CN202164373U - Recycling equipment for nickel in waste electroplating water - Google Patents

Recycling equipment for nickel in waste electroplating water Download PDF

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Publication number
CN202164373U
CN202164373U CN2011202709033U CN201120270903U CN202164373U CN 202164373 U CN202164373 U CN 202164373U CN 2011202709033 U CN2011202709033 U CN 2011202709033U CN 201120270903 U CN201120270903 U CN 201120270903U CN 202164373 U CN202164373 U CN 202164373U
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China
Prior art keywords
nickel
rotating cathode
bucket
electroplating wastewater
outlet
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Expired - Fee Related
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CN2011202709033U
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Chinese (zh)
Inventor
明果英
周军
陈建敏
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Hunan Vary Technology Co Ltd
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Hunan Vary Technology Co Ltd
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Priority to CN2011202709033U priority Critical patent/CN202164373U/en
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Publication of CN202164373U publication Critical patent/CN202164373U/en
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  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The utility model discloses recycling equipment for nickel in waste electroplating water, which comprises an electrolyte circulating bucket, a rotating cathode electro-deposition cell, a resin adsorbing pot, an adsorbing liquid storing bucket and an electric control device connected in sequence, wherein the electrolyte circulating bucket has a waste electroplating water inlet on the top thereof, an electrolyte outlet and a secondary electro-deposition solution inlet respectively at the lower part thereof; the electrolyte outlet is connected to an inlet of the rotating cathode electro-deposition cell by a circulating pump and a pipeline; an outlet of the rotating cathode electro-deposition cell is connected with the resin adsorbing pot; the waste water adsorbed by the resin adsorbing pot is divided into two paths which are respectively connected with the electrolyte circulating bucket and an external discharging pipeline. The recycling equipment for nickel in waste electroplating water has high efficiency for recycling nickel; the purity is as high as 99%; the treated waste water has low nickel content and satisfies the discharge standard of our country.

Description

The recovery system of nickel in the electroplating wastewater
Technical field
The utility model relates to the sewage treatment equipment of electroplating industry, is specifically related to the recovery system of nickel in a kind of electroplating wastewater.
Background technology
Electroplating industry all produces a large amount of plating nickel-containing waste waters every year, and directly a kind of wasting of resources is not only in discharging, and environment is caused severe contamination.Electroplate the processing of nickel-containing waste water at present and mainly use the method for regulating pH value in the waste water that nickel is precipitated, handle nickel-containing waste water in this way, not only be difficult to reach the environment protection emission requirement, and the nickeliferous product nickel content of gained is low, recovery difficult is big.
Summary of the invention
The utility model technical problem to be solved is: solve the problem that above-mentioned prior art exists, and provide that a kind of nickel organic efficiency is high, purity reaches 99%, the recovery system of nickel in low, the electroplating wastewater that reaches discharging standards of nickel content in the processed waste water.
The technical scheme that the utility model adopts is: the recovery system of nickel comprises circulation of elecrolyte bucket, rotating cathode Winning cell, resin absorption jar, adsorption liquid storage barrel and the electric control gear that connects successively in this electroplating wastewater; Circulation of elecrolyte bucket top has the electroplating wastewater import; Circulation of elecrolyte bucket bottom has electrolyte outlet and secondary electrodeposition solution inlet port respectively; Electrolyte outlet is through recycle pump, pipe connection to rotating cathode Winning cell inlet; The outlet of rotating cathode Winning cell connects the resin adsorption tanks, and the waste water after the absorption of resin absorption jar is divided into two-way, connects circulation of elecrolyte bucket and outer discharge pipe respectively.
In the technique scheme, have electrodeposition on the rotating cathode Winning cell and go out the nickel mouth, have rich nickel liquid relief outlet on the resin absorption jar.
In the technique scheme, the rotating cathode Winning cell is added with the pH value setting device.
In the technique scheme, reproducible cationic exchange coloum is installed in the resin absorption jar.
In the technique scheme, the input channel of adsorption liquid storage barrel is connected adsorption liquid liquid feeding pump and adsorption liquid Sendout pump respectively with output channel.
Principle of work:
At first will add sulfuric acid or sodium hydroxide, the pH value of solution will be transferred between the 2.5-6.5, and send into rotating cathode electrodeposition machine then and carry out electrodeposition according to the manufacturing technique requirent of nickel electrodeposition.Configuration solution PH value adjusting device is to guarantee the cathode efficiency in the electrolytic deposition process in the equipment.Solution constantly circulates in electrolytic deposition process.When the nickel ion concentration of solution being reduced to 0.2-0.5g/L, solution being drained into the resin absorption operation carry out adsorption treatment through electrodeposition process.Resin absorption adopts cationic exchange resin adsorption, through to the pH value of entering adsorption column solution and the control of flow velocity, guarantees through the solution nickel content after the adsorption treatment less than 1ppm.Solution after adsorption treatment 70% turns back to electroplating assembly line as wash water, and residue 30% can directly be discharged.After polymeric adsorbent is saturated, send into the regeneration of backwash operation, the solution containing nickel that backwash obtains is sent to the rotating cathode Winning cell, and the secondary electrodeposition is handled.
Equipment that the utility model adopted and technology have greatly reduced the discharging of electroplating wastewater, and will be wherein 99% nickel reclaim with the metallic state of purity 99%, entire treatment technology is carried out in airtight equipment; Reduced and the contacting of external environment, reduced pollution, had only waste water and metallic nickel in the product simultaneously, do not had mud; Stopped secondary pollution, therefore, the utility model nickel organic efficiency is high; Purity is good, and discharge of wastewater is up to state standards, good environmental protection.
Description of drawings:
Fig. 1 is the utility model structural representation
The explanation of accompanying drawing mark:
1---the circulation of elecrolyte bucket, 2---the rotating cathode Winning cell, 3---the resin absorption jar,
4---the adsorption liquid storage barrel, 5---electric control gear, 6---the electroplating wastewater import,
7---electrolyte outlet, 8---secondary electrodeposition solution inlet port, 9---recycle pump,
10---electrodeposition goes out the nickel mouth, and 11---rich nickel liquid relief outlet, 12---the pH value setting device,
13---the adsorption liquid liquid feeding pump, 14---the adsorption liquid Sendout pump, 15---valve.
Embodiment:
Referring to Fig. 1; The recovery system of nickel comprises circulation of elecrolyte bucket 1, rotating cathode Winning cell 2, resin absorption jar 3, adsorption liquid storage barrel 4 and the electric control gear 5 that connects successively in the electroplating wastewater of the utility model; Circulation of elecrolyte bucket top has electroplating wastewater import 6, and circulation of elecrolyte bucket 1 bottom has electrolyte outlet 7 and secondary electrodeposition solution inlet port 8 respectively, and electrolyte outlet is through recycle pump 9, pipe connection to rotating cathode Winning cell inlet; The outlet of rotating cathode Winning cell connects the resin adsorption tanks; Waste water after the absorption of resin absorption jar is divided into two-way, connects circulation of elecrolyte bucket and outer discharge pipe respectively, has electrodeposition on the rotating cathode Winning cell and goes out nickel mouth 10; Has rich nickel liquid relief outlet 11 on the resin absorption jar; The rotating cathode Winning cell is added with pH value setting device 12, and reproducible cationic exchange coloum is installed in the resin absorption jar, and the input channel of adsorption liquid storage barrel is connected adsorption liquid liquid feeding pump 13 and adsorption liquid Sendout pump 14 respectively with output channel.

Claims (5)

1. the recovery system of nickel in the electroplating wastewater; It is characterized in that: comprise the circulation of elecrolyte bucket, rotating cathode Winning cell, resin absorption jar, adsorption liquid storage barrel and the electric control gear that connect successively; Circulation of elecrolyte bucket top has the electroplating wastewater import; Circulation of elecrolyte bucket bottom has electrolyte outlet and secondary electrodeposition solution inlet port respectively, and electrolyte outlet is through recycle pump, pipe connection to rotating cathode Winning cell inlet, and the outlet of rotating cathode Winning cell connects the resin adsorption tanks; Waste water after the absorption of resin absorption jar is divided into two-way, connects circulation of elecrolyte bucket and outer discharge pipe respectively.
2. the recovery system of nickel in the electroplating wastewater according to claim 1 is characterized in that: have electrodeposition on the rotating cathode Winning cell and go out the nickel mouth, have rich nickel liquid relief outlet on the resin absorption jar.
3. the recovery system of nickel in the electroplating wastewater according to claim 1, it is characterized in that: the rotating cathode Winning cell is added with the pH value setting device.
4. the recovery system of nickel in the electroplating wastewater according to claim 1 is characterized in that: reproducible cationic exchange coloum is installed in the resin absorption jar.
5. the recovery system of nickel in the electroplating wastewater according to claim 1 is characterized in that: the input channel of adsorption liquid storage barrel is connected adsorption liquid liquid feeding pump and adsorption liquid Sendout pump respectively with output channel.
CN2011202709033U 2011-07-28 2011-07-28 Recycling equipment for nickel in waste electroplating water Expired - Fee Related CN202164373U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011202709033U CN202164373U (en) 2011-07-28 2011-07-28 Recycling equipment for nickel in waste electroplating water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011202709033U CN202164373U (en) 2011-07-28 2011-07-28 Recycling equipment for nickel in waste electroplating water

Publications (1)

Publication Number Publication Date
CN202164373U true CN202164373U (en) 2012-03-14

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CN2011202709033U Expired - Fee Related CN202164373U (en) 2011-07-28 2011-07-28 Recycling equipment for nickel in waste electroplating water

Country Status (1)

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CN (1) CN202164373U (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086421A (en) * 2016-08-08 2016-11-09 陈灏康 A kind of nickel-containing waste water nickel reclaimer and recovery method
CN107034364A (en) * 2017-04-25 2017-08-11 上海问鼎环保科技有限公司 A kind of method adsorbed from electroplating wastewater and reclaim metallic nickel
CN107129093A (en) * 2017-06-07 2017-09-05 深圳市世清环保科技有限公司 The chemically quick, method of high efficiente callback nickel and equipment therefor in nickel-plating waste liquid
CN109852995A (en) * 2019-01-23 2019-06-07 郑宏 Ion exchange-electrolysis combination method produces electrolytic nickel technique
CN115156161A (en) * 2021-04-07 2022-10-11 台州善敏机械有限公司 Electroplated part washing method and electroplating method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086421A (en) * 2016-08-08 2016-11-09 陈灏康 A kind of nickel-containing waste water nickel reclaimer and recovery method
CN107034364A (en) * 2017-04-25 2017-08-11 上海问鼎环保科技有限公司 A kind of method adsorbed from electroplating wastewater and reclaim metallic nickel
CN107129093A (en) * 2017-06-07 2017-09-05 深圳市世清环保科技有限公司 The chemically quick, method of high efficiente callback nickel and equipment therefor in nickel-plating waste liquid
CN109852995A (en) * 2019-01-23 2019-06-07 郑宏 Ion exchange-electrolysis combination method produces electrolytic nickel technique
CN109852995B (en) * 2019-01-23 2021-03-05 郑宏 Process for producing electrolytic nickel by ion exchange-electrolysis combined method
CN115156161A (en) * 2021-04-07 2022-10-11 台州善敏机械有限公司 Electroplated part washing method and electroplating method

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Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee
CP02 Change in the address of a patent holder

Address after: 410100 Changsha hunters road in Hunan Province Economic and Technological Development Zone No. 11

Patentee after: Hunan Vary Sci-Tech Co., Ltd.

Address before: 410100 Hunan province Changsha Panpan Changsha economic and Technological Development Zone, Road No. 11

Patentee before: Hunan Vary Sci-Tech Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120314

Termination date: 20200728

CF01 Termination of patent right due to non-payment of annual fee