CN202380106U - Graphite anode - Google Patents

Graphite anode Download PDF

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Publication number
CN202380106U
CN202380106U CN 201120516126 CN201120516126U CN202380106U CN 202380106 U CN202380106 U CN 202380106U CN 201120516126 CN201120516126 CN 201120516126 CN 201120516126 U CN201120516126 U CN 201120516126U CN 202380106 U CN202380106 U CN 202380106U
Authority
CN
China
Prior art keywords
anode
graphite
internal thread
graphite anode
thread hole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 201120516126
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Chinese (zh)
Inventor
袁萍
刘建钢
陶利明
徐秋华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Rare Earth and Rare Metals Tungsten Group Holding Co Ltd
Original Assignee
Jiangxi Rare Earth and Rare Metals Tungsten Group Holding Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangxi Rare Earth and Rare Metals Tungsten Group Holding Co Ltd filed Critical Jiangxi Rare Earth and Rare Metals Tungsten Group Holding Co Ltd
Priority to CN 201120516126 priority Critical patent/CN202380106U/en
Application granted granted Critical
Publication of CN202380106U publication Critical patent/CN202380106U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model provides a graphite anode, which is integrally provided with a hollow cylindrical body. The graphite anode is characterized by comprising a plurality of anode plates, wherein the anode plates are connected in parallel; at least two inner wire holes are formed in the top surface of each anode plate; adjacent anode plates are connected through anode clamps; each anode clamp is arranged above a graphite electrolytic cell, spans two adjacent anode plates and is a section of circular-ring-shaped metal plate of which the inner diameter and the outer diameter are equal to those of the corresponding graphite anode plate; each metal plate is connected with the positive electrode of a power source; at least two inner wire holes are formed in each metal sheet and are aligned with the inner wire holes in two corresponding adjacent graphite anode plates; and the inner wire holes in the metal plates are connected with the corresponding inner wire holes in the anode plates through bolts. The graphite anode provided by the utility model is easy to replace and has the advantages that the fluctuation caused to the liquid level of molten salt in an electrolytic furnace is small, the fluctuation of the furnace temperature is small, temperature changes are small, the phenomena of furnace shutdown is avoided, and the service life of the electrolytic furnace is prolonged.

Description

A kind of graphite anode
Technical field
The utility model relates to a kind of graphite anode, and particularly rare earth oxide-fluoride molten salt electrolytic process is produced employed graphite anode in rare earth metal and the alloy process, and refers in particular to employed graphite anode in circular electrolyzer.
Background technology
Because employed graphite anode is a kind of consumable anode in rare earth oxide-fluoride molten salt electrolysis system, need in process of production regularly to change.
Production practice are found, adopt the hollow cylinder graphite anode to have following defective: inconvenient operation, because graphite anode is an integral body, heavy, difficulty is carried during replacing; Before and after the anode change, the fused salt liquid fluctuating is big in the electrolytic furnace; Before and after the anode change, furnace temperature fluctuation is big.
Because the new graphite anode tube of changing is a cold conditions; Occur new anode easily and put down the dead stove phenomenon that the back causes owing to the furnace temperature rapid drawdown, this has not only had a strong impact on electrolysis production, also makes fused salt be condensed in inboard wall of burner hearth easily simultaneously; Burner hearth is diminished, thereby influence the work-ing life of electrolytic furnace.
Secondly the anode tube that more renews will cut off the power supply, and furnace temperature is fallen too fastly, and to be replaced finishing need be heated up again, has only furnace temperature to rise to normal temps and just begins electrolysis, promptly influences output and influences quality product again.
Summary of the invention
The purpose of the utility model provides a kind of graphite anode; Its fluctuation of changing easily, when changing fused salt liquid level in the electrolytic furnace being caused is little, replacing front and back furnace temperature fluctuation is little, be difficult for producing violent difference variation; Overcome because the dead stove phenomenon that the furnace temperature rapid drawdown causes; Improve electrolytic furnace work-ing life, and do not needed the preheating that heats up again in the whole replacing process, thereby do not influenced quality product and output.
For this reason, the utility model provides a kind of graphite anode, and this anode integral body is hollow cylinder, and it is characterized in that: graphite anode is made up of a plurality of anode strips, parallel connection between each anode strip, and the end face of each anode strip is provided with at least two internal thread holes; Connect through the anode folder between the adjacent anode strip, each anode folder is arranged at above graphitic cell, crosses over two adjacent anode strips; Each anode folder is the tinsel of the one section annular all identical with outside dimension with graphite anode sheet internal diameter; This tinsel links to each other with positive source; Also be provided with at least two internal thread holes on this tinsel; Internal thread hole on this tinsel is aimed at the internal thread hole on corresponding two adjacent graphite anode sheets one by one, and corresponding internal thread hole is connected through bolt on the internal thread hole on this tinsel and the anode strip.
Preferably, the quantity in said internal thread hole is 2-6.
Preferably, the quantity in said internal thread hole is 2-5.
Preferably, the quantity in said internal thread hole is 2.
Preferably, said metal clip is the A3 iron plate.
Preferably, the quantity of said anode strip is 4~12.
Preferably, the size of each said anode strip is all identical.
Preferably, the size of each said anode folder is all identical.
Preferably, the internal thread hole uniform distribution of each said anode strip.
Preferably, the internal thread hole uniform distribution of each said anode folder.
According to the utility model, every graphite anode is lighter, carries easily during replacing; Because graphite anode has been divided into small pieces, the fluctuation that during every replacing fused salt liquid level in the electrolytic furnace is caused is little; Furnace temperature fluctuation was little before and after graphite anode was changed.Change the small pieces anode, be difficult for producing violent difference variation.Overcome because the dead stove phenomenon that the furnace temperature rapid drawdown causes, improved electrolytic furnace work-ing life.
Description of drawings
Fig. 1 is the synoptic diagram according to the graphite anode of the utility model.
Embodiment
At present, in circular electrolyzer, rare earth oxide-fluoride molten salt system electrolysis production rare earth metal and alloy prior, employed graphite anode is a hollow cylinder.
In an embodiment of the utility model, hollow cylinder graphite anode 1 is divided into 6 anode strips 11,12,13,14,15,16.
In other embodiment, the sheet scope of counting of anode strip is 4~12 usually.
Anode strip 11,12,13,14,15, be parallelly connected between 16, the voltage on each sheet graphite anode strip 11,12,13,14,15,16 is all identical, and total Faradaic current is then evenly assigned on each graphite anode sheet 11,12,13,14,15,16.
In an embodiment of the utility model, an end face of every graphite anode strip 2 is provided with two internal thread holes 10.In other embodiment, an end face of every graphite anode strip 2 is provided with 2-5 internal thread hole 10.
Every graphite anode strip 11,12,13,14,15,16 is connected supporting use through bolt 15 with anode folder 2.
During replacing, the graphite anode sheet 11,12,13,14,15,16 and the anode folder 2 usefulness bolts 15 that only need newly to change are fixed.
Anode folder 2 be above graphitic cell with graphite anode sheet 11,12,13,14,15,16 internal diameters, one section circular ring plate 21,22,23,24,25,26 that external diameter is all identical.
Graphite anode sheet 11,12,13,14,15,16 and circular ring plate 21,22,23,24,25,26 are arranged alternately.In other words, each section circular ring plate is all crossed over two pieces of graphite anode sheets.In the embodiment shown in fig. 1, circular ring plate 21 is crossed over graphite anode sheet 16,11; Circular ring plate 22 is crossed over graphite anode sheet 11,12; Circular ring plate 23 is crossed over graphite anode sheet 12,13; Circular ring plate 24 is crossed over graphite anode sheet 13,14; Circular ring plate 25 is crossed over graphite anode sheet 14,15; Circular ring plate 26 is crossed over graphite anode sheet 15,16.
In an embodiment of the utility model; Circular ring plate is the A3 iron plate; This iron plate links to each other with positive source; 2-5 the internal thread hole 20 that distributing arranged on this iron plate, bore on the graphite anode sheet 11,12,13,14,15,16 and aim at the internal thread hole 10 that distributes with it one by one, the internal thread hole 10 on internal thread hole on the iron plate 20 and the anode strip 11,12,13,14,15,16 is coupled together with bolt 15.
In an embodiment of the utility model, each anode strip 11,12,13,14,15,16 measure-alike.In other embodiments, the size of each anode strip 11,12,13,14,15,16 also can have nothing in common with each other.
In an embodiment of the utility model, each circular ring plate 21,22,23,24,25,26 measure-alike.In other embodiments, the size of circular ring plate 21,22,23,24,25,26 also can have nothing in common with each other.
According to an embodiment of the utility model, the graphite anode of a hollow cylinder is divided into 4~12, concrete sheet number can be regulated according to the body of heater size, and two internal thread holes are arranged at every top, and every presss from both sides with the self-control anode through bolt and to be connected supporting use.

Claims (10)

1. graphite anode, this anode integral body is hollow cylinder, it is characterized in that: graphite anode is made up of a plurality of anode strips, parallel connection between each anode strip, the end face of each anode strip is provided with at least two internal thread holes; Connect through the anode folder between the adjacent anode strip, each anode folder is arranged at above graphitic cell, crosses over two adjacent anode strips; Each anode folder is the tinsel of the one section annular all identical with outside dimension with graphite anode sheet internal diameter; This tinsel links to each other with positive source; Also be provided with at least two internal thread holes on this tinsel; Internal thread hole on this tinsel is aimed at the internal thread hole on corresponding two adjacent graphite anode sheets one by one, and corresponding internal thread hole is connected through bolt on the internal thread hole on this tinsel and the anode strip.
2. graphite anode according to claim 1 is characterized in that: the quantity in said internal thread hole is 2-6.
3. graphite anode according to claim 1 is characterized in that: the quantity in said internal thread hole is 2-5.
4. graphite anode according to claim 1 is characterized in that: the quantity in said internal thread hole is 2.
5. graphite anode according to claim 1 is characterized in that: said metal clip is the A3 iron plate.
6. graphite anode according to claim 1 is characterized in that: the quantity of said anode strip is 4~12.
7. graphite anode according to claim 1 is characterized in that: the size of each said anode strip is all identical.
8. graphite anode according to claim 1 is characterized in that: the size of each said anode folder is all identical.
9. graphite anode according to claim 1 is characterized in that: the internal thread hole uniform distribution of each said anode strip.
10. graphite anode according to claim 1 is characterized in that: the internal thread hole uniform distribution of each said anode folder.
CN 201120516126 2011-12-12 2011-12-12 Graphite anode Expired - Fee Related CN202380106U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201120516126 CN202380106U (en) 2011-12-12 2011-12-12 Graphite anode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201120516126 CN202380106U (en) 2011-12-12 2011-12-12 Graphite anode

Publications (1)

Publication Number Publication Date
CN202380106U true CN202380106U (en) 2012-08-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201120516126 Expired - Fee Related CN202380106U (en) 2011-12-12 2011-12-12 Graphite anode

Country Status (1)

Country Link
CN (1) CN202380106U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453930A (en) * 2011-12-12 2012-05-16 江西稀有稀土金属钨业集团有限公司 Graphite anode and replacing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453930A (en) * 2011-12-12 2012-05-16 江西稀有稀土金属钨业集团有限公司 Graphite anode and replacing method thereof
CN102453930B (en) * 2011-12-12 2015-02-04 江西稀有稀土金属钨业集团有限公司 Graphite anode and replacing method thereof

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120815

Termination date: 20171212

CF01 Termination of patent right due to non-payment of annual fee