CN100464816C - Filter core for removing nitrite-nitrogen from drinking water and method for preparing same - Google Patents

Filter core for removing nitrite-nitrogen from drinking water and method for preparing same Download PDF

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Publication number
CN100464816C
CN100464816C CNB2006101673606A CN200610167360A CN100464816C CN 100464816 C CN100464816 C CN 100464816C CN B2006101673606 A CNB2006101673606 A CN B2006101673606A CN 200610167360 A CN200610167360 A CN 200610167360A CN 100464816 C CN100464816 C CN 100464816C
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filter core
drinking water
nitrite nitrogen
powder
water according
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CN1994515A (en
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苟全伦
栾云堂
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Beijing Zhongke Green Hydrogen Technology Co ltd
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BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd
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Abstract

The invention relates to a filter element which can remove the nitrite nitrogen of drinking water, and relative production, wherein it can effectively remove nitrite nitrogen and purify drinking water, to protect people.

Description

A kind of filter core of removing nitrite nitrogen in the drinking water and preparation method thereof
Technical field
The present invention relates to a kind of filter core, particularly relate to a kind of filter core of removing nitrite nitrogen in the drinking water and preparation method thereof.
Background technology
Nitrite nitrogen extensively is present in occurring in nature as a kind of environmental contaminants, especially in vaporous water, surface water and the underground water.The pollution source of nitrite nitrogen is a lot of in the environment, as artificial chemical fertilizer; Sanitary sewage, house refuse; Factories such as food, fuel, oil refining discharge a large amount of ammonia discarded objects that contain and enter in the environment through all forming nitrite nitrogen after biological, the chemical conversion; Burning petroleum class A fuel A, coal, natural gases such as automobile, train, steamer, aircraft, boiler, domestic burners produce a large amount of nitrogen oxide and can form nitrate nitrogen drop in ground and the water body behind the precipitation leaching.Nitrite nitrogen can make the people directly poison, nitrite nitrogen and blood of human body effect, form ferrihemoglobin, thereby make blood lose function of carrying oxygen, people's anoxic is poisoned, the lighter's giddy, palpitaition, vomiting, cyanotic lips, are twitched, are short of breath at weight person's obnubilation, but rescue untimely threat to life.Moreover, nitrite nitrogen forms nitrosamines with the effect of secondary amine class inside and outside human body, and it is carcinogenic, teratogenesis, mutagenic material when reaching doses in human body, but the serious harm health.
Traditional nitrite nitrogen removal method mainly contains ion-exchange and membrane separation process.Though these two kinds of methods can be handled, and still have many deficiencies: the disposal cost height, the water rate of recovery is low, as only be 30%-60%.And the water that adopts these two kinds of methods to handle generally all needs preliminary treatment and last handling process, is not easy to promote in family's water purifier.
Summary of the invention
The present invention provides a kind of drink water purifying that is used in order to address the above problem, and improves water quality, especially can effectively remove the filter core of nitrite nitrogen in the drinking water, prevents that effectively nitrite nitrogen from working the mischief to human body, the protection health.
An object of the present invention is to provide a kind of filter core of removing nitrite nitrogen in the drinking water.
Another object of the present invention provides the preparation method of the filter core of nitrite nitrogen in the described removal drinking water.
The objective of the invention is to be achieved through the following technical solutions:
A kind of filter core of removing nitrite nitrogen in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-200 of activated carbon powder 10-150 1,500,000-7,000,000 molecular weight
Atlapulgite powder 10-100 triiodide resin 100-300
Gas generation agent 20-100
Preferably, a kind of filter core of removing nitrite nitrogen in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 120-180 of activated carbon powder 50-100 1,500,000-7,000,000 molecular weight
Atlapulgite powder 30-80 triiodide resin 160-250
Gas generation agent 30-70
More preferably, a kind of filter core of removing nitrite nitrogen in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150 of activated carbon powder 70 150 ten thousand-7,000,000 molecular weight
Atlapulgite powder 30 triiodide resins 200
Gas generation agent 40
Activated carbon powder described in the present invention is the medicinal active powdered carbon, has the effect of efficient absorption chemical fertilizer, residues of pesticides, heterochromatic peculiar smell, chlorine and heavy metals such as lead and mercury, and its order number is the 60-180 order.
Polyethylene powder described in the present invention has the effect of powerful static dynamic absorption, can capture trickle, superfine particle that microfiltration can not filtration resistance, and its order number is the 20-200 order, and molecular weight is 1,500,000-7,000,000, and preferred, molecular weight is 2,500,000-4,000,000.
Atlapulgite powder described in the present invention has the effect of removing nitrite nitrogen, and its order number is the 100-300 order.
Triiodide resin described in the present invention can effectively be removed the nitrite nitrogen in the drinking water.
Gas generation agent described in the present invention is food-grade carbonic hydroammonium, Celogen Az, oxalic acid, can play pore-creating and make the effect in chamber, and is preferred, food-grade carbonic hydroammonium.
A kind of preparation method who removes the filter core of nitrite nitrogen in the drinking water of the present invention, it may further comprise the steps;
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, at high temperature through sinter molding, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness, height of porous;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again, in the process of handling water, run off to prevent triiodide resin; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.During use, with filter core one end that is stained with porose end cap up, be positioned in stainless steel or the plastic casing, the filter core external-compression type used with the water source.
Sintering temperature is at 200-300 ℃ among a kind of preparation method who removes the filter core of nitrite nitrogen in the drinking water of the present invention, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
Of the present inventionly a kind ofly remove that the filter core of nitrite nitrogen has in purifying drinking water in the drinking water, can effectively remove nitrite nitrogen in the drinking water, effectively prevent the harm that nitrite nitrogen causes human body, the protection health.
The specific embodiment
Following examples are in order further to describe the present invention for example, rather than limit the present invention by any way.
Embodiment 1
Medicinal active powdered carbon (100 order) 70g triiodide resin 200g
Atlapulgite powder (250 order) 30g food-grade carbonic hydroammonium 40g
The polyethylene powder of 4,000,000 molecular weight (100 order) 150g
Its preparation method is as follows:
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, at 250 ℃ of following sintering after 150 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.
Embodiment 2
Medicinal active powdered carbon (150 order) 150g triiodide resin 100g
Atlapulgite powder (150 order) 20g food-grade carbonic hydroammonium 20g
The polyethylene powder of 5,000,000 molecular weight (200 order) 180g
Its preparation method is as follows:
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, at 260 ℃ of following sintering after 130 minutes, the demoulding after 45 ℃ of drying in the air.Promptly become the tubular structure filter core of porous;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.
Embodiment 3
Medicinal active powdered carbon (80 order) 100g triiodide resin 150g
Atlapulgite powder (120 order) 80g food-grade carbonic hydroammonium 30g
The polyethylene powder of 3,000,000 molecular weight (50 order) 110g
Its preparation method is as follows:
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, at 230 ℃ of following sintering after 160 minutes, the demoulding after 50 ℃ of drying in the air.Promptly become the tubular structure filter core of porous;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.
Embodiment 4
Medicinal active powdered carbon (160 order) 30g triiodide resin 250g
Atlapulgite powder (200 order) 50g food-grade carbonic hydroammonium 90g
The polyethylene powder of 3,500,000 molecular weight (150 order) 160g
Its preparation method is as follows:
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, at 280 ℃ of following sintering after 120 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.
Below a kind of effect of removing the filter core of nitrite nitrogen in the drinking-water by the survey report explanation embodiment of the invention 1;
Institute for Environment Hygiene and Health Related Product Safety, China CDC
Survey report
Sample is accepted numbering: the 2005KF0896 date: on December 9th, 2005
The sample title The filter core of the embodiment of the invention 1Kind of inspection Entrust
Interventions Requested The filter element filtering performance testDate of manufacture In September, 2005
Be subjected to the sample date On November 28th, 2005Inspected the date On December 8th, 2005
Assay:
According to " Drinking Water water quality treater safe and sanitary and functional evaluation scope _ general water quality treater " (2001), the structure filtering element (cartridge) of the embodiment of the invention 1 is carried out the filter element filtering performance test.At specified aquifer yield 2.00m 3In, running water is with flow 1.00L/min this filtering element (cartridge) 0m that flows through 3, 0.50m 3, 1.00m 3, 1.50m 3, 2.00m 3The time, this filter core sees Table 1-5 to the clearance of nitrite nitrogen
Water examination result (0m before and after the filter core of table 1 embodiment of the invention 1 filters 3)
Go out water removal rate (%) clearance behind the mensuration project unit mark-on raw water filtration and require (%)
Nitrite nitrogen mg/L 0.182 0.001 99.5/
Water examination result (0.50m before and after the filter core of table 2 embodiment of the invention 1 filters 3)
Go out water removal rate (%) clearance behind the mensuration project unit mark-on raw water filtration and require (%)
Nitrite nitrogen mg/L 0.151<0.001 99.7/
Water examination result (1.00m before and after the filter core of table 3 embodiment of the invention 1 filters 3)
Go out water removal rate (%) clearance behind the mensuration project unit mark-on raw water filtration and require (%)
Nitrite nitrogen mg/L 0.142 0.002 98.6/
Water examination result (1.50m before and after the filter core of table 4 embodiment of the invention 1 filters 3)
Go out water removal rate (%) clearance behind the mensuration project unit mark-on raw water filtration and require (%)
Nitrite nitrogen mg/L 0.177<0.001 99.7/
Water examination result (2.00m before and after the filter core of table 5 embodiment of the invention 1 filters 3)
Go out water removal rate (%) clearance behind the mensuration project unit mark-on raw water filtration and require (%)
Nitrite nitrogen mg/L 0.150<0.001 99.7/

Claims (9)

1. filter core of removing nitrite nitrogen in the drinking water, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-200 of activated carbon powder 10-150 1,500,000-7,000,000 molecular weight
Atlapulgite powder 10-100 triiodide resin 100-300
Gas generation agent 20-100.
2. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 1, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 120-180 of activated carbon powder 50-100 1,500,000-7,000,000 molecular weight
Atlapulgite powder 30-80 triiodide resin 160-250
Gas generation agent 30-70.
3. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 2, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150 of activated carbon powder 70 150 ten thousand-7,000,000 molecular weight
Atlapulgite powder 30 triiodide resins 200
Gas generation agent 40.
4. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 1, wherein said activated carbon powder is the medicinal active powdered carbon, its order number is the 60-180 order.
5. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 4, the polyethylene powder of wherein said 1,500,000-7,000,000 molecular weight, molecular weight are 2,500,000-4,000,000, its order number is the 20-200 order.
6. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 5, wherein said gas generation agent are food-grade carbonic hydroammonium or Celogen Az or oxalic acid.
7. a kind of filter core of removing nitrite nitrogen in the drinking water according to claim 6, the order number of wherein said atlapulgite powder is the 100-300 order.
8. the described a kind of preparation method who removes the filter core of nitrite nitrogen in the drinking water of claim 1, it may further comprise the steps;
A, take by weighing each raw material by formula ratio, earlier that triiodide resin is standby, after all the other each raw material mixing and stirring, insert in the tubular die, through sinter molding, the demoulding after 40-60 ℃ of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness and height of porous under 200-300 ℃;
B, this naked filter core endoporus lining two-layer nonwoven, the skin nonwoven of double-baging, wrap polypropylene porous net at skin again, the end cap of atresia on filter core one end is bonding then, keep flat the permeable nonwoven of one deck in again from the filter core other end toward endoporus, then in endoporus, insert the triiodide resin of A step, on triiodide resin, keep flat the permeable nonwoven of one deck again; At last at the filter core bonding end cap that centre bore is arranged of an end of cohesive end lid not.
9. a kind of preparation method who removes the filter core of nitrite nitrogen in the drinking water according to claim 8, wherein said sintering time is 120-160 minute.
CNB2006101673606A 2006-12-29 2006-12-29 Filter core for removing nitrite-nitrogen from drinking water and method for preparing same Active CN100464816C (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102698509A (en) * 2012-06-20 2012-10-03 福州大学 Inorganic gelatinous active carbon filter core and preparation method thereof

Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
CN102527155A (en) * 2011-10-20 2012-07-04 常州亚环环保科技有限公司 Structural filter element for removing acraldehyde from drinking water and preparation method of structural filter element
CN103463869B (en) * 2013-06-20 2015-08-19 天长市天乐电器厂 A kind of Straw powder filter element and preparation method thereof
CN106673110B (en) * 2017-01-10 2021-10-12 北京佳康尔水处理技术有限公司 Filter element for purifying water, manufacturing method thereof and water dispenser

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CN1075975C (en) * 1999-05-21 2001-12-12 徐祝平 Technology for producing filter element cup
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Publication number Priority date Publication date Assignee Title
CN102698509A (en) * 2012-06-20 2012-10-03 福州大学 Inorganic gelatinous active carbon filter core and preparation method thereof

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Address after: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee after: Beijing Zhongke Green Hydrogen Technology Co.,Ltd.

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Address before: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee before: Beijing Genecare Water Treatment Technology Co.,Ltd.

Country or region before: China