CN201206108Y - Electro-adsorption desalination system for sewage advanced treatment - Google Patents

Electro-adsorption desalination system for sewage advanced treatment Download PDF

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Publication number
CN201206108Y
CN201206108Y CNU2008200796961U CN200820079696U CN201206108Y CN 201206108 Y CN201206108 Y CN 201206108Y CN U2008200796961 U CNU2008200796961 U CN U2008200796961U CN 200820079696 U CN200820079696 U CN 200820079696U CN 201206108 Y CN201206108 Y CN 201206108Y
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China
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electro
sewage
treatment
water
adsorption demineralization
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CNU2008200796961U
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Chinese (zh)
Inventor
寇彦德
张岩岗
魏涛
杨端
马昕
黄凤旭
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Beijing Shougang International Engineering Technology Co Ltd
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Beijing Shougang International Engineering Technology Co Ltd
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Abstract

The utility model relates to an electro adsorption desalination system for advanced sewage treatment, wherein a desalination facility, which is the main body of the system, has low requirement for the inlet water quality; and sewage only flows between electrodes of modules during the operation process, thereby avoiding the phenomena of fouling, cementing and the like which produced by the direct contact between the sewage and tangible materials, such as film components of the traditional double-film method technology and the like. The electro adsorption desalination system is suitable for advanced sewage desalination treatment and recycling projects in various industries, such as the advanced treatment and recycling for downstream comprehensive sewage in the steel industry, the advanced treatment and recycling for cold rolling sewage, the advanced treatment and recycling for coking sewage, and the advanced sewage treatment and recycling for the petrochemical industry, the electric industry, the food industry and the like. The electro adsorption desalination system has the advantages that the construction investment can be saved, the operation maintenance is reduced, the comprehensive operation cost is reduced, 'zero' emissions of sewage in various industries can be almost realized, the water environment can be better protected, and preferable economic benefit and social benefit can be achieved.

Description

Advanced treatment of wastewater electro-adsorption demineralization system
Technical field
The utility model relates to a kind of advanced treatment of wastewater electro-adsorption demineralization system, the sewage deep desalination that is specially adapted to multiple industry is handled reuse project, as industry advanced treatment of wastewater reuses such as steel industry afterbody composite wastewater advanced treatment and reclamation, advanced treatment and recycle of cold rolling wastewater, coked waste water advanced treatment and reclamation and petrochemical industry, electronics, food etc.
Background technology
The technology that present advanced treatment of wastewater desalination is adopted mostly is two membrane process crafts, be UF+R0, but because UF in this technology and R0 are to coming water pollutant (as oil, heavy metal etc.) responsive especially, come the influence of factors such as water temp instability and leading portion dosing quantitative changeization in addition, make two embrane methods run into many problems in actual applications, stifled serious as dirt, producing water ratio is low, film is changed frequent, failure rate is high, operating performance is very undesirable, cause whole process flow to have some setbacks, the water outlet qualification rate is difficult to guarantee, influence the backwater quality of water system, even destroyed the water balance of full factory of water enterprise, though adopted strict preprocessing means at above situation in actual engineering, operating performance still is difficult to improve.
Summary of the invention
In order to overcome the deficiencies in the prior art, seek more suitable sewage desalination technology, the utility model provides the advanced treatment of wastewater electro-adsorption demineralization system that a kind of flow process is reasonable, control is advanced, treatment effect is good, running cost is low, producing water ratio is stable.Main body desalting facilities in this desalting system is to utilize electrostatic force between the electrode effectively to remove saltiness in the sewage, is different from traditional embrane method technology from ultimate principle, and front end only needs simple pre-treatment.The main body desalting facilities adopts electro-adsorption demineralization, apply voltage at the electrode two ends, water flows through between electrode, in the water charged particle under electrostatic forcing to different electrode generation directional migrations, the a large amount of electrolyte ion of electrostatic double layer absorption that electrode forms, and store certain energy, in case electric field is removed in outage, the ion of absorption will be released in the bulk solution, thereby so realize desalination by the power on/off of control electrode and the recovery and the discharging of bulk solution.
The technical scheme that the utility model adopted is: the electro-adsorption demineralization system comprises that pre-treatment promotes water pump, pretreatment filters, middle water pot, electro-adsorption demineralization module working shaft, regeneration wash-water pump, security personnel's strainer, electro-adsorption demineralization module, cleans facility, the water inlet of electro-adsorption demineralization module, the water outlet of electro-adsorption demineralization module, carbon dioxide process carbon electrode negative pole, carbon dioxide process carbon electrode positive pole; Sewage promotes water pump through pre-treatment and sends into pretreatment filters, and strainer water outlet band is compressed into into middle water pot, is promoted through security personnel's strainer by electro-adsorption demineralization module working shaft and enters the electro-adsorption demineralization module; The strong brine that the electro-adsorption demineralization module produces in desalting process washes regeneration continuously by the regeneration wash-water pump.
The electro-adsorption demineralization module forms electrostatic field planar water intermediate ion by carbon dioxide process carbon electrode negative pole and carbon dioxide process carbon electrode positive pole, thereby realizes desalination, and can realize the cyclic regeneration of electro-adsorption demineralization module.
The beneficial effects of the utility model are: this electro-adsorption demineralization system can carry out the advanced treatment of sewage, the variety of issue of effectively avoiding at present two membrane process crafts to be run into.This system's anti impulsion load height, less demanding to raw water quality, pre-treatment is simpler, and energy consumption is low, do not add any medicament in the operational process, non-secondary pollution, ratio of desalinization are adjustable between 70%-85%, and technology is flexible, running cost is low, the stability of system and safe, operation and easy maintenance can realize multiple industry sewage basic " zero " discharging.
Description of drawings:
Below in conjunction with accompanying drawing embodiment of the present utility model is described further.
Fig. 1 is the system diagram of the utility model embodiment;
Fig. 2 is an electro-adsorption demineralization principle schematic of the present utility model.
Among the figure: 1, pre-treatment promotes water pump, 2, pretreatment filters, 3, middle water pot, 4, electro-adsorption demineralization module working shaft, 5, regeneration wash-water pump, 6, security personnel's strainer, 7, the electro-adsorption demineralization module, 8, clean facility, 9, electro-adsorption demineralization module water inlet, 10, electro-adsorption demineralization module water outlet, 11, the carbon dioxide process carbon electrode negative pole, 12, the carbon dioxide process carbon electrode positive pole.
Embodiment
Before selecting this advanced treatment of wastewater electro-adsorption demineralization system for use, at first by calculating sewage quantity, detecting sewage quality, clear and definite effluent quality requirement etc., to select appropriate pretreatment filter type and electro-adsorption demineralization type of modules etc.Wherein pretreatment filters can be according to pretreatment filters such as the different choice sand filtration that comes the water water yield and water quality, multi-medium filtering, fibre-ball filtrations; The electro-adsorption demineralization module then can be according to different choice single-stage module of coming the water water yield and Inlet and outlet water water quality or twin-stage module, and its desalination rate and the rate of recovery can be regulated at 75%~85%.
As shown in FIG., the shell of pretreatment filters 2 and middle water pot 3 form by carbon steel or Low Alloy Steel Plate processing and manufacturing, inside and outside be coated with antifouling paste; Security personnel's strainer 6 is formed by the stainless material processing and fabricating; The major parts electrode of electro-adsorption demineralization module 7 is made by carbon material, and assembles complete by support and shell; Supporting with it pre-treatment promotes water pump 1, electro-adsorption demineralization module working shaft 4, regeneration wash-water pump 5 and cleans facility 8 and all carry out supporting setting according to treatment scale and flow process; Wherein pre-treatment promotes water pump 1, pretreatment filters 2, intermediate water tank 3, electro-adsorption demineralization module working shaft 4, regeneration wash-water pump 5, security personnel's strainer 6 and cleans facility 8 and is installed on the basis that is formed by concrete casting, and electro-adsorption demineralization module 7 is installed on the general frame that is welded by carbon steel material; Come waterpipe and the middle process pipe that connects to adopt anticorrosion Welded Steel Pipe, in-duct installation; Pipe blow-through can adopt vinyl tube, and pipe support lays; For guaranteeing the normal operation of system, except that above facility, also need supporting electric autocontrol facility and other water tank, pipeline, valve etc.; Plane and elevation combination water flow path direction are optimized layout according to practical situation.
Above structures construction is finished, after being in place, equipment can carry out zero load test run, water-filling debugging and commencement of commercial operation, roughly process is: come sewage to promote water pump 1 through pre-treatment and send into pretreatment filters 2, the removal of macrobead suspended substance and floating matter in this finishes water, to guarantee the long-term continous-stable operation of follow-up electro-adsorption demineralization module, strainer water outlet band is compressed into into middle water pot 3, promote through security personnel's strainer 6 by electro-adsorption demineralization module working shaft 4 again and enter electro-adsorption demineralization module 7, before entering the electro-adsorption demineralization module, 6 pairs of pretreatment filters water outlets of security personnel's strainer carry out secondary filtration, will effectively remove protection electro-adsorption demineralization module through the pollutent of pretreatment filters; The strong brine that the electro-adsorption demineralization module produces in desalting process washes regeneration continuously by regeneration wash-water pump 5; And electro-adsorption demineralization module 7 is cleaned by cleaning facility behind the operation certain hour, to improve the operational efficiency of electro-adsorption demineralization module.
Electro-adsorption demineralization module 7 forms electrostatic field planar water intermediate ion by carbon dioxide process carbon electrode negative pole 11 and carbon dioxide process carbon electrode anodal 12, thereby realizes desalination, and can realize the cyclic regeneration of electro-adsorption demineralization module.
Do not add any medicament in the operational process of electro-adsorption demineralization module, operate fairly simplely, during system regeneration, need not acid-alkali regeneration, only need get final product with the discharge of electrode short circuit and with former water flushing.Its operational process roughly is divided into three steps: workflow, regeneration flow process and blowdown flow process.Workflow: come water to send into the electro-adsorption demineralization module by electro-adsorption demineralization module working shaft 4, deliquescent salt is adsorbed removal in the water, and saltiness and specific conductivity reduce in the water.The regeneration flow process: be exactly the strong brine backwash process of module, be used for the module that water flushing short circuit leaves standstill, make electrode regeneration, the water after the back flushing can be admitted to and store the pond, waits until next cycle blowdown flushing and uses.The blowdown process: its essence of blowdown process is the same with regeneration, it is a backwashing procedures of module, but have any different in the water source, what the blowdown process was used is the water that stores the pond, the dense water after promptly regenerating, and this is an effective water saving process, because do not reach capacity as yet through the dense water after the regeneration, so with the back dense water that the produces wash module once more of regenerating, just saved the water consumption in the flushing process, improved producing water ratio.
Though described embodiment of the present utility model in conjunction with the accompanying drawings, those of ordinary skill in the art can make various distortion or modification in the scope of described claim.

Claims (2)

1, a kind of advanced treatment of wastewater electro-adsorption demineralization system is characterized in that: comprise that pre-treatment promotes water pump (1), pretreatment filters (2), middle water pot (3), electro-adsorption demineralization module working shaft (4), regeneration wash-water pump (5), security personnel's strainer (6), electro-adsorption demineralization module (7), cleans facility (8); Sewage promotes water pump (1) through pre-treatment and sends into pretreatment filters (2), and strainer water outlet band is compressed into into middle water pot (3), is promoted through security personnel's strainers (6) by electro-adsorption demineralization module working shaft (4) and enters electro-adsorption demineralization module (7); The strong brine that the electro-adsorption demineralization module produces in desalting process washes regeneration continuously by regeneration wash-water pump (5).
2, according to the described advanced treatment of wastewater electro-adsorption demineralization of claim 1 system, it is characterized in that: described electro-adsorption demineralization module (7) forms electrostatic field planar water intermediate ion by carbon dioxide process carbon electrode negative pole (11) and carbon dioxide process carbon electrode positive pole (12).
CNU2008200796961U 2008-04-01 2008-04-01 Electro-adsorption desalination system for sewage advanced treatment Expired - Lifetime CN201206108Y (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102001776A (en) * 2010-11-03 2011-04-06 中国华电工程(集团)有限公司 Method and device for recycling organic wastewater with high salinity
CN102010039A (en) * 2010-10-21 2011-04-13 常州爱思特净化设备有限公司 Method and system for desalting and backwashing through electric absorption
CN102701340A (en) * 2012-06-12 2012-10-03 爱思特水务科技有限公司 Electro-adsorption desalting system, regeneration system and corresponding method
CN102874991A (en) * 2012-10-26 2013-01-16 武汉钢铁(集团)公司 Electrochemical combined coking wastewater deep treatment process and equipment thereof
CN103253799A (en) * 2012-02-17 2013-08-21 中冶赛迪工程技术股份有限公司 Steel production wastewater reuse treatment process
CN103864248A (en) * 2012-12-11 2014-06-18 兰州交通大学 Small-scale electro-absorption desalination apparatus
CN104803565A (en) * 2015-05-13 2015-07-29 武汉钢铁(集团)公司 Comprehensive wastewater treatment system for coke making enterprise and treatment and recycle method
CN110885115A (en) * 2019-11-21 2020-03-17 河北涿州京源热电有限责任公司 Processing method and system for improving quality of circulating water of main machine
CN111204904A (en) * 2020-03-12 2020-05-29 生态环境部南京环境科学研究所 Flowing electrode-based wastewater recycling treatment system and treatment method thereof
CN113149159A (en) * 2020-12-29 2021-07-23 北京京能能源技术研究有限责任公司 Reverse osmosis concentrated water recycling treatment system and method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010039A (en) * 2010-10-21 2011-04-13 常州爱思特净化设备有限公司 Method and system for desalting and backwashing through electric absorption
CN102010039B (en) * 2010-10-21 2012-05-02 常州爱思特净化设备有限公司 Method and system for desalting and backwashing through electric absorption
CN102001776A (en) * 2010-11-03 2011-04-06 中国华电工程(集团)有限公司 Method and device for recycling organic wastewater with high salinity
CN102001776B (en) * 2010-11-03 2012-07-11 华电水务工程有限公司 Method and device for recycling organic wastewater with high salinity
CN103253799A (en) * 2012-02-17 2013-08-21 中冶赛迪工程技术股份有限公司 Steel production wastewater reuse treatment process
CN102701340A (en) * 2012-06-12 2012-10-03 爱思特水务科技有限公司 Electro-adsorption desalting system, regeneration system and corresponding method
CN102874991A (en) * 2012-10-26 2013-01-16 武汉钢铁(集团)公司 Electrochemical combined coking wastewater deep treatment process and equipment thereof
CN102874991B (en) * 2012-10-26 2014-06-18 武汉钢铁(集团)公司 Electrochemical combined coking wastewater deep treatment process and equipment thereof
CN103864248A (en) * 2012-12-11 2014-06-18 兰州交通大学 Small-scale electro-absorption desalination apparatus
CN104803565A (en) * 2015-05-13 2015-07-29 武汉钢铁(集团)公司 Comprehensive wastewater treatment system for coke making enterprise and treatment and recycle method
CN110885115A (en) * 2019-11-21 2020-03-17 河北涿州京源热电有限责任公司 Processing method and system for improving quality of circulating water of main machine
CN111204904A (en) * 2020-03-12 2020-05-29 生态环境部南京环境科学研究所 Flowing electrode-based wastewater recycling treatment system and treatment method thereof
CN113149159A (en) * 2020-12-29 2021-07-23 北京京能能源技术研究有限责任公司 Reverse osmosis concentrated water recycling treatment system and method

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