CN201088124Y - Fruit and vegetable decortication and peeling coating device - Google Patents
Fruit and vegetable decortication and peeling coating device Download PDFInfo
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- CN201088124Y CN201088124Y CNU2007200646353U CN200720064635U CN201088124Y CN 201088124 Y CN201088124 Y CN 201088124Y CN U2007200646353 U CNU2007200646353 U CN U2007200646353U CN 200720064635 U CN200720064635 U CN 200720064635U CN 201088124 Y CN201088124 Y CN 201088124Y
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- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title description 3
- 238000000576 coating method Methods 0.000 title description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 86
- 239000011229 interlayer Substances 0.000 claims description 18
- 238000001914 filtration Methods 0.000 claims description 6
- 239000012774 insulation material Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 239000002775 capsule Substances 0.000 abstract description 17
- 241000207199 Citrus Species 0.000 abstract description 12
- 235000020971 citrus fruits Nutrition 0.000 abstract description 12
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 239000002585 base Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 14
- 238000010992 reflux Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920005372 Plexiglas® Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
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- Apparatuses For Bulk Treatment Of Fruits And Vegetables And Apparatuses For Preparing Feeds (AREA)
Abstract
Description
技术领域technical field
本实用新型属于一种食品加工机械,具体涉及一种柑橘等果蔬脱皮、脱囊衣的装置。The utility model belongs to a food processing machine, in particular to a device for peeling and removing capsules of citrus and other fruits and vegetables.
背景技术Background technique
中国是世界柑橘生产大国,2005年种植面积171.4万公顷,居世界首位,产量达1601.95万吨,居世界第二位。柑橘罐头是中国柑橘加工的主导产品,占国际市场的70%以上,是我国柑橘产业在国际市场上最有竞争力的产品。柑橘橘瓣由一层半透明薄膜包裹,这层薄膜就是囊衣。脱囊衣是指在不影响橘瓣果肉的前提下,通过外力作用分解橘瓣囊衣中的原果胶质、纤维素和半纤维素,使橘瓣囊衣崩解,与橘瓣脱离。常采用的外力作用方式主要有酸碱处理和微生物(酶)处理。现有脱除柑橘囊衣的酸碱处理方法主要有:经典酸碱二步法、改良重酸碱二步法、磷酸盐-NaOH一步法及以EDTA或EDTA二钠盐(乙二胺四乙酸或乙二胺四乙酸二钠)为助剂的低碱去囊衣法等,其中以EDTA为助剂的低碱去囊衣法使用较多。经典酸碱二步法的主要工艺为:分瓣后的橘片(橘瓣)在一定浓度的盐酸溶液池中浸泡处理一段时间,然后在一定浓度的氢氧化钠溶液池中处理一段时间,最后用清水流动漂洗一段时间。以EDTA为助剂的低碱去囊衣法的主要工艺为:分瓣后的橘瓣用一定浓度EDTA-Na2和NaOH溶液处理一段时间后,用清水漂洗脱碱,再用一定浓度柠檬酸溶液浸泡处理一段时间,然后用清水漂洗。China is a major producer of citrus in the world. In 2005, the planting area was 1.714 million hectares, ranking first in the world, and the output reached 16.0195 million tons, ranking second in the world. Canned citrus is the leading product of citrus processing in China, accounting for more than 70% of the international market, and is the most competitive product of my country's citrus industry in the international market. The citrus segments are covered by a translucent film called the sac. Decapsulation refers to decomposing the protopectin, cellulose and hemicellulose in the capsule of the capsule by external force without affecting the pulp of the orange section, so that the capsule of the capsule is disintegrated and separated from the capsule. Commonly used external force methods mainly include acid-base treatment and microbial (enzyme) treatment. Existing acid-base treatment methods for removing citrus capsule coat mainly include: classic acid-base two-step method, improved heavy acid-base two-step method, phosphate-NaOH one-step method and EDTA or EDTA disodium salt (ethylenediaminetetraacetic acid or disodium ethylenediaminetetraacetic acid) as the low-alkali decapsulation method of the auxiliary agent, etc., wherein the low-alkali decapsulation method with EDTA as the auxiliary agent is used more. The main process of the classic acid-base two-step method is: the orange slices (orange petals) after the split are soaked in a certain concentration of hydrochloric acid solution pool for a period of time, then treated for a period of time in a certain concentration of sodium hydroxide solution pool, and finally Rinse with running water for a period of time. The main process of the low-alkali decapsulation method with EDTA as an auxiliary agent is: after the split orange petals are treated with a certain concentration of EDTA-Na2 and NaOH solution for a period of time, rinse with water to dealkalize, and then use a certain concentration of citric acid solution. Soak for a while, then rinse with water.
目前,通过酸碱处理方法脱除柑橘等果蔬囊衣一般采用两种处理设备:一种是酸碱池,另一种是酸碱流槽。酸碱流槽是对传统酸碱池的一种自动化改进,是酸碱液在自然落差驱动下带动浸泡在其中的橘瓣或其它果蔬瓣在盘旋流槽中流动。无论是酸碱脱囊衣,还是微生物(酶)法脱囊衣,适当升高处理溶液温度、溶液流动都可以提高囊衣脱除的效率。酸碱池脱囊衣由于没有外力源,酸碱液不流动,脱囊衣的浸泡时间较长,影响了橘瓣等的口感(硬脆度);而酸碱流槽脱囊衣没有装设温控装置,囊衣脱除的效率较低。At present, two types of treatment equipment are generally used to remove the coats of fruits and vegetables such as citrus by acid-base treatment: one is an acid-base pool, and the other is an acid-base launder. The acid-base trough is an automatic improvement of the traditional acid-base pool. Driven by the natural drop, the acid-base liquid drives the soaked orange segments or other fruit and vegetable segments to flow in the spiral trough. Whether it is acid-base decapsulation or microbial (enzyme) decapsulation, appropriately increasing the temperature of the treatment solution and the flow of the solution can improve the efficiency of decapsulation. Because there is no external source of force in the acid-base tank, the acid-base solution does not flow, and the soaking time of the capsule is longer, which affects the taste (hardness and brittleness) of orange petals; and the acid-base launder is not installed. Temperature control device, the efficiency of capsule coat removal is low.
实用新型内容Utility model content
本实用新型所要解决的技术问题是克服上述现有技术的不足,提供一种可以保证处理溶液流动,且可以方便调节溶液温度,以提高柑橘等果蔬皮、囊衣的脱除效率和处理溶液利用率的果蔬脱皮、脱囊衣装置。The technical problem to be solved by the utility model is to overcome the deficiencies of the above-mentioned prior art, provide a method that can ensure the flow of the treatment solution, and can conveniently adjust the temperature of the solution, so as to improve the removal efficiency of citrus and other fruit and vegetable peels and capsules and the utilization of the treatment solution. High-efficiency fruit and vegetable peeling and capsule removal device.
为解决上述技术问题,本实用新型提出的技术方案为:In order to solve the problems of the technologies described above, the technical solution proposed by the utility model is:
一种果蔬脱皮、脱囊衣装置,包括工作槽部件和一台或一台以上的水泵,所述工作槽部件包括外壳和设置于外壳内腔中的环状工作池,外壳与环状工作池之间设有间隙,形成处理溶液的回流槽,所述环状工作池的内、外两侧壁和底板围成环状工作流槽,外侧壁的高度低于内侧壁和外壳的高度,所述环状工作流槽内靠近回流槽的一侧由固定钢板固定有带过滤孔的过滤板,所述过滤板的高度在外侧壁的高度和内侧壁的高度之间,环状工作池的两侧壁和底板均为夹层壁,各夹层壁内的空腔相互连通形成容水腔,且各夹层壁的内壁上设有将容水腔与环状工作流槽连通的进水孔,各台水泵的进水端通过回流管路与回流槽相连通,各台水泵的出水端通过进水管路与容水腔相连通。A fruit and vegetable peeling and capsule-removing device, comprising a working tank part and one or more than one water pump, the working tank part includes a shell and an annular working pool arranged in the inner cavity of the shell, between the shell and the annular working pool There is a gap between them to form a reflux tank for the treatment solution. The inner and outer side walls and the bottom plate of the annular working pool form an annular working flow tank, and the height of the outer side wall is lower than the height of the inner side wall and the shell. The side of the ring-shaped working flow tank close to the return tank is fixed with a filter plate with filter holes by a fixed steel plate. The height of the filter plate is between the height of the outer wall and the height of the inner wall. The two sides of the ring-shaped working pool Both the wall and the bottom plate are interlayer walls, and the cavities in each interlayer wall are connected to each other to form a water chamber, and the inner wall of each interlayer wall is provided with a water inlet hole connecting the water chamber with the annular working flow groove, and each water pump The water inlet end of each water pump is connected with the return tank through the return pipeline, and the water outlet end of each water pump is connected with the water holding chamber through the water inlet pipeline.
所述进水孔的开口沿同一环向设置。The openings of the water inlet holes are arranged along the same ring direction.
所述环状工作流槽内设有与回流槽连通的溢水管。An overflow pipe communicating with the return flow groove is arranged in the annular working flow groove.
所述水泵设有四台,各台水泵所连进水管路的出口均匀布置于容水腔底部。There are four water pumps, and the outlets of the water inlet pipelines connected to each water pump are evenly arranged at the bottom of the water holding chamber.
所述回流槽内装设有加热器。A heater is installed in the reflux tank.
所述回流槽中设有粗滤头,所述粗滤头通过连接管路与回流管路的相通,所述进水管路上装设有精滤器。A coarse filter head is arranged in the return tank, and the coarse filter head communicates with the return pipeline through a connecting pipeline, and a fine filter is installed on the water inlet pipeline.
所述外壳设为夹层,夹层内部填充有保温材料。The outer shell is set as an interlayer, and the interior of the interlayer is filled with thermal insulation materials.
与现有技术相比,本实用新型的优点在于:Compared with the prior art, the utility model has the advantages of:
1、该装置构成了一个整体的循环回路,可以实现处理溶液的循环利用,提高处理溶液的利用率;1. The device constitutes an overall circulation loop, which can realize the recycling of the treatment solution and improve the utilization rate of the treatment solution;
2、通过水泵提供动力,使环状工作池内的处理溶液得到充分搅拌,使柑橘等果蔬的果瓣与处理溶液充分接触,加快处理速度,节省处理时间,提高处理效率;2. The power is provided by the water pump to fully stir the treatment solution in the annular working pool, so that the petals of citrus and other fruits and vegetables can fully contact with the treatment solution, speed up the treatment speed, save treatment time and improve treatment efficiency;
3、四台水泵所连进水管路的出口均匀布置于容水腔底部,连通容水腔与环状工作流槽的进水孔的开口沿同一环向设置,环状工作池内的处理溶液在水泵作用下形成环流,可更加均匀的搅拌处理溶液;3. The outlets of the water inlet pipelines connected to the four pumps are evenly arranged at the bottom of the water chamber, and the openings of the water inlet holes connecting the water chamber and the annular working flow tank are set along the same ring direction, and the treatment solution in the annular working pool is in the Under the action of the water pump, a circulation is formed, which can stir the solution more evenly;
4、在回流槽内装设有加热器,在外壳的夹层内部填充有保温材料,可以使处理溶液保持最佳的处理温度,提高果蔬皮、囊衣脱除效率,减少浸泡时间,提高橘瓣等果蔬的口感(硬脆度);4. A heater is installed in the reflux tank, and the interlayer of the shell is filled with insulation materials, which can keep the treatment solution at the best treatment temperature, improve the removal efficiency of fruit and vegetable skins and capsules, reduce the soaking time, and improve the efficiency of orange petals, etc. The taste of fruits and vegetables (hardness and crispness);
5、在回流槽中设有粗滤头,使被脱除后的果蔬皮、囊衣集中在回流槽中,便于集中清理,在进水管路上装设有精滤器,提高回流溶液的质量。5. There is a coarse filter head in the reflux tank, so that the removed fruit and vegetable skins and capsules are concentrated in the reflux tank, which is convenient for centralized cleaning. A fine filter is installed on the water inlet pipeline to improve the quality of the reflux solution.
附图说明Description of drawings
图1为本实用新型的俯视图;Fig. 1 is the top view of the utility model;
图2为图1的A-A剖视图;Fig. 2 is A-A sectional view of Fig. 1;
图3为图2的B-B剖视图;Fig. 3 is the B-B sectional view of Fig. 2;
图4为本实用新型的左视图;Fig. 4 is the left view of the utility model;
图5为图2的C处局部放大图。FIG. 5 is a partial enlarged view of C in FIG. 2 .
图例说明:illustration:
1、控制装置 2、加热器1.
3、有机玻璃盖 4、粗滤头3. Plexiglass
5、放料口 6、环状工作池5. Discharging
61、容水腔 62、环状工作流槽61.
7、回流槽 8、溢水管7.
9、保温材料 10、外壳9.
11、精滤器 12、水泵11.
13、过滤板 131、固定钢板13. Filter plate 131. Fixed steel plate
132、过滤孔 14、底座132.
15、进水孔 16、进水管路15.
17、回流管路17. Return pipeline
具体实施方式Detailed ways
如图1至图5所示,本实用新型的果蔬脱皮、脱囊衣装置,包括支撑于底座14上的工作槽部件和一台或一台以上的水泵12,机器运转时在工作槽部件上盖有一层有机玻璃盖3,工作槽部件包括外壳10和设置于外壳10内腔中的环状工作池6,外壳10设为夹层,外壳10与环状工作池6之间设有间隙,形成处理溶液的回流槽7,回流槽7内靠近底部装设有两个加热器2,加热器2固定于外壳10上。环状工作池6的内、外两侧壁和底板围成环状工作流槽62,由内侧壁围成一腰形槽,在该腰形槽内以及外壳10的夹层内部填充有保温材料9。外侧壁的高度低于内侧壁和外壳10的高度,环状工作流槽62内靠近回流槽7的一侧由固定钢板131固定有带过滤孔132的过滤板13,过滤板13的高度在外侧壁的高度和内侧壁的高度之间,环状工作流槽62内还设有与回流槽7连通的溢水管8,环状工作池6的两侧壁和底板均为夹层壁,各夹层壁内的空腔相互连通形成容水腔61,且各夹层壁的内壁上设有将容水腔61与环状工作流槽62连通的进水孔15,进水孔15的开口沿同一环向设置。本实施例中水泵12设有四台,各台水泵12的进水端通过回流管路17与回流槽7相连通,各台水泵12的出水端通过进水管路16与容水腔61相连通,各进水管路16的出口均匀布置于容水腔61的底部,进水管路16上靠近水泵12的位置装设有精滤器11,水泵12的启闭通过控制装置1进行控制。在回流槽7的两直线槽段各设有十个粗滤头4,每五个粗滤头4通过一条回流管路17与一台水泵12连通,粗滤头4在回流槽7中的位置、数量以及精滤器11的布置可以视具体情况予以调整。环状工作流槽62中设有通向本装置外部的放料口5。本实施例中的控制装置1可控制加热器2实现自动控温,还可控制各水泵12实现无级变速和步进式启闭,以根据加工工艺的需要对处理溶液的流速、温度进行调节,实现柑橘等果蔬皮、囊衣的全部脱除。As shown in Figures 1 to 5, the fruit and vegetable peeling and bagging device of the present invention includes a working tank part supported on a
下面以对橘瓣进行脱囊衣处理为例,说明本实用新型的工作原理:在环状工作池6和回流槽7内加入水与一定比例的脱囊衣助剂(酸、碱或酶制剂)形成处理溶液,开启加热器2,将溶液温度加热到设定温度后停止加热,控制装置1对水温实时监控,保持溶液恒温。往环状工作流槽62中放入橘瓣,打开水泵12的总开关,四个水泵12在控制装置1的控制下以步进方式逐个开启和关闭,将处理溶液泵送至容水腔61,再经进水孔15注入环状工作流槽62,实现环状工作流槽62的步进式进水,使环状工作流槽62内的处理溶液带动橘瓣作环形流动,流动方向如图2中环状工作池6内的实心箭头方向所示。环状工作流槽62中的处理溶液在流动过程中,一部分通过溢水管8流到回流槽7,流动方向如图3环状工作流槽62中的实心短箭头所示,一部分经过滤板13及过滤孔132外溢到回流槽7,流动方向如图3环状工作流槽62中的实心长箭头所示。回流槽7中收集的处理溶液被粗滤头4过滤,再经回流管路17分别输送至与其连通的各水泵12,水泵12加压后输送到进水管路16上的精滤器11,经精滤器11精滤后回流到容水腔61内,再经进水孔15回流到环状工作流槽62中,形成循环,管路中的水流方向如附图上相应管路中的箭头所示。在水流的外力作用与脱囊衣助剂的作用下,橘瓣囊衣逐渐破裂、脱落,甚至溶解,经粗滤头4过滤后,被脱除、处理掉的囊衣逐渐聚集在回流槽7中,可人工取出。待囊衣全部脱除后,打开放料口5的盖板,将处理溶液、脱囊衣的橘瓣全部放出。处理溶液经处理后可回收再利用。Carrying out the capsule-coating treatment of orange petals below is an example, illustrates the working principle of the present utility model: add water and a certain proportion of capsule-coating auxiliary agent (acid, alkali or enzyme preparation in annular working
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| CNU2007200646353U CN201088124Y (en) | 2007-09-30 | 2007-09-30 | Fruit and vegetable decortication and peeling coating device |
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| CNU2007200646353U Expired - Lifetime CN201088124Y (en) | 2007-09-30 | 2007-09-30 | Fruit and vegetable decortication and peeling coating device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201088124Y (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102429315A (en) * | 2011-11-22 | 2012-05-02 | 浙江省农业科学院 | citrus peeling machine |
| CN103054140A (en) * | 2013-02-08 | 2013-04-24 | 上海绿晟实业有限公司 | Food enzymolysis equipment and operating method thereof |
| CN106174622A (en) * | 2016-08-30 | 2016-12-07 | 江苏楷益智能科技有限公司 | A kind of fruit Deskining Device |
| CN109517924A (en) * | 2019-01-17 | 2019-03-26 | 四川省农业科学院园艺研究所 | A kind of citrus anthocyanin accumulates the molecular detecting method to form red meat character |
| CN114451565A (en) * | 2021-08-05 | 2022-05-10 | 山东鲁海食品有限公司 | A diversion trough for removing citrus fruit capsules |
-
2007
- 2007-09-30 CN CNU2007200646353U patent/CN201088124Y/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102429315A (en) * | 2011-11-22 | 2012-05-02 | 浙江省农业科学院 | citrus peeling machine |
| CN102429315B (en) * | 2011-11-22 | 2013-12-11 | 浙江省农业科学院 | Citrus peeler |
| CN103054140A (en) * | 2013-02-08 | 2013-04-24 | 上海绿晟实业有限公司 | Food enzymolysis equipment and operating method thereof |
| CN106174622A (en) * | 2016-08-30 | 2016-12-07 | 江苏楷益智能科技有限公司 | A kind of fruit Deskining Device |
| CN109517924A (en) * | 2019-01-17 | 2019-03-26 | 四川省农业科学院园艺研究所 | A kind of citrus anthocyanin accumulates the molecular detecting method to form red meat character |
| CN114451565A (en) * | 2021-08-05 | 2022-05-10 | 山东鲁海食品有限公司 | A diversion trough for removing citrus fruit capsules |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: HUNAN CHIC FOODS CO., LTD. Assignor: Hunan Prov. Agricultural Product Processing Inst. Contract fulfillment period: 2008.10.1 to 2015.9.30 Contract record no.: 2008430000042 Denomination of utility model: Fruit and vegetable decortication and peeling coating device Granted publication date: 20080723 License type: Exclusive license Record date: 20081128 |
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| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.10.1 TO 2015.9.30; CHANGE OF CONTRACT Name of requester: HUNAN XIKE FOOD CO., LTD. Effective date: 20081128 |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20080723 |