CN1994518A - Filter core for removing lead and mercury from drinking water and preparation method thereof - Google Patents

Filter core for removing lead and mercury from drinking water and preparation method thereof Download PDF

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Publication number
CN1994518A
CN1994518A CN 200610170661 CN200610170661A CN1994518A CN 1994518 A CN1994518 A CN 1994518A CN 200610170661 CN200610170661 CN 200610170661 CN 200610170661 A CN200610170661 A CN 200610170661A CN 1994518 A CN1994518 A CN 1994518A
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China
Prior art keywords
filter core
drinking water
mercury
powder
molecular weight
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CN 200610170661
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Chinese (zh)
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CN100464817C (en
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苟全伦
栾云堂
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Beijing Zhongke Green Hydrogen Technology Co ltd
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BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd
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Publication of CN1994518A publication Critical patent/CN1994518A/en
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Abstract

The invention relates to a filter element which can remove the lead and Hg in drinking water and relative production, wherein its production comprises that: preparing materials via formula, mixing and putting into mould; sintering at high temperature, drying to normal temperature, removing mould, to obtain the porous filter element. The invention can effectively remove lead and Hg at 73-96%.

Description

A kind of filter core of removing Pb in Drinking Water and mercury and preparation method thereof
Technical field
The present invention relates to a kind of filter core, particularly relate to a kind of filter core of removing Pb in Drinking Water and mercury and preparation method thereof.
Background technology
Plumbous and mercury is to human body and the very harmful extremely toxic substance of animal.Modern industry and communications develop rapidly, and the thing followed is the discharging wantonly of a large amount of dirts and waste gas.Lead is mainly derived from automobile exhaust gas and industrial emissions, and family's Corrosion of Pipeline also causes the drinking water lead tolerance to increase easily.After lead enters human body, but major part accumulate in people's bone, infringement bone hemopoietic system and nervous system, clinical manifestation is anaemia, peripheral neuritis, motion and cacesthesia occur.Mercury (Hg) and compound thereof belong to extremely toxic substance, can accumulate in vivo.Mercury in the water body is mainly derived from industrial wastewaters such as precious metal smelting, instrument and meter manufacturing, salt electrolysis, chemical industry, agricultural chemicals, plastics.Mercury mainly shows as headache, dizziness, extremity numbness and pain etc. to the harm of human body in the water body, and severe patient is understood injured brain tissue even impelled death.
At present, industrially mainly remove mercury in the waste water by chemical precipitation method and ion-exchange.But, adopt the one-level treatment process to be difficult to reach emission request, and operating cost is very high.Water treatment effect is relevant with multiple factor, often several method is combined in the actual engineering, thereby reaches cost-effective removal of mercury purpose.As adopt chemical precipitation method to handle as the one-level of mercury-containing waste water, and remove most of mercury ion, adopt flocculation sediment and filtration method that mercury-containing waste water is carried out the secondary advanced treating.This method complex process, the processing cost height is not suitable for household drinking water and handles.And plumbous removal method exists similar difficulty and problem equally.
Summary of the invention
The present invention provides a kind of drink water purifying that is used in order to address the above problem, and improves water quality, especially can effectively remove the filter core of plumbous and mercury, is highly suitable for being subjected to lead, the serious water source of mercury pollution.
An object of the present invention is to provide a kind of filter core of removing Pb in Drinking Water and mercury.
Another object of the present invention provides the preparation method of the filter core of described removal Pb in Drinking Water and mercury.
The objective of the invention is to be achieved through the following technical solutions:
A kind of filter core of removing Pb in Drinking Water and mercury, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-300 of activated carbon powder 50-200 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 5-50 gas generation agent 10-200
Preferably, a kind of filter core of removing Pb in Drinking Water and mercury, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 130-200 of activated carbon powder 90-150 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 15-35 gas generation agent 20-150
More preferably, a kind of filter core of removing Pb in Drinking Water and mercury, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150 of activated carbon powder 100 150 ten thousand-7,000,000 molecular weight
4A molecular sieve powder 30 gas generation agents 20
Activated carbon powder described in the present invention is the medicinal active powdered carbon, has the effect of efficient absorption chemical fertilizer, residues of pesticides, heterochromatic peculiar smell, chlorine and heavy metals such as lead and mercury, and its order number is the 40-200 order.
Polyethylene powder described in the present invention has the effect of powerful static dynamic absorption, can capture trickle, superfine particle that microfiltration can not filtration resistance, and its order number is the 20-200 order, and molecular weight is 1,500,000-7,000,000, and preferred, molecular weight is 2,500,000-4,000,000.
4A molecular sieve powder described in the present invention also has very strong suction-operated to heavy metal lead, mercury.
Gas generation agent described in the present invention is food-grade carbonic hydroammonium, Celogen Az, oxalic acid, can play pore-creating and make the effect in chamber, and is preferred, food-grade carbonic hydroammonium.
A kind of preparation method who removes the filter core of Pb in Drinking Water and mercury of the present invention, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through sinter molding, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness, height of porous.In use, this naked filter core liner two-layer nonwoven, the outsourcing two-layer nonwoven wraps polypropylene porous net at skin again, and bonding the going up in filter core two ends connects end cap, is positioned over stainless steel or plastic casing, gets final product.
Sintering temperature is at 200-300 ℃ among the preparation method of a kind of filter core of removing Pb in Drinking Water and mercury of the present invention, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
A kind of filter core of removing Pb in Drinking Water and mercury of the present invention has in purifying drinking water, exempts exceed standard lead and the mercury effect that generation endangers to human body in the drinking water, is fit to very much the home terminal drinking water treatment.After testing, this filter core to the clearance of Pb in Drinking Water and mercury between 73%-96%.
The specific embodiment
Following examples are in order further to describe the present invention for example, rather than limit the present invention by any way.
Embodiment 1
Medicinal active powdered carbon (160 order) 100g
The polyethylene powder of 4,000,000 molecular weight (120 order) 150g
4A molecular sieve powder 30g
Food-grade carbonic hydroammonium 20g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 250 ℃ of following sintering after 150 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 2
Medicinal active powdered carbon (100 order) 50g
The polyethylene powder of 5,000,000 molecular weight (40 order) 100g
4A molecular sieve powder 40g
Food-grade carbonic hydroammonium 150g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 260 ℃ of following sintering after 130 minutes, the demoulding after 45 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 3
Medicinal active powdered carbon (60 order) 180g
The polyethylene powder of 2,500,000 molecular weight (180 order) 100g
4A molecular sieve powder 20g
Celogen Az 60g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 230 ℃ of following sintering after 160 minutes, the demoulding after 50 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 4
Medicinal active powdered carbon (120 order) 80g
The polyethylene powder of 3,000,000 molecular weight (120 order) 250g
4A molecular sieve powder 10g
Oxalic acid 40g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 220 ℃ of following sintering after 120 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Below remove the effect of the filter core of plumbous and mercury in the drinking-water by the survey report explanation embodiment of the invention 1 a kind of;
Institute for Environment Hygiene and Health Related Product Safety, China CDC
Survey report
Sample is accepted numbering: the 2005KF0896 date: on December 9th, 2005
The sample title The filter core of the embodiment of the invention 1Kind of inspection Entrust
Interventions Requested The filter element filtering performance testDate of manufacture In September, 2005
Be subjected to the sample date On November 28th, 2005Inspected the date On December 8th, 2005
Assay:
According to " Drinking Water water quality treater safe and sanitary and functional evaluation scope _ general water quality treater " (2001), the structure filtering element (cartridge) of the embodiment of the invention 1 is carried out the filter element filtering performance test.At specified aquifer yield 2.00m 3In, running water is with flow 1.00L/min this filtering element (cartridge) 0m that flows through 3, 0.50m 3, 1.00m 3, 1.50m 3, 2.00m 3The time, this filter core sees Table 1-5 to clearance plumbous, mercury
Water examination result (0m before and after the filter core of table 1 embodiment of the invention 1 filters 3)
The mensuration project Unit The former water of mark-on Filter the back water outlet Clearance (%) Clearance requires (%)
Plumbous mercury mg/L mg/L 0.0385 0.0075 <0.0005 <0.0002 99.4 98.7 / /
Water examination result (0.50m before and after the filter core of table 2 embodiment of the invention 1 filters 3)
The mensuration project Unit The former water of mark-on Filter the back water outlet Clearance (%) Clearance requires (%)
Plumbous mercury mg/L mg/L 0.0090 0.0078 <0.0015 <0.0002 83.3 98.7 / /
Water examination result (1.00m before and after the filter core of table 3 embodiment of the invention 1 filters 3)
The mensuration project Unit The former water of mark-on Filter the back water outlet Clearance (%) Clearance requires (%)
Plumbous mercury mg/L mg/L 0.0086 0.0077 <0.0023 <0.0002 73.3 98.7 / /
Water examination result (1.50m before and after the filter core of table 4 embodiment of the invention 1 filters 3)
The mensuration project Unit The former water of mark-on Filter the back water outlet Clearance (%) Clearance requires (%)
Plumbous mercury mg/L mg/L 0.0073 0.0078 <0.0007 <0.0002 90.4 98.7 / /
Water examination result (2.00m before and after the filter core of table 5 embodiment of the invention 1 filters 3)
The mensuration project Unit The former water of mark-on Filter the back water outlet Clearance (%) Clearance requires (%)
Plumbous mercury mg/L mg/L 0.0385 0.0075 <0.0005 <0.0002 96.2 98.8 / /

Claims (8)

1. filter core of removing Pb in Drinking Water and mercury, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-300 of activated carbon powder 50-200 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 5-50 gas generation agent 10-200
2. a kind of filter core of removing Pb in Drinking Water and mercury according to claim 1, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 130-200 of activated carbon powder 90-150 1,500,000-7,000,000 molecular weight
4A molecular sieve powder 15-35 gas generation agent 20-150
3. a kind of filter core of removing Pb in Drinking Water and mercury according to claim 2, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150 of activated carbon powder 100 150 ten thousand-7,000,000 molecular weight
4A molecular sieve powder 30 gas generation agents 20
4. a kind of filter core of removing Pb in Drinking Water and mercury according to claim 1, wherein said activated carbon powder is the medicinal active powdered carbon, its order number is the 40-200 order.
5. a kind of filter core of removing Pb in Drinking Water and mercury according to claim 4, the polyethylene powder of wherein said 1,500,000-7,000,000 molecular weight, molecular weight are 2,500,000-4,000,000, its order number is the 20-200 order.
6. a kind of filter core of removing Pb in Drinking Water and mercury according to claim 5, wherein said gas generation agent are food-grade carbonic hydroammonium or Celogen Az or oxalic acid.
7. a kind of preparation method who removes the filter core of Pb in Drinking Water and mercury according to claim 1, it may further comprise the steps:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through sinter molding, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness and height of porous.
8. a kind of preparation method who removes the filter core of Pb in Drinking Water and mercury according to claim 7, wherein said sintering temperature is at 200-300 ℃, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
CNB2006101706614A 2006-12-27 2006-12-27 Filter core for removing lead and mercury from drinking water and preparation method thereof Active CN100464817C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020337A (en) * 2009-09-17 2011-04-20 北京久和开源营养科技有限公司 Water purifying filter element and preparation method thereof
CN101569856B (en) * 2008-04-30 2011-06-01 周奇迪 Filtering medium for removing metallic lead in water and preparation method thereof
CN102294151A (en) * 2011-06-29 2011-12-28 无锡光旭新材料科技有限公司 Biomass filtering material
CN101569855B (en) * 2008-04-30 2012-01-04 奇迪电器集团有限公司 Filtering medium for removing perchlorate in water and preparation method thereof
CN102698505A (en) * 2012-05-23 2012-10-03 北京佳康尔水处理技术有限公司 Method for preparing 13x molecular sieve filtering element for purifying drinking water
CN101898117B (en) * 2009-05-25 2013-01-02 奇迪电器集团有限公司 Filter medium, preparation method thereof, filter element, water purifying plant and water dispenser
CN104028042A (en) * 2014-05-19 2014-09-10 梁晓 Filtering medium for removing mercury in water and preparation method thereof
CN104083944A (en) * 2014-06-24 2014-10-08 潘峰 Filtering medium for removing lead from drinking water, filter core and preparation method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055869C (en) * 1997-12-12 2000-08-30 马昆 Structural filter element for purifying water and preparing process thereof
US20060000763A1 (en) * 2004-06-30 2006-01-05 Rinker Edward B Gravity flow carbon block filter
CN1329114C (en) * 2004-12-24 2007-08-01 上海化工研究院 Formulation of dry filter core for refrigerating system

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101569856B (en) * 2008-04-30 2011-06-01 周奇迪 Filtering medium for removing metallic lead in water and preparation method thereof
CN101569855B (en) * 2008-04-30 2012-01-04 奇迪电器集团有限公司 Filtering medium for removing perchlorate in water and preparation method thereof
CN101898117B (en) * 2009-05-25 2013-01-02 奇迪电器集团有限公司 Filter medium, preparation method thereof, filter element, water purifying plant and water dispenser
CN102020337A (en) * 2009-09-17 2011-04-20 北京久和开源营养科技有限公司 Water purifying filter element and preparation method thereof
CN102294151A (en) * 2011-06-29 2011-12-28 无锡光旭新材料科技有限公司 Biomass filtering material
CN102294151B (en) * 2011-06-29 2013-06-12 无锡光旭新材料科技有限公司 Biomass filtering material
CN102698505A (en) * 2012-05-23 2012-10-03 北京佳康尔水处理技术有限公司 Method for preparing 13x molecular sieve filtering element for purifying drinking water
CN102698505B (en) * 2012-05-23 2015-08-26 北京佳康尔水处理技术有限公司 A kind of preparation method of 13x molecular sieve filter element of purifying drinking water
CN104028042A (en) * 2014-05-19 2014-09-10 梁晓 Filtering medium for removing mercury in water and preparation method thereof
CN104028042B (en) * 2014-05-19 2016-01-27 广西北流桂丰源农业科技有限公司 A kind of filter medium for removing mercury in water and preparation method thereof
CN104083944A (en) * 2014-06-24 2014-10-08 潘峰 Filtering medium for removing lead from drinking water, filter core and preparation method
CN104083944B (en) * 2014-06-24 2016-01-13 潘峰 For removing the filter medium of Pb in Drinking Water, filter core and preparation method

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Address after: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee after: Beijing Zhongke Green Hydrogen Technology Co.,Ltd.

Country or region after: China

Address before: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee before: Beijing Genecare Water Treatment Technology Co.,Ltd.

Country or region before: China

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