The electrolytic copper anode device
Technical field
The utility model relates to a kind of electrolytic copper anode device.
Background technology
Along with the high speed development of hyundai electronics information industry, the development of printed circuit board (PCB) industry is very rapid.In the production process of printed circuit board, the processing of etching waste liquor and the improvement of factory effluent are the great environmental issues that printed circuit board manufacturing enterprise runs into.The particularly processing of etching waste liquor substantially all is to take out set point to process enterprise, because etching waste liquor can not reclaim, has increased the operation cost of enterprise.In order to address this problem, a lot of PCB producers adopt some modernized novel apptss, these equipment can be processed alkaline etching waste liquid for producing in process of production, make it to regenerate behind the extracting copper, realize that alkaline etching liquid recycles, and extraction agent is recycled, the copper sulfate that reextraction is extracted also can become electrolytic copper through electrolysis, electrolytic solution can be recycled, thereby reaches changing waste into resources, the purpose that turns waste into wealth.Can this scheme bring larger economic benefit to be decided by whether electrolysis step can electrolysis go out highly purified metallic copper, is to guarantee that electrolysis goes out the key of high-quality high-purity copper and use suitable electrolytic anode device in the production process.Therefore, the electrolytic anode device of general configuration surface of metal titanium plating iridium in the above-mentioned modernized novel appts, such electrolytic anode device materials is very expensive, and the electrolysis procedure error is easy to cause anode to burn out, and has a strong impact on the whole economic efficiency that etching waste liquor reclaims.
The utility model content
The utility model provides a kind of novel electrolytic copper anode device that cooperates described modernized novel appts to use for the problems referred to above.
The design that the utility model is taked is:
The electrolytic copper anode device comprises anode plating iridium titanium plate, is arranged on naturally several crowns on the anode plating iridium titanium plate, and described crown is cylindrical.
Preferably, the figure that described naturally several crowns form is zhou duicheng tuxing, and its symmetry axis is the line of two horizontal sides mid points of anode plating iridium titanium plate.
Preferably, described crown is 12, and minute four lines is symmetrically distributed in the line both sides of anode plating iridium titanium plate two horizontal sides mid points, 3 of the first rows, 4 of the second row, 3 of the third lines, 2 of fourth lines.
Preferably, described crown is 12, divide four lines to distribute, the first row is distributed with the first crown, the second crown, the 3rd crown successively, the second row is distributed with successively the 4th crown, the 5th crown, the 6th crown, the 7th crown, the third line and is distributed with successively the 8th crown, the 9th crown, the tenth crown, and fourth line is distributed with the 11 crown, the 12 crown successively; Described plating iridium titanium plate front is of a size of the 1000mm*700mm rectangle, between the first crown, the second crown, adjacent two crowns of the 3rd crown apart from 190mm, between the 4th crown, the 5th crown, the 6th crown, adjacent two crowns of the 7th crown apart from 190mm, between the 8th crown, the 9th crown, adjacent two crowns of the tenth crown apart from 190mm; The first crown, the second crown, the formed straight line of the 3rd crown and the 4th crown, the 5th crown, the 6th crown, the formed straight line of the 7th crown are parallel lines, and the distance between this two straight line is 300mm; The 8th crown, the 9th crown, the formed straight line of the tenth crown and the 4th crown, the 5th crown, the 6th crown, the formed straight line of the 7th crown are parallel lines, and the distance between this two straight line is 500mm; The 8th crown, the 9th crown, the formed straight line parallel of the tenth crown are in plating iridium titanium plate level limit, apart from the horizontal sides 100mm of plating iridium titanium plate lower end; The 11 crown, the 12 crown are apart from the horizontal sides 60mm that plates iridium titanium plate lower end, and the 11 crown is apart from plating iridium titanium plate plate left end vertical edge 60mm, and the 12 crown is apart from plating iridium titanium plate plate right-hand member vertical edge 60mm; The figure that described 12 crowns form is zhou duicheng tuxing, and its symmetry axis is the line of the second crown and the 9th crown.
Preferably, crown is the cylinder round end body of diameter 20mm, high 30mm,
Preferably, also comprise anode copper bar strip, PVC clamping plate; The anode copper bar strip is connected with the upper end of anode plating iridium titanium plate, and by the annexation between PVC clamping plate reinforcement anode copper bar strip and the anode plating iridium titanium plate.
Preferably, chamfering has been designed respectively in the both sides of described anode plating iridium titanium plate lower end.
In sum, the utlity model has following significant beneficial effect:
(1) application the application's anode assembly, the purity of copper is very high when reclaiming electrolytic copper, and the application's electrolytic copper anode device is by arranging crown at anode plating iridium titanium plate, the size of crown rationally is set, highly, guarantee on the one hand easy to operate, be convenient to the anode loading and unloading, guarantee the normal growth of cathode copper, guarantee on the other hand the appropriate distance between the anode and cathode, can guarantee that optimum current distributes, can prevent from again causing the anode and cathode short circuit in movable cathode and the process of growth, play the provide protection of good antianode, adopt at plating iridium titanium plate roof fall is set, the one, play protection plating iridium titanium plate effect (plating iridium titanium plate rapid wear is expensive), the 2nd, better bring into play the effect of titanizing plate, make plating iridium titanium plate and cathode distribution of current more even, thereby common reason guarantee that the purity of copper of electrolytic copper is very high;
(2) anode plating iridium titanium plate is connected with the anode copper bar strip, guarantee anode can with rectifier output cable good contact, can there be again enough intensity to be convenient to the loop wheel machine lifting, the anode copper bar strip is connected iridium titanium plate and connects use PVC clamping plate reinforcement with anode, the pulling force that anode copper bar strip and anode plating iridium titanium plate junction will be born is transferred to load-bearing on the PVC clamping plate, the effect of playing protection plating iridium titanium plate and increasing the service life;
(3) designed respectively chamfering in the both sides of anode plating iridium titanium plate lower end, be convenient to anode plating iridium titanium plate and enter cell body;
(4) electrolytic copper anode apparatus structure described in the utility model is succinct, and production cost is low, is easy to scale operation.
Description of drawings
Accompanying drawing 1 is the example structure schematic diagram of electrolytic copper anode device described in the utility model.
Embodiment
In order to allow those skilled in the art understand better the technical solution of the utility model, below in conjunction with accompanying drawing the utility model is further elaborated.
As shown in Figure 1, the electrolytic copper anode device comprises anode plating iridium titanium plate 1 in the present embodiment, is arranged on naturally several crowns 4 on the anode plating iridium titanium plate, and described crown 4 is cylindrical, also comprises anode copper bar strip 2, PVC clamping plate 3; Anode copper bar strip 2 is connected with the upper end of anode plating iridium titanium plate 1, and by the annexation between PVC clamping plate 3 reinforcement anode copper bar strips 2 and the anode plating iridium titanium plate 1.The anode copper bar strip can play electric action, has simultaneously the effect of fixed anode, and anode copper bar strip two ends respectively exceed plating iridium titanium plate 150mm, and crane lifting easy to use so that fitting operation is simple, is fit to use the overhead traveling crane loading and unloading, reduces labor strength.
12 crowns are set in the present embodiment, and these 12 crowns divide four lines to distribute 3 of the first rows, 4 of the second row, 3 of the third lines, 2 of fourth lines.It is the cylinder round end body of 20mm, high 30mm that these crowns all adopt diameter.Such as Fig. 1, the first row is distributed with the first crown, the second crown, the 3rd crown successively, the second row is distributed with successively the 4th crown, the 5th crown, the 6th crown, the 7th crown, the third line and is distributed with successively the 8th crown, the 9th crown, the tenth crown, and fourth line is distributed with the 11 crown, the 12 crown successively.Be of a size of on the 1000mm*700mm rectangle plating iridium titanium plate in the front, between the first crown, the second crown, adjacent two crowns of the 3rd crown apart from 190mm, between the 4th crown, the 5th crown, the 6th crown, adjacent two crowns of the 7th crown apart from 190mm, between the 8th crown, the 9th crown, adjacent two crowns of the tenth crown apart from 190mm; The first crown, the second crown, the formed straight line of the 3rd crown and the 4th crown, the 5th crown, the 6th crown, the formed straight line of the 7th crown are parallel lines, and the distance between this two straight line is 300mm; The 8th crown, the 9th crown, the formed straight line of the tenth crown and the 4th crown, the 5th crown, the 6th crown, the formed straight line of the 7th crown are parallel lines, and the distance between this two straight line is 500mm; The 8th crown, the 9th crown, the formed straight line parallel of the tenth crown are in plating iridium titanium plate level limit, apart from the horizontal sides 100mm of plating iridium titanium plate lower end; The 11 crown, the 12 crown are apart from the horizontal sides 60mm that plates iridium titanium plate lower end, and the 11 crown is apart from plating iridium titanium plate plate left end vertical edge 60mm, and the 12 crown is apart from plating iridium titanium plate plate right-hand member vertical edge 60mm; The figure that described 12 crowns form is zhou duicheng tuxing, and its symmetry axis is the line of the second crown and the 9th crown.Chamfering has been designed respectively in the both sides of anode plating iridium titanium plate lower end, is convenient to the electrolytic copper anode device and enters cell body.Chamfer angle can according to circumstances be made change, is 45 degree here.
In the present embodiment; the cylinder round end body that 12 crown specifications that design on the plating iridium titanium plate are diameter 20mm, high 30mm; described crown is made by anti-high acid corrosion PVC material; can prevent anode direct and negative electrode short circuit in copper sulfate electrolyte; prevent movable cathode, play simultaneously the effect of protection anode plating iridium titanium plate.During concrete operations, can be at anode assembly two sides reasonable Arrangement crown.Need guarantee appropriate distance between the anode and cathode to the requirement of crown height, can guarantee that optimum current distributes, can prevent from again causing the anode and cathode short circuit in movable cathode and the process of growth, play the provide protection of good antianode.
In general, adopt this electro-coppering anode assembly can prolong anode work-ing life, avoid negative electrode and anode in short circuit when electrolysis, occurring, cause anode to burn out; Use this electrolytic copper anode device can also guarantee the normal growth of cathode copper, guarantee the copper facing even thickness, guarantee that the distance between the anode and cathode is consistent, prevent that the negative electrode drift from causing plating is uneven thickness, the long copper knurl of negative electrode; Use this anode assembly can guarantee that negative electrode copper facing is enough thick, reduce the cathode consumption cost.
Manufacture method and the mounting means of the application's electrolytic copper anode device are as follows: (1) makes anode plating iridium titanium plate; (2) at the anode surface of anode plating iridium titanium plate crown is installed; (3) the anode copper bar strip that joins with anode plating iridium titanium plate upper end is installed; (4) being connected with PVC clamping plate fixed anode plating iridium titanium plate and anode copper bar strip; (5) the electrolytic copper anode device is lifted into the copper sulfate electrolyzer; (6) be connected with electrolysis distiller output cable.
Need to prove; in the situation that do not deviate from the utility model spirit and essence thereof; those of ordinary skill in the art work as can make various corresponding changes and distortion according to the utility model, but these changes and distortion all should belong to the protection domain of the appended claim of the utility model.