CN105056714A - System and method for efficiently removing sulfur oxide in ship waste gas - Google Patents
System and method for efficiently removing sulfur oxide in ship waste gas Download PDFInfo
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- CN105056714A CN105056714A CN201510487384.9A CN201510487384A CN105056714A CN 105056714 A CN105056714 A CN 105056714A CN 201510487384 A CN201510487384 A CN 201510487384A CN 105056714 A CN105056714 A CN 105056714A
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Abstract
The present invention discloses a system and a method for efficiently removing sulfur oxide in ship waste gas. The removal process is divided into three stages: a pre-treatment stage, bubbling and primary desulfurization stage, and a spraying and secondary desulfurization stage. The method comprises the following steps of: respectively introducing fresh sea water into a pre-spraying chamber, a desulfurization tower and an aeration tank through pipelines; firstly cooling the high-temperature waste gas, and removing part of sulfur oxides in the pre-spraying chamber; introducing the cooled waste gas into the desulfurization tower and uniformly spraying the cooled waste gas into a sea water bubbling zone through a gas distribution tube; introducing the waste gas into a spraying zone through an ascending passage of the desulfurization tower so as to carry out further removal of sulfur oxides; demisting the waste gas by a demister, and discharging the demisted waste gas into the atmosphere through a chimney; and restoring the water quality of desulfurized seawater by virtue of primary aeration in the desulfurization tower and secondary aeration in an aeration tank. Compared with a traditional seawater desulfurization technology, on the premise of not increasing the space occupancy rate of the seawater desulfurization system, the method solves the problem that the desulfurization efficiency is generally low when seawater desulfurization technology is applied in ships.
Description
Technical field
The invention belongs to marine exhaust pollution prevention technique field, be specifically related to a kind of system and method utilizing seawater to remove marine exhaust sulphur oxide.
Background technology
Along with the increase of volume of world trade, boats and ships are as important means of transport, and its transport capacity obtains in 21 century and develops fast, and current global tonnage has reached more than 85000 more than the boats and ships of 100t.But the pollution from exhaust emission brought because of shipbuilding industry development makes people worried, especially the pollution of oxysulfide.According to statistics, the annual emissions of global boats and ships oxysulfide reaches more than 900 ten thousand tons, accounts for 7% of World Sulfur emissions of oxides total amount, accounts for 60% of whole carrier sulfur oxides emissions.
The method of current reduction boats and ships sulfur oxide emission mainly contains two kinds: use low-sulphur fuel and carry out exhuast gas desulfurization.Low-sulphur fuel use cost is high, and uses this fuel need transform the fuel oil equipment of boats and ships, economically and technically sees that this method is not reduce the optimal selection of sulfur oxide emission.MARPOL pact supplemental provisions VI points out, boats and ships can use the waste gas cleaning system of the directive/guide accreditation worked out by IMO through competent authority.Based on the successful Application of sea water desulfuration technology on the land facilities such as thermal power plant, nearly more than ten years people start consideration and apply it on boats and ships.It is low that sea water desulfuration technology has operating cost, without solid waste, without the need to outstanding advantages such as any artificial chemical desulfurization agent.For the boats and ships navigated by water on ocean, seawater resources enrich, boats and ships can be gathered materials on the spot, the seawater after desulfurization treated up to standard after can flow back to ocean again, economize on resources, therefore sea water desulfuration technology has extraordinary application prospect in marine exhaust desulfurization.
Although sea water desulfuration technology has above-mentioned advantage, this technology is applied on boats and ships and is also faced with some technology barriers.Sea water desulfuration technology be applied in land facility as thermal power plant, oil plant etc. can reach more than 90% desulfuration efficiency.But being different from land facility, boats and ships are mobile pollution source, and whole desulphurization system all must be arranged on boats and ships.And the limited free space of boats and ships seriously limits the scale of desulphurization system, this means that seawater need absorb a large amount of oxysulfides within the very short time of staying.But seawater is extremely limited to the absorbability of oxysulfide at short notice, therefore sea water desulfuration technology is applied in desulfuration efficiency on boats and ships generally lower than 90%.
And be mostly spray and filler mode for the desulfurization method of sea water desulfuration technology at present.Although spray mode good economy performance, energy consumption is low, and structure is simple, and distribution of gas is uneven, there is edge effect, causes desulfuration efficiency lower.Be the spray tube bank that the desulfuration efficiency reaching more than 90% often need arrange more than 3 layers when boats and ships are applied, add system complexity and maintenance difficulty.Also need the multiple EGR of peripheral hardware to realize the circulated sprinkling of seawater, not only energy consumption is large, also takies boats and ships additional space simultaneously.Although and the control of filler mode is simple, gas-liquid contact is good, because resistance is comparatively large, easily produces wall flow phenomenon, cause desulfuration efficiency limited, and boats and ships additional space storage filler need be taken.Absorption and neutralization are integrated in bubbling pond by the bubbling desulfurization method that the Ecosilencer seawater desulfurization device of MES company invention adopts, reduce the area occupied of whole device, but because this desulfurization method same pond seawater realizes the cooling effect of high-temp waste gas and the absorption process of oxysulfide, cause gas-liquid mass transfer declines, sea water desulfuration efficiency is lower.
To sum up, on boats and ships, sea water desulfuration technology problems faced is applied at present mainly:
1) sea water desulfuration efficiency is general lower;
2) there is the problem that distribution of gas is uneven and device area occupied is larger in desulfurization method;
3) all there is the contradiction between system space occupancy in various degree and desulfuration efficiency in existing technical scheme.
If above problem can not get effective solution, then the application of sea water desulfuration technology on boats and ships will can not get promoting.And the boats and ships not installing Deuslfurizing system for sea water cannot arrive region boats and ships sulfur oxides emissions being had to strict restriction, seriously hinder the Trade Development between different country.Each marine site, the world can be freed in and out for making foreign-going ship, better realize the international trade of diversification, the method for efficient removal marine exhaust sulphur oxide under a kind of prerequisite not increasing Deuslfurizing system for sea water space occupancy rate of pluses and minuses proposition of the comprehensive above desulfurization method of the present invention.
Summary of the invention
For above-mentioned the deficiencies in the prior art, the object of this invention is to provide a kind of system and method for efficient removal marine exhaust sulphur oxide, to solve the general lower problem of desulfuration efficiency when sea water desulfuration technology is applied on boats and ships, alleviate the contradiction between the space occupancy rate of Deuslfurizing system for sea water and desulfuration efficiency.
For achieving the above object, the present invention is by the following technical solutions:
A kind of system of efficient removal marine exhaust sulphur oxide, comprise fresh seawater pond, aeration tank, pre-spray chamber, desulfurizing tower, described fresh seawater pond respectively with aeration tank, pre-spray chamber and desulfurizing tower connect, described pre-spray chamber exports with marine exhaust and is connected, and connect desulfurizing tower by pipeline, desulfurizing tower bottom is seawater bubbling area, gas distribution tube is provided with in it, the bottom of gas distribution tube is connected with the first Aeration fan, also aeration tank is connected by sea water pump bottom desulfurizing tower, the second Aeration fan is connected with bottom aeration tank, the top of desulfurizing tower is also connected with chimney.
Further, pH value monitor is provided with in described aeration tank.
Further, described pre-spray chamber is arranged in the exhaust piping being connected to marine exhaust outlet.
Further, described gas distribution tube is playpipe or coil pipe.
Further, described fresh seawater pond is connected with the top of desulfurizing tower.
A method for efficient removal marine exhaust sulphur oxide, the subtractive process of oxysulfide comprises three phases, i.e. pretreatment stage, bubbling first grade desulfurizing stage and spray two-grade desulfurizing stage, specifically comprise the following steps:
A). be admitted to pre-spray chamber, desulfurizing tower and aeration tank from the fresh seawater in ocean respectively through pipeline;
B). pretreatment stage: the high-temp waste gas utilizing air-introduced machine Ship Power Equipment to be produced sends into pre-spray chamber through pipeline, and fresh seawater sprays waste gas at this;
C). the bubbling first grade desulfurizing stage: evenly to spray into the seawater bubbling area in desulfurizing tower through gas distribution tube through the waste gas of supercooling and pre-desulfurization, in seawater bubbling area, gas-liquid contact is abundant, realizes the efficient first grade desulfurizing of bubbling;
D). the spray two-grade desulfurizing stage: complete the rising passway of waste gas in desulfurizing tower after bubbling first grade desulfurizing and enter spray district, top, contact with the sea water drops after spray atomizing, complete removing further of waste gas sulphur oxide;
E). the waste gas after desulfurization, after being arranged on the demister demist on spray top, district, enters air by ship chimney;
F). the restoring sea water stage: first stage aeration is carried out to the seawater after desulfurization by the aerator be arranged on bottom desulfurizing tower, realize the oxidation of part sulphite, reduce the processing load of outside aeration tank, then the seawater after one-level aeration is sent into aeration tank, in aeration tank, carry out second stage aerating oxidation and seawater dilution, after seawater is up to standard after testing, enter ocean.
Further, high-temp waste gas is cooled to 60-120 DEG C by described pretreatment stage.
Further, the bubbling mode in the described bubbling first grade desulfurizing stage is JBR or coil pipe bubbling mode.
The invention has the beneficial effects as follows:
The present invention contrasts prior art and has following remarkable advantage:
1. adopt the sea water preprocessing stage, not only remove part oxysulfide in advance, reduce the desulfurization load of unit volume seawater in desulfurizing tower, also high-temp waste gas is cooled, solve the contradiction of traditional bubbling mode cooling down high-temperature waste gas and seawater low temperature absorption;
2. adopt seawater bubbling as main desulfurization stage, on the one hand the oxidation of the absorption of oxysulfide and desulfurization seawater is integrated in same tower body and completes, effectively reduce the area occupied of desulphurization system; By gas distribution tube, gas uniform is blasted in seawater on the other hand, wall flow phenomenon does not occur, produce the minute bubbles of high diffusion, strong reaction, the mass transfer between strengthening gas-liquid, comparatively in other desulfurization methods, the desulfurization degree of unit volume seawater increases, and bulk devulcanization efficiency improves;
3. adopt seawater bubbling as main desulfurization stage, seawater spraying, as auxiliary desulfurization stage, substantially reduce the number the seawater amount needed for spray, saves the Sea-water cycle set needed for traditional spray mode on the one hand, and reduce system energy consumption, minimizing takes up room; The number of plies of spray tube bank can be reduced on the other hand, while improving desulfuration efficiency, do not increase the complexity of system;
4. in desulfurizing tower, carry out one-level aeration, complete the oxidation of part sulphite in advance, improve mass transfer rate on the one hand, be beneficial to the absorption of oxysulfide in seawater bubbling area; The fresh seawater demand of aeration tank can be reduced on the other hand, thus reduce the area occupied of aeration tank;
5. to sum up, be different from the single desulfurization method that traditional sea water desulfuration technology adopts, the inventive method adopts three desulfurization stage, i.e. pretreatment stage, bubbling first grade desulfurizing stage and the spray two-grade desulfurizing stage, under the prerequisite not increasing Deuslfurizing system for sea water space occupancy rate, significantly improve the desulfuration efficiency of seawater, to the application of sea water desulfuration technology on boats and ships, there are good promotion and application and be worth.
Accompanying drawing explanation
Fig. 1 is the process schematic representation of efficient removal marine exhaust sulphur oxide method of the present invention;
Fig. 2 is an embodiment system schematic of efficient removal marine exhaust sulphur oxide method of the present invention;
Fig. 3 is another embodiment system schematic of efficient removal marine exhaust sulphur oxide method of the present invention.
In figure, 1-chimney; The pre-spray chamber of 2-; 3-first Aeration fan; 4-second Aeration fan; 5-aeration tank; 61-playpipe; 62-coil pipe; 7-sea water pump; 8-pH value monitor; 9-desulfurizing tower; 10-fresh seawater pond.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is further described.
Be illustrated in figure 1 the method for a kind of efficient removal marine exhaust sulphur oxide of this invention, comprise three and remove the stage, be i.e. pretreatment stage, bubbling first grade desulfurizing stage and spray two-grade desulfurizing stage, specifically comprise the following steps:
A). be admitted to pre-spray chamber, desulfurizing tower and aeration tank from the fresh seawater in ocean respectively through pipeline;
B). pretreatment stage: the high-temp waste gas utilizing air-introduced machine Ship Power Equipment to be produced sends into pre-spray chamber through pipeline, fresh seawater sprays waste gas at this, not only can remove the part oxysulfide in waste gas, also achieve cooling of high-temp waste gas, be beneficial to the desulfurization of follow-up phase; High-temp waste gas is cooled to 60-120 DEG C by pretreatment stage;
C). the bubbling first grade desulfurizing stage: this stage is main desulfurization stage.Desulfurizing tower bottom is seawater bubbling area, is furnished with submergence gas distribution tube in the seawater, and the waste gas through supercooling and pre-desulfurization evenly sprays into seawater bubbling area through gas distribution tube; In seawater bubbling area, gas-liquid contact is abundant, and effect of mass transmitting is strong, realizes the efficient first grade desulfurizing of bubbling;
D). the spray two-grade desulfurizing stage: this stage is auxiliary desulfurization stage.Complete the rising passway of waste gas in desulfurizing tower after bubbling first grade desulfurizing and enter spray district, top, contact with the sea water drops after spray atomizing, complete removing further of waste gas sulphur oxide;
E). the waste gas after desulfurization, after being arranged on the demister demist on spray top, district, enters air by ship chimney;
F). the restoring sea water stage: first stage aeration is carried out to the seawater after desulfurization by the aerator be arranged on bottom desulfurizing tower, realize the oxidation of part sulphite, reduce the processing load of outside aeration tank, then the seawater after one-level aeration is sent into aeration tank, second stage aerating oxidation and seawater dilution is carried out in aeration tank, ocean is entered, the generation of whole process no coupling product after seawater is up to standard after testing.
The bubbling mode in bubbling first grade desulfurizing stage is JBR or coil pipe bubbling mode.
Embodiment 1
An embodiment system schematic of efficient removal boats and ships oxysulfide method of the present invention as shown in Figure 2, the system of the present embodiment comprises fresh seawater pond 10, aeration tank 5, pre-spray chamber 2, desulfurizing tower 9, fresh seawater pond 10 is connected with aeration tank 5, pre-spray chamber 2 and desulfurizing tower 9 respectively, and fresh seawater pond 10 is connected with the top of desulfurizing tower 9; Pre-spray chamber 2 exports with marine exhaust and is connected, and connect desulfurizing tower 9 by pipeline, desulfurizing tower 9 bottom is seawater bubbling area, gas distribution tube is provided with in it, the bottom of gas distribution tube is connected with the first Aeration fan 3, also connect aeration tank 5 by sea water pump 7 bottom desulfurizing tower 9, be connected with the second Aeration fan 4 bottom aeration tank 5, the top of desulfurizing tower 9 is also connected with chimney 1; PH value monitor 8 is provided with in aeration tank 5.
Pre-spray chamber 2 is arranged in the exhaust piping being connected to marine exhaust outlet, does not take boats and ships additional space.
In the present embodiment, gas distribution tube is playpipe 61.
The present embodiment mainly comprises waste gas system, Absorption by Sea Water system, restoring sea water system, and wherein bubbling mode adopts playpipe bubbling, exhaust gas inlet pipe level or vertically arrange.
Waste gas system: the waste gas from Ship Power Equipment enters in the exhaust piping of desulphurization system by the effect of air-introduced machine, enter in desulfurizing tower 9 after being arranged on the cooling of ducted pre-spray chamber 2 and pre-desulfurization, evenly blast in seawater through gas injection tube 6 and complete bubbling first grade desulfurizing, then through rising passway enter spray district and seawater complete spray two-grade desulfurizing, after demister demist, enter air by chimney 1.
Absorption by Sea Water system: comprise three absorption stages, i.e. pretreatment stage, bubbling first grade desulfurizing stage and spray two-grade desulfurizing stage, there is following reaction in absorption process:
SO
2+H
2O→H
2SO
3(a)
H
2SO
3→H
++HSO
3 -(b)
HSO
3 -→H
++SO
3 2-(c)
H
++HCO
3 -→CO
2+H
2O(d)
Owing to being provided with aeration tube bottom the seawater bubbling area in desulfurizing tower (9), in bubbling desulfurization stage except above course of reaction, the reaction that also generation one is important:
2SO
3 2-+O
2→2SO
4 2-(d)
Owing to reacting the generation of (d), improve reaction (a), (b), (c) reaction rate to the right, improve mass transport process, waste gas is made to obtain efficient removal in the bubbling first grade desulfurizing stage, reduce the sea water desulfuration load in two-grade desulfurizing stage, thus reduce the seawater amount needed for spray.Because the desulfurization load of spray phase unit volume seawater is lower, so the edge effect adopting spray mode to produce in the present invention and not obvious.
Restoring sea water system: air is admitted to by the first Aeration fan 3 aeration tube be arranged in bottom desulfurizing tower, promote the carrying out of reaction (d), complete the oxidation of part sulphite in advance, reduce the fresh seawater demand of aeration tank, thus reduce the area occupied of aeration tank.Seawater after one-level Air Exposure is admitted to aeration tank 5 by sea water pump 7, through the dilution of fresh seawater and the aeration of the second Aeration fan 4, completes the recovery process of desulfurization seawater, through pH value monitor 8 detect seawater quality up to standard after can enter ocean.The desulfuration efficiency of the present embodiment can reach more than 95%.
Embodiment 2
Another embodiment system schematic of efficient removal boats and ships oxysulfide method of the present invention as shown in Figure 3, the bubbling mode of the present embodiment adopts coil pipe bubbling as different from Example 1, under coil pipe 62 is all immersed in seawater liquid level, exhaust gas inlet pipeline is vertically arranged, all the other systems are consistent with embodiment 1 with desulfurized step.The desulfuration efficiency of the present embodiment can reach more than 95%.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. the system of an efficient removal marine exhaust sulphur oxide, it is characterized in that: comprise fresh seawater pond (10), aeration tank (5), pre-spray chamber (2), desulfurizing tower (9), described fresh seawater pond (10) respectively with aeration tank (5), pre-spray chamber (2) and desulfurizing tower (9) connect, described pre-spray chamber (2) exports with marine exhaust and is connected, and connect desulfurizing tower (9) by pipeline, desulfurizing tower (9) bottom is seawater bubbling area, gas distribution tube is provided with in it, the bottom of gas distribution tube is connected with the first Aeration fan (3), desulfurizing tower (9) bottom also connects aeration tank (5) by sea water pump (7), bottom, aeration tank (5) is connected with the second Aeration fan (4), the top of desulfurizing tower (9) is also connected with chimney (1).
2. the system of efficient removal marine exhaust sulphur oxide as claimed in claim 1, is characterized in that: be provided with pH value monitor (8) in described aeration tank (5).
3. the system of efficient removal marine exhaust sulphur oxide as claimed in claim 1, is characterized in that: described pre-spray chamber (2) is arranged in the exhaust piping being connected to marine exhaust outlet.
4. the system of efficient removal marine exhaust sulphur oxide as claimed in claim 1, is characterized in that: described gas distribution tube is playpipe (61) or coil pipe (62).
5. the system of efficient removal marine exhaust sulphur oxide as claimed in claim 1, is characterized in that: described fresh seawater pond (10) is connected with the top of desulfurizing tower (9).
6. a method for efficient removal marine exhaust sulphur oxide, is characterized in that: the subtractive process of oxysulfide comprises three phases, i.e. pretreatment stage, bubbling first grade desulfurizing stage and spray two-grade desulfurizing stage, specifically comprise the following steps:
A). be admitted to pre-spray chamber, desulfurizing tower and aeration tank from the fresh seawater in ocean respectively through pipeline;
B). pretreatment stage: the high-temp waste gas utilizing air-introduced machine Ship Power Equipment to be produced sends into pre-spray chamber through pipeline, and fresh seawater sprays waste gas at this;
C). the bubbling first grade desulfurizing stage: evenly to spray into the seawater bubbling area in desulfurizing tower through gas distribution tube through the waste gas of supercooling and pre-desulfurization, in seawater bubbling area, gas-liquid contact is abundant, realizes the efficient first grade desulfurizing of bubbling;
D). the spray two-grade desulfurizing stage: complete the rising passway of waste gas in desulfurizing tower after bubbling first grade desulfurizing and enter spray district, top, contact with the sea water drops after spray atomizing, complete removing further of waste gas sulphur oxide;
E). the waste gas after desulfurization, after being arranged on the demister demist on spray top, district, enters air by ship chimney;
F). the restoring sea water stage: first stage aeration is carried out to the seawater after desulfurization by the aerator be arranged on bottom desulfurizing tower, realize the oxidation of part sulphite, reduce the processing load of outside aeration tank, then the seawater after one-level aeration is sent into aeration tank, in aeration tank, carry out second stage aerating oxidation and seawater dilution, after seawater is up to standard after testing, enter ocean.
7. the method for efficient removal marine exhaust sulphur oxide as claimed in claim 6, is characterized in that: high-temp waste gas is cooled to 60-120 DEG C by described pretreatment stage.
8. the method for efficient removal marine exhaust sulphur oxide as claimed in claim 6, is characterized in that: the bubbling mode in the described bubbling first grade desulfurizing stage is JBR or coil pipe bubbling mode.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108543368A (en) * | 2018-05-09 | 2018-09-18 | 武汉烽火兴业节能环保科技有限公司 | A kind of exhaust gas processing device containing cigarette |
CN109758895A (en) * | 2019-03-18 | 2019-05-17 | 山东交通学院 | A kind of marine exhaust desulfurizer |
CN110496506A (en) * | 2019-07-30 | 2019-11-26 | 上海蓝魂环保科技有限公司 | A kind of ship seawater desulfurization device |
CN112870934A (en) * | 2021-03-01 | 2021-06-01 | 宁波大学 | Novel marine exhaust gas seawater desulfurization method and device |
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CN201880464U (en) * | 2010-11-17 | 2011-06-29 | 东方电气集团东方锅炉股份有限公司 | Seawater desulfurizer |
CN104069702A (en) * | 2014-06-23 | 2014-10-01 | 陈淼 | Efficient desulfurization and dust removal integrated device and dust removing method thereof |
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CN1032493A (en) * | 1987-09-16 | 1989-04-26 | 千代田化工建设株式会社 | Handle the wet desulfurizing process of waste gas |
CN201880464U (en) * | 2010-11-17 | 2011-06-29 | 东方电气集团东方锅炉股份有限公司 | Seawater desulfurizer |
CN104069702A (en) * | 2014-06-23 | 2014-10-01 | 陈淼 | Efficient desulfurization and dust removal integrated device and dust removing method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108543368A (en) * | 2018-05-09 | 2018-09-18 | 武汉烽火兴业节能环保科技有限公司 | A kind of exhaust gas processing device containing cigarette |
CN109758895A (en) * | 2019-03-18 | 2019-05-17 | 山东交通学院 | A kind of marine exhaust desulfurizer |
CN109758895B (en) * | 2019-03-18 | 2019-11-05 | 山东交通学院 | A kind of marine exhaust desulfurizer |
CN110496506A (en) * | 2019-07-30 | 2019-11-26 | 上海蓝魂环保科技有限公司 | A kind of ship seawater desulfurization device |
CN112870934A (en) * | 2021-03-01 | 2021-06-01 | 宁波大学 | Novel marine exhaust gas seawater desulfurization method and device |
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Application publication date: 20151118 |