear body of location footwear, this alarm switch 5 links to each other with central processing module 2, is used for central processing module 2 is triggered.When central processing module 2 receives the triggering of alarm switch 5, then control GPS locating module 3 and position.Wherein, alarm switch can be one or more in the following type: snap switch, pushbutton switch, vibration switch and audio-switch.If alarm switch is snap switch or pushbutton switch, then when the user pushed for emergency switch, alarm switch can send a trigger pip from the trend central processing module, and central processing module is controlled the GPS locating module according to this trigger pip and positioned; If alarm switch is vibration switch or audio-switch, then the vibrations degree when the location footwear exceeds default vibrations threshold value, when perhaps the frequency of ambient sound exceeds the frequency preset threshold value, alarm switch can send a trigger pip from the trend central processing module, and central processing module is controlled the GPS locating module according to this trigger pip and positioned.Initiatively the mode that triggers can be by the user in lost or triggered location function on one's own initiative when facing a danger, to obtain rescue.This mode is applicable to user's freedom of action and the situation that can initiatively trigger.
In the mode of passive triggering, when needs position the user, send the positioning control signal by external unit (for example mobile phone, pager etc.) to the wireless communication module of footwear inside, location by kith and kin or police.Wireless communication module is transmitted to central processing module with it after receiving this positioning control signal, and central processing module is controlled the GPS locating module and positioned after receiving this positioning control signal.The mode of passive triggering can initiatively not initiated when contacting the user by kith and kin, in order to know user's whereabouts.This mode is applicable to the situation that the user is handicapped and can't initiatively trigger.And this mode is specially adapted to suffer from the old man of senile dementia or the child who runs away from home.When the control that is subjected to central processing module when the GPS locating module positions, at first need to catch gps satellite signal, and position calculating according to the satellite-signal that captures, thereby obtain the residing positional information of user, also be locating information, and this locating information offered wireless communication module by central processing module, by wireless communication module this locating information is sent to predetermined receiving end.Wherein, can carry out with reference to the locator meams of routine according to the detailed process that gps satellite signal positions, repeat no more herein.In addition, because location Calculation is a kind of very complicated calculating, so positioning when calculating, the GPS locating module need expend a large amount of electric energy, therefore, preferably can adopt a kind of cloud GPS technology in the utility model, the calculation task of complexity is transferred to large-scale high in the clouds server process, thereby reduce the calculated amount of GPS locating module, saves energy.
Wireless communication module sends to above-mentioned locating information the predetermined receiving end except being used for, and can also send alerting signal to predetermined receiving end simultaneously, in order to arouse attention.Wherein, predetermined receiving end can be this location footwear user's kith and kin's mobile phone, perhaps, also can be the phone etc. of local police station, and for this reason, needs be stored in kith and kin's cell-phone number or the telephone number of local police station in the wireless communication module 4 in advance.In addition, can also be the receiving end of emergency telephone number correspondence, for example, wireless communication module 4 will be called out 110 emergency numbers such as grade, and be transferred to 110 nearest information desks automatically.And, can in time obtain rescue in order to ensure the user, this predetermined receiving end can be a plurality of, for example, can send locating information to a plurality of kith and kin respectively.Wherein, the delivery form of locating information can arrange as required flexibly, for example, can transmit by short message, also can transmit by voice, can also transmit by short message and voice simultaneously.
Above-mentioned wireless communication module can comprise one or more in GSM transceiver, Wi-Fi transceiver, WCDMA transceiver and the GPRS transceiver.When wireless communication module comprises multiple in the above-mentioned transceiver, can select a kind of suitable transceiver to use according to the concrete condition of environment for use.Be that example is introduced with the wireless communication module for the GSM transceiver below.When wireless communication module is the GSM transceiver, this GSM transceiver is the transfer table in the gsm system, except transfer table, gsm system also needs to comprise base station sub-system and network subsystem, so that finish communicating by letter between transfer table and other communication facilitiess (for example kith and kin's mobile phone), belong to those skilled in the art's common practise about the concrete formation of base station sub-system and network subsystem, repeat no more herein.
Among the utility model embodiment, power for the location footwear by the nano friction generator, to realize positioning function.Because the nano friction generator can be converted to electric energy with mechanical energy, thereby realize self-energizing, need not battery or external power supply, thereby the problem that can not in time power when having avoided power supply to exhaust.And because wireless communication module can initiatively receive the positioning control signal that kith and kin send, thereby when the user can't initiatively position because of fortuitous event, the external world also can relate to the user of these location footwear, thereby succours.
In the above-described embodiments, the nano friction generator is core component, just because of the spontaneous electrical function of nano friction generator, just makes the location footwear be achieved self-powered.Following mask body is introduced nano friction generator Structure and principle of work wherein.
First kind of structure of nano friction generator is shown in Fig. 3 a and Fig. 3 b.Fig. 3 a and Fig. 3 b show perspective view and the cross-sectional view of first kind of structure of nano friction generator respectively.This nano friction generator comprises: first electrode, 111, the first high molecular polymer insulation courses 112 that are cascading, and second electrode 113.Particularly, described first electrode 111 is arranged on first side surface of the first high molecular polymer insulation course 112; And the surperficial contact friction of second side surface of the described first high molecular polymer insulation course 112 and second electrode 113 also induces electric charge at second electrode and the first electrode place.Therefore, above-mentioned first electrode and second electrode first output terminal and second output terminal that also can be called the nano friction generator respectively.
In order to improve the generating capacity of nano friction generator, at second side surface (being on the face of relative second electrode 113) of the first high molecular polymer insulation course 112 micro-nano structure 120 can be set further.Therefore, when the nano friction generator is squeezed, apparent surface's contact friction better of the described first high molecular polymer insulation course 112 and second electrode 113, and induce more electric charge at first electrode 111 and second electrode, 113 places.Because the second above-mentioned electrode is mainly used in and the friction of the first high molecular polymer insulation course, therefore, second electrode also can be referred to as the electrode that rubs.
Above-mentioned micro-nano structure 120 specifically can be taked following two kinds of possible implementations: first kind of mode is that this micro-nano structure is micron order or nano level very little concaveconvex structure.This concaveconvex structure can increase frictional resistance, improves generating efficiency.Described concaveconvex structure can directly form when film preparation, and method that also can enough polishings makes the surface of the first high molecular polymer insulation course form irregular concaveconvex structure.Particularly, this concaveconvex structure can be the concaveconvex structure of semicircle, striated, cubic type, rectangular pyramid type or shape such as cylindrical.The second way is, this micro-nano structure is the poroid structure of nanoscale, this moment, the first high molecular polymer insulation course material therefor was preferably Kynoar (PVDF), and its thickness is the preferred 1.0mm of 0.5-1.2mm(), and the face of its relative second electrode is provided with a plurality of nano-pores.Wherein, the size of each nano-pore, namely width and the degree of depth can be selected according to the needs of using, and preferred nano-pore is of a size of: width is that 10-100nm and the degree of depth are 4-50 μ m.The quantity of nano-pore can as required output current value and magnitude of voltage be adjusted, and preferably these nano-pores are that pitch of holes is the even distribution of 2-30 μ m, and preferred average pitch of holes is the even distribution of 9 μ m.
Following mask body is introduced the principle of work of above-mentioned nano friction generator.When crooked under each course of this nano friction generator, second electrode in the nano friction generator produces static charge with the first high molecular polymer surface of insulating layer phase mutual friction, the generation of static charge can make the electric capacity between first electrode and second electrode change, thereby cause electric potential difference occurring between first electrode and second electrode, thereby free electron will be by first electrode and second electrode respectively by the low effluent of electromotive force to the high side of electromotive force, thereby in external circuit, form electric current.In addition, when each layer of this nano friction generator returns to original state, at this moment the built-in potential that is formed between first electrode and second electrode disappears, to again produce reverse electric potential difference between Balanced first electrode and second electrode this moment, and then free electron forms inverse current by external circuit.By repeated friction and recovery, just can in external circuit, form periodic ac signal.
According to discovering of inventor, metal and high molecular polymer friction, therefore the more volatile de-electromation of metal adopts metal electrode and high molecular polymer friction can improve energy output.Correspondingly, in the nano generator shown in Fig. 3 a and Fig. 3 b, second electrode is owing to need to rub as friction electrode (being metal) and the first high molecular polymer insulation course, therefore its material can be selected from metal or alloy, and wherein metal can be gold, silver, platinum, palladium, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy can be aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy, aldary, kirsite, manganese alloy, nickel alloy, lead alloy, ashbury metal, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungalloy, molybdenum alloy, niobium alloy or tantalum alloy.First electrode is not owing to need to rub, therefore, except the material that can select above-mentioned second electrode of enumerating for use, other materials that can make electrode also can be used, that is to say, first electrode is except being selected from metal or alloy, and wherein metal can be gold, silver, platinum, palladium, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy can be outside aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy, aldary, kirsite, manganese alloy, nickel alloy, lead alloy, ashbury metal, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungalloy, molybdenum alloy, niobium alloy or the tantalum alloy, can also be selected from nonmetallic materials such as indium tin oxide, Graphene, nano silver wire film.
This shows, nano generator shown in Fig. 3 a and Fig. 3 b mainly produces electric signal by the friction between metal (second electrode) and the polymkeric substance (the first high molecular polymer insulation course), mainly utilized metal to lose the characteristic of electronics easily, make between second electrode and the first high molecular polymer insulation course and form induction field, thereby produce voltage or electric current.
Second kind of structure of nano friction generator is shown in Fig. 4 a and Fig. 4 b.Fig. 4 a and Fig. 4 b show perspective view and the cross-sectional view of second kind of structure of nano friction generator respectively.This nano friction generator comprises: first electrode 111, the first high molecular polymer insulation courses, 112, the second high molecular polymer insulation courses 114 and second electrode 113 that is cascading.Particularly, first electrode 111 is arranged on first side surface of the first high molecular polymer insulation course 112; Described second electrode 113 is arranged on first side surface of the second high molecular polymer insulation course 114; Wherein, the second side surface contact friction of second side surface of the described first high molecular polymer insulation course 112 and the second high molecular polymer insulation course 114 and induce electric charge at first electrode and the second electrode place.Wherein, first electrode and second electrode also can be called first output terminal and second output terminal of nano friction generator respectively.
In order to improve the generating capacity of nano friction generator, at least one face in two faces that the described first high molecular polymer insulation course 112 and the second high molecular polymer insulation course 114 are oppositely arranged is provided with micro-nano structure 120.Therefore, when the nano friction generator is squeezed, apparent surface's contact friction better of the described first high molecular polymer insulation course 112 and the second high molecular polymer insulation course 114, and induce more electric charge at first electrode 111 and second electrode, 113 places.Above-mentioned micro-nano structure can repeat no more with reference to description above herein.
The principle of work of the nano friction generator shown in the principle of work of the nano friction generator shown in Fig. 4 a and Fig. 4 b and Fig. 3 a and Fig. 3 b is similar.Difference only is, when each layer of the nano friction generator shown in Fig. 4 a and Fig. 4 b is crooked, is that the surperficial phase mutual friction by the first high molecular polymer insulation course and the second high molecular polymer insulation course produces static charge.Therefore, the principle of work about the nano friction generator shown in Fig. 4 a and Fig. 4 b repeats no more herein.
Nano friction generator shown in Fig. 4 a and Fig. 4 b mainly produces electric signal by the friction between polymkeric substance (the first high molecular polymer insulation course) and the polymkeric substance (the second high molecular polymer insulation course).
First electrode and the second electrode material therefor can be indium tin oxide, Graphene, nano silver wire film, metal or alloy in the structure shown in Fig. 4 a and Fig. 4 b, and wherein metal can be gold, silver, platinum, palladium, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy can be aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy, aldary, kirsite, manganese alloy, nickel alloy, lead alloy, ashbury metal, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungalloy, molybdenum alloy, niobium alloy or tantalum alloy.As can be seen, because in the structure shown in Fig. 4 a and Fig. 4 b, second electrode does not need as the friction electrode, therefore, second electrode also can be chosen nonmetallic materials and realize.
In above-mentioned two kinds of structures, the above-mentioned first high molecular polymer insulation course and the second high molecular polymer insulation course are selected from Kapton respectively, the aniline formaldehyde resin film, the polyoxymethylene film, ethyl cellulose film, polyamide film, the melamino-formaldehyde film, polyglycol succinate film, cellophane, cellulose acetate film, the polyethylene glycol adipate film, the polydiallyl phthalate film, fiber (regeneration) sponge film, the elastic polyurethane body thin film, the styrene-acrylonitrile copolymer copolymer film, the styrene-butadiene-copolymer film, the regenerated fiber film, poly-methyl film, the methacrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, the polyisobutylene film, polyurethane flexible sponge film, pet film, polyvinyl butyral film, formaldehyde phenol film, the neoprene film, the butadiene-propylene copolymer film, the natural rubber film, the polyacrylonitrile film, a kind of in vinyl cyanide vinyl chloride film and the tygon third diphenol carbonate film.Wherein, the material of the first high molecular polymer insulation course and the second high molecular polymer insulation course can be identical in principle, also can be different.But, if the material of two-layer high molecular polymer insulation course is all identical, can cause the quantity of electric charge of electrification by friction very little.Therefore preferably, the first high molecular polymer insulation course is different with the material of the second high molecular polymer insulation course.
Except above-mentioned two kinds of structures, the nano friction generator can also adopt the third structure to realize, shown in Fig. 5 a and Fig. 5 b.Fig. 5 a and Fig. 5 b show perspective view and the cross-sectional view of the third structure of nano friction generator respectively.As can be seen from the figure, the third structure has increased a thin layer between two parties on the basis of second kind of structure, that is: the nano friction generator of the third structure comprises first electrode 111 that is cascading, the first high molecular polymer insulation course 112, thin layer 110, the second high molecular polymer insulation course 114 and second electrode 113 between two parties.Particularly, described first electrode is arranged on first side surface of the first high molecular polymer insulation course; Described second electrode is arranged on first side surface of the second high molecular polymer insulation course, and thin layer is arranged between second side surface of second side surface of the first high molecular polymer insulation course and the second high molecular polymer insulation course between two parties.Wherein, at least one face in two faces that described thin layer between two parties and the first high molecular polymer insulation course are oppositely arranged is provided with micro-nano structure, and/or at least one face in two faces being oppositely arranged of described thin layer between two parties and the second high molecular polymer insulation course is provided with micro-nano structure, concrete set-up mode about micro-nano structure can repeat no more with reference to above describing herein.
Preferably, first side surface of thin layer is arranged on second side surface of the second high molecular polymer insulation course between two parties, and second side surface of thin layer contacts with second side surface of the first high molecular polymer insulation course between two parties, at this moment, because thin layer and the second high molecular polymer insulation course relative fixed between two parties, therefore, when this nano generator was squeezed, second side surface of the described first high molecular polymer insulation course induced electric charge with the second side surface contact friction of thin layer between two parties and at first electrode and the second electrode place.This shows that described first electrode and second electrode are respectively as two output terminals of described nano generator.
In the nano friction generator shown in Fig. 5 a and Fig. 5 b, first side surface of thin layer 110 (namely not being provided with a side of micro-nano structure) is to be fixed on second side surface of the second high molecular polymer insulation course 114 between two parties, fixing method can be to use the thin uncured high molecular polymer insulation course of one deck as tack coat, behind overcuring, thin layer 110 will be fixed on the second high molecular polymer insulation course 114 firmly between two parties.Thin layer 110 side that is provided with micro-nano structure contacts with second side surface of the first high molecular polymer insulation course 112 between two parties.
The material of the nano friction generator shown in Fig. 5 a and Fig. 5 b can be selected with reference to the material of the nano friction generator of second kind of structure.Wherein, thin layer also can be selected from transparent high polymer polyethylene terephthalate (PET), dimethyl silicone polymer (PDMS), polystyrene (PS), polymethylmethacrylate (PMMA), polycarbonate (PC) and the polymeric liquid crystal copolymer (LCP) any one between two parties.Wherein, the material preferably clear superpolymer polyethylene terephthalate (PET) of the described first high molecular polymer insulation course and the second high molecular polymer insulation course; Wherein, the preferred dimethyl silicone polymer of the material of described thin layer between two parties (PDMS).The first above-mentioned high molecular polymer insulation course, the second high molecular polymer insulation course, the material of thin layer can be identical between two parties, also can be different.But, if the material of three floor height Molecularly Imprinted Polymer insulation courses is all identical, can cause the quantity of electric charge of electrification by friction very little, therefore, in order to improve friction effect, the material of thin layer is different from the first high molecular polymer insulation course and the second high molecular polymer insulation course between two parties, the first high molecular polymer insulation course is then preferably identical with the material of the second high molecular polymer insulation course, like this, can reduce material category, make making of the present utility model convenient.
In the implementation shown in Fig. 5 a and Fig. 5 b, thin layer 110 is one layer of polymeric films between two parties, therefore similar with the implementation shown in Fig. 4 a and Fig. 4 b in fact, remain and generate electricity by the friction between polymkeric substance (thin layer 10 between two parties) and the polymkeric substance (the first high molecular polymer insulation course).Wherein, film preparation and stable performance easily between two parties.
In addition, the nano friction generator can also adopt the 4th kind of structure to realize, shown in Fig. 6 a and Fig. 6 b, comprise: first electrode 111 that is cascading, the first high molecular polymer insulation course 112, electrode layer 180, the second high molecular polymer insulation courses 114 and second electrode 113 between two parties; Wherein, first electrode 111 is arranged on first side surface of the first high molecular polymer insulation course 112; Second electrode 113 is arranged on first side surface of the second high molecular polymer insulation course 114, and described electrode layer between two parties 180 is arranged between second side surface of second side surface of the first high molecular polymer insulation course 112 and the second high molecular polymer insulation course 114.Wherein, the first high molecular polymer insulation course 112 relatively between two parties at least one face in the face of the face of electrode layers 180 and electrode layer 180 relative first high molecular polymer insulation courses 112 between two parties be provided with the micro-nano structure (not shown); The second high molecular polymer insulation course 114 at least one face in the face of the face of electrode layers 180 and electrode layer 180 relative second high molecular polymer insulation courses 114 between two parties relatively between two parties is provided with the micro-nano structure (not shown).In this mode, produce static charge by rubbing between electrode layer 180 and the first high molecular polymer insulation course and the second high molecular polymer insulation course between two parties, thus will be between two parties produce electric potential difference between electrode layer 180 and first electrode and second electrode, at this moment, the series connection of first electrode and second electrode is an output terminal of nano friction generator; Another output terminal that described electrode layer between two parties is the nano friction generator.
In the structure shown in Fig. 6 a and Fig. 6 b, the material of the first high molecular polymer insulation course, the second high molecular polymer insulation course, first electrode and second electrode can be selected with reference to the nano generator of second kind of structure.Electrode layer 80 can be selected conductive film, conducting polymer, metal material between two parties, metal material comprises simple metal and alloy, simple metal is selected from gold, silver, platinum, palladium, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten, vanadium etc., and alloy can be selected from light-alloy (aluminium alloy, titanium alloy, magnesium alloy, beryllium alloy etc.), heavy non-ferrous alloy (aldary, kirsite, manganese alloy, nickel alloy etc.), low-melting alloy (lead, tin, cadmium, bismuth, indium, gallium and alloy thereof), refractory alloy (tungalloy, molybdenum alloy, niobium alloy, tantalum alloy etc.).Preferred 100 μ m-500 μ m, more preferably 200 μ m of the thickness of electrode layer 80 between two parties.
The nano generator of introducing above is the friction nano generator, and in actual conditions, nano generator can also be the piezoelectric nano generator of being made by piezoelectric (for example zinc oxide nanowire).
In addition, in order to improve generated energy, the nano friction generator in the footwear of above-mentioned location can further be set to a plurality of nano friction generators.When the quantity of nano friction generator when being a plurality of, a plurality of nano friction generators can be connected also can be in parallel.Wherein, when the nano friction generator is in parallel, can improve the output intensity of electric current, and the series connection of nano friction generator the time can improve the output size of voltage, thereby the curtage size that can solve single nano friction generator output can not satisfy the problem of location footwear demand.In order to obtain above-mentioned advantage simultaneously, also can consider the parallel connection of a part of nano friction generator, another part nano friction generator is connected.
Self-powered of the present utility model location footwear adopt the nano friction generator to power, as long as jamming on friction, the user just can produce electric weight for locating the footwear power supply, this has not only solved the problem that can not power after battery electric quantity uses up, also save the trouble of changing battery or charging and bring to rechargeable battery, saved resource greatly.In addition, self-powered of the present utility model is located footwear owing to have the wireless receiving function, thereby can open the GPS positioning function by far-end control location footwear, controls so can realize far-end better.
In addition, in the utility model, power module, central processing module, GPS locating module and wireless communication module in the footwear of location all can be arranged on sole inside, make self-powered location footwear and city shoe exteriorly not have difference, thereby realize good disguise, the GPS locating module of wherein hiding can be finished location and warning function under the prerequisite of not discovered by the people.
Though it will be understood by those skilled in the art that in the above-mentioned explanation, for ease of understanding, the step of method has been adopted the succession description, should be pointed out that for the order of above-mentioned steps and do not do strict the restriction.
One of ordinary skill in the art will appreciate that all or part of step that realizes in above-described embodiment method is to instruct relevant hardware to finish by program, this program can be stored in the computer read/write memory medium, as: ROM/RAM, magnetic disc, CD etc.
Will also be appreciated that the apparatus structure shown in accompanying drawing or the embodiment only is schematically, the presentation logic structure.Wherein the module that shows as separating component may or may not be physically to separate, and the parts that show as module may be or may not be physical modules.
Obviously, those skilled in the art can carry out various changes and modification to the utility model and not break away from spirit and scope of the present utility model.Like this, if of the present utility model these are revised and modification belongs within the scope of the utility model claim and equivalent technologies thereof, then the utility model also is intended to comprise these changes and modification interior.
Claims (14)
1. self-powered location footwear comprise the footwear body, it is characterized in that, further comprise in the described footwear body: power module, and central processing module, GPS locating module and wireless communication module, wherein,
Described power module links to each other with described central processing module, and described power module further comprises nano friction generator and energy storage device;
Described central processing module links to each other with described GPS locating module and controls described GPS locating module and positions;
Described central processing module further links to each other with described wireless communication module and locating information that described GPS locating module is produced offers described wireless communication module.
2. self-powered as claimed in claim 1 is located footwear, it is characterized in that, further comprises:
Trigger the alarm switch that described central processing module control GPS locating module positions, it is arranged on the described footwear body, and links to each other with described central processing module.
3. self-powered as claimed in claim 2 is located footwear, it is characterized in that described alarm switch comprises one or more in the following type: snap switch, pushbutton switch, vibration switch and audio-switch.
4. self-powered as claimed in claim 1 is located footwear, it is characterized in that, described wireless communication module further receives the positioning control signal from external unit, described positioning control signal is sent to central processing module, and described central processing module is controlled described GPS locating module and is positioned when receiving described positioning control signal.
5. self-powered as claimed in claim 1 location footwear is characterized in that, described wireless communication module comprises one or more in GSM transceiver, Wi-Fi transceiver, WCDMA transceiver, the GPRS transceiver.
6. self-powered as claimed in claim 1 is located footwear, it is characterized in that described nano friction generator comprises: first electrode that is cascading, the first high molecular polymer insulation course, and second electrode; Wherein, described first electrode is arranged on first side surface of the described first high molecular polymer insulation course; And second side surface of the described first high molecular polymer insulation course is towards the described second electrode setting, and described first electrode and second electrode are respectively first output terminal and second output terminal of described nano friction generator.
7. self-powered as claimed in claim 6 is located footwear, it is characterized in that the described first high molecular polymer insulation course is provided with micro-nano structure towards the face of second electrode.
8. self-powered as claimed in claim 6 is located footwear, it is characterized in that, described nano friction generator further comprises: be arranged on the second high molecular polymer insulation course between described second electrode and the described first high molecular polymer insulation course, then described second electrode is arranged on first side surface of the described second high molecular polymer insulation course; And second side surface of second side surface of the described second high molecular polymer insulation course and the described first high molecular polymer insulation course is oppositely arranged.
9. self-powered as claimed in claim 8 is located footwear, it is characterized in that at least one face in two faces that the described first high molecular polymer insulation course and the second high molecular polymer insulation course are oppositely arranged is provided with micro-nano structure.
10. self-powered as claimed in claim 8 is located footwear, it is characterized in that, described nano friction generator further comprises: be arranged on the thin layer between two parties between the described first high molecular polymer insulation course and the described second high molecular polymer insulation course, wherein, described thin layer between two parties is polymer film layer, and at least one face in two faces that described thin layer between two parties and the first high molecular polymer insulation course are oppositely arranged is provided with micro-nano structure, and/or at least one face in two faces being oppositely arranged of described thin layer between two parties and the second high molecular polymer insulation course is provided with micro-nano structure.
11. self-powered as claimed in claim 1 location footwear, it is characterized in that described nano friction generator comprises: first electrode that is cascading, the first high molecular polymer insulation course, electrode layer between two parties, the second high molecular polymer insulation course and second electrode; Wherein, described first electrode is arranged on first side surface of the described first high molecular polymer insulation course; Described second electrode is arranged on first side surface of the described second high molecular polymer insulation course, described electrode layer between two parties is arranged between second side surface of second side surface of the described first high molecular polymer insulation course and the described second high molecular polymer insulation course, and on the face of the described relatively electrode layer between two parties of the described first high molecular polymer insulation course and/or the face of the described relatively electrode layer between two parties of the described second high molecular polymer insulation course be provided with micro-nano structure, described first electrode and the series connection of second electrode are that first output terminal of described nano friction generator, described electrode layer between two parties are second output terminal of described nano friction generator.
12. self-powered as claimed in claim 1 location footwear is characterized in that described energy storage device comprises:
The electric signal that links to each other with the output electrode of nano friction generator, described nano friction generator is exported carries out the rectification circuit module that rectification is handled;
Link to each other with described rectification circuit module, the unidirectional Rectified alternating current of described rectification circuit module output is carried out that filtering is handled and the filtering circuit module that obtains dc signal;
The energy-storage travelling wave tube that links to each other with described filtering circuit module, the dc signal of described filtering circuit module output is stored.
13. self-powered as claimed in claim 12 location footwear is characterized in that described energy-storage travelling wave tube is ultracapacitor, then described energy storage device also comprises: charge control module and switch/transformation module;
Described charge control module is connected with the filtering circuit module, receives the dc signal of described filtering circuit module output; Described charge control module is connected with described ultracapacitor, receives the charging voltage of described ultracapacitor feedback; Described charge control module is connected with described switch/transformation module, and described charge control module is exported described control signal according to described dc signal and the controlled signal of described charging voltage to described switch/transformation module;
Described switch/transformation module is connected with described filtering circuit module, the dc signal of the circuit module that accepts filter output; Described switch/transformation module is connected with described ultracapacitor, and described switch/transformation module is carried out the switch switching according to the control signal that receives and the dc signal that described filtering circuit module is exported is carried out exporting to described ultracapacitor after transformation is handled.
14. self-powered as claimed in claim 13 location footwear is characterized in that described energy storage device also comprises: the generator control module;
Described generator control module is connected with described ultracapacitor, receives the charging voltage of described ultracapacitor feedback;
Described generator control module is connected with described nano friction generator, the signal that described generator control module stops to generate electricity to described nano friction generator output according to described charging voltage.
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CN104076378A (en) * | 2013-03-27 | 2014-10-01 | 纳米新能源(唐山)有限责任公司 | Self-power positioning shoe |
WO2015055012A1 (en) * | 2013-10-18 | 2015-04-23 | 纳米新能源(唐山)有限责任公司 | Friction generator and vibration sensor using dipolymer composite film and preparation method therefor |
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CN104720784A (en) * | 2013-12-20 | 2015-06-24 | 纳米新能源(唐山)有限责任公司 | Vibration sensor and production method thereof |
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CN104076378A (en) * | 2013-03-27 | 2014-10-01 | 纳米新能源(唐山)有限责任公司 | Self-power positioning shoe |
WO2015055012A1 (en) * | 2013-10-18 | 2015-04-23 | 纳米新能源(唐山)有限责任公司 | Friction generator and vibration sensor using dipolymer composite film and preparation method therefor |
CN104643370A (en) * | 2013-11-22 | 2015-05-27 | 纳米新能源(唐山)有限责任公司 | Wireless self-powered step calculating shoes, step calculating system and step calculating method |
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CN104643370B (en) * | 2013-11-22 | 2016-09-07 | 纳米新能源(唐山)有限责任公司 | Without line self-powered pedometer shoes, step counting system and step-recording method |
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CN110934374A (en) * | 2018-09-25 | 2020-03-31 | 北京纳米能源与系统研究所 | Self-driven step counting shoes |
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