CN202710767U - Ultra-wideband antireflection-film lens - Google Patents

Ultra-wideband antireflection-film lens Download PDF

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Publication number
CN202710767U
CN202710767U CN2011205032087U CN201120503208U CN202710767U CN 202710767 U CN202710767 U CN 202710767U CN 2011205032087 U CN2011205032087 U CN 2011205032087U CN 201120503208 U CN201120503208 U CN 201120503208U CN 202710767 U CN202710767 U CN 202710767U
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China
Prior art keywords
film
ultra
rete
thickness
layer
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Expired - Fee Related
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CN2011205032087U
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Chinese (zh)
Inventor
徐海兵
姚斌
吴双六
王雷
张喜文
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PHENIX OPTICAL (GUANGDONG) CO Ltd
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PHENIX OPTICAL (GUANGDONG) CO Ltd
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Priority to CN2011205032087U priority Critical patent/CN202710767U/en
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Abstract

The utility model discloses an ultra-wide band antireflection-film lens. The ultra-wide band antireflection-film lens includes a substrate and a film layer covered on the surface of the substrate, wherein the film layer is obtained through superposing at least two film layers, wherein the odd-numberth film lays are magnesium fluoride layers, the even-numberth film lays are zirconium/titanium mixture film layers. According to the ultra-wide band antireflection-film lens of the utility model, magnesium fluoride is adopted as a low- refractive index material, and at the same time, a zirconium/titanium mixture is adopted as a high-refractive index material; the high-refractive index material is matched with the low- refractive index material so as to be plated for forming a multilayer film; and further the ultra-wide band antireflection-film lens is advantageous in strong adhesiveness of the film layers, high temperature resistant performance and structural simplicity, and has greater imaging effect than that of a lens which is combined by other materials.

Description

A kind of ultra-wideband antireflective film glass
(1) technical field:
The utility model relates to a kind of ultra-wideband antireflective film glass.
(2) background technology:
Along with the use of mobile phone camera is more prevalent, everybody requires also more and more higher to the image quality of camera.In order to improve imaging effect, usually plate certain thickness single or multiple lift film at lens surface, purpose is in order to reduce the reflected light of lens surface, and such film is optical anti-reflective film, and existing plating anti-reflection film eyeglass has following weak point:
1. microminiaturized in order to realize camera lens, the deviser can use the very large glass mirror of curvature in a large number, under general plated film situation, can't guarantee that for the large eyeglass of curvature the position of each point of lens surface reaches the effect that improves transmitance;
2. general anti-reflection film specification requirement is visible wavelength range, ignored the impact of near infrared at shooting at night, so that the shooting at night imaging definition is relatively poor.
3. general anti-reflection film improves transmittance in order to increase bandwidth, usually uses the material collocation of high, medium and low three kinds of different refractivities to make multilayer film, and the most frequently used is that Al2O3-ZrO2-MgF2 arranges in pairs or groups, but this matching structure is complicated.
(3) utility model content:
In order to overcome the deficiencies in the prior art, the purpose of this utility model provides a kind of glass mirror its surperficial every bit position and high transmitance is arranged at infrared band behind plated film that guarantees, day night, shooting effect was good, the eyeglass of high definition.
The utility model is to realize by following technical scheme:
A kind of ultra-wideband antireflective film glass comprises substrate and covers rete on the substrate surface, and wherein said rete is formed by stacking by two membranes at least, and wherein the odd number rete is the magnesium fluoride layer, and the even number rete is zirconium titanium mixture film.
Substrate described above is glass mirror.
Glass mirror described above, its parameter is:
Refractive index n d=1.92286;
Abbe number ν d=18.9;
Degree of staining λ 70=440, λ 5=390;
Knoop hardness Hk=450;
Thermal expansivity: in the time of-30~70 ℃, α=67; In the time of 100~300 ℃, α=83.
Rete described above is that 9 tunics are formed by stacking, and described each thicknesses of layers is respectively:
Ground floor thickness is 21.03nm;
Second layer thickness is 34.32nm;
The threeply degree is 47.97nm;
The 4th layer thickness is 35.57nm;
Layer 5 thickness is 35.32nm;
Layer 6 thickness is 66.68nm;
Layer 7 thickness is 19.8nm;
The 8th layer thickness is 41.76nm;
The 9th layer thickness is 107.2nm.
The wherein one side of substrate described above is concave surface, and described rete covers on this concave surface.
The utility model compared with prior art, following advantage is arranged: the refractive index of magnesium fluoride is near glass, and and Stability Analysis of Structures, it is the most frequently used anti-reflection coating materials, the utility model select magnesium fluoride as low-index material, select zirconium titanium potpourri to arrange in pairs or groups with it as high-index material simultaneously to be coated with multilayer film, not only the rete tack is strong, and is high temperature resistant, and simple in structure, imaging effect is good than other material collocation; Only need 9 tunics just can reach the effect that the visual angle is large, imaging is good, printing opacity is good.
(4) description of drawings:
Fig. 1 is structural representation of the present utility model;
Fig. 2 is the utility model in incident angle is 30 the curves of spectrum when spending;
Fig. 3 is the utility model in incident angle is 0 the curve of spectrum when spending.
(5) embodiment:
Below in conjunction with accompanying drawing the utility model is described in detail:
As shown in the figure, the utility model comprises substrate 1 and covers lip-deep rete of substrate, and wherein said rete is formed by stacking by two membranes at least, and wherein the odd number rete is magnesium fluoride layer 2, and the even number rete is zirconium titanium mixture film 3.The refractive index of magnesium fluoride is near glass, and Stability Analysis of Structures, it is the most frequently used anti-reflection coating materials, the utility model select magnesium fluoride as low-index material, select zirconium titanium potpourri to arrange in pairs or groups with it as high-index material simultaneously to be coated with multilayer film, not only the rete tack is strong, high temperature resistant, and simple in structure, only need 9 tunics just can reach the effect that the visual angle is large, imaging is good, printing opacity is good.
Substrate 1 described above is glass mirror.Described glass mirror uses the trade mark of OHARA company to be the glass of S-NPH2, and its major parameter is:
Refractive index n d=1.92286;
Abbe number ν d=18.9;
Degree of staining λ 70=440, λ 5=390;
Knoop hardness Hk=450;
Described zirconium titanium potpourri is that principal ingredient is TiO 2And ZrO 2Potpourri.
The wherein one side of described substrate is concave surface, and described rete covers on this concave surface.
Rete described above is that 9 tunics are formed by stacking,
The material of described each rete and thickness such as following table:
Layer sequence number The coating materials name Thicknesses of layers (unit: nm)
1 Magnesium fluoride 21.03
2 Zirconium titanium potpourri 34.32
3 Magnesium fluoride 47.97
4 Zirconium titanium potpourri 35.57
5 Magnesium fluoride 35.32
6 Zirconium titanium potpourri 66.68
7 Magnesium fluoride 19.8
8 Zirconium titanium potpourri 41.76
9 Magnesium fluoride 107.2
Such as Fig. 2, shown in Figure 3, ultra-wideband antireflective film glass spectral characteristic described in the utility model is: 400--800nm R ﹤ 0.5%, 800--900nm R<4%; In the scope of incident angle 0-30 degree, 400--700nm R ﹤ 0.6%, 800--900nm R<5% can satisfy the visual angle when larger, the requirement when visible light and near infrared imaging simultaneously.Eyeglass can be 85 ± 1 ℃ of temperature by 85 ℃, RH85%(in hot and humid environment test, relative humidity 85%) place 720 hours retes without coming off under the above condition; Can be by-40 ℃ in the middle of high low temperature Cyclic Rings border test--90 ℃ 200 circulations 720 hours, namely at subzero 40 ℃--under the environment that 90 ℃ low temperature high temperature changes, circulated 200 times totally 720 hours, rete is without coming off.The more existing anti-reflection film eyeglass of the utility model is greatly improved in performance.

Claims (5)

1. ultra-wideband antireflective film glass comprises substrate and covers rete on the substrate surface, it is characterized in that: described rete is formed by stacking by two membranes at least, and wherein the odd number rete is the magnesium fluoride layer, and the even number rete is zirconium titanium mixture film.
2. a kind of ultra-wideband antireflective film glass according to claim 1, it is characterized in that: described substrate is glass mirror.
3. a kind of ultra-wideband antireflective film glass according to claim 2 is characterized in that: described glass mirror, and its parameter is:
Refractive index n d=1.92286;
Abbe number ν d=18.9;
Degree of staining λ 70=440, λ 5=390;
Knoop hardness Hk=450;
Thermal expansivity: in the time of-30~70 ℃, α=67; In the time of 100~300 ℃, α=83.
4. a kind of ultra-wideband antireflective film glass according to claim 1, it is characterized in that: described rete is that 9 tunics are formed by stacking, and described each thicknesses of layers is respectively:
Ground floor thickness is 21.03nm;
Second layer thickness is 34.32nm;
The threeply degree is 47.97nm;
The 4th layer thickness is 35.57nm;
Layer 5 thickness is 35.32nm;
Layer 6 thickness is 66.68nm;
Layer 7 thickness is 19.8nm;
The 8th layer thickness is 41.76nm;
The 9th layer thickness is 107.2nm.
5. a kind of ultra-wideband antireflective film glass according to claim 1 is characterized in that: the wherein one side of described substrate is concave surface, and described rete covers on this concave surface.
CN2011205032087U 2011-12-06 2011-12-06 Ultra-wideband antireflection-film lens Expired - Fee Related CN202710767U (en)

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Application Number Priority Date Filing Date Title
CN2011205032087U CN202710767U (en) 2011-12-06 2011-12-06 Ultra-wideband antireflection-film lens

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103616737A (en) * 2013-11-11 2014-03-05 成都市晶林电子技术有限公司 Infrared coating lens
CN104614787A (en) * 2015-03-02 2015-05-13 山东阳谷恒晶光电有限公司 Ultra-wideband reflection reducing film and preparation method thereof
CN106291781A (en) * 2016-08-30 2017-01-04 东兴华鸿光学科技有限公司 Optical glass anti-reflection film
CN107450116A (en) * 2017-10-13 2017-12-08 广东诚卓光电科技有限公司 One kind is latent to hope reflective prism
CN107479163A (en) * 2017-09-15 2017-12-15 宁波永新光学股份有限公司 A kind of optical veneering lens group
CN107703567A (en) * 2017-11-06 2018-02-16 广东弘景光电科技股份有限公司 High rigidity antireflective plated film lens
CN108490511A (en) * 2017-12-21 2018-09-04 山东非金属材料研究所 Anti-reflection composite film
CN108897077A (en) * 2018-09-04 2018-11-27 浙江舜宇光学有限公司 Film layer structure and camera lens for resin lens
CN109884737A (en) * 2018-12-29 2019-06-14 瑞声科技(新加坡)有限公司 A kind of eyeglass and preparation method thereof and camera lens

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103616737A (en) * 2013-11-11 2014-03-05 成都市晶林电子技术有限公司 Infrared coating lens
CN104614787A (en) * 2015-03-02 2015-05-13 山东阳谷恒晶光电有限公司 Ultra-wideband reflection reducing film and preparation method thereof
CN104614787B (en) * 2015-03-02 2016-01-13 山东阳谷恒晶光电有限公司 A kind of ultra broadband antireflecting film and preparation method thereof
CN106291781A (en) * 2016-08-30 2017-01-04 东兴华鸿光学科技有限公司 Optical glass anti-reflection film
CN107479163A (en) * 2017-09-15 2017-12-15 宁波永新光学股份有限公司 A kind of optical veneering lens group
CN107450116A (en) * 2017-10-13 2017-12-08 广东诚卓光电科技有限公司 One kind is latent to hope reflective prism
CN107450116B (en) * 2017-10-13 2024-04-09 南京优瑞谱科技有限公司 Periscope reflective triple prism
CN107703567A (en) * 2017-11-06 2018-02-16 广东弘景光电科技股份有限公司 High rigidity antireflective plated film lens
CN107703567B (en) * 2017-11-06 2024-05-03 广东弘景光电科技股份有限公司 High-hardness antireflection coated lens
CN108490511A (en) * 2017-12-21 2018-09-04 山东非金属材料研究所 Anti-reflection composite film
CN108897077A (en) * 2018-09-04 2018-11-27 浙江舜宇光学有限公司 Film layer structure and camera lens for resin lens
CN109884737A (en) * 2018-12-29 2019-06-14 瑞声科技(新加坡)有限公司 A kind of eyeglass and preparation method thereof and camera lens

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20130130

Termination date: 20171206