CN201534792U - Water treatment device for internal circulation film coagulation reactor - Google Patents
Water treatment device for internal circulation film coagulation reactor Download PDFInfo
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- CN201534792U CN201534792U CN200920220453XU CN200920220453U CN201534792U CN 201534792 U CN201534792 U CN 201534792U CN 200920220453X U CN200920220453X U CN 200920220453XU CN 200920220453 U CN200920220453 U CN 200920220453U CN 201534792 U CN201534792 U CN 201534792U
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Abstract
The utility model discloses a water treatment device for an internal circulation film coagulation reactor, and belongs to the field of water treatment. The water treatment device comprises the internal circulation film coagulation reactor; the main body of the internal circulation film coagulation reactor adopts a reaction tank; the reaction tank comprises an upper part and a lower part; an internal circulation cylinder with both the upper and the lower ends open is arranged in the upper part; a film component is mounted in the internal circulation cylinder; a water outlet is formed on the film component, and an aeration tube or an aeration plate is arranged below the film component; and turbulence members are arranged at the upper part of the reaction tank and between the inner wall of the reaction tank and the wall of the internal circulation cylinder. The water treatment device of the utility model can effectively relieve contamination of films in the water treatment device, remove contaminants in water, and has small occupied area, and low construction investment and running cost.
Description
Technical field
The utility model relates to a kind of internal circulating membrane coagulation reactor water treatment device, belongs to water treatment field.
Background technology
Water is Source of life, is one of element indispensable in Economic development, the industrial and agricultural production, also is the human basic substance that exists.In decades, along with the reform and opening-up of China, industrialized developing rapidly, the often below standard water body that just directly enters of the trade effluent of various complicated components and sanitary sewage, cause drinking water source water quality sharply to descend, traditional drink water purifying technology is faced with many challenges.In addition, China is the country of a serious water shortage, and the water resources occupation rate only is 1/4 of a world average level per capita, and the water loss of ten thousand yuan of GDP is higher than international most advanced level far away, and shortage of water resources has had a strong impact on the economic growth and social progress of China at present.Therefore, development of new high-effect drinking-water purification techniques and useless (dirt) water depth treatment technology are for ensureing drinking water safety, improve useless (dirt) ratio of water recycle, reduce the water consumption, promoting society and sustainable economic development to have great importance.
Coagulation is to use a kind of very widely water and wastewater processing technology at present, not only can be used for drink water purifying, and (dirt) water pretreatment or advanced treatment also can be used for giving up.Traditional coagulation process comprises coagulation-precipitation, coagulation-deep-bed filtration and coagulation-air supporting etc., and coagulation can significantly improve precipitation, deep-bed filtration and pneumatically supported separation efficiency.Coagulation generally is divided into mixing and flocculates two stages.Inorganic flocculating agent is in mix stages generation hydrolysis, and with former water in suspended particle and interaction such as colloid, make suspended particle and colloid etc. take off steady and collision, coalescent mutually, form small flco.Flocculation is an important step of reaction that follows mix stages closely, and the small flco that mix stages forms further increases by the effect such as catch of absorption, net under hydraulic action gradually, form satisfy the demand than big flocculating body.Relative flocculation process, mixing process is more complicated, and is also even more important.Therefore, the enhanced coagulation effect should at first be set about from improving mixed effect, can play a multiplier role like this.Hybrid mode at present commonly used comprises that water pump mixes, (machinery) mixes, dividing plate mixes and line-blending (static mixing) etc.Static mixer is used commonplace owing to have good mixing effect, simple to operate, advantage such as floor space is little, energy consumption is low, compact construction and manufacturing are easy for installation in recent years.According to the difference of alr mode, flocculation mainly can be divided into waterpower stirs and the mechanical stirring dual mode, and wherein the former can be divided into reciprocating type dividing plate flocculation, the flocculation of rotary type dividing plate, eddy current type flocculation, grid flocculation, tubular type flocculation and eddy flow flocculation etc. again.The running cost that waterpower stirs is lower, and equipment is simple, convenient operating maintenance, and is more in the application of China.Can significantly reduce flocculation time, save medicament, improve flocculating effect based on technology such as the grid flocculation of micro-vortex theory, the flocculations of eddy flow flow-disturbing, obtain extensive concern in recent years, use increasing.
Membrane technique became drink water purifying and the research of useless (dirt) water depth process field and the hot issue of application in the last few years gradually.Ultrafiltration or micro-filtration can be removed the natural organic matter (NOM) in the water body and the precursor of chlorine disinfection by-product (DBPs) most effectively, to the clearance of turbidity and bacterium near 100%.And the film coagulation reactor technology that membrane sepn and coagulation process are organically combined is an important development direction in useless in recent years (dirt) water treatment and drink water purifying field.Replace the precipitation process in conventional coagulation-depositing technology not only can significantly shorten disengaging time with membrane sepn, reduce floor space; Simultaneously, coagulation can be removed the colloidalmaterial of particle diameter＜5 μ m, pollutes thereby reduce film, improves membrane flux, prolongs the work-ing life of film.In addition, the combination of the two can improve effluent quality greatly, improves the clearance of pollutents such as germ, natural organic matter (NOM), fluorine, phosphorus.Therefore, the film coagulation reactor technology is very extensive in the applied research in fields such as drink water purifying, useless (dirt) water depth processing and reuse.
But, existing film coagulation reactor technology is just with coagulation and membrane sepn simple combination, there is following problem: the detachable membrane coagulation reactor technology that 1. is respectively two separate units for coagulating and membrane sepn, water body is during by the pipeline between the two, what coagulation formed is easy to take place broken phenomenon than big flocculating body, thereby influence the performance of coagulation, and have the bigger problem of plant area area; Place existing integrated film coagulation reactor technology in the reactor fully for coagulating and membrane sepn, because the mix stages of coagulating needs different hydraulics with the flocculation stage, thereby there are mixing or problems such as flocculating effect is undesirable, coagulating agent large usage quantity; The fine flco or the colloid that are easy to cause film to pollute that exist because of coagulation is insufficient simultaneously the phenomenon that concentration increases gradually occurs because of being difficult to effective coagulation, easily cause film to pollute, and influence membrane flux and membrane lifetime.2. for detachable membrane coagulation reactor and existing integrated film coagulation reactor, the flco that coagulation forms all enters the membrane sepn part, and the higher and rising gradually of flco concentration easily causes film to pollute, and influences membrane flux and membrane lifetime.
The utility model content
The utility model provides a kind of internal circulating membrane coagulation reactor water treatment device, its objective is the pollution of alleviating film in the water treatment device, prolongs film work-ing life, improves the removal efficient of the pollutent in the water simultaneously.
Internal circulating membrane coagulation reactor water treatment device of the present utility model, comprise the internal circulating membrane coagulation reactor, it is characterized in that: the main body of described internal circulating membrane coagulation reactor is a reaction tank, described reaction tank is divided into upper and lower two portions, is provided with the internal recycle tube of both ends open up and down in the top; In the described internal recycle tube membrane module is housed, described membrane module is provided with water outlet, and the below of described membrane module is provided with aeration tube or aeration plate; The top of described reaction tank is provided with the flow-disturbing member, and described flow-disturbing member is arranged between the barrel of described reaction tank inwall and described internal recycle tube.
Described internal circulating membrane coagulation reactor water treatment device also can comprise mixing system, water inlet system, medicine system, outlet system, mud discharging system, aerating system and back-purge system; Described mixing system is a static mixer.
Described water inlet system and described medicine system are tightly connected by pipeline and described mixing system; Described mixing system links to each other with described film coagulation reactor sealing by the water-in of pipeline through described film coagulation reactor.
The sphere that is shaped as grizzly bar structure, net structure, hollow out of described flow-disturbing member, hollow out cylindrical etc.
Described membrane module is hollow fiber film assembly or plate type membrane assembly.
Described reaction tank is provided with water-in, aeration opening and mud discharging mouth.
Beneficial effect: internal circulating membrane coagulation reactor water treatment device of the present utility model, Collecting flocculation, precipitation and membrane sepn act on one, can slow down the pollution of film in the water treatment procedure, prolong the work-ing life of film; Use internal circulating membrane coagulation reactor water treatment device treating water of the present utility model, can efficiently remove the pollutent in the water; Internal circulating membrane coagulation reactor water treatment device floor space of the present utility model is little, construction investment and running cost are low.
Description of drawings
Fig. 1 is the synoptic diagram in internal circulating membrane coagulation reactor of the present utility model longitudinal section;
Fig. 2 is the sectional view of Fig. 1 along the A-A direction;
Fig. 3 is the sectional view of Fig. 1 along the B-B direction;
Fig. 4 is the synoptic diagram of internal circulating membrane coagulation reactor water treatment device of the present utility model.
Embodiment
Present embodiment is in conjunction with Fig. 1 to Fig. 4 sets forth in detail internal circulating membrane coagulation reactor of the present utility model water treatment device.
Internal circulating membrane coagulation reactor water treatment device of the present utility model, comprise film coagulation reactor, the main body of film coagulation reactor is a reaction tank 7, and reaction tank 7 is divided into (I), following (II) two portions, main flocculation and two processes of membrane sepn of taking place in top (I) are flocculation-membrane separation zone; Flco gravitational settling and gravity concentration process mainly take place in lower section (II), are the settling region.Internal space, top (I) is provided with internal recycle tube 10, and internal recycle tube 10 is the equal cylinder of complete closed (cross section can be square or rectangle) not in two ends; Internal recycle tube 10 inside are the film separation reaction district, are provided with the membrane module 8 of inner water outlet, and membrane module 8 is hollow fiber film assembly or plate type membrane assembly, and film coagulation reactor of the present utility model by membrane module 8 the membrane sepn effect takes place; Water outlet 22 on the membrane module 8 is in communication with the outside by pipeline, is provided with aeration plate 9 under the membrane module 8, and also available aeration tube substitutes aeration plate 9, and the aeration scope is no more than the inner section scope of internal recycle tube 10; Flocculation reaction takes place in the space between the sidewall of internal recycle tube 10 and reaction tank 7 inwalls, be the flocculation reaction district, flow-disturbing member 23 be housed, flow-disturbing member 23 be shaped as grizzly bar, also can be sphere, hollow out cylindrical etc. of net structure, hollow out, as long as can play the flow-disturbing effect.Flow-disturbing member 23 can be made by materials such as metal, plastics or potteries.The top pool wall of reaction tank 7 is provided with water-in 21 and aeration opening; The lower section pool wall of described reaction tank is provided with mud discharging mouth, also water-in 21, aeration opening and mud discharging mouth can be set on the reaction tank, metallic conduit, and aerated conduit and spoil disposal pipeline can enter reaction tank from the reaction tank top.
Internal circulating membrane coagulation reactor water treatment device of the present utility model, also can comprise water inlet system, medicine system, mixing system, outlet system, mud discharging system, back-purge system and aerating system by above-mentioned film coagulation reactor water treatment device except that comprising.Water inlet system is connected and composed by seal for pipe joints by water tank 1, intake pump 2, under meter 3; Medicine system is connected and composed by seal for pipe joints by dosing tank 4, volume pump 5; Mixing system is made of static mixer 6; Water inlet system and medicine system are tightly connected by pipeline and mixing system; Mixing system is tightly connected by the water-in and the film coagulation reactor of pipeline through film coagulation reactor, water-in 21 is positioned at the top of the film coagulation reactor of film coagulation reactor water treatment device, and the former water that is mixed with coagulating agent tangentially enters the flocculation reaction district of film coagulation reactor; The aeration tube of film coagulation reactor or aeration plate 9 by aerated conduit 24 through the aeration opening air pump 17 that is tightly connected, aerated conduit and aeration opening are tightly connected, aerated conduit 24 is provided with gas meter 16 simultaneously, and aerated conduit 24, air pump 17 and gas meter 16 have constituted aerating system; The water outlet 22 of membrane module 8 by pipeline with go out water pump 13 and be tightly connected, membrane module 8 and the pipeline that goes out between the water pump 13 are provided with valve 12 and vacuum pressure gauge 11.Outlet system mainly by valve 12, vacuum pressure gauge 11, go out water pump 13, valve 20 etc. and form by pipe connection.Go out on the pipeline between water pump 13 and the valve 20 to connect an arm, the other end of this arm is connected on the pipeline between valve 12 and the membrane module 8, and this arm is provided with valve 19, and this arm is the passage of backwashing water.Valve 12 and go out to connect an arm on the pipeline between the water pump 13, this arm is provided with valve 18, and this arm also is the passage of backwashing water.Back-purge system and 22 airtight connections of membrane module water outlet mainly constitute by pipe connection by going out water pump 13, back flush valves 18 and valve 19.During backwash operation, must open back flush valves 18 and valve 19, valve-off 12 and valve 20.And during the normal water outlet of film, then must close back flush valves 18 and valve 19, Open valve 12 and valve 20.The lower section pool wall of reaction tank 7 is provided with shore pipe 15 and mud valve, and the two forms the mud discharging system, utilizes action of gravity to carry out spoil disposal.
Sanitary sewage, municipal effluent or trade effluent with little polluted river water, lake water or qualified discharge are that example is carried out water treatment:
At first Open valve 12, valve 20, back flush valves 18, valve 19 are closed, and open intake pump 2, water pump 13 and air pump 17, adopt continuous aeration mode aeration; Pending former water enters static mixer 6 by water tank 1 through the pump action of intake pump 2, and coagulating agent also enters static mixer 6 via volume pump 5 simultaneously.Dosing coagulant can be removed larger molecular organics, suspended substance, total phosphorus, colourity etc., coagulating agent can select to use at present inorganic coagulant and various composite flocculation agents such as polymerize aluminum chloride, bodied ferric sulfate, Tai-Ace S 150, iron(ic) chloride more widely, also can select materials such as potassium permanganate, Powdered Activated Carbon for use simultaneously; Former water and coagulating agent be mixing and contacting reaction in static mixer 6, tangentially enter the flocculation reaction district of film coagulation reactor subsequently by pipeline, tangentially enter and can form eddy flow, but the micro-vortex enhanced flocculation effect that utilizes the flow-disturbing effect of centrifugal force that eddy flow forms and flow-disturbing member to form.Because the gas lift effect that aeration tube or aeration plate 9 aerations are produced, the water inlet of film coagulation reactor flows downward around 10 rotations of internal recycle tube, in eddy flow process from top to bottom, because the flow-disturbing effect of rubbing effect and flow-disturbing member, swirl velocity reduces gradually, can satisfy the requirement of the flco of continuous increase to hydraulics; Former water after the flocculation reaction upwards flows after the lower port of internal recycle tube 10 enters internal recycle tube 10, enters membrane separation zone, finishes sepn process by film; The former water that does not pass film flows out the back from the upper port of internal recycle tube 10 to be mixed with the former water that is mixed with coagulating agent and is rotated down mobilely, and flocculation reaction further takes place, and so then forms internal recycle.Flocculation reaction district and membrane separation zone are adjacent, and directly link can at utmost avoid generating broken phenomenon takes place than big flocculating body, be beneficial to precipitation and membrane sepn.Bigger and the closely knit flco of the particle diameter that flocculation forms is owing to the effect that can overcome ascending current settles down, thereby can avoid aggravating because of sludge concentration is too high the film pollution; The less flco of particle diameter then enters the flocculation reaction district with ascending current through membrane separation zone, once more flocculation reaction takes place and increases.The settling region is provided with mud valve, regularly carries out spoil disposal according to the mud generation, sludge quantity in the controlling reactor, thus help further decelerating membrane pollution.Because the existence of ascending current and come-up bubble, so-called " dynamic filtration " takes place in former water when flowing through membrane module, thereby can reduce deposition and the absorption on the film surface of flco, especially small flco, reducing film pollutes, alleviate concentration polarization, reduce filtration resistance, thereby improve membrane flux.Because the disturbance of bubble will form small vortex in the former water, be beneficial to the mutual collision and the throwing out of flco.
The film coagulation reactor water treatment system is carried out spoil disposal by 15 pairs of film coagulation reactor water treatment systems of mud valve after operation for some time, and according to the fluctuation situation difference of raw water quality, sludge discharging period is about 1～5 day.Regularly carry out back flushing according to the situation that film pollutes, close outlet valve 12,20 during back flushing, Open valve 18,19 is closed intake pump 2 and air pump 17, opens 13 pairs of membrane modules of water pump 8 and carries out back flushing.
Carry out water treatment according to the method described above, the comparing result of every index of effluent quality and raw water quality is as shown in table 1.
Turbidity measurement is with reference to water and effluent monitoring analytical procedure (the 4th edition) portable turbidimeter method in the table 1; PH measures with reference to water and effluent monitoring analytical procedure (the 4th edition) glass electrode method; TOC measures and adopts total organic carbon analyzer; UV
254By passing through spectrophotometric determination; COD
MnMensuration is with reference to water and effluent monitoring analytical procedure (the 4th edition) acid process; By total phosphorus in ion-chromatographic determination water and the waste water.
Table 1
| Test event | Raw water quality | Effluent quality | Clearance |
| Turbidity (NTU) | 11.3-81 | ＜0.1 | ＞99％ |
| TOC(mg/L) | 5.72-8.57 | 3.29-4.54 | 42％-51％ |
| UV 254(cm -1) | 0.084-0.108 | 0.032-0.045 | 58％-61％ |
| COD Mn(mg/L) | 3.81-4.78 | 1.74-2.25 | 48％-54％ |
| Test event | Raw water quality | Effluent quality | Clearance |
| Total phosphorus (mg/L) | 0.162-0.183 | 0.002-0.003 | 98.4％-98.8％ |
Water treatment device of the present utility model is used in the The above results explanation, can improve the removal efficient of the pollutent in the water.Film coagulation reactor water treatment device of the present utility model can slow down the pollution of film in the water treatment procedure, prolongs the work-ing life of film.When transmembrane pressure was 0.1MPa, the membrane flux that moves after 75 hours still was more than 70% of initial flux, and flux descends comparatively slow, can keep big aquifer yield for a long time.
The above, it only is preferred embodiment of the present utility model, be not that the utility model is done any pro forma restriction, though the utility model discloses as above with preferred embodiment, yet be not in order to limit the utility model, any those skilled in the art, in not breaking away from the technical solutions of the utility model scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, in every case be the content that does not break away from technical solutions of the utility model, according to technical spirit of the present utility model to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solutions of the utility model.
Claims (8)
1. internal circulating membrane coagulation reactor water treatment device, comprise the internal circulating membrane coagulation reactor, it is characterized in that: the main body of described internal circulating membrane coagulation reactor is a reaction tank, and described reaction tank is divided into upper and lower two portions, is provided with the internal recycle tube of both ends open up and down in the top; In the described internal recycle tube membrane module is housed, described membrane module is provided with water outlet, and the below of described membrane module is provided with aeration tube or aeration plate; The top of described reaction tank is provided with the flow-disturbing member, and described flow-disturbing member is arranged between the barrel of described reaction tank inwall and described internal recycle tube.
2. internal circulating membrane coagulation reactor water treatment device according to claim 1 is characterized in that: also comprise mixing system, water inlet system, medicine system, outlet system, mud discharging system, aerating system and back-purge system; Described mixing system is a static mixer.
3. internal circulating membrane coagulation reactor water treatment device according to claim 2 is characterized in that: described water inlet system and described medicine system are tightly connected by pipeline and described mixing system; Described mixing system links to each other with described internal circulating membrane coagulation reactor sealing by the water-in of pipeline through described film coagulation reactor.
4. according to claim 1 or 2 or 3 described internal circulating membrane coagulation reactor water treatment device, it is characterized in that: the sphere that is shaped as grizzly bar structure, net structure, hollow out of described flow-disturbing member or hollow out cylindrical.
5. according to claim 1 or 2 or 3 described internal circulating membrane coagulation reactor water treatment device, it is characterized in that: described membrane module is hollow fiber film assembly or plate type membrane assembly.
6. internal circulating membrane coagulation reactor water treatment device according to claim 4 is characterized in that: described membrane module is hollow fiber film assembly or plate type membrane assembly.
7. internal circulating membrane coagulation reactor water treatment device according to claim 5, it is characterized in that: described reaction tank is provided with water-in, aeration opening and mud discharging mouth.
8. internal circulating membrane coagulation reactor water treatment device according to claim 6, it is characterized in that: described reaction tank is provided with water-in, aeration opening and mud discharging mouth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200920220453XU CN201534792U (en) | 2009-10-28 | 2009-10-28 | Water treatment device for internal circulation film coagulation reactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200920220453XU CN201534792U (en) | 2009-10-28 | 2009-10-28 | Water treatment device for internal circulation film coagulation reactor |
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| Publication Number | Publication Date |
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| CN201534792U true CN201534792U (en) | 2010-07-28 |
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| CN200920220453XU Expired - Fee Related CN201534792U (en) | 2009-10-28 | 2009-10-28 | Water treatment device for internal circulation film coagulation reactor |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102050529A (en) * | 2009-10-28 | 2011-05-11 | 轻工业环境保护研究所 | Immersed water treatment device of inner circulating membrane coagulation reactor |
-
2009
- 2009-10-28 CN CN200920220453XU patent/CN201534792U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102050529A (en) * | 2009-10-28 | 2011-05-11 | 轻工业环境保护研究所 | Immersed water treatment device of inner circulating membrane coagulation reactor |
| CN102050529B (en) * | 2009-10-28 | 2012-09-05 | 轻工业环境保护研究所 | Immersed water treatment device of inner circulating membrane coagulation reactor |
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Granted publication date: 20100728 Termination date: 20121028 |