CN201042665Y - Plasma ionization reaction equipment for both water treatment and oil treatment - Google Patents
Plasma ionization reaction equipment for both water treatment and oil treatment Download PDFInfo
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- CN201042665Y CN201042665Y CNU2007200122146U CN200720012214U CN201042665Y CN 201042665 Y CN201042665 Y CN 201042665Y CN U2007200122146 U CNU2007200122146 U CN U2007200122146U CN 200720012214 U CN200720012214 U CN 200720012214U CN 201042665 Y CN201042665 Y CN 201042665Y
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Abstract
A plasma ionization reaction device for both water and oil treatment is provided, which solves the problems of large power consumption and serious wearing of electrode during sewage or oil treatment. The plasma ionization reaction device for both water and oil treatment is characterized in that a second electrode arranged in the periphery of a first electrode; a first catalytic reaction coating and a second catalytic reaction coating are on the opposite surfaces of the first and second electrodes respectively, the catalytic reaction coating is formed by ordered superposition of a nonmetal insulating layer and a crystalline conductor or formed by either of the nonmetal insulating layer and the crystalline conductor, or either of the catalytic reaction coatings is formed by the nonmetal insulating layer or the crystalline conductor; the first and second electrodes are configured to a plate rectangle; and a third catalytic reaction coating is arranged in the discharge zone between the first and second catalytic reaction coatings. The utility model has the advantages of low power consumption for sewage treatment and waste oil treatment, yield of purified water and fuel oil, minimal wearing of electrode, and long service life of electrode.
Description
Technical field: the invention is to be used to handle waste oil become fuel oil or dispose of sewage the processing water that becomes water purification, the equipment of oil.
Background technology: along with the industry high development; pollution situation to water quality little by little becomes significant problem anxious to be solved, and to this, countries in the world are the protection environment; not only formulate relevant rules and set up management organization, and take the pollution abatement surrounding material and reduce the measure in generation source.However, up to now, use the trend of synthetic detergent still to increase, cause the water quality severe contamination, make the people feel very big worry, though immediate cause obtains the technical development that reduces environmental pollution and improve function, sizable part has removed that people are to the worry of water pollution in the past, and water pollution still becomes subject matter.
Want to make the surface-active lotion of any character not cause water pollution, must send the following water that contains lotion draining to handle and discharge to rivers after the field purifies, but present following water treatment capacity still is faint state, pollutes so inevitable rivers produce.
Therefore, replace synthetic detergent, utilize the what is called of brine electrolysis not have the lotion washing methods and be suggested with the sterilization remover.No lotion washing methods is to use brine electrolysis, utilizes electrolyzed alkaline water can remove the effect of protein and the sterilization of acidic electrolytic water energy.
This no lotion washing methods is being with multiple frequency interchange or direct current, pulse to connect two strip electrodes, destroying the insulation endurance of water, coming decomposition water with consumption electric power.
This method is that Ionized mode has consumption more to many shortcoming of electric power than aquation; When continuing to connect high electric energy in addition the very big shortcoming of wear to electrodes is arranged, so the electric field shakiness, the wearing and tearing of electrode are serious more.
Summary of the invention: when the purpose of the invention provides a kind of disposing of sewage with the dynamical generation alkaline water of low consumption electric power and acid electrolyzed functional water and Ozone Water and when handling oil by stable light emitting discharge, can be oiling low-molecular-weight and the water treatment, oil processing dual-purpose plasma electric that reduce the wearing and tearing of electrode from consersion unit; The purpose of the invention is achieved through the following technical solutions:
Water treatment, oil processing dual-purpose plasma electric are from consersion unit, at equidistant peripheral second electrode of installing of first electrode, equidistant formation water between first electrode and second electrode, oil circuit, be region of discharge, first, second catalytic reaction layer is installed on first electrode, the second electrode forward surface.
The 3rd catalytic reaction layer is installed in the region of discharge.
First, second catalytic reaction layer be by among non-metallic material insulating barrier and the overlapping successively installation of crystallinity electrics layer or non-metallic material insulating barrier and the crystallinity electrics layer one constitute,
First, second catalytic reaction layer is made the Yangtze River Delta, sharp cone distal, dome-type brush needle construction.
In first, second catalytic reaction layer, wherein one deck is to be made of one deck among non-metallic material insulating barrier and the crystallinity electrics layer,
The 3rd catalytic reaction layer is to be made of pellet shapes electricity body or electric conductor,
First, second electrode is made copper axle cylinder shape.
Boss structure or sharp cone distal structure are made in crystallinity electricity surface.
First, second electrode is made dull and stereotyped square type structure.
Install second electrode outside has water or the input port of oil and the consersion unit casing of delivery outlet.
The advantage of the invention: its advantage is when using water treatment, oil processing dual-purpose plasma electric to handle water from consersion unit:
Because being housed, first, second, third catalytic reaction layer maximizes, with the dynamical output alkaline water of low consumption electric power and acid electrolyzed functional water and Ozone Water by discharging efficiency; Because of catalytic reaction layer is arranged, electrode is direct contact water and oil not, minimizes so the wearing and tearing of electrode reduce to, and prolongs electrode life; Plasma electric from discharge in water can eliminate various harmful bacterium, improve the quality of drinking water.
Use water treatment, oil processing dual-purpose plasma electric its advantage when the consersion unit handling oil to be: gasoline, kerosene, machine oil, waste oil etc. are changed to low-molecular-weightization, last, all oil plants and waste oil are become gas, oil acts as a fuel; The discharge form is not corona discharge or electron stream (Streamer) form, and therefore the but plasma ionic discharge form on the stable pipeline can decompose the oils of volume with low consumption electric power; Oil molecule after discharge becomes the combination of the low-molecular-weight hydrocarbon of ionization or activate, in winter automobile is started easily; Low-molecular-weight oil firing produces fume amount and reduces to minimized; Come the rectifying column of separating oil can make and process more senior gas and oil as this equipment being used in by the difference in specific gravity of temperature.Utilize the discharge energy of electricity can produce heating fuel and heating gas with the liquids of animals grease.
Description of drawings:
Fig. 1 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 1 structural representation;
Fig. 2 is the sectional drawing of the I-I line among Fig. 1;
Fig. 3 is the part enlarged drawing of Fig. 2;
Fig. 4 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 1 oblique view;
Fig. 5, the 6th, water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 2 structural representations;
Fig. 7 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 3 structural representations;
Fig. 8 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 4 structural representations;
Fig. 9, the 10th, water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 5 structural representations;
Figure 11 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 6 structural representations;
Figure 12, the 13rd, water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 7 structural representations;
Figure 14, the 15th, water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 8 structural representations;
Figure 16 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 9 structural representations;
Figure 17 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 10 structural representations;
Figure 18 is that water treatment, oil processing dual-purpose plasma electric are from consersion unit embodiment 11 structural representations.
The specific embodiment:,, will do described separately from consersion unit to water treatment and oil processing plasma electric for more easy explanation in conjunction with water treatment, oil processing dual-purpose plasma electric being described from the consersion unit structure from Fig. 1 to Figure 18.
At first, the plasma electric that water treatment is described is from reaction unit: at first electrode, 11 equidistant peripheral second electrodes 15 of installing, equidistant formation water between first electrode and second electrode, oil circuit 19, it is region of discharge, first, second catalytic reaction layer 13,17 is installed on first electrode, the second electrode forward surface is constituted, first, second electrode adopts platinum or silver to make.
The 3rd catalytic reaction layer 21 is installed in region of discharge.
First, second catalytic reaction layer is by non-metallic material insulating barrier 13a, 17a and crystallinity electrics layer 13b, one deck constitutes among the overlapping successively installation of 17b or non-metallic material insulating barrier and the crystallinity electrics layer, the non-metallic material insulating barrier is to adopt glass, quartzy, heat resistant glass, a kind of manufacturing among the ZrO2, the dielectric constant of crystallinity electrics layer from several to hundreds of, adopt TiO2 to make, first, second catalytic reaction layer is made Yangtze River Delta shape, sharp cone distal, dome-type brush needle construction, the 3rd catalytic reaction layer is made of pellet shapes electricity body or electric conductor
In first, second catalytic reaction layer, wherein one deck is to be made of one deck among non-metallic material insulating barrier and the crystallinity electrics layer,
First, second electrode is made copper axle cylinder shape structure.
Boss structure or sharp cone distal structure are made in crystallinity electricity surface.
First, second electrode can also be made dull and stereotyped rectangular configuration.
Input port and delivery outlet consersion unit casing 100 with water or oil is installed in second electrode outside.
Water treatment, oil processing dual-purpose plasma electric form the discharge catalytic layer of tape insulation at least on the electrode in two electrodes in consersion unit embodiment, thereby react the discharging efficiency that maximizes by above-mentioned discharge catalytic, by between electrode and electrode and the whole region of discharge in the water uniform plasma ionized state or plasma electric take place from light, thereby maximize dynamical disposing of sewage.Here, above-mentioned discharge catalytic layer can be the non-metallic material insulating barrier on a complete insulating electrode surface and crystallinity electrics layer laminar structure in order, also can be the single layer structure of non-metallic material insulating barrier or crystallinity electrics layer.And the above-mentioned discharge catalytic layer outstanding form in surface such as Yangtze River Delta shape, pointed cone type, dome-type brush pin preferably.The outstanding position contact-making surface that can make above-mentioned discharge catalytic layer like this is to electrode, and therefore the discharge that the electronics that produces in the outstanding position is spread towards periphery along the surface can solve the electric field concentration problem that part takes place.Compare with original electric discharge between electrodes, can minimize the wearing and tearing of electrode.And the special-purpose plasma electric of the water treatment of this programme can be copper axle cylinder shape or dull and stereotyped rectangle from reaction unit.On the one hand, above-mentioned insulating barrier is that dielectric constant is a complete insulator of counting to the non-metallic material of hundreds of degree, and the material of glass, quartz, heat resistant glass and ZrO2 series is more suitable, and above-mentioned crystallinity electrics layer is fit to use TiO2.So at least one electrode in two electrodes is insulated fully with insulating barrier, above-mentioned crystallinity electrics layer causes the stream discharge of electricity when electrifying electrodes is pressed, and to the intergranular direction of an electric field generation of each the electric body that constitutes above-mentioned crystallinity electrics layer part electric field, the therefore wear to electrodes that more is easy to generate the ionization of water ionic medium and has the electric field inequality between the electrode to cause.
Electrode above form catalytic reaction layer from reaction unit at least one of two electrodes with plasma electric according to the discharge in water of other embodiment of this programme, form another catalytic reaction layer that constitutes by pellet shapes electricity body or electric conductor between two electrodes, catalytic reaction by above-mentioned discharge catalytic layer reaches the maximization discharging efficiency, be whole uniform plasma ionized state or the plasma electric of taking place in electrode and electric discharge between electrodes zone from light, the efficient thereby the maximization unit energy is disposed of sewage.So between two electrodes, form pellet shapes electricity body or electric conductor, can produce triple point 1 and the concentrated increase that causes electric-field intensity of electric field between air, catalytic reaction, pellet shapes electricity body or electric conductor when energising is pressed behind the air or oxygen of input minute bubbles form in reaction unit, therefore stronger discharge can take place.Be more detailed description below.
The 1st embodiment:
Fig. 1 and 2 is according to the water treatment plasma electric of first embodiment of this programme diagram from reaction unit, Fig. 1 is Facad structure figure, Fig. 2 is according to the sectional drawing of I-I line among Fig. 1, Fig. 3 is the part enlarged drawing of Fig. 2, and Fig. 4 is according to the water treatment of first embodiment oblique view of plasma electric from reaction unit.Is copper axle inflator shape according to the special-purpose plasma electric of the water treatment of the 1st embodiment of this programme on the whole from reaction unit.As shown in Figure 1, by inflator shape first electrode 11, form non-metallic material insulating barrier 13a and crystallinity electrics layer 13b first catalytic reaction layer 13 of lamination in order along the outer cylinder of first electrode 11, second electrode 15 that keeps predetermined distances and form with above-mentioned first catalytic reaction layer 13 round above-mentioned first catalytic reaction layer 13, along the inner cylinder of above-mentioned second electrode 15 form non-metallic material insulating barrier 17a and crystallinity electrics layer 17b in order second catalytic reaction layer 17 of lamination constitute, wherein the interval between first catalytic reaction layer 13 and second catalytic reaction layer 17 becomes water route 19, above-mentioned non-metallic material insulating barrier 13a, 17a is a glass, quartzy, heat resistant glass, the complete insulator of pore-frees such as ZrO2, the crystallinity electrics layer 13b of lamination on the above-mentioned insulating barrier, 17b is fit to use TiO2.The material of above-mentioned first electrode 11 and second electrode 15 is platinum (Pt), can connect the interchange of direct current or multiple frequency or direct current, pulse voltage, is fit to connect the above medium frequency once-through type pulse of hundreds of MHz.Owing on the surface of first electrode 11 of reaction unit and second electrode 15, respectively form first, second catalytic reaction layer 13,17 of non-metallic material insulator 13a, 17a and crystallinity electrics layer 13b, 17b and lamination form with plasma electric according to the first embodiment water treatment of this programme.When therefore connecting above-mentioned direct current, pulse, above-mentioned first, the inside of second catalytic reaction layer 13,17 and surface temperature rise, produce blue plasma electric from light, therefore, form during discharge and discharge differently according to the heat of the conductive characteristic of water,, obtain high efficiency alkaline water and acid electrolyzed functional water and Ozone Water with low current according to the stable discharging of high electric field and low current.That is to say, with only exist the original situation of water to compare between first electrode 11 and second electrode 15, respectively form first catalytic reaction layer 13 and second catalytic reaction layer 17 by surface at first electrode 11 and second electrode 15, easier formation electric field in water, and the moment connection electric field stronger than hydrone, therefore can obtain high efficiency alkaline water and acid electrolyzed functional water and Ozone Water.Moreover, different with the heat discharge, have the stability in discharge of high electric field low current.Therefore can connect reliability and the accuracy that can control discharge condition drives reaction unit safely.Because first electrode 11 does not directly contact with water with second electrode 15, therefore can minimize the wearing and tearing of electrode.The enlarged drawing of Fig. 3 is the form that constitutes first catalytic reaction layer 13 and second catalytic reaction layer, 17 non-metallic material insulating barrier 13a, 17a and crystallinity electrics layer 13b, 17b.
The 2nd embodiment:
Second embodiment of this programme is the distortion of first embodiment, forms first, second catalytic reaction layer 13,17 of non-metallic material insulator 13a, 17a and crystallinity electrics layer 13b, 17b and lamination form on above-mentioned first electrode 11 and second electrode 15.Second embodiment of this programme is the catalytic reaction layer that forms non-metallic material insulating barrier and crystallinity electrics layer lamination in two electrodes on some electrodes, forms the individual layer catalytic reaction layer that is made of crystallinity electricity body on another electrode.As shown in Figure 5, form non-metallic material insulating barrier 13a and crystallinity electrics layer 13b first catalytic reaction layer 13 of lamination form in order on first electrode 11, form second catalytic reaction layer 17 that constitutes by crystallinity electrics layer 17b on second electrode 15, as shown in Figure 6, form on first electrode 11 individual layer first catalytic reaction layer 13 that constitutes by crystallinity electrics layer 13b, on second electrode 15, form nonmetal insulating barrier 17a and crystallinity electrics layer 17b second catalytic reaction layer 17 of lamination form in order.At this moment, above-mentioned non-metallic material insulating barrier 13a, 17a are fit to use glass, quartz, heat resistant glass and ZrO2, and above-mentioned crystallinity electrics layer 13b, 17b are fit to use TiO2.If do not form the non-metallic material insulating barrier on each electrode, and when directly forming crystallinity electricity body, for fear of directly contacting with water, the electric body of above-mentioned crystallinity does not have pore.Discharge is easier can use any electric body material that has boss structure or have the sharp cone distal sample in order to make.
The 3rd embodiment:
The 3rd embodiment of this programme is that catalytic reaction layer only constitutes example by complete insulator.Promptly as shown in Figure 7, by inflator shape first electrode 11, form non-metallic material insulating barrier 13a and crystallinity electrics layer 13b first catalytic reaction layer 13 of lamination in order along the outer cylinder of first electrode 11, second electrode 15 that keeps predetermined distances and form with above-mentioned first catalytic reaction layer 13 round above-mentioned first catalytic reaction layer 13, along the inner cylinder of above-mentioned second electrode 15 form non-metallic material insulating barrier 17a and crystallinity electrics layer 17b in order second catalytic reaction layer 17 of lamination constitute, in this above-mentioned formation first, second catalytic reaction layer 13,17 insulating barrier 13a, 17a is a glass, quartzy, the complete insulator of heat resistant glass and ZrO2 non-metallic material.
And though do not illustrate, the catalytic reaction layer that is made of non-metallic material insulating barrier 13a, 17a can form on any one electrode in first electrode 11 and second electrode 15.
Promptly can on first electrode 11, only form first catalytic reaction layer 13 that constitutes by non-metallic material insulating barrier 13a, perhaps only form second catalytic reaction layer 17 that constitutes by non-metallic material insulating barrier 17a in the inner cylinder of second electrode 15.
The 4th embodiment:
The 4th embodiment of this programme and foregoing the 3rd embodiment are relatively, catalytic reaction layer is made of the crystallinity electrics layer, promptly the catalytic reaction layer of the 3rd embodiment is made of complete insulators of non-metallic material such as glass, quartz, heat resistant glass and ZrO2, and the 4th embodiment of this programme directly contacts with water for fear of electrode, does not have pore.Discharge is easier can use any electric body material with boss structure or sharp cone distal sample in order to make.Say again, as shown in Figure 8, first catalytic reaction layer 13 that constitutes by crystallinity electrics layer 13b that forms from reaction unit inflator shape first electrode 11, along the outer cylinder of first electrode 11 with plasma electric according to the discharge in water of the 4th embodiment of this programme, keep predetermined distances and second electrode 15 that forms round above-mentioned first catalytic reaction layer 13, form and form with above-mentioned first catalytic reaction layer 13 by second catalytic reaction layer 17 that crystallinity electrics layer 17b constitutes along the inner cylinder of above-mentioned second electrode 15.Wherein above-mentioned the first, the second catalytic reaction layer 13,17 directly contacts with first, second electrode 11,15 for the water that prevents water route 19, does not therefore possess gas porosity.Discharge is easier can use any electric body material with boss structure or sharp cone distal sample in order to make.And though do not illustrate, the catalytic reaction layer that crystallinity electricity body constitutes can form on some electrodes in first, second electrode 11,15, can not form the catalytic reaction layer structure on another electrode.Promptly, only on first electrode 11, form first catalytic reaction layer 13 of the individual layer that constitutes by crystallinity electrics layer 13b, the medial surface of second electrode 15 forms catalytic reaction layer, or first form catalytic reaction layer on the electrode 11, can be at individual layer second catalytic reaction layer 17 that is made of crystallinity electrics layer 17b along the inner cylinder of second electrode 15 and form.
The 5th embodiment:
Is in two electrodes some electrode on to form non-metallic material insulating barrier and the crystallinity electrics layer in order catalytic reaction layer of lamination with plasma electric from reaction unit according to the discharge in water of the 5th embodiment of this programme, forms by the individual layer catalytic reaction layer on another electrode.Promptly, as shown in Figure 9, comprise inflator shape first electrode 11, along the outer cylinder of above-mentioned first electrode 11 form by non-metallic material insulating barrier 13a and crystallinity electrics layer 13b in order lamination first catalytic reaction layer 13, keep second catalytic reaction layer 17 that predetermined distances form, form with above-mentioned first catalytic reaction layer 13 by second catalytic reaction layer 17 that constitutes along the inner cylinder of above-mentioned second electrode 15 and towards the non-metallic material insulating barrier 17a that first catalytic reaction layer 13 forms.And, as shown in figure 10, form first catalytic reaction layer 13 by non-metallic material insulating barrier 13a, by non-metallic material insulating barrier 17a and crystallinity electrics layer 17b in order the form of lamination form second catalytic reaction layer 17.In addition, all people with the general knowledge in this field can give prominence to multiple example.Describe form the electrics layer of pellet shapes or various example of conductor construction in the water route below.
The 6th embodiment:
The 6th embodiment of this programme is electric body or the conductor construction that adds pellet shapes on the water route, use plasma electric from reaction unit from the discharge in water of the first above-mentioned example structure, added the 3rd catalytic reaction layer that constitutes by pellet shapes electricity body or electric conductor between first catalytic reaction layer and second catalytic reaction layer on the water route in flowing water zone.Promptly, as shown in figure 11, comprise inflator shape first electrode 11, form non-metallic material insulating barrier 13a and crystallinity electrics layer 13b first catalytic reaction layer 13 of lamination in order along the outer cylinder of above-mentioned first electrode 11, second electrode 15 that keeps predetermined distances and form with above-mentioned first catalytic reaction layer 13 round above-mentioned first catalytic reaction layer 13, form non-metallic material insulating barrier 17a and crystallinity electrics layer 17b second catalytic reaction layer 17 of lamination in order along the inner cylinder of above-mentioned second electrode 15, added the 3rd catalytic reaction layer 21 that constitutes by pellet shapes electricity body or electric conductor between above-mentioned first catalytic reaction layer and second catalytic reaction layer on the water route 19 in flowing water zone and formed.So carry water route 19 when forming the 3rd catalytic reaction layer 21 that is made of pellet shapes electricity body or electric conductor, compare with the discharge in water of only water being used as medium, it is tens of to more than thousands of times that the part electric-field intensity of connecting in water reaches.Therefore compare the ionization aspect and the unit interval output of water, just can know to obtain alkaline water and acid electrolyzed functional water and Ozone Water with consumption electric power still less.And, along with the formation of the first, the second catalytic reaction layer 13,17 and the 3rd catalytic reaction layer 21, produce plasma electric in the reaction unit from light.At this moment the plasma ionizing energy that the ultraviolet ray of Chan Shenging helps in the water is handled the Escherichia coli in the water, the processing that white is read multiple harmful bacterium such as coccus together, therefore can improve the quality of drinking water.And non-metallic material insulating barrier 13a, 17a can make first electrode 11 and second electrode 15 isolate fully with water, therefore can minimize the wearing and tearing and long-time repeated use of electrode.
The 7th embodiment:
The 7th embodiment of this programme is the distortion of above-mentioned the 6th embodiment, it is very similar using the 3rd catalytic reaction layer 21 that is made of pellet shapes electricity body on water route 19, but difference is that at least one is to be made of nonmetal insulating barrier in first catalytic reaction layer 13 and second catalytic reaction layer 17.Promptly, as shown in figure 12, first catalytic reaction layer 13 is non-metallic material insulating barrier 13a and crystallinity electrics layer 13b forms of lamination in order, second catalytic reaction layer 17 that forms on second electrode 15 can only be made of non-metallic material insulating barrier 17a, in contrast, as shown in figure 13, first catalytic reaction layer 13 can only be made of non-metallic material insulating barrier 13a, and second catalytic reaction layer 17 is non-metallic material insulating barrier 17a and crystallinity electrics layer 17b lamination morphotic in order.
The 8th embodiment:
The 8th embodiment of this programme also is the distortion of the 7th embodiment, as shown in figure 14, first catalytic reaction layer 13 is to be made of crystallinity electrics layer 13b, and second catalytic reaction layer 17 is by nonmetal insulating barrier 17a and the crystallinity electrics layer 17b form that constitutes of lamination in order.As shown in figure 15, first catalytic reaction layer 13 is by non-metallic material insulating barrier 13a and the crystallinity electrics layer 13b form that constitutes of lamination in order, second catalytic reaction layer 17 can only be made of crystallinity electrics layer 17b, here ought not form above-mentioned non-metallic material insulating barrier, and when directly on electrode, forming the crystallinity electrics layer, directly contact with water for fear of electrode, the crystallinity of submitting a written statement to a higher authority electrics layer does not have pore.For the discharging efficiency that maximizes, preferably use electric body with boss structure or sharp cone distal sample.Though diagram form the catalytic reaction layer that is made of non-metallic material insulating barrier or crystallinity electrics layer in first electrode 11 and second electrode 15 at least on some electrodes, and another does not form catalytic reaction layer.Form the catalytic reaction layer that constitutes by pellet shapes electricity body or electric conductor obviously on the water route 19.So, according to how being combined in the catalytic reaction layer material that forms on two electrodes or each electrode, can select more embodiments, the professional person can easily implement.
The 9th embodiment:
The 9th embodiment of this programme compares with front narration embodiment, it is characterized in that having used dull and stereotyped square rectangular electrode.Narration embodiment in front is cylinder shape first electrode and the block-head cylinder form that forms catalytic reaction layer around the inner cylinder of the outer cylinder of second electrode of first electrode, first electrode and second electrode.But first electrode 11 and second electrode 15 of the 9th embodiment of this programme are not cylinder shapes, but platform plate type structure.Promptly, as shown in figure 16, comprise at regular intervals first electrode 11 that is provided with in opposite directions and second electrode 15, at surperficial non-metallic material insulating barrier 13a, the 17a of above-mentioned first electrode 11 and second electrode 15 and crystallinity electrics layer 13b, 17b the first, the second catalytic reaction layer 13,17 that forms of lamination and forming in order.The 9th embodiment according to this programme, because above-mentioned first, second electrode, 11,15 surfaces respectively form first, second catalytic reaction layer 13,17, therefore the first, the second catalytic reaction layer, 13,17 inside and surface field intensity rise when interchange of connecting direct current or multiple frequency or dc pulse voltage, thereby blue plasma electric take place from light, what therefore produce is not the heat discharge that utilizes the electric conductivity of water, but utilizes the stabilized plasma ionization of high electric field earth-current.And obtain high efficiency alkaline water and acid electrolyzed functional water and Ozone Water with electric power still less.Among the 9th embodiment of this programme, embodiment can be combined in the catalytic reaction layer that electrode surface forms in a variety of forms as previously described.According to the catalytic reaction layer structure on each electrode, can select multiple example.
The 10th embodiment:
In the 10th embodiment of this programme and the comparison of the 6th embodiment, can readily appreciate that this is dull and stereotyped rectangle rather than cylinder shape.Except the electrode structure difference, as 19 forming the 3rd catalytic reaction layer 21 that constitutes by pellet shapes electricity body or electric conductor to wait on each electrode catalytic reaction layer structure and front to narrate example structure identical in the water route.Promptly, as shown in figure 17, the 3rd catalytic reaction layer 21 that comprises dull and stereotyped rectangle second electrode 15 that is provided with in opposite directions at regular intervals with dull and stereotyped rectangle first electrode 11 and above-mentioned first electrode 11, on the space-water route 19 between each first catalytic reaction layer 13 that forms of the surface of above-mentioned first electrode 11 and second electrode 15 and second catalytic reaction layer 17, above-mentioned first catalytic reaction layer, 13, the second catalytic reaction layers 17, forms and constitute by pellet shapes electricity body or electric conductor and forming.At this moment, above-mentioned first, second catalytic reaction layer 13,17 can by non-metallic material insulating barrier 13a, 17a and crystallinity electrics layer 13b, 17b in order form and non-metallic material insulating barrier 13a, the 17a such as glass, quartz, heat resistant glass and ZrO2 of lamination form, also can only form by crystallinity electrics layer 13b, 17b.When only forming catalytic reaction layer, directly contact, do not have gas porosity with water for fear of the first, the second electrode 11,15 with above-mentioned crystallinity electricity body.In order to make discharge easier, preferably use the surface to have the crystallinity electricity body material of boss structure or sharp cone distal sample.The 10th embodiment according to this programme, when forming the 3rd catalytic reaction layer 21 that constitutes by pellet shapes electricity body or electric conductor on the water route 19, there is the situation of water that bigger electric-field intensity takes place in water than only, therefore uses consumption electric power still less to produce alkaline water and acid electrolyzed functional water and Ozone Water.The plasma electric that produces can be handled the Escherichia coli in the water, the processing that white is read multiple harmful bacterium such as coccus from light, therefore can improve the quality of drinking water.Moreover first electrode 11 and second electrode 15 are isolated fully with water, therefore can minimize the wearing and tearing and long-time repeated use of electrode.Though diagram can not selected various example by assembly catalyze conversion zone structure and layout form.The description of this and the 6th embodiment that narrates previously sees, except the electrode structure difference, and catalytic reaction layer structure and arrange that form can use simultaneously.Do some annotated words, also can use honeycomb structure as shown in figure 18.Promptly as shown in the figure, arrange a plurality of dull and stereotyped rectangular electrode 101a, 101b, 101c at regular intervals, form cancellated catalytic reaction layer 103 between each electrode, by the water route, 105 one-tenth water routes of pore of above-mentioned network structure definition.Have water or the input port of oil and the consersion unit fuselage 100 of delivery outlet in the installation of second electrode outside.At this moment, can on above-mentioned water route, form pellet shapes electricity body or electric conductor.
The 11st embodiment according to this programme, when on above-mentioned electrode 101a, 101b, 101c, connecting the interchange of direct current or multiple frequency or dc pulse voltage, interface portion generation highfield at catalytic reaction layer 103 and water is concentrated, thereby produce the ionization of water plasma discharging, therefore more effectively produce alkaline water and acid electrolyzed functional water and Ozone Water.And, when in pore 105, forming pellet shapes electricity body or electric conductor, can under lower voltage, produce and put a little, therefore can maximize and put point efficiency.Since discharge have stable than Hot plasma electric from flash-over characteristic, therefore very safe and have very high reliability and an accuracy to putting a little control.
More than be to of the explanation of the special-purpose plasma electric of water treatment, the following describes the special-purpose plasma electric of oil processing from reaction unit from reaction unit.
At first the special-purpose plasma electric of the oil processing of this programme is identical with before discharge in water plasma electric description architecture in a plurality of embodiment of reaction unit from reaction unit.Have only that discharge medium is the difference of water or oil (Oil) between electrode and the electrode, therefore the following describes omission to discharge in water with plasma electric from the explanation of reaction unit structure, be that the center describes by the reacting phenomenon of each embodiment.
Discharge is to make oils low-molecular-weightizations such as gasoline, kerosene, machine oil, oils product and the waste oil that finally gasifies all with plasma electric from the purpose of reaction unit in the oil of this programme.And wait by gasification gasoline, kerosene, machine oil, waste oil and to be used for starting and the fuel of warming oneself of automobile, the oil processing that machine oil and kerosene is treated to this programme can be handled gasoline car with plasma electric when the reaction unit, by improve the output that oil minimizes (Shoot) and coal smoke with low-molecular-weight.Make the molecular structure of oil become the low-molecular-weight hydrocarbon of strong ionization or strong activate by electric energy, therefore also be easy to start up the car in winter.
In as Fig. 1 structure, electric surface electric-field intensity rises the oil processing usefulness plasma electric of this programme, thereby produces blue plasma electric from light from reaction unit.And when putting, oily inside is not unstable electron stream (Streamer) property discharge form, but stable plasma discharging ionized state minimizes consumption electric power by high electric field, low current type discharge form.And, therefore can minimize the wearing and tearing of electrode owing to the insulator guard electrode, can semi-permanently reuse.Can do explanation to the form of electrode later on, electrode can be twine (Mesh) face, multiplets, multiple Needles form.When using the electrode beyond the face shape electrode at that time, the vibrations that electrode resonance causes when being designed to discharge are little, make radius of curvature littleization of trying one's best.
Be that the oil processing plasma electric of this programme can form the 3rd catalytic reaction layer 21 that is made of pellet shapes electricity body from reaction unit as Figure 11 on oil circuit.Promptly, surface at first, second electrode 11,15 forms first, second catalytic reaction layer 13,17 that is made of non-metallic material insulating barrier 13a, 17a and crystallinity electrics layer 13b, 17b, and the 3rd catalytic reaction layer 21 that formation is made of pellet shapes electricity body or electric conductor on oil circuit, compare with only oil being used as to discharge in the oil of medium, it is tens of to more than thousands of times that the part electric-field intensity of connecting in oil reaches.Therefore relatively more oily ionization aspect and unit interval converted quantity just can be known to produce hydrogen and carbon coal gas more.And can produce plasma electric from light, the ultraviolet ray of generation and the plasma ionizing energy in the oil help the boundary of oil, reduce discharge inception voltage by form pellet shapes electricity body or electric conductor on oil circuit.On the other hand, the oil processing plasma electric of this programme can be made dull and stereotyped rectangle to electrode structure as the 9th example structure of narrating previously from reaction unit.Dull and stereotyped rectangle shown in Figure 17 be can make, pellet shapes electricity body or electric conductor also can be formed on the oil circuit.And, can make honeycomb structure as shown in figure 18.So, the oil processing plasma electric of this programme from reaction unit and the water treatment narrated previously with each embodiment of plasma ionization device in structure identical.As the explanation of doing above, the water treatment of this programme, oil processing dual-purpose plasma electric from reaction unit or oil processing easy with discharge in water easily or plasma electric identical from the reaction unit structure.But, in order to discharge, on the electrode of connecting voltage, formed the catalytic reaction layer that complete insulating barrier and crystallinity electrics layer by non-metallic material constitute.Form the another kind of catalytic reaction layer of bead form on water route or the oil circuit, therefore can reduce discharge inception voltage.And can be under low consumption electric power, obtain more alkaline water and acid electrolyzed functional water and Ozone Water during the water discharge, obtain more carburetted hydrogen gas, hydrogen and carbon coal gas during the oil discharge.
This equipment is used in the processing wash water, and alternative to pesticide improves acid soil property, eliminates virus, in and chemical waste such as phenol; Be used in decomposition, purification, in and industry sewage such as household water filter, animal husbandry sewage, swimming pool, water purifying tank; By the gaseous fuelization of various oils and waste oil, use during this device processes oil as the energy.
Claims (10)
1. water treatment, oil processing dual-purpose plasma electric are from consersion unit, it is characterized in that at equidistant peripheral second electrode of installing of first electrode, equidistant formation water between first electrode and second electrode, oil circuit, be region of discharge, first, second catalytic reaction layer is installed on first electrode, the second electrode forward surface.
2. water treatment according to claim 1, oil processing dual-purpose plasma electric is characterized in that from consersion unit: the 3rd catalytic reaction layer is installed in the region of discharge.
3. water treatment according to claim 1, oil processing dual-purpose plasma electric are from consersion unit, it is characterized in that: first, second catalytic reaction layer be by among non-metallic material insulating barrier and the overlapping successively installation of crystallinity electrics layer or non-metallic material insulating barrier and the crystallinity electrics layer one constitute
4. water treatment according to claim 1, oil processing dual-purpose plasma electric are from consersion unit, and it is characterized in that: first, second catalytic reaction layer is made the Yangtze River Delta, sharp cone distal, dome-type brush needle construction.
5. water treatment according to claim 1, oil processing dual-purpose plasma electric is characterized in that from consersion unit: in first, second catalytic reaction layer, wherein one deck is to be made of one deck among non-metallic material insulating barrier and the crystallinity electrics layer,
6. water treatment according to claim 2, oil processing dual-purpose plasma electric is characterized in that from consersion unit: the 3rd catalytic reaction layer is to be made of pellet shapes electricity body or electric conductor,
7. water treatment according to claim 1, oil processing dual-purpose plasma electric is characterized in that from consersion unit: first, second electrode is made coaxial cylinder shape.
8. water treatment according to claim 3, oil processing dual-purpose plasma electric is characterized in that from consersion unit: boss structure or sharp cone distal structure are made in crystallinity electricity surface.
According to claim 1,2 described water treatments, oil processing dual-purpose plasma electric from consersion unit, it is characterized in that: first, second electrode is made dull and stereotyped square type structure.
10. water treatment according to claim 1, oil processing dual-purpose plasma electric is characterized in that from consersion unit: install second electrode outside has water or the input port of oil and the consersion unit casing of delivery outlet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2007200122146U CN201042665Y (en) | 2007-05-22 | 2007-05-22 | Plasma ionization reaction equipment for both water treatment and oil treatment |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2007200122146U CN201042665Y (en) | 2007-05-22 | 2007-05-22 | Plasma ionization reaction equipment for both water treatment and oil treatment |
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| CN201042665Y true CN201042665Y (en) | 2008-04-02 |
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| CNU2007200122146U Expired - Fee Related CN201042665Y (en) | 2007-05-22 | 2007-05-22 | Plasma ionization reaction equipment for both water treatment and oil treatment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105449117A (en) * | 2015-12-30 | 2016-03-30 | 昆山工研院新型平板显示技术中心有限公司 | Ionization device, OLED module and preparation method and electronic equipment |
| CN109689198A (en) * | 2016-01-25 | 2019-04-26 | 明尼苏达大学董事会 | Liqu id plasmas tapping equipment and the method for synthesizing biologic diesel oil for using it |
-
2007
- 2007-05-22 CN CNU2007200122146U patent/CN201042665Y/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105449117A (en) * | 2015-12-30 | 2016-03-30 | 昆山工研院新型平板显示技术中心有限公司 | Ionization device, OLED module and preparation method and electronic equipment |
| CN105449117B (en) * | 2015-12-30 | 2017-09-19 | 昆山工研院新型平板显示技术中心有限公司 | Ionization device, OLED modules and preparation method and electronic equipment |
| CN109689198A (en) * | 2016-01-25 | 2019-04-26 | 明尼苏达大学董事会 | Liqu id plasmas tapping equipment and the method for synthesizing biologic diesel oil for using it |
| CN109689198B (en) * | 2016-01-25 | 2022-03-29 | 明尼苏达大学董事会 | Liquid plasma discharge device and biodiesel synthesis method using same |
| US11679369B2 (en) | 2016-01-25 | 2023-06-20 | Regents Of The University Of Minnesota | Liquid plasma discharge device and method for biodiesel synthesis using same |
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