CN201701870U - Ferrous chloride introduced chlorine absorber - Google Patents

Ferrous chloride introduced chlorine absorber Download PDF

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Publication number
CN201701870U
CN201701870U CN2010201933022U CN201020193302U CN201701870U CN 201701870 U CN201701870 U CN 201701870U CN 2010201933022 U CN2010201933022 U CN 2010201933022U CN 201020193302 U CN201020193302 U CN 201020193302U CN 201701870 U CN201701870 U CN 201701870U
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CN
China
Prior art keywords
chlorine
absorption
main
absorbing
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2010201933022U
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Chinese (zh)
Inventor
庄永
邹鸿图
赵中华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BYEN KUNSHAN RENSE AVFALL QIANDENG Co Ltd
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BYEN KUNSHAN RENSE AVFALL QIANDENG Co Ltd
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Priority to CN2010201933022U priority Critical patent/CN201701870U/en
Application granted granted Critical
Publication of CN201701870U publication Critical patent/CN201701870U/en
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Abstract

The utility model relates to a ferrous chloride introduced chlorine absorber, which is characterized in that the absorber comprises a chloride gas steel cylinder, a chloride gas buffer tank, a main absorbing system and a sub absorbing system, wherein the main absorbing system comprises a main absorbing tank, a main absorbing circulation pump, a plate type heat exchanger and a Venturi injector, the main absorbing tank is used for storing reaction liquid, the plate type heat exchanger is used for cooling the reaction liquid, the Venturi injector is used for absorbing and mixing gas, the sub absorbing system mainly comprises a sub absorbing tank and a sub absorbing circulation pump. The utility model has the advantages of simple structure, high chloride introduction efficiency and no damage to equipment.

Description

A kind of protochloride Tie Tong chlorine absorption plant
Technical field
The utility model belongs to technical field of chemical, relates in particular to a kind of protochloride Tie Tong chlorine absorption plant.
Background technology
At present, the chlorine absorption unit that China adopts all is filler absorption patterns, and filler is housed in the tower, and frerrous chloride is from top spray, and chlorine is sucked by blower fan from the bottom, and chlorine and solution of ferrous chloride react absorption in filler.Though this equipment is simple in structure, chlorine content is greater than 20mg/m in the exhaust emissions 3, air has been caused pollution, in course of reaction, the solution reaction temperature might rise to more than 100 ℃, equipment is had big damage effect, and the absorption efficiency of chlorine is low in entire reaction course.
Summary of the invention
The technical problem that the utility model solved provides a kind of simple in structure just at deficiency of the prior art, and the absorption efficiency height is to the harmless protochloride of equipment Tie Tong chlorine absorption plant.
The technical solution of the utility model is as follows: a kind of protochloride Tie Tong chlorine absorption plant, it is characterized in that this absorption plant comprises chlorine cylinder, Chlorine Buffer Vessel, main absorption system and secondary absorption system, described main absorption system comprises main absorption cell and the main absorbent recirculation pump that is used to deposit reaction liquid, and described secondary absorption system comprises secondary absorption cell and secondary absorbent recirculation pump.
As a kind of improvement of the present utility model, described main absorption system also comprises the plate type heat exchanger that cools off reaction liquid.
As a kind of improvement of the present utility model, described main absorption system also comprises the venturi-type eductors that gas is absorbed and mixes.
As a kind of improvement of the present utility model, described secondary absorption system also comprises the plate type heat exchanger that cools off reaction liquid.
As a kind of improvement of the present utility model, described secondary absorption system also comprises the venturi-type eductors that gas is absorbed and mixes.
With respect to prior art, the utlity model has following advantage, this absorption plant is simple in structure, to the absorption efficiency height of chlorine, and the use of plate type heat exchanger, can reduce the temperature of reaction liquid, reduces the infringement to equipment.
Description of drawings
Fig. 1 is an entire reaction apparatus structure schematic diagram;
Among the figure: 1 is chlorine cylinder, and 2 is Chlorine Buffer Vessel, and 3 is main absorption system,
3-1 is main absorption cell, and 3-2 is main absorbent recirculation pump, and 3-3 is a plate type heat exchanger,
3-4 is a venturi-type eductors, and 4 is secondary absorption system, and 4-1 is secondary absorption cell,
4-2 is secondary absorbent recirculation pump, and 4-3 is a plate type heat exchanger, and 4-4 is a venturi-type eductors.
The specific embodiment
Below in conjunction with accompanying drawing the utility model is further described, can see that whole absorption plant comprises chlorine cylinder 1, Chlorine Buffer Vessel 2, main absorption system 3 and secondary absorption system 4, main absorption system 3 comprises main absorption cell 3-1 and the main absorbent recirculation pump 3-2 that is used to deposit reaction liquid, the plate type heat exchanger 3-3 of cooling reaction liquid, the venturi-type eductors 3-4 that gas is absorbed and mixes; Secondary absorption system 4 comprises the plate type heat exchanger 4-3 of secondary absorption cell 4-1 and secondary absorbent recirculation pump 4-2 cooling reaction liquid, the venturi-type eductors 4-4 that gas is absorbed and mixes.
Entire reaction technology is as follows, main, insert the frerrous chloride about 9 tons in the secondary absorption cell, open main, secondary absorption cell circulating pump, open the master, secondary absorption cell heat exchanger cooling water valve, open chlorine cylinder 1 valve, open steel cylinder trickle valve, regulate chlorine flowrate to correct position, solution of ferrous chloride in the main absorption cell 3-1 enters plate type heat exchanger 3-3 through main absorbent recirculation pump 3-2 and cools off, after being cooled to 50~60 ℃ to venturi-type eductors 3-4, liquid can produce negative pressure when venturi-type eductors ejects, chlorine is absorbed, with react after frerrous chloride liquid mixes, reacted liquid sprays back in the main absorption cell 3-1 again, and the chlorine inlet in this process in the venturi-type eductors can produce stronger negative pressure, the chlorine of gasification in the liquid chlorine cylinder 1 is absorbed among the venturi-type eductors 3-4 mix with frerrous chloride, spray into together in the solution of ferrous chloride in the main absorption cell 3-1, the generation ferric trichloride reacts; The unreacted chlorine of part overflows from the chlorine overfall of main absorption cell top, enter among the venturi-type eductors 4-4 of secondary absorption cell 4-1 top, chlorine enters, the more weak negative pressure of the same generation of the venturi-type eductors 4-4 of secondary absorption cell 4-1, suck unreacted chlorine of part and the interior frerrous chloride reaction of secondary absorption cell in the main absorption cell, chlorine is after twice absorption like this, and the chlorine absorption efficiency reaches 99.99%; Behind the complete oxidized formation ferric trichloride of the frerrous chloride in the main absorption cell 3-1, stop logical chlorine, solution of ferrous chloride in the secondary absorption cell 4-1 is transferred to main absorption cell 3-1, enter fresh frerrous chloride again in the secondary absorption cell 4-1, continue logical chlorine then, in secondary absorption cell, keep fresh state so always, guaranteed the absorption fully of chlorine.Above-mentioned whole process has realized protochloride Tie Tong chlorine, and logical chlorine efficient height, reaches 99.99%, and to not infringement of equipment.
Above embodiment is the comparatively complete embodiment of the utility model; be not to be used for limiting protection domain of the present utility model; if its technical scheme is identical with technical scheme in the utility model claims or carry out simple substitution, all belong to protection domain of the present utility model.

Claims (5)

1. protochloride Tie Tong chlorine absorption plant, it is characterized in that: this absorption plant comprises chlorine cylinder, Chlorine Buffer Vessel, main absorption system and secondary absorption system, described main absorption system comprises main absorption cell and the main absorbent recirculation pump that is used to deposit reaction liquid, and described secondary absorption system comprises secondary absorption cell and secondary absorbent recirculation pump.
2. protochloride according to claim 1 Tie Tong chlorine absorption plant, it is characterized in that: described main absorption system also comprises the plate type heat exchanger that cools off reaction liquid.
3. protochloride according to claim 1 and 2 Tie Tong chlorine absorption plant, it is characterized in that: described main absorption system also comprises the venturi-type eductors that gas is absorbed and mixes.
4. protochloride according to claim 1 Tie Tong chlorine absorption plant, it is characterized in that: described secondary absorption system also comprises the plate type heat exchanger that cools off reaction liquid.
5. according to claim 1 or 4 described protochloride Tie Tong chlorine absorption plants, it is characterized in that: described secondary absorption system also comprises the venturi-type eductors that gas is absorbed and mixes.
CN2010201933022U 2010-05-18 2010-05-18 Ferrous chloride introduced chlorine absorber Expired - Lifetime CN201701870U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010201933022U CN201701870U (en) 2010-05-18 2010-05-18 Ferrous chloride introduced chlorine absorber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010201933022U CN201701870U (en) 2010-05-18 2010-05-18 Ferrous chloride introduced chlorine absorber

Publications (1)

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CN201701870U true CN201701870U (en) 2011-01-12

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CN2010201933022U Expired - Lifetime CN201701870U (en) 2010-05-18 2010-05-18 Ferrous chloride introduced chlorine absorber

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103111171A (en) * 2012-12-27 2013-05-22 山东瑞博龙化工科技股份有限公司 Cracking tail gas absorption and treatment device for production device of dimethyl acrylamide
CN111777101A (en) * 2020-07-23 2020-10-16 昆山市大洋环境净化有限公司 Ferrous chloride-containing waste liquid treatment device
CN114797415A (en) * 2022-05-20 2022-07-29 攀钢集团钒钛资源股份有限公司 Method for treating residual chlorine in chlorination tail gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103111171A (en) * 2012-12-27 2013-05-22 山东瑞博龙化工科技股份有限公司 Cracking tail gas absorption and treatment device for production device of dimethyl acrylamide
CN111777101A (en) * 2020-07-23 2020-10-16 昆山市大洋环境净化有限公司 Ferrous chloride-containing waste liquid treatment device
CN114797415A (en) * 2022-05-20 2022-07-29 攀钢集团钒钛资源股份有限公司 Method for treating residual chlorine in chlorination tail gas

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