CN1995438A - Method for preparing elconite - Google Patents
Method for preparing elconite Download PDFInfo
- Publication number
- CN1995438A CN1995438A CN 200610136919 CN200610136919A CN1995438A CN 1995438 A CN1995438 A CN 1995438A CN 200610136919 CN200610136919 CN 200610136919 CN 200610136919 A CN200610136919 A CN 200610136919A CN 1995438 A CN1995438 A CN 1995438A
- Authority
- CN
- China
- Prior art keywords
- copper
- tungsten
- copper alloy
- powder
- pressed compact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Powder Metallurgy (AREA)
Abstract
The invention discloses a making method of high-copper elconite with copper content at 25wt%-40wt%, which comprises the following steps: blending 5wt%-20wt% copper powder with purity over 99. 5% and grain size at 15-20um and tungsten 60-75wt% powder with purity over 99% and grain size at 3-6um evenly; moulding; shaping; controlling the degree of porosity lamda within 35%+-2%; sintering; obtaining the frame of elconite; calculating cupric cemented content; placing copper powder with purity over 99. 5% and grain size below 76um and copper piece with the same size as frame surface size on the elconite frame; loading in the graphite copple; adopting alumina to fill; heating to permeate copper.
Description
Technical field
The present invention relates to the preparation of tungsten-copper composite material, particularly copper mass percentage ratio is the preparation method of the tungsten-copper alloy of 25% to 40% high copper content.
Background technology
The equally distributed neither solid solution of two-phase that tungsten-copper alloy is made up of tungsten and copper does not form a class matrix material of compound again, have the high-melting-point of tungsten, anti-galvanic corrosion, resistance fusion welding and hot strength concurrently, and the high conductivity of copper, high thermal conductivity, plasticity and workability, and copper can absorb a large amount of arc energies when evaporating under high arc temperature, reduce arc temperature, improve working conditions and reduce galvanic action.Because tungsten-copper alloy has above advantage, has obtained widespread use as electrical contact and electrode materials, and more and more has been applied to aerospace as jet pipe throat lining, electron beam target and packaged material etc., in the high-tech areas such as nuclear industry and electronic industry.
Because the fusing point of tungsten and copper differs greatly, be difficult to the disposable tungsten-copper alloy that makes high densification of normal sintering method.Relatively commonly used have hybrid system, infiltration method, nano composite powder sintering process or the like.Traditional hybrid system is mixed the tungsten powder and the copper powder of set component, reshaping and sintering, this method can prepare the tungsten-copper alloy of various composition proportion, but under the situation of not adding activator (nickel, cobalt, iron etc.), be difficult to reach fine and close, if the interpolation activator but can make the conductive performance of alloy descend greatly, do not satisfy service requirements.And traditional infiltration method is the first preparation pure tungsten skeleton copper of minute quantity (or add in the skeleton), carries out infiltration with copper liquid again, or directly immerses the copper pond and ooze copper.This method can only prepare the tungsten-copper alloy of copper content 5~25%, and W content hangs down excessively and is difficult to form stable skeleton.In addition, many the passing through of research at present prepares the method for tungsten copper nano composite powder and produces high fine and close tungsten-copper alloy aspect, also concentrate on the tungsten-copper alloy of copper content below 25%, and owing to have very high gas content and the low relatively problems of pressed density such as oxygen in the nanometer powder easily, direct sintering also is difficult to densification when causing actual production.
Summary of the invention
The object of the present invention is to provide that a kind of mass percent for preparing copper is 25%~40%, surplus is the method for the high copper content tungsten-copper alloy of tungsten, can obtain the high-compactness more than 98%, the conductive performance excellence is suitable for electrical contact and electrode materials, electronic package material, high temperature transpiring material etc.
The preparation method of the tungsten-copper alloy of the high copper content that copper mass per-cent of the present invention is 25%~40%, surplus is tungsten may further comprise the steps successively:
(1) to adopt mass percent be 5%~20% copper powder and have the tungsten powder uniform mixing 8 hours~16 hours of equal in quality per-cent with tungsten in the described tungsten-copper alloy;
(2) with compound compression molding under the pressure that is 180MPa~200Mpa, obtain pressed compact;
(3) pressed compact is placed hydrogen furnace carry out presintering, 900~1000 ℃ of sintering temperatures are incubated 0.5 hour~1 hour, obtain the tungsten-copper alloy skeleton;
(4) calculate its porosity behind the mass M by measuring pressed compact after the presintering, the volume V
And then copper amount=λ * V * ρ is oozed in calculating
Cu, ρ wherein
BaseTheoretical density, ρ for the tungsten-copper alloy identical with the pressed compact composition
CuTheoretical density for copper;
(5) will be set by step the copper sheet that copper powder is molded into and the skeleton surface is measure-alike of 1.1 times~1.2 times of amounts of (4) the copper amount of oozing calculated;
(6) copper sheet is placed above the tungsten-copper alloy skeleton and alignment, in the plumbago crucible of packing into, adopt the aluminum oxide landfill, be warming up to 1350~1400 ℃ and ooze copper, the mass percent that insulation promptly obtained copper in 1~3 hour is 25%~40%, surplus is the tungsten-copper alloy of tungsten.
Purity 〉=99.5%, the granularity of the described copper powder of step (1) is 15 μ m~20 μ m, and the purity of described tungsten powder 〉=99%, granularity are 3~6 μ m; The described pressed compact porosity of step (4) λ is controlled in 35% ± 2% the scope; Purity 〉=99.5% of the described copper powder of step (5), granularity<76um.
Description of drawings
Fig. 1 is for mass percent of the present invention is 25%, surplus is the section SEM photo of the tungsten-copper alloy of tungsten;
Fig. 2 is for mass percent of the present invention is 35%, surplus is the section SEM photo of the tungsten-copper alloy of tungsten;
Fig. 3 is for mass percent of the present invention is 40%, surplus is the section SEM photo of the tungsten-copper alloy of tungsten.
Embodiment
Embodiment 1: copper mass per-cent is 25%, surplus is the preparation of the tungsten-copper alloy of tungsten
Adopting 5wt%, purity 〉=99.5%, granularity is the copper powder of 15 μ m; with with the tungsten-copper alloy of described 25wt% copper content in tungsten have the tungsten powder of equal in quality per-cent; be that quality 75wt% and purity 99.5%, granularity are the tungsten powder of 4.2 μ m; pack in the mixing drum; and add a small amount of sintered carbide ball; mix 12 hours to mixing, shut down cooling discharging again after 1 hour.Compound compression molding under the pressure of 200Mpa (be pressed into the disk that diameter is 40mm in punching block, following examples together) places hydrogen furnace to carry out presintering the pressed compact that obtains, and 950 ℃ of sintering temperatures are incubated 1 hour, obtain the tungsten-copper alloy skeleton.After the cooling discharging, mass M=120g, the volume V=10.30cm of pressed compact after the mensuration presintering
3After, calculate its porosity
And then copper amount=λ * V * ρ is oozed in calculating
Cu=32.3g (ρ wherein
BaseBe the theoretical density of the tungsten-copper alloy identical, i.e. 17.98g/cm with the pressed compact composition
3ρ
CuBe the theoretical density of copper, i.e. 8.9g/cm
3, following examples are together).The actual copper amount of oozing adopts 1.1 times of calculated amount, i.e. 35.5g is molded into and copper sheet that the skeleton surface is measure-alike, and promptly diameter is the disk (following examples with) of 40mm, the purity of copper powder 〉=99.5% wherein, granularity 15um; Place above the tungsten-copper alloy skeleton copper sheet and alignment, in the plumbago crucible of packing into, build aluminum oxide and bury material.Then boat is pushed in the hydrogen shield stove intensification sintering.Be raised to 1400 ℃ with 3 hours from 950 ℃, be incubated 2 hours, the cooling cooling promptly obtains tungsten-copper alloy.
Product is carried out correlated performance to be detected: copper content 24.9%, in allowing content 25% ± 2% scope; Density 14.8g/cm
3, relative density 99.0%, hardness HB199, tensile strength 685MPa.As can be seen from Figure 1, form extraordinary copper mesh structure, all filled full copper around each tungsten particle, the even structure densification; Measuring its specific conductivity is 22.3MS.m
-1
Above detected result shows, what obtain is that copper mass per-cent is 25%, surplus is the tungsten-copper alloy of tungsten, and in the high copper content that guarantees 25wt%, degree of causing is close 〉=and 98%, have superior performance.
Embodiment 2: copper mass per-cent is 35%, surplus is the preparation of the tungsten-copper alloy of tungsten
Adopting 15wt%, purity 〉=99.5%, granularity is the copper powder of 18 μ m; with with the tungsten-copper alloy of described 35wt% copper content in tungsten have the tungsten powder of equal in quality per-cent; be that quality 65wt% and purity 99.5%, granularity are the tungsten powder of 3.7 μ m; pack in the mixing drum; and add a small amount of sintered carbide ball; mix 12 hours to mixing, shut down cooling discharging again after 1 hour.Compound compression molding under the pressure of 190Mpa (being pressed into the disk that diameter is 40mm in punching block) places hydrogen furnace to carry out presintering the pressed compact that obtains, and 900 ℃ of sintering temperatures are incubated 1.5 hours, obtain the tungsten-copper alloy skeleton.After the cooling discharging, behind mass M=120g, the volume V=11.59cm3 of pressed compact, calculate its porosity after the mensuration presintering
, and then copper amount=λ * V * ρ is oozed in calculating
Cu=35.7g.The actual copper amount of oozing adopts 1.1 times of calculated amount, i.e. 39.3g is molded into and copper sheet that the skeleton surface is measure-alike, and promptly diameter is the disk of 40mm, the purity of copper powder 〉=99.5% wherein, granularity 40um; Place above the tungsten-copper alloy skeleton copper sheet and alignment, in the plumbago crucible of packing into, build aluminum oxide and bury material.Then boat is pushed in the hydrogen shield stove intensification sintering.Be raised to 1380 ℃ with 3 hours from 950 ℃, be incubated 2 hours, the cooling cooling promptly obtains tungsten-copper alloy.
Product is carried out correlated performance to be detected: copper content 35.7% (in allowing content 35% ± 2% scope), density 13.5g/cm
3, relative density 99.2%, hardness HB166, tensile strength 496MPa.As can be seen from Figure 2, form extraordinary copper mesh structure, all filled full copper around each tungsten particle, the even structure densification; Measuring its specific conductivity is 27.4MS.m
-1
Above detected result shows, what obtain is that copper mass per-cent is 35%, surplus is the tungsten-copper alloy of tungsten, and in the high copper content that guarantees 35wt%, degree of causing is close 〉=and 98%, have superior performance.
Embodiment 3: copper mass per-cent is 40%, surplus is the preparation of the tungsten-copper alloy of tungsten
Adopting 20wt%, purity 〉=99.5%, granularity is the copper powder of 20 μ m; with with the tungsten-copper alloy of described 40wt% copper content in tungsten have the tungsten powder of equal in quality per-cent; be that quality 60wt% and purity 99.5%, granularity are the tungsten powder of 5.0 μ m; pack in the mixing drum; and add a small amount of sintered carbide ball; mix 16 hours to mixing, shut down cooling discharging again after 1 hour.Compound compression molding under the pressure of 180Mpa (being pressed into the disk that diameter is 40mm in punching block) places hydrogen furnace to carry out presintering the pressed compact that obtains, and 900 ℃ of sintering temperatures are incubated 1 hour, obtain the tungsten-copper alloy skeleton.After the cooling discharging, mass M=120g, the volume V=12.35cm of pressed compact after the mensuration presintering
3After, calculate its porosity
, and then copper amount=λ * V * ρ is oozed in calculating
Cu=38.4g.The actual copper amount of oozing adopts 1.1 times of calculated amount, i.e. 42.2g is molded into and copper sheet that the skeleton surface is measure-alike, and promptly diameter is the disk of 40mm, the purity of copper powder 〉=99.5% wherein, granularity 75um; Place above the tungsten-copper alloy skeleton copper sheet and alignment, in the plumbago crucible of packing into, build aluminum oxide and bury material.Then boat is pushed in the hydrogen shield stove intensification sintering.Be raised to 1350 ℃ with 3 hours from 950 ℃, be incubated 2 hours, the cooling cooling promptly obtains tungsten-copper alloy.
Product is carried out correlated performance to be detected: copper content 39.7% (in allowing content 40% ± 2% scope), density 12.77g/cm
3, relative density 99.8%, hardness HB143, tensile strength 445MPa.As can be seen from Figure 3, form extraordinary copper mesh structure, all filled full copper around each tungsten particle, the even structure densification; Measuring its specific conductivity is 27.8MS.m
-1
Above detected result shows, what obtain is that copper mass per-cent is 40%, surplus is the tungsten-copper alloy of tungsten, and in the high copper content that guarantees 40wt%, degree of causing is close 〉=and 98%, have superior performance.
Claims (4)
1, a kind of mass percent of copper is 25%~40%, surplus is the preparation method of the tungsten-copper alloy of tungsten, may further comprise the steps successively:
(1) to adopt mass percent be 5%~20% copper powder and have the tungsten powder uniform mixing 8 hours~16 hours of equal in quality per-cent with tungsten in the described tungsten-copper alloy;
(2) with compound compression molding under the pressure that is 180MPa~200Mpa, obtain pressed compact;
(3) pressed compact is placed hydrogen furnace carry out presintering, 900~1000 ℃ of sintering temperatures are incubated 0.5 hour~1 hour, obtain the tungsten-copper alloy skeleton;
(4) calculate its porosity behind the mass M by measuring pressed compact after the presintering, the volume V
And then copper amount=λ * V * ρ is oozed in calculating
Cu, ρ wherein
BaseTheoretical density, ρ for the tungsten-copper alloy identical with the pressed compact composition
CuTheoretical density for copper;
(5) will be set by step the copper sheet that (1.1~1.2) copper powder doubly is molded into and the skeleton surface is measure-alike of (4) the copper amount of oozing calculated;
(6) copper sheet is placed above the tungsten-copper alloy skeleton and alignment, in the plumbago crucible of packing into, adopt the aluminum oxide landfill, be warming up to 1350~1400 ℃ and ooze copper, the mass percent that insulation promptly obtained copper in 1~3 hour is 25%~40%, surplus is the tungsten-copper alloy of tungsten.
2, according to the preparation method of the described tungsten-copper alloy of claim 1, it is characterized in that: purity 〉=99.5%, the granularity of the described copper powder of step (1) is 15 μ m~20 μ m, and the purity of described tungsten powder 〉=99%, granularity are 3~6 μ m.
3, according to the preparation method of the described tungsten-copper alloy of claim 1, it is characterized in that: the described pressed compact porosity of step (4) λ is controlled in 35% ± 2% the scope.
4, according to the preparation method of the described tungsten-copper alloy of claim 1, it is characterized in that: purity 〉=99.5% of the described copper powder of step (5), granularity<76um.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101369199A CN100455694C (en) | 2006-12-22 | 2006-12-22 | Method for preparing elconite |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101369199A CN100455694C (en) | 2006-12-22 | 2006-12-22 | Method for preparing elconite |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1995438A true CN1995438A (en) | 2007-07-11 |
CN100455694C CN100455694C (en) | 2009-01-28 |
Family
ID=38250639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2006101369199A Active CN100455694C (en) | 2006-12-22 | 2006-12-22 | Method for preparing elconite |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100455694C (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928867A (en) * | 2010-04-09 | 2010-12-29 | 西安理工大学 | Method for preparing tungsten-copper alloy based on loose-loading infiltration method |
CN102162055A (en) * | 2011-04-08 | 2011-08-24 | 福州博力达机电有限公司 | Method for preparing a tungsten-copper composite material with high arc ablation resistance |
CN102248160A (en) * | 2011-07-07 | 2011-11-23 | 中国科学院理化技术研究所 | Tungsten/copper gradient material and preparation method thereof |
CN102433480A (en) * | 2011-12-01 | 2012-05-02 | 北京理工大学 | Tungsten-copper alloy with low skeleton connectivity and preparation method thereof |
CN102847933A (en) * | 2012-09-12 | 2013-01-02 | 江西重科机械有限公司 | High-temperature wear-resistant material adapted to lining of blast-furnace tuyere and preparation method of high-temperature wear-resistant material |
CN104152734A (en) * | 2014-06-12 | 2014-11-19 | 陕西斯瑞工业有限责任公司 | Method for preparing tungsten-copper alloy from spherical tungsten powder |
CN104213009A (en) * | 2014-08-29 | 2014-12-17 | 浙江立泰复合材料有限公司 | Method for cladding copper on surface of infiltration sintered tungsten-copper composite material |
CN104561625A (en) * | 2014-12-11 | 2015-04-29 | 陕西斯瑞工业有限责任公司 | Method for preparing copper-tungsten composite with high electric erosive resistance by virtue of microwave sintering |
CN107739862A (en) * | 2017-10-24 | 2018-02-27 | 宝鸡市铭坤有色金属有限公司 | A kind of preparation method of tungsten-copper alloy material |
CN109609792A (en) * | 2018-12-17 | 2019-04-12 | 河源市凯源硬质合金有限公司 | A method of preparing tungsten-copper alloy |
CN111485179A (en) * | 2020-04-02 | 2020-08-04 | 安庆帝伯粉末冶金有限公司 | Valve guide material, valve guide and device |
CN111863488A (en) * | 2020-07-13 | 2020-10-30 | 安徽恒均粉末冶金科技股份有限公司 | Method for preparing electric appliance switch contact by powder metallurgy copper-tungsten alloy |
CN112011711A (en) * | 2020-08-31 | 2020-12-01 | 江苏腾征新材料研究院有限公司 | Method for manufacturing novel tungsten-copper alloy material |
CN114700480A (en) * | 2022-04-25 | 2022-07-05 | 长沙升华微电子材料有限公司 | Production method for obtaining high-thermal-conductivity tungsten-copper alloy |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110172598A (en) * | 2018-12-13 | 2019-08-27 | 苏州赛特锐精密机械配件有限公司 | A kind of method of co-injection preparation bi-component tungsten-copper alloy |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1132954C (en) * | 2001-12-13 | 2003-12-31 | 北京科技大学 | Process for preparing W-Cu alloy with superfine crystal grains |
CN1600883A (en) * | 2003-09-25 | 2005-03-30 | 中国科学院金属研究所 | Tungsten-copper alloy piece in superfine crystal and preparation |
-
2006
- 2006-12-22 CN CNB2006101369199A patent/CN100455694C/en active Active
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928867A (en) * | 2010-04-09 | 2010-12-29 | 西安理工大学 | Method for preparing tungsten-copper alloy based on loose-loading infiltration method |
CN101928867B (en) * | 2010-04-09 | 2012-04-04 | 西安理工大学 | Method for preparing tungsten-copper alloy based on loose-loading infiltration method |
CN102162055A (en) * | 2011-04-08 | 2011-08-24 | 福州博力达机电有限公司 | Method for preparing a tungsten-copper composite material with high arc ablation resistance |
CN102162055B (en) * | 2011-04-08 | 2012-08-22 | 福州博力达机电有限公司 | Method for preparing a tungsten-copper composite material with high arc ablation resistance |
CN102248160A (en) * | 2011-07-07 | 2011-11-23 | 中国科学院理化技术研究所 | Tungsten/copper gradient material and preparation method thereof |
CN102248160B (en) * | 2011-07-07 | 2013-01-23 | 中国科学院理化技术研究所 | Preparation method of tungsten/copper gradient material |
CN102433480A (en) * | 2011-12-01 | 2012-05-02 | 北京理工大学 | Tungsten-copper alloy with low skeleton connectivity and preparation method thereof |
CN102847933A (en) * | 2012-09-12 | 2013-01-02 | 江西重科机械有限公司 | High-temperature wear-resistant material adapted to lining of blast-furnace tuyere and preparation method of high-temperature wear-resistant material |
CN104152734A (en) * | 2014-06-12 | 2014-11-19 | 陕西斯瑞工业有限责任公司 | Method for preparing tungsten-copper alloy from spherical tungsten powder |
CN104213009A (en) * | 2014-08-29 | 2014-12-17 | 浙江立泰复合材料有限公司 | Method for cladding copper on surface of infiltration sintered tungsten-copper composite material |
CN104561625A (en) * | 2014-12-11 | 2015-04-29 | 陕西斯瑞工业有限责任公司 | Method for preparing copper-tungsten composite with high electric erosive resistance by virtue of microwave sintering |
CN107739862A (en) * | 2017-10-24 | 2018-02-27 | 宝鸡市铭坤有色金属有限公司 | A kind of preparation method of tungsten-copper alloy material |
CN109609792A (en) * | 2018-12-17 | 2019-04-12 | 河源市凯源硬质合金有限公司 | A method of preparing tungsten-copper alloy |
CN111485179A (en) * | 2020-04-02 | 2020-08-04 | 安庆帝伯粉末冶金有限公司 | Valve guide material, valve guide and device |
CN111485179B (en) * | 2020-04-02 | 2023-12-01 | 安庆帝伯粉末冶金有限公司 | Valve guide material, valve guide and device |
CN111863488A (en) * | 2020-07-13 | 2020-10-30 | 安徽恒均粉末冶金科技股份有限公司 | Method for preparing electric appliance switch contact by powder metallurgy copper-tungsten alloy |
CN112011711A (en) * | 2020-08-31 | 2020-12-01 | 江苏腾征新材料研究院有限公司 | Method for manufacturing novel tungsten-copper alloy material |
CN114700480A (en) * | 2022-04-25 | 2022-07-05 | 长沙升华微电子材料有限公司 | Production method for obtaining high-thermal-conductivity tungsten-copper alloy |
Also Published As
Publication number | Publication date |
---|---|
CN100455694C (en) | 2009-01-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100455694C (en) | Method for preparing elconite | |
CN104711443B (en) | A kind of graphene/copper composite material and preparation method thereof | |
CN103981389B (en) | A kind of method that low-temperature sintering W skeleton prepares tungsten-copper alloy | |
CN106086567B (en) | A kind of high scandium content aluminium-scandium alloy and preparation method thereof | |
CN110157932B (en) | Preparation method of graphene modified copper-based electrical contact material based on in-situ synthesis | |
CN109338148B (en) | Graphene-copper-chromium-zirconium alloy and preparation method thereof | |
CN105603247B (en) | A kind of graphene enhancing copper rare earth base electric contact material and preparation method thereof | |
CN102162055B (en) | Method for preparing a tungsten-copper composite material with high arc ablation resistance | |
CN107557609B (en) | A kind of copper alloy and preparation method thereof of single phase nano alumina particle dispersion-strengtherning | |
CN101707146B (en) | Ag based electrical contact material and preparation method thereof | |
CN104213009A (en) | Method for cladding copper on surface of infiltration sintered tungsten-copper composite material | |
CN108149059B (en) | A kind of TiC enhances the preparation method of copper-based electric contact composite material | |
CN114525438B (en) | Tungsten copper composite material and preparation method thereof | |
CN103387422A (en) | Method for preparing silicon carbide/molybdenum disiticide composite coating on surface of carbon material | |
CN110216282A (en) | The preparation method of acid bronze alloy contact | |
CN105671401A (en) | Nanometer tungsten carbide silver contact material and manufacturing method | |
CN106319288B (en) | Be introduced directly into strengthens nickel-base composite material and its preparation method and application jointly with In-situ Synthesis TiC Particle | |
CN105624505A (en) | Metal based superhard composite and preparation method thereof | |
CN101423395B (en) | Method for preparing Ti3SiC2 material by melting infiltration sintering | |
CN101944397A (en) | Silver-based ceramic electric contact material and preparation method thereof | |
CN105018815A (en) | High-Cr-content high-pressure-resistance copper-chromium contact material and manufacturing method thereof | |
CN103553619A (en) | Titanium carbide and vanadium carbide composite material as well as production method and application thereof | |
CN103205589B (en) | Hard alloy taking Ni-Al intermetallic compound as binding phase and preparation method thereof | |
CN105543535B (en) | Al4SiC4With Cr cooperative reinforcings net/spherical copper product and preparation method | |
JP2006045596A (en) | Composite body with high thermal conductivity and low thermal expansion, and its manufacturing method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |