CN202052455U - Solar auxiliary extraction flue gas decarburization and refrigeration combination system with liquid absorbent - Google Patents
Solar auxiliary extraction flue gas decarburization and refrigeration combination system with liquid absorbent Download PDFInfo
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- CN202052455U CN202052455U CN2011201261176U CN201120126117U CN202052455U CN 202052455 U CN202052455 U CN 202052455U CN 2011201261176 U CN2011201261176 U CN 2011201261176U CN 201120126117 U CN201120126117 U CN 201120126117U CN 202052455 U CN202052455 U CN 202052455U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
- Y02A30/274—Relating to heating, ventilation or air conditioning [HVAC] technologies using waste energy, e.g. from internal combustion engine
Abstract
A solar auxiliary extraction flue gas decarburization and refrigeration combination system with liquid absorbent belongs to the technical field of flue gas decarburization and utilization in a thermal power plant. An outlet at the bottom end of an absorption tower is connected to a lean-rich liquid heat exchanger through a rich liquid pump; an outlet of the lean-rich liquid heat exchanger includes two paths; one path is connected into the upper portion of the absorption tower through a lean liquid cooler; the other path is connected into the upper portion of a regeneration tower; an outlet on the lower portion of the regeneration tower is divided into two paths; one path is connected onto the a lean-rich liquid heat exchanger through a lean liquid pump; the other path is connected back to the regeneration tower through a reboiler; solar equipment is respectively connected onto the regeneration tower and the reboiler; an outlet at the top of the regeneration tower is connected with a refrigeration system; and a loop of the refrigeration system is connected into a separator. The solar auxiliary extraction flue gas decarburization and refrigeration combination system with the liquid absorbent is wide in applicable range and suitable for decarburization with the liquid absorbent in terms of decarburization, different solar devices can be selected for auxiliary heating according to requirements of decarburization modes, the combination system is suitable for various refrigerants in terms of refrigeration, and different low temperatures can be obtained by using different refrigerants.
Description
Technical field
The utility model belongs to the coal steam-electric plant smoke decarburization and utilizes technical field, particularly a kind of heat drive absorption system that utilizes the auxiliary liquid-absorbant of bleeding of solar energy carbon dioxide stream to the coal steam-electric plant smoke decarburization and after utilizing decarburization.
Background technology
Along with the proposition of " 12 " planning, subjects under discussion such as energy-saving and emission-reduction, protection environment are put once more in critical positions.In China, thermal power generation is the type of mainly generating electricity, and therefore, the energy-saving and emission-reduction task of thermal power plant is great, of far-reaching significance.
At present, carbon dioxide discharge-reduction has caused international extensive concern, and chemical absorbing formula separating carbon dioxide method is one of comparatively ripe method of technology, but its operation needs consumption of calorie.Solar energy should be utilized by people most possibly as a kind of inexhaustible clean energy resource.At power domain, solar energy can the assistant coal unit generation.But because influences such as solar energy is subjected to round the clock, environment, its energy supply continuation and stability are restricted, and therefore can consider to be used for to assist the capturing carbon dioxide of bleeding.
In recent years, along with the development of society, the freezing and refrigeration technology obtains application more and more widely in life and industry.Absorption refrigeration is because of realizing that effective utilization comes into one's own to low-grade energies such as solar energy, geothermal energy, equipment waste heats.Use different working medium to obtaining required low temperature to the absorption refrigeration agent.
The many waste heats of power plant, used heat do not obtain fine utilization at present, and the cold increase station service that needs of the many equipment of power plant drives the refrigeration machine realization.This device can utilize some utilizing waste heat for refrigeration, and not only can supply with plant area and use, and can business development.
Summary of the invention
In order to realize the efficient of energy-saving and emission-reduction, raising system, realize cascaded utilization of energy and low temperature exhaust heat utilization simultaneously, the utility model proposes the auxiliary liquid-absorbant of bleeding of a kind of solar energy to flue gas decarbonization and refrigeration association system.
The technical solution adopted in the utility model is:
The bottom outlet on absorption tower is connected on the poor rich liquid heat exchanger by the rich solution pump; The outlet of poor rich liquid heat exchanger is divided into two-way, and the lean solution cooler of leading up to inserts the top on absorption tower, and the top of regenerator is inserted on another road; The lower part outlet of regenerator is divided into two-way, and the lean pump of leading up to is connected on the poor rich liquid heat exchanger, and another road takes back regenerator by reboiler; Solar facilities is connected respectively on regenerator and the reboiler; The outlet of regenerator top is connected with refrigeration system by pipeline, and separator is inserted in the loop of refrigeration system; The outlet of separator is divided into two-way, and the solution pump of leading up to takes back the top of regenerator, and CO is inserted by dehydrator in another road
2Storage container.
Described solar facilities is slot type, tower or disc type solar energy equipment.
The beneficial effects of the utility model are, utilize the auxiliary decarburization of bleeding of solar energy, and drive the Absorption Cooling System operation, use different cold-producing mediums acquisitions low temperature in various degree with the part of waste heat of decarbonization system, improve the utilization ratio of energy, reach the effect of energy-saving and emission-reduction.
Description of drawings
Fig. 1 is the system diagram of auxiliary bleed liquid-absorbant decarburization and refrigeration association system of solar energy.
Number in the figure:
The 1-solar facilities; The 2-absorption tower; The 3-regenerator; 4-lean solution cooler; 5-rich solution pump, the 6-poor rich liquid heat exchanger; The 7-reboiler, the 8-lean pump; The 9-solution pump; The 10-separator; The 11-dehydrator; 12-CO
2Storage container; The 13-generator; The 14-condenser; The 15-evaporimeter; 16-uses cold space; The 17-absorber.
The specific embodiment
The utility model provides the auxiliary liquid-absorbant of bleeding of a kind of solar energy to flue gas decarbonization and refrigeration association system, below in conjunction with the drawings and specific embodiments the utility model is described further.
The bottom outlet on absorption tower 2 is connected on the poor rich liquid heat exchanger 6 by rich solution pump 5; The outlet of poor rich liquid heat exchanger 6 is divided into two-way, and the lean solution cooler 4 of leading up to inserts the top on absorption tower 2, and the top of regenerator 3 is inserted on another road; The lower part outlet of regenerator 3 is divided into two-way, and the lean pump 8 of leading up to is connected on the poor rich liquid heat exchanger 6, and another road takes back regenerator 3 by reboiler 7; Solar facilities 1 is connected respectively on regenerator 3 and the reboiler 7; Regenerator 3 top exits are connected with refrigeration system by pipeline, and separator 10 is inserted in the loop of refrigeration system; The outlet of separator is divided into two-way, and the solution pump 9 of leading up to takes back the top of regenerator 3, and CO is inserted by dehydrator 11 in another road
2Storage container 12.
Liquid-absorbant relatively more commonly used at present has monoethanolamine etc., and kind of refrigeration cycle working medium commonly used is to having ammonia-aqueous solution (ammonia is cold-producing medium, and water is absorbent), water-lithium bromide solution (water is cold-producing medium, and lithium bromide is an absorbent) etc.Wherein adopt ammonia-aqueous solution workmanship confrontation can produce the low temperature below 0 ℃; Because the cold-producing medium of lithium-bromide absorption-type refrigerating machine is a water, cryogenic temperature can only generally be not less than 5 ℃ more than 0 ℃.Be that example illustrates the workflow of this system with monoethanolamine (MEA) and ammonia-aqueous solution below.
In flow process shown in Figure 2, power-plant flue gas is admitted to absorption tower 2, and in absorption tower 2, the carbon dioxide in the flue gas is absorbed by MEA solution, contains the CO that does not catch on a small quantity after the purification
2Flue gas send into chimney from cat head and discharge.Absorbed CO
2The MEA rich solution flow into poor rich liquid heat exchangers 6 through rich solution pump 5, in poor rich liquid heat exchanger 6, utilize the waste heat of the absorbent solution (lean solution) after the regeneration that rich solution is heated, also reach the effect of cooling actified solution simultaneously.The MEA rich solution enters in the regenerator 3 through the top of choke valve 7 by regenerator 3, provides the energy heating to make absorbent MEA regeneration by solar facilities 1 auxiliary bleeding.Then lean solution is sent into reboiler 10, utilized auxiliary the bleeding of solar energy to heat the further desorb of carbon dioxide that makes wherein.Lean solution behind the desorb carbon dioxide flows out from regenerator 3 bottoms, by lean pump 8 pressurizations, enters absorption tower 2 again after delivering to 4 coolings of lean solution cooler after poor rich liquid heat exchanger 6 heat exchange.Circulation constitutes the flow process of continuous absorption and desorption carbon dioxide thus.
The pure CO that comes out from regenerator 3
2Enter separator 10 behind the concentrated ammonia liquor heat-shift in stream and the generator 13 and carry out carbonated drink and separate, condensed water returns regenerator by solution pump 9, and isolated carbon dioxide enters dehydrator 11 and removes moisture, enters CO2 storage container 12 then.Concentrated ammonia solution is heated in generator 13, and saturated ammonia is separated from solution and entered condenser 14, is saturated liquid ammonia through water quench in condenser.Liquid ammonia becomes the very little wet saturated ammonia steam of mass dryness fraction through choke valve step-down, cooling, entering that heat absorption becomes dried saturated ammonia steam in the evaporimeter 15, enters absorber 17 then and is dissolved by dilute ammonia solution, and the liberated heat water that is cooled is taken away during dissolving.Evaporimeter 15 and with carrying out solution exchange between the cold space 16 to reduce temperature.Pressurization enters the circulation of the ammonia generator continuation next one to concentrated ammonia solution after the absorption ammonia through solution pump.In generator 13, decomposite ammonia dilute ammonia solution afterwards and return absorber 17 again by the continuation utilization through pressure-reducing valve.
Claims (2)
1. auxiliary liquid-absorbant flue gas decarbonization and the refrigeration association system of bleeding of solar energy is characterized in that the bottom outlet of absorption tower (2) is connected on the poor rich liquid heat exchanger (6) by rich solution pump (5); The outlet of poor rich liquid heat exchanger (6) is divided into two-way, and the lean solution cooler (4) of leading up to inserts the top on absorption tower (2), and the top of regenerator (3) is inserted on another road; The lower part outlet of regenerator (3) is divided into two-way, and the lean pump (8) of leading up to is connected on the poor rich liquid heat exchanger (6), and another road takes back regenerator (3) by reboiler (7); Solar facilities (1) is connected respectively on regenerator (3) and the reboiler (7); Regenerator (3) top exit is connected with refrigeration system by pipeline, and separator (10) is inserted in the loop of refrigeration system; The outlet of separator is divided into two-way, and the solution pump (9) of leading up to takes back the top of regenerator (3), and CO is inserted by dehydrator (11) in another road
2Storage container (12).
2. auxiliary liquid-absorbant flue gas decarbonization and the refrigeration association system of bleeding of solar energy according to claim 1 is characterized in that described solar facilities is slot type, tower or disc type solar energy equipment.
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CN2011201261176U CN202052455U (en) | 2011-04-26 | 2011-04-26 | Solar auxiliary extraction flue gas decarburization and refrigeration combination system with liquid absorbent |
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CN2011201261176U CN202052455U (en) | 2011-04-26 | 2011-04-26 | Solar auxiliary extraction flue gas decarburization and refrigeration combination system with liquid absorbent |
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Cited By (7)
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US20130152596A1 (en) * | 2010-09-03 | 2013-06-20 | Siemens Aktiengesellschaft | Fossil fuel-fired power station having a removal apparatus for carbon dioxide and process for separating carbon dioxide from an offgas from a fossil fuel-fired power station |
CN104174273A (en) * | 2014-08-12 | 2014-12-03 | 天津大学 | Direct solar driven carbon dioxide flash evaporation and desorption integrated system and method |
CN104307308A (en) * | 2014-10-26 | 2015-01-28 | 华北电力大学(保定) | Process system for decarbonizing by using photovoltaic assisted coal combustion set |
CN105582794A (en) * | 2016-01-19 | 2016-05-18 | 河北工程大学 | Solar energy and geothermal energy assisted CO2 Rankine cycle assisted decarbonization and denitrification system for coal-fired unit |
CN105727697A (en) * | 2016-03-23 | 2016-07-06 | 天津大学 | Solar photovoltaic refrigeration assisted hydrate method carbon capture system |
CN106247683A (en) * | 2016-10-20 | 2016-12-21 | 广东电网有限责任公司电力科学研究院 | A kind of CO2seizure system and technique |
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2011
- 2011-04-26 CN CN2011201261176U patent/CN202052455U/en not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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US20130152596A1 (en) * | 2010-09-03 | 2013-06-20 | Siemens Aktiengesellschaft | Fossil fuel-fired power station having a removal apparatus for carbon dioxide and process for separating carbon dioxide from an offgas from a fossil fuel-fired power station |
US9464571B2 (en) * | 2010-09-03 | 2016-10-11 | Siemens Aktiengesellschaft | Fossil fuel-fired power station having a removal apparatus for carbon dioxide and process for separating carbon dioxide from an offgas from a fossil fuel-fired power station |
CN104174273A (en) * | 2014-08-12 | 2014-12-03 | 天津大学 | Direct solar driven carbon dioxide flash evaporation and desorption integrated system and method |
CN104174273B (en) * | 2014-08-12 | 2016-09-07 | 天津大学 | A kind of solar energy directly drives the integrated system and method that carbon dioxide flash distillation desorbs |
CN104307308A (en) * | 2014-10-26 | 2015-01-28 | 华北电力大学(保定) | Process system for decarbonizing by using photovoltaic assisted coal combustion set |
CN104307308B (en) * | 2014-10-26 | 2017-04-19 | 华北电力大学(保定) | Process system for decarbonizing by using photovoltaic assisted coal combustion set |
CN105582794A (en) * | 2016-01-19 | 2016-05-18 | 河北工程大学 | Solar energy and geothermal energy assisted CO2 Rankine cycle assisted decarbonization and denitrification system for coal-fired unit |
CN105727697A (en) * | 2016-03-23 | 2016-07-06 | 天津大学 | Solar photovoltaic refrigeration assisted hydrate method carbon capture system |
CN105727697B (en) * | 2016-03-23 | 2018-07-10 | 天津大学 | Solar photoelectric refrigeration auxiliary hydrate carbon trapping system |
CN106247683A (en) * | 2016-10-20 | 2016-12-21 | 广东电网有限责任公司电力科学研究院 | A kind of CO2seizure system and technique |
CN109954382A (en) * | 2019-04-12 | 2019-07-02 | 天津大学 | A kind of solar energy interface evaporate direct desorption type carbon capture system and its control method |
CN109954382B (en) * | 2019-04-12 | 2023-09-08 | 天津大学 | Direct desorption type carbon capture system for solar energy interface evaporation and control method thereof |
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Granted publication date: 20111130 Termination date: 20140426 |