CN202388878U - High-barrier composite membrane - Google Patents

High-barrier composite membrane Download PDF

Info

Publication number
CN202388878U
CN202388878U CN2011205418400U CN201120541840U CN202388878U CN 202388878 U CN202388878 U CN 202388878U CN 2011205418400 U CN2011205418400 U CN 2011205418400U CN 201120541840 U CN201120541840 U CN 201120541840U CN 202388878 U CN202388878 U CN 202388878U
Authority
CN
China
Prior art keywords
film
composite membrane
layer
substrate layer
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2011205418400U
Other languages
Chinese (zh)
Inventor
李子繁
孙红旗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
8511 Research Institute of CASIC
Original Assignee
8511 Research Institute of CASIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 8511 Research Institute of CASIC filed Critical 8511 Research Institute of CASIC
Priority to CN2011205418400U priority Critical patent/CN202388878U/en
Application granted granted Critical
Publication of CN202388878U publication Critical patent/CN202388878U/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Landscapes

  • Laminated Bodies (AREA)

Abstract

The utility model discloses a high-barrier composite membrane which is formed by compounding a heat seal layer, a functional layer and a structural layer in sequence, and the high-barrier composite membrane is characterized in that the heat seal layer is composed of a thin-film substrate layer and a polyvinyl alcohol coating which is applied to the corona treatment surface of the thin-film substrate layer; the functional layer is composed of a thin-film substrate layer and a polyvinyl alcohol coating which is applied to the corona treatment surface of the thin-film substrate layer, wherein the PVA (Polyvinyl Acetate) serves as a high oxygen barrier layer in stead of an aluminum foil and a PVDC (Polyvinyl Dichloride) coating; and the coating is made of a biodegradable material, which is convenient for recycling the whole composite membrane and friendly to the environment; and simultaneously, the cost of the coating is lower than that of the aluminum foil and the PVDC; and therefore, the high-barrier composite membrane has more advantages.

Description

The high-barrier composite membrane
Technical field
The utility model belongs to the packaging material field, particularly a kind of high-barrier composite membrane.
Background technology
In the packing of some purposes, require the plastic foil of liner that very low OTR oxygen transmission rate and moisture-vapor transmission are arranged.Because the liner bag can be rubbed folding inevitably repeatedly in the use, therefore require this film to have good pliability simultaneously.
At present, the composite membrane that contains aluminium foil has extremely low OTR oxygen transmission rate and moisture-vapor transmission, but the composite membrane that contains aluminium foil is rubbing to be folded down and be easy to generate folding line and pin hole repeatedly, and in actual use, its barrier is had a greatly reduced quality; Therefore as barrel of beer liner bag in the beer packing, its application is restricted.The composite membrane that contains the PVDC coating also has very low moisture-vapor transmission and good oxygen barrier property.But contain chlorine in the coating, be limited to use, and its oxygen barrier property can not reach the effect of aluminium foil.
Summary of the invention
It is a kind of that have low oxygen transmitance, carbon dioxide transmitance and a moisture-vapor transmission and have good pliability and the anti-folding endurance of rubbing that the purpose of the utility model is to provide, and be easy to reclaim the high-barrier composite membrane of post processing.
The technical solution that realizes the utility model purpose is:
A kind of high-barrier composite membrane is composited by hot sealing layer, functional layer, structure sheaf sequentially, and described hot sealing layer is made up of film substrate layer and polyethylene coating, and polyethylene coating is coated the corona treatment face of film substrate layer; Described functional layer is made up of film substrate layer and polyethylene coating, and polyethylene coating is coated the corona treatment face of film substrate layer
The utility model compared with prior art; Its remarkable advantage: the utility model is adopted the modified polyvinylalcohol coating and is substituted aluminium foil; Can obtain with suitable oxygen-barrier property, carbon dioxide barrier, the steam barrier of aluminium foil; This material is a degradation material simultaneously, is easy to waste disposal, and can reduce cost; Because this coating is very thin, and the intensity of polyvinyl alcohol own and toughness are all fine, so this composite membrane has excellent mechanical intensity and pliability, can anti-ly rub folding repeatedly
Below in conjunction with accompanying drawing the utility model is described in further detail.
Description of drawings
Fig. 1 is the structural representation according to the laminated film of the utility model proposition.
The specific embodiment
A kind of high-barrier composite membrane of the utility model; Be composited sequentially by hot sealing layer 1, functional layer 2, structure sheaf 3; Described hot sealing layer 1 is made up of film substrate layer 1-1 and polyethylene coating 1-2, and polyethylene coating 1-2 coats the corona treatment face of film substrate layer 1-1; Described functional layer 2 is made up of film substrate layer 2-1 and polyethylene coating 2-2, and polyethylene coating 2-2 coats the corona treatment of film substrate layer 2-1; Wherein, described film substrate layer 1-1 is polyethylene film or cast polypropylene film; Described film substrate layer 2-1 is biaxially oriented polyester film or BON biaxially oriented nylon film; Described structure sheaf 3 materials are biaxially oriented polyester film or BON biaxially oriented nylon film.
Specify concrete structure and the working condition that proposes according to the utility model below in conjunction with Fig. 1.
This high-barrier structure of composite membrane is: be composited and comprised that three layers constitute from outside to inside by hot sealing layer 1, functional layer 2, structure sheaf 3 orders, compound order is as shown in the figure.
Hot sealing layer 1 is made up of film substrate layer 1-1 and polyethylene coating 1-2, and polyethylene coating 1-2 coats the inside, corona place of film substrate layer 1-1 in advance; Film ground 1-1 is polyethylene film or cast polypropylene film, gives this composite film heat sealing property, has moisture barrier property concurrently, and polyethylene coating 1-2 gives composite membrane good fragrance protectiveness ability.
Functional layer 2 is made up of film substrate layer 2-1 and polyethylene coating 2-2, and polyethylene coating 2-2 coats the inside, corona place of film substrate layer 2-1 in advance.Film substrate layer 2-1 is biaxially oriented polyester film or BON biaxially oriented nylon film; These two kinds of material moisture-vapor transmissions are bigger; The aqueous dispersion that helps in the polyethylene coating sends out, and guarantees the performance of polyethylene coating, can strengthen the mechanical strength of composite membrane simultaneously; Polyethylene coating 2-2 provides good oxygen barrier property.
Structure sheaf 3 is the high mechanical properties material, mainly gives enough mechanical strengths of composite membrane and surface property, and structure sheaf 3 materials are BON biaxially oriented nylon film or biaxially oriented polyester film.
Can adopt the compound adhesive of the special trade mark according to different purposes.
Embodiment one: structure of composite membrane is (BON biaxially oriented nylon film) BOPA//(polyethylene coating-biaxially oriented polyester film) PVA-BOPET//(polyethylene coating-polyethylene film) PVA-LLDPE; It promptly is the inside, the corona place coating PVA coating of the LLDPE film of 70 μ m at thickness; At thickness is the BOPET film corona treated side coating PVA coating of 12 μ m; Again that the two is compound, compound order is that the inside, non-corona place of PVA-BOPET coated film is compound with the PVA coated face of PVA-LLDPE coated film; Be that the BOPA film of 15 μ m is compound with thickness again, compound order is that the PVA coated face of corona treatment face and PVA-BOPET//PVA-LLDPE composite membrane of BOPA film is compound.The oxygen transit dose of this composite membrane is 0.063cm3/ (m224h1atm), and steam penetrating capacity is 1.5g/ (24hm2), and its oxygen-barrier property reaches the performance of aluminium foil.
Embodiment two: structure of composite membrane is BOPA//PVA-BOPET//PVA-CPP (polyethylene coating-cast polypropylene film); It promptly is the inside, the corona place coating PVA coating of the CPP film of 30 μ m at thickness; At thickness is the BOPET film corona treated side coating PVA coating of 12 μ m; Again that the two is compound, compound order is that the inside, non-corona place of PVA-BOPET coated film is compound with the PVA coated face of PVA-CPP coated film; Be that the BOPA film of 15 μ m is compound with thickness again, compound order is that the PVA coated face of corona treatment face and PVA-BOPET//PVA-CPP composite membrane of BOPA film is compound.The oxygen transit dose of this composite membrane is 0.165cm3/ (m224h1atm), and steam penetrating capacity is lower than 2g/ (24hm2).

Claims (4)

1. high-barrier composite membrane; Be composited sequentially by hot sealing layer [1], functional layer [2], structure sheaf [3]; It is characterized in that: described hot sealing layer [1] is made up of film substrate layer [1-1] and polyethylene coating [1-2], and polyethylene coating [1-2] is coated the corona treatment face of film substrate layer [1-1]; Described functional layer [2] is made up of film substrate layer [2-1] and polyethylene coating [2-2], and polyethylene coating [2-2] is coated the corona treatment face of film substrate layer [2-1].
2. a kind of high-barrier composite membrane according to claim 1 is characterized in that: described film substrate layer [1-1] is polyethylene film or cast polypropylene film.
3. a kind of high-barrier composite membrane according to claim 1 is characterized in that: described film substrate layer [2-1] is biaxially oriented polyester film or BON biaxially oriented nylon film.
4. a kind of high-barrier composite membrane according to claim 1 is characterized in that: described structure sheaf [3] material is biaxially oriented polyester film or BON biaxially oriented nylon film.
CN2011205418400U 2011-12-22 2011-12-22 High-barrier composite membrane Expired - Lifetime CN202388878U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011205418400U CN202388878U (en) 2011-12-22 2011-12-22 High-barrier composite membrane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011205418400U CN202388878U (en) 2011-12-22 2011-12-22 High-barrier composite membrane

Publications (1)

Publication Number Publication Date
CN202388878U true CN202388878U (en) 2012-08-22

Family

ID=46663828

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011205418400U Expired - Lifetime CN202388878U (en) 2011-12-22 2011-12-22 High-barrier composite membrane

Country Status (1)

Country Link
CN (1) CN202388878U (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103264559A (en) * 2013-05-19 2013-08-28 海南赛诺实业有限公司 Novel betelnut packaging composite membrane and preparation method thereof
CN105774161A (en) * 2014-12-19 2016-07-20 中国航天科工集团八五研究所 Anti-UV transparent high-barrier diaphragm and preparation method thereof
CN105947422A (en) * 2016-04-28 2016-09-21 青岛日之容塑料制品有限公司 Packaging bag for microwave oven and preparation method of packaging bag
CN107226271A (en) * 2017-06-12 2017-10-03 尼古特斯 Packaging bag with buffering band structure
CN108045044A (en) * 2017-12-07 2018-05-18 上海久诚包装有限公司 A kind of transparent high-barrier composite material and its production technology

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103264559A (en) * 2013-05-19 2013-08-28 海南赛诺实业有限公司 Novel betelnut packaging composite membrane and preparation method thereof
CN103264559B (en) * 2013-05-19 2015-04-08 海南赛诺实业有限公司 Novel betelnut packaging composite membrane and preparation method thereof
CN105774161A (en) * 2014-12-19 2016-07-20 中国航天科工集团八五研究所 Anti-UV transparent high-barrier diaphragm and preparation method thereof
CN105947422A (en) * 2016-04-28 2016-09-21 青岛日之容塑料制品有限公司 Packaging bag for microwave oven and preparation method of packaging bag
CN107226271A (en) * 2017-06-12 2017-10-03 尼古特斯 Packaging bag with buffering band structure
CN107226271B (en) * 2017-06-12 2019-04-09 尼古特斯 Packaging bag with buffering band structure
CN108045044A (en) * 2017-12-07 2018-05-18 上海久诚包装有限公司 A kind of transparent high-barrier composite material and its production technology

Similar Documents

Publication Publication Date Title
CN202388878U (en) High-barrier composite membrane
CN103112226B (en) Seven-layer co-extrusion high-isolating hyaline membrane and preparation method thereof
JP6162410B2 (en) LAMINATE FOR PACKAGING MATERIAL, PROCESS FOR PRODUCING THE SAME AND PACKAGING MATERIAL
CN103753914A (en) Five-layer co-extrusion packaging material having high moisture barrier and barrier properties and preparation method thereof
CN202388877U (en) High-barrier composite sheet
JP5815373B2 (en) Packaging materials
CN104786600A (en) Degradable food packaging film
JP6007565B2 (en) Multilayer film for laminate tube and laminate tube using the multilayer film
JP2021057232A (en) Packaging material and packaging body for all-solid lithium ion battery
CN2913229Y (en) High-obstruct seepage proof plastic-aluminum composite membrane for liquid state dairy product packing
CN206242617U (en) The flexible package ultra-thin composite membrane of environment protecting paper plastic-aluminum
CN2913230Y (en) High-obstruct aluminizing composite membrane for liquid state dairy product packing
JP2019014043A (en) Laminate and packaging bag using the same
CN202046562U (en) Composite packaging film with high-resistance aluminized layer
CN203624197U (en) Biaxially-oriented polyethylene ecological packaging composite membrane
CN201520090U (en) Enhanced modified PVA high barrier composite film
JP2019038575A (en) Laminate for tube container and tube container having the same
CN207984237U (en) Complete biodegradable multilayer extrusion print film
SE1351552A1 (en) Packaging material for a packaging container
CN204160828U (en) High-brightness cosmetic composite sheet
JP2005035243A (en) Multi-layered film for laminate tube and laminate tube
CN202368022U (en) Food packing bag
CN207643846U (en) High-barrier transparent composite film structure
CN214111812U (en) Biaxially oriented EVOH (ethylene vinyl alcohol) composite hard sheet
JP2021057230A (en) Packaging material and packaging body for all-solid lithium ion battery

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20120822